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By Zizheng Zhou

The separation of cobalt from other base metals can be achieved using diffusion dialysis in a two-compartment reactor separated by an anion exchange membrane. In this work, a Neosepta AFX membrane was used to study the separation of various metals in an acid-chloride solution. The separation of one metal from another was investigated on the basis of the various chloro-complex stabilities. The metals investigated included cobalt, nickel, copper(II), iron(III), aluminum, zinc and cadmium. The impact of several critical experimental conditions, including the initial metal and chloride concentration in the feed solution and their initial concentration in the receiving solution, on the separation factor and the metal transfer rate is reported in this work. Effective separation of different metal pairs was achieved under the experimental conditions.

By Juan Patricio Ibáñez

Separation of arsenic and copper from Cu-As-H2S04 electrolytes by electrodialysis has been investigated at room temperature. The effects of current density and pH were studied. An arsenic-free copper solution was obtained for all the tested conditions. The transport efficiency for copper ions was found to be higher than 98% after 3 hours' test. Transport of arsenic and copper through the ion exchange membranes was increased by increasing pH and current density. Solution pH was found to be a key parameter for the separation process, since it controls the speciation of the ions to be transported and the formation of unwanted precipitates which reduce the global efficiency of the electrodialysis process. The main conclusion is that electrodialysis is a promising technique to be used in separating and/or concentrating ions of interest in copper electrometallurgy.

Jan 1, 2003

By Soner Top

In this study, a process to separate manganese and iron from manganiferous iron ores by reductive acid leaching followed by magnetic separation was conceived and experimentally tested. In the leaching process, sulfuric acid was used as lixiviant and oxalic acid was used as reductant. The experimental results showed that the manganese and iron separation was optimal when the concentrations of the sulfuric acid and oxalic acid were 0.75 M and 30 g/L, respectively, at a temperature of 80 °C, a solid/liquid ratio of 67 g/L, stirring speed of 400 rpm and leaching duration of 60 min. Under these conditions, 90.49 percent and 6.78 percent of Mn and Fe were dissolved, respectively, from the ore sample in a size fraction of smaller than 106 µm. It was determined that the leaching of manganese from the ores was a second-order reaction with activation energy, Ea, of 53.38 kJ/mol. The leaching residues obtained under the optimal conditions were subjected to wet high-intensity magnetic separation tests to recover the remaining iron content. This separation process produced a concentrate containing 56.20 percent Fe and 1.79 percent Mn with iron and manganese recoveries of 56.83 and 66.73 percent, respectively. To the best of our knowledge, this is the first time that a magnetic separation process was used on a residue obtained from the reductive acid leaching of manganiferous iron ores to recover iron.

By J M. Menacho, L Zhang, A Hoadley, L Verdugo, B Etschmann, W Bruckard

Since the introduction of Lithium-Ion Batteries (LIBs) in 1991, the market for lithium-ion cells has been driven by the high demand for portable electronic devices and more recently for batteries for the electric car industry. It is expected to grow rapidly to reach 2600 GWh globally by 2030 (US Government, Office of Energy Efficiency and Renewable Energy, 2021). However, there is a desperate need to recycle LIBs to recover valuable cathode materials and graphite. For this reason, several physical and chemical recycling technologies have been proposed to recover these materials from spent batteries. Amongst these, froth flotation technology is a potential cost-effective technology for separation of the graphite fraction from the lithium oxide components due to the natural hydrophobicity of graphite and density difference between graphite and cathode materials (Folayan et al, 2021).

Aug 24, 2022

By S. Kelebek

Efficient separation of minerals is the essence of mineral processing. Separation of hexagonal pyrrhotite in processing of Ni-Cu sulphide ores was investigated together with particle size effects with respect to selective flotation recovery of pentlandite and nickel. The recovery by size response was compared for sodium metabisulphite (SMBS), triethylenetetramine (TETA) and their combinations with amyl xanthate as a collector. The pyrrhotite recovery for all sizes was lower than that of pentlandite for the blank case as well as individual cases with SMBS and TETA. For pyrrhotite, the recovery by size relations in the case of individual uses of reagents were mainly determined by recovery losses at coarser size range (>74 um), which occurs at a coarser size for pentlandite (>212 um). The combined use of SMBS and TETA, and the associated synergistic effect very significantly knocked down the pyrrhotite recovery to less than 7% that was a maximum for the –10 um (attributable to hydraulic entrainment). High recovery of pentlandite in a wide range of intermediate sizes and drastically low recovery of pyrrhotite resulted in a very efficient separation of pentlandite from pyrrhotite in all sizes. Separation of this mineral is discussed in relation to fundamental functionality of the reagents used.

Jan 1, 2017

Spent automobile catalyst is an important secondary resource of PGMs (platinum group metals) and the recovery is significant. Various methods of recovery technology have been reported and applied in practical production, including pyro- and hydrometallurgical processes. Since the grade of PGMs in the catalysts is so low, approximately 0.5 wt. %, the present recycling technologies require high energy-consumption, it is of great significance to enrich the PGMs with some energy saving physical separation methods as a pretreatment. Automobile catalyst is usually composed of cordierite phase as a substrate and alumina phase, with PGMs, which covers the cordierite phase. We adopted the quenching pretreatment, one method of thermal shock, to generate micro-cracks between the two phases and separate the alumina phase from cordierite. Quenching was carried out by heating the catalysts in an electric furnace of different temperatures followed by rapid soaking into cold water. It was found that the phase boundary between alumina and cordierite was broken in the quenching and selective separation (detachment) of alumina from the cordierite could be achieved in the following surface grinding. The effect of quenching was checked by microscopic observation, hardness measurement, and chemical analysis. This paper figures out the stress formula of the quenching process, which is largely connected with layer thickness and temperature gradient by using an FEM (Finite Element Method) simulation and clarifies the mechanism of crack generation in the quenching process. Keywords: automobile catalyst, PGM, quenching process, FEM

Sep 1, 2012

By D E. G Connelly, K Y. Wong

Gold at the Harbour Lights Mine (HLM), WA occurs principally in pyrite (Py) and arsenopyrite (AsPy) minerals rendering it inaccessible to direct cyanidation. Froth flotation produces a concentrate with low mass recovery and with high recoveries of sulfides. After investigating several alternatives, a novel flotation process has been developed to separate the concentrate into pyrite and arsenopyrite rich fractions. The pyrite fraction is finely ground and cyanide leached, while the arsenopyrite is treated off-site. This paper describes the separation process from laboratory bench scale through to commercial operation at the HLM gold plant.

Jan 1, 2005

By B. Mishra

The application of various bydrometallurgical, pyrometallurgical and electrochemical processes in the extraction, purification and production of radioactive metals as well as the use of various materials, eg. metals and alloys, ceramics, polymers, etc. in the process, construction and handling equipment in the nuclear industry has generated a large stockpile of radioactively contaminated waste material and scrap metal which can not be directly discarded, recycled or considered for long-term storage due to its volume and potential hazards, without the separation of radionuclides. This paper reviews the emerging methods that have been 'investigated and suggested for dealing with some of these wastes' and scrap material. The separation technologies studied for the recovery of radioactive components from the pyrometallurgical and electrochemical processing wastes have been discussed in details with results from some of the recent theoretical and physical modeling work as well as the data obtained? from the actual waste treatment. Specific processes shall be described in terms of its advantages and limitations. These emerging separation technologies are being considered by the US Department of Energy as alternatives for dealing with the issues of environmental management [EMI' and decontamination and decommissioning [D&D].

Jan 1, 1996

By B. Mishra, W. A. Averill

"The application of various hydrometallurgical, pyrometallurgical and electrochemical processes in the extraction, purification and production of radioactive metals as well as the use of various materials, ego metals and alloys, ceramics, polymers, etc. in the process, construction and handling equipment in the nuclear industry has generated a large stockpile of radioactively contaminated waste material and scrap metal which can not be directly discarded, recycled or considered for long-term storage due to its volume and potential hazards, without the separation of radionuclides. This paper reviews the emerging methods that have been investigated and suggested for dealing with some of these wastes and scrap material.The separation technologies studied for the recovery of radioactive components from the pyrometallurgical and electrochemical processing wastes have been discussed in details with results from some of the recent theoretical and physical modeling work as well as the data obtained from the actual waste treatment. Specific processes shall be described in terms of its advantages and limitations. These emerging separation technologies are being considered by the US Department of Energy as alternatives for dealing with the issues of environmental management [EM] and decontamination and decommissioning [D&D].IntroductionThe high temperature carbothermic or metallothermic smelting reduction methods for metal production are associated with the generation of significant quantity of waste as slags, flue dusts, sludges, residues, effluent salts etc. Certain hydrometallurgical processes also generate lots of aqueous waste due to the inherent nature of the technique. Also, the gas-based reduction processes are not applicable to many stable metal compounds, such as alumina, titania, beryllia, lanthanide and actinide oxides, etc. due to thermodynamic considerations. All these methods cause substantial environmental hazard. There is a need to develop alternative processes which have low waste or ideally a ""zero-waste"" generation.Pyrochemical processes using molten salts provide a unique opportunity for the extraction and refining of many reactive and valuable metals either directly from the beneficiated ore (aluminum, beryllium, neodymium, plutonium, uranium, etc.) or from other process effluent that contain reactive metal compounds. The processes reduce metal compounds electrolytically (A12O 3 and BeCI2) on a carbon anode or by calciothermic reduction (Po, Nd). The by-product, in the latter case, is a calcium oxide saturated halide salt. The waste-treatment to recycle the halide has to be done as a separate step or stored as a contaminated waste. A successful separation technology can provide a new insight to the waste minimization strategy for the nuclear industry."

Jan 1, 1996

By M. J. Collins

A hydrometallurgical process has been tested at the Sherritt Research Centre for separation of zinc, lead, copper and precious metal values from the zinc oxide fume leach residue stockpiled at the HBM&S operations in Flin Flon, Manitoba. Zinc is found primarily as zinc femte and sphalerite in the residue, lead as lead sulphate and jarosite, and copper as sulphide and jarositic compounds. Gypsum and siliceous gangue are significant diluents. The separation process includes hot acid, atmospheric and reducing (sulphur dioxide) leaching; zinc, copper and lead flotation; and atmospheric iron removal steps. Zinc is recovered to a high strength zinc sulphate solution and to a zinc sulphide concentrate suitable for feed to a roaster or to a zinc pressure leach plant; lead to a high grade lead sulphate concentrate suitable for feed to a lead smelter, and copper to a high grade copper sulphide concentrate suitable for feed to a copper smelter. Precious metals are divided between the zinc, lead and copper concentrates.

Jan 1, 1993

By B. Li

"Sepiolite is a magnesium-rich, porous, and fibrous clay mineral with broad applications. These applications take advantage of sepiolite’s high specific surface area and unique nano-sized channel structure. Over the past years, numerous materials and techniques based on the structure and property of sepiolite have been developed. This article reviewed the recent achievements in developments and applications of sepiolite in environmental protection, catalysis area, and nanocomposites. The prospectives of sepiolite applications is also discussed. INTRODUCTION Sepiolite is a magnesium-rich, porous, and fibrous clay mineral. The typical chemical formula of sepiolite is Si12Mg8O30[OH]4[OH2]4·8H2O [1]. Sepiolite has a high specific surface area and nano-sized channels because of its special structure [2]. This unusual crystal structure projected onto the [001] plane is shown in Fig.1 [3]. As it can be seen, silicon and oxygen atoms make up for the tetrahedral structure and magnesium and oxygen atoms form octahedral structure, respectively. Those tetrahedral-octahedral-tetrahedral ribbons expand boundlessly in one direction, leading to the special fibrous structure of the sepiolite. Every tetrahedral-octahedral-tetrahedral ribbon is combined to the next by an inverted Si–O–Si bond, which causes an interlaced layer with a continuous tetrahedral sheet and a discontinuous octahedral sheet. Terminal MgO at the edges of the ribbons is coordinated with two structural water molecules, which can form hydrogen bonds with zeolitic water molecules that are located in the channels running parallel to the fiber axis [3,4]. The Mg2+ ions inside the channels can be exchanged with other cations in solution. Therefore, sepiolite can be used to remove metal cations from aqueous solutions [5,6].It can be seen from Figure. 1 and Table 1 [7], the unique structure endows sepiolite with a substantial surface area and nanoscale channels. Its specific surface area reaches 320 m2/g and channel dimensions up to 3.7×10.6 Å. There are three active adsorption sites on the surface of sepiolite: one is oxygen atoms of the Si-O tetrahedron. The second is the structural water molecules paired with magnesium ions at the edges of the ribbons, which can form hydrogen bond with adsorbent. The last one is the Si-OH groups due to the breaks of the Si-O-Si bonds on the surface of Si-O tetrahedron. Thus, sepiolite has strong adsorption ability which has been widely used in environmental protection. Moreover, sepiolite has many significant features such as good mechanical and thermal stability, rheological property, porous, and easily modification, making it be a hotspot in chemical and biological researches. However, with the development of technology, broader and more advanced applications of sepiolite have been carried out in recent years. In this study, the recent achievement in sepiolite applications is summarized, the further tendency is also discussed."

Jan 1, 2018

By Stephen Njoloma, William Bracken, Harald Cordes, Ivan Hee

"DC Water’s First Street Tunnel (FST) is part of the $2.6 billion Clean Rivers Project designed to reduce the occurrence of combined sewer overflows into local waterways. Due to flood events in the Bloomingdale and LeDroit Park neighborhoods, the FST Project was accelerated by DC Water to mitigate future flooding by boosting storage capacity and thus relieving the undersized combined sewers.The FST Project was finalized in 2016 as a collaborative effort between DC Water, its consulting team consisting of Greeley & Hansen and McMillen Jacobs Associates, and the design-build team of Skanska, Jay Dee Contractors (SKJD) with WSP Parsons Brinckerhoff as the designer.Scope of project. The FST Project (Fig. 1) included four primary shaft sites, a large 6 m (20 ft) internal diameter, 823- m (2,700-ft) long bored tunnel and three adit connections from the off-line shafts to the large-diameter tunnel. The adits which vary in size and length, are the subject of this article. The Channing Street site (Fig. 2) was established as the main site for an Earth pressure balance tunnel boring machine (TBM) and included a 49-m (160-ft) deep shaft with slurry wall support of excavation and 20-m (65-ft) internal diameter final cast-in-place permanent concrete liner. The construction sites at Adams Street, V Street and Thomas Street each consisted of off-line shaft structures tied to near-surface sewer diversion chambers and ventilation facilities. These three off-line shafts were connected to the large bored TBM tunnel via adit tunnels. Each of the three adits had a portion or the entire length excavated by sequential excavation method (SEM) in frozen ground.The Adams Street adit (Fig. 3) was constructed in two phases. The first phase is the 23-m (75-ft) long and 5-m (16-ft) diameter section immediately outside the drop shaft which also serves as the deaeration chamber and was excavated by SEM. The second phase which is 91 m (300 ft) long and 3 m (10 ft) in diameter was excavated by Micro TBM (MTBM) launched from within the permanently lined deaeration chamber. MTBM excavation commenced toward a reception chamber that was excavated by SEM from the previously bored FST TBM tunnel. This SEM excavation had a 5 m (17 ft) diameter and a length of 4.5 m (15 ft)"

Jan 3, 2018

By Koppe J. C

This paper describes the methodology developed to establish a sequentia mining plan applied to a coal mine, using computers. Firstly, isocontou. maps were generated from the drill holes and outcrop description information, representing the thickness and depth of the rock formation: present in the mine site. The procedure relies on the repeated application of the cross validation techniques, until the standard deviation of thi estimation is reduced to a minimum.From this map the coal reserves of the two coal seams, the overburdet (separated in hard and soft material) and the interburden were calculated After that, the maps were transferred in digital files to AutoCAI software, where different mining plan simulations were performed. 7b ore evaluation in each case was done automatically, including tonnages volumes and stripping relations. The final mine configuration consider the economic aspects of the operation.

Jan 1, 1993

By M. Z. He

Attractive particle interactions which underpin the sliming of gangue mineral particles onto valuable mineral phases are encountered in a number of flotation circuits. Sliming leads to poor flotation recovery of the valuable minerals and high recovery of the gangue particles in the concentrate. To mitigate sliming, low molecular weight poly-electrolytes are commonly used as dispersants during pulp conditioning prior to flotation separation of the valuable and gangue mineral phases. In the present work, the sliming mechanism of sericite onto chalcocite and the influence of interfacial chemistry and two anionic copolymer dispersants (carboxylate substituted polyacrylamide, polymer Cyquest 3223 and sulfonate substituted polymaleic acid, polymer P80) on the sliming interactions were probed in the pH range 5~9. It was shown that the sliming occurred under solution conditions where both chalcocite and sericite particles were negatively charged, as evidenced by their apparent particle zeta potentials. The suspension pH had a profound effect on sliming process as the extent was markedly greater at lower than higher pH. The sliming was found to be due to the chalcocite dissolution, Cu (I) release and oxidation to Cu (II), followed by hydrolysis and specific adsorption, leading to sericite particle surface charge reversal and the formation of electropositive sites on chalcocite surface in the pH range 5~9. Addition of polymer Cyquest 3223 or P80 not only increased the magnitude of zeta potentials of both sericite and chalcocite particles but also reduced the formation of Cu (II) ions and complexes, which mitigated the sliming behaviour. The adsorption of polymer Cyquest 3223 or P80 at 3 g polymer / kg solid or more had a significant impact on the zeta potentials of both sericite and chalcocite particles. Sericite-chalcocite particulate adsorption studies showed that sliming was completely suppressed via an electro-steric repulsion mechanism resulting from anionic polymeric dispersant adsorption at dosages > 3 g polymer / kg solid.

Jan 1, 2014

By Richard Jr. Ray, David Johnston, Phil Blankenship

Injection of inert gases to combat mine fires has been practiced in various parts of the world for a long time. Of late, nitrogen has become the preferred inert gas for control of mine fires and safe salvage of longwall equipment as compared to carbon dioxide or fuel gases produced from burning of fuel. In India, carbon dioxide has been used for fire fighting in a number of mines during the 1960s and 1970s. More recently inert gas produced from burning of fuel oil in surface plants has been used in controlling the atmosphere in fire areas in two mines. In yet other cases, liquid nitrogen has either been poured directly into fire areas in liquid form or injected in gaseous form to keep the fire in check. Nitrogen produced in liquid form in an oxygen plant is more costly than nitrogen produced from PSA (pressure swing adsorption) based plants. A PSA-based plant has been installed in one of the Indian mines in 1986 and more are in the offing. This paper reviews the application of various inert gases in Indian mines and discusses the likely trend of inert gas application in Indian mines in the future.

Jan 1, 1989

"The Ohio River Bridge East End Crossing Tunnel requires a 75-year service life of its cast-in-place reinforced concrete lining. This twin-tube 3-lane (each tube) highway tunnel is about 55-ft wide and 30-ft high. Since unified tunnel service life prediction methodology does not exist in the US, challenges occurred during the design-build phase of this project. These challenges include the methodologies in determining the reinforced concrete’s degradation mode, the lining’s surface chloride concentration level, the reinforcing steel’s critical chloride threshold value for corrosion, how to verify the concrete’s diffusion coefficient, and the durability impact from concrete crack width. This paper presents a methodology in verifying the proposed concrete mix can achieve the service life requirements. This methodology can be adopted for service life prediction for future tunnels to be built in the US. INTRODUCTION The Ohio River Bridge East End Crossing (ORBEE) Tunnel is part of a Public Private Partnership project, which connects transportation network between Louisville, Kentucky and southern Indiana. Located in Louisville, Kentucky, the twin-tube highway tunnel provides northbound and southbound lanes of the Kentucky approach to a new bridge across the Ohio River. Tunnel lengths are approximately 1,675-ft and 1,685 for the northbound tube and the southbound tube, respectively. Connected by two cross-passages, both tubes have a roadway width of 40-ft, for 3-lane traffic, and a vertical clearance of 26.5-ft.The tunnel was constructed by drill and blast method with shotcrete and rock dowels as initial ground supports. The final tunnel lining system includes: •,Nominal 16” cast-in-place reinforced concrete lining, with 2” and 3” concrete covers over reinforcing steel for its extrados and intrados, respectively. •,20” cast-in-place reinforced concrete invert slab, with 4” and 3” concrete covers over reinforcing steel on its top face and bottom face, respectively. •,PVC waterproofing system around tunnel perimeter, excluding invert slab. •,Perforated PVC groundwater collection pipes on both sides of the tubes and one below the invert slab of each tube."

Jan 1, 2016

By Peter Iovino

Unfortunately, I don't know the unit cost per cubic yard of treatment. I reflected on that yesterday and I don't think that we considered the use of micropiles. They could have been an option. The challenge may have been picking up some of the lateral load but I think the micropiles could have been installed on a batter and perhaps extended to rock. We could have considered them, but I do not believe we explored micropiles as an option for this project.

Feb 10, 2003

By Mary Ellen Bruce

Let me first address the issue of the wet grab samples. The wet grab samples that were attempted to take on the Central Artery were hindered by the fact that the way the mixing was being done was only by injecting grout on the way out, during withdrawal of the mixing tools. They would auger down to the required depth (usually with some water being injected), which took anywhere from 45 minutes to an hour, and then when coming out, the grout would be injected with grout. That was leaving a column of grout in the center where the shaft had been (i.e. inside of the blades of the mixing tools), which would end up being something like a foot in diameter because the pipe that was used for the drill shaft was a foot in diameter. So we had 10 inches to a foot of almost pure grout in the middle of our column and then we had 2 feet on either side that was mixed soil cement. So when they went down with the wet grab sampler not knowing where that was in the column sometimes they/we were getting strengths of 1500 psi, and sometimes they/we were getting strength of 500 psi or 100 psi. So what was it that we were taking into the wet grab sampler? In those cases you don't really know, but it wasn't representative of the core samples we were taking. We were purposely not coring in the center because we knew that was going to be high cement content, almost pure grout. So the issue of wet grab sampling particularly on this project, the Central Artery Project, was that we didn't really know what we were sampling. What becomes an issue with wet grab sampling in other projects is that you have to have another device (machine) in most cases, a cherry picker crane or something similar that can raise and lower with a beam that is used to forces the sampler down into the freshly mixed soil-cement. And regarding economics, is it more economical to have that crane standing by with its operator or to have a drill rig to come along later and do the coring and take the material out that's fairly identical to what you're finding in situ? The complaint of micro-fracturing in the core samples as you're taking the cores was raised by Seiko as causing large strength reductions. But, if you're doing it carefully, then I don't think that's much of an issue anymore, on research basis perhaps but not on a practical level.

Feb 10, 2003

By Jim Bruce

No answer required. From the drilling equipment suppliers, but the specifications must be tailored to be project-specific. Yes, the sonic technique is very interesting as we said, and it is not so much as an issue of the magnitude of power, it's about the efficient use of the power. The efficiency of the machine is not necessarily related to size so it is best to talk to the two contractors that supply the service about that. I think it can be scaled down but it is quite a big head, so therefore there are practical limitations on the size of the door it can walk through and also the size of the casings and rods that it can use. You might defeat the economic advantages if you were to use too short casing lengths. Boart Longyear have a low head room machine that can work within an 8 foot verical clearance.

Feb 10, 2003

By Timothy Flaherty

We observed the boiling in the water very close to the water adjacent to where we were drilling. That only happened at the very beginning before it was switched to water flushing. Yes, it was performed with water flush.

Feb 10, 2003