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By Agnes Y. Lee

As part of the U.S. Bureau of Mines program to improve base metal leach systems, pressure leaching of galena (PbS) concentrates in fluosilicic acid (H2SiF6) solution was investigated. Lead extraction was 93 pct when PbS was pressure leached in H2SiF6 at 95° C with 2OO-psig O2 pressure for 40 min, using ferric nitrate [Fe(N03)3] as a catalyst. The effects of several catalysts, O2 pressure, time, and acid concentration on leaching were determined. The purified leach solution was electrowon to recover high-purity Pb metal. The H2SiF6 used in leaching and electrowinning can be recycled continuously. A flow diagram was proposed based on this investigation. Elemental sulfur (SO) was recovered from the leach residue by solvent extraction. A method was also developed for treating the flnal residue to segregate the important byproduct elements such as Ag, Cu, and Zn and enable their recovery by standard commercial processes.

Jan 1, 1990

By J. J. Lukasko

The U.S. Bureau of Mines developed an alternative electrochemical process for the production of calcium metal. The current industrial practice is costly, complex, and inefficient. The Bureau method involved electrowinning of a calcium-tin alloy followed by electrorefining to produce calcium metal. In the electrowinning cell, CaCI2 was fed to a KCI2-CaCI2 electrolyte. The calcium was electrowon at 6500 C into the pure molten tin cathode until the cathode contained 7.5 wt pct Ca. Current efficiency for electrowinning averaged over 90 pct. The resulting calcium-tin alloy served as the anode for the electrorefming cell, which employed a [CaC~-CaF2] fused salt as the electrolyte. Calcium metal was electrorefmed at 8500 C with a current efficiency of 85 pct based on calcium metal recovered. The calcium metal analyzed 99.2 pct, which is purer than commercially produced calcium.

Jan 1, 1990

By N. Kyriazi

The U.S. Bureau of Mines subjected the CSE SR-lOO self-contained self-rescuer (SCSR) approved by the National Institute for Occupational Safety and Health (NIOSH) and the Mine Safety and Health Administration (MSHA) to a series of laboratory treatments designed to simulate various environmental conditions in underground coal mines. The tests were designed to predict the ability of the self-rescuers to withstand those environmental stresses without causing a decrease in wearer protection. The apparatus were heated to 710 C for 48 h, cooled to -450 C for 16 h, vibrated for 9 h, and dropped 1 m on each axis. A critical concern was internal damage to an apparatus, without any obvious external signs, that would cause it to malfunction or seriously degrade its performance. Carbon dioxide (C02) levels in apparatus with combined treatments were higher than in apparatus with individual treatments and untreated apparatus. The higher levels remained within safe limits, however. None of the treatments caused venting of the small oxygen cylinder that provides starter oxygen. Some bottles were found to be empty because of manufacturing defects in the burst disks. This problem was corrected in later models. The heat treatments did make the case ends more difficult to remove and the breathing bag sticky and subsequently more difficult to unfold. An apparatus that was dropped and vibrated had a broken desiccant bag that released some of its contents which compromised the seal of the relief valve. The case was dented from the drops. As with the first-generation self-rescuers, if there is visible damage to the case of the apparatus, the apparatus should be considered to be internally damaged and must be removed from service.

Jan 1, 1990

By Paul W. Jeran

Subsidence was monitored by the U.S. Bureau of Mines over the ends of longwall panels operating in the Pittsburgh, Kittanning, and No. 2 Gas Coalbeds of the northern Appalachian Coal Basin. The final subsidence over the finishing ends of three panels in the Pittsburgh Coalbed are compared with the subsidence measured over the rib at these panels. The characteristics of subsidence are different. At Mine A, data over the start of a longwall panel shows similar characteristics to the subsidence measured over the rib. Subsidence over the fmishing ends of panels in the Kittanning and No.2 Gas Coalbeds are also different from the subsidence over the rib. The use of a subsidence prediction model based on data gathered over the rib of a panel will not yield accurate results if it is applied to the finishing end of a longwall panel. Acceptable results may be obtained along the centerline over the starting end of a panel.

Jan 1, 1991

By T. H. Jeffers

The U.S. Bureau of Mines has developed porous beads containing immobilized biological materials for removing metal contaminants from waste waters. The beads, designated as BID-FIX beads, are prepared by blending biomass, such as sphagnum peat moss or algae, into a polymer solution and spraying the mixture into water. Laboratory studies were conducted to determine bead sorption and elution characteristics. Batch and continuous tests demonstrated that BIO-FIX beads sorbed arsenic, cadmium, lead, and other toxic metals from acid mine drainage waters collected from several sites. Selectivity for heavy and toxic metal ions over calcium and magnesium was demonstrated. The beads exhibited excellent metal sorption and handling characteristics in stirred tanks, column contactors, and a low-maintenance passive system. The sorption process was reversible, and metal ions were eluted from the beads using dilute mineral acids. Cyclic tests indicated that the beads continued to extract metal ions after repeated loading-elution cycles.

Jan 1, 1991

By Robert F. Chaiken

Burnout Control is a process developed by the U.S. Bureau of Mines for accelerating the burning of wasted coal fires in situ, while at the same time controlling the heat and fumes produced. The Albright fIre project is a fIrst fIeld trial of Burnout Control as applied to a coal waste bank. An exhaust ventilation system was designed and constructed and then operated over a 1-year period at the site of an existing abandoned mine land fire near the town of Albright, WV. While predicted exhaust gas temperatures of 900° C and thermal power levels of 5 MW were achieved at 20-to 3O-in H20 vacuum levels, problems were encountered with engineering designs, equipment breakdown, and fuel-rich combustion that curtailed the time period of satisfactory operation. Effective afterburning of the exhaust gases (as they were drawn from the bank) corrected the problems associated with combustion stoichiometry and led to high thermal outputs. It is believed that with (1) improvements in engineering design and construction, (2) better control of the afterburning process, and (3) the use of conventional stack gas air-pollution controls, Burnout Control can be applied successfully to a coal waste bank fire.

Jan 1, 1991

By Ann G. Kim

The U.S. Bureau of Mines mine fIre diagnostic methodology to locate and monitor fIres in abandoned mines and waste banks is based on the controlled sampling of the mine atmosphere to determine changes in the concentration of hydrocarbons desorbed from heated coal. To provide background data for this methodology, a laboratory study was conducted in which samples of coal and coal waste were heated under controlled conditions. Gas samples from the combustion furnace were analyzed for standard gases CO2 and CO and for the C1 to Cs hydrocarbons. In all tests, the concentration of desorbed hydrocarbons increased during heating and decreased during cooling. A dimensionless hydrocarbon ratio, Rl, was developed as the signature for heated coal. For bituminous coals, the value of Rl increases during heating of coal samples and decreases during cooling of the same samples. Generally, Rl values of 100 or more indicate coal sample temperatures of at least 100° C. The emission of higher molecular weight hydrocarbons from anthracite samples was very low, resulting in relatively low Rl values at all temperatures. Data from fIeld projects confIrmed these results.

Jan 1, 1991

By Sathit Tandanand

Horizontal displacements and ground strains induced by mine subsidence are significant information needed for calculating damage and developing precautions against subsidence effects on surface structures. To devise a simple method for determining the surface horizonal displacements and strains simultaneously with the subsidence prediction, the U.S. Bureau of Mines examined the significance of the tilt number, which is the proportionality constant in the relationship between the horizontal displacement and the slope of the subsidence profile. The ratio of the tilt number to the critical radius of the subsidence trough is identical to the ratio of the maximum possible horizontal displacement to the full subsidence, which is found to be constant in most European coalfields. If this ratio is known for a particular minesite in the United States, then horizontal displacement and ground strains can be readily obtained from the primary subsidence data.

Jan 1, 2010

By D. R. Tesarik

As part of its research program to investigate ways of improving resource recovery and reducing subsidence, researchers from the U.S. Bureau of Mines placed instruments in the B-North ore body of the Cannon Mine, Wenatchee, WA, to monitor cemented backfill and rock deformation during mining. The vibrating-wire gauges proved to be reliable and versatile, and approximately half of the instruments are providing data after 2 years of use. A two-dimensional, finite-element model was used to analyze the Cannon Mine's multilevel bench cut-and-fill mining method and predict rock and backfill displacements. The model accurately predicted rock displacements, but the predicted and measured displacements in cemented backfill had a correlation coefficient near zero, indicating that the model should only be used to predict rock displacements and not backfill displacements. A finite-difference model was also used to evaluate the stability of a cemented backfill pillar. Results can be used to conservatively predict backfill stresses, but on-site observation of pillar failures coupled with in situ measurements are needed to make more accurate predictions. An ongoing evaluation of the mining system has indicated that filling the primary stopes tight to the back with cemented backfill allowed these pillars to carry overburden loads soon after the cemented backfill was placed.

Jan 1, 2010

By W. P. Stroud

In this U.S. Bureau of Mines report, the conditions required for the direct reconstruction of a tomogram from observed line integrals are examined. Because of the limited access to the working faces in coal mines, the special case of access to only two opposite faces is emphasized. Classical matrix methods were used for small dimensional (2 by 2, 3 by 3, and 4 by 4) applications to determine the limitations and the requirements for a solution. The results for large (n by n) grids were then inferred and generalized from those of the smaller grids and matrices. Limited access tomography is found to be appropriate for in-seam hazard detection from seismic and microwave data, but it is shown that additional data must be added to obtain a direct solution.

Jan 1, 2010

By Louis E. Dalverny

U.S. Bureau of Mines research to develop diagnostic methods to locate and evaluate fires in abandoned mines and waste banks and techniques to extinguish such fires was applied to an abandoned 60-acre underground bituminous coal mine (Renton, Allegheny County, PA) to locate and extinguish three separated fire zones. Mine fire diagnostics interpret changes from baseline values in subsurface pressures, temperatures, and mine gas composition under imposed pressure gradients induced by a borehole exhaust fan. The effective gas sampling area surrounding each borehole is greatly enlarged. Sampling iterations, using a "communicating" boreholes set, provide "fire signature" information for locating both heated and cold areas. Time-dependent monitoring differentiates heating and cooling periods resulting from combustion front movement and/or fire extinguishment activities. A water injection with fume exhaustion extinguishment effort involved injecting water through boreholes to quench the heated zones while exhaust fans actively removed heated gases from the mine. The technique was ineffective as implemented, primarily because of inadequate spreading of water from the injection points. The Bureau's diagnostic method determined the fire locations and the effectiveness of the water injection with fume exhaustion extinguishment technique.

Jan 1, 2010

By Dennis R. Dolinar

The danger to personnel, equipment, and pillar structure created by the spalling of a coal rib can be minimized by installing rib bolts. To assure that a configured support system will maintain a coal rib, the U.S. Bureau of Mines developed a rib bolt system based on a nonpreventable failure concept. A statistical equation quantitatively relates the amount of rib retained to the bolt spacing and the width of the spalled material. Laboratory test results show that the equation accurately predicts the amount of material retained and confirm the validity of the support concept. The examination of rib bolting at a coal mine experiencing rib sloughage provides evidence that the effectiveness of the support can be related to the failure pattern of the spalled material. An analysis of roof and roof support reaction to rib sloughage at the mine indicated that the rib sloughage had little effect on roof stability. Although supporting ribs might not affect roof stability, laboratory test results indicate that the material retained by the support can sustain a load up to 20 pct of the intact compressive strength of the material.

Jan 1, 2010

By Maria I. De Rosa

The U.S. Bureau of Mines performed experiments to determine the embedded hydrogen chloride (HCI) and smoke particle characteristics during combustion of polyvinyl chloride (PVC) and chlorinated mine materials for development of a test parameter. The experiments were conducted in an approximately 20-L furnace at set furnace temperatures of 250° and 1,000° C, for a 14-min duration, with an airflow through the furnace of 10 L/min. The variables studied, as a function of time, were hydrogen chloride embedded on smoke particles, hydrogen chloride concentrations in the gas phase, smoke particle average diameter (dg) and particle concentration (no), and product of smoke particle diameter and concentration (dgno). Other variables included carbon monoxide (CO), carbon dioxide (CO2), and oxygen (O2) concentrations; sample mass weight loss; and furnace temperatures. Results show that there is a correlation between embedded hydrogen chloride, hydrogen chloride gas concentrations, and inverse of the smoke particle diameter-concentration product (1/dgno); the higher the hydrogen chloride gas concentrations, the higher the embedded hydrogen chloride, the higher the 1/(dgno) values. These correlations will enable development of a simple test parameter to assess the toxic hazard that these materials pose during fire.

Jan 1, 2010

By Pamela J. Watson

The U.S. Bureau of Mines has demonstrated in laboratory tests that drilling with surface-charge-neutralizing concentrations of polyethylene oxide (PEO) polymer solutions simultaneously improves penetration rates and extends bit life. The applicability of this additive to improve drilling performance in coal measure rocks was demonstrated under field conditions at an abandoned mine land site in Pennsylvania and a producing coal mine property in Ohio. Penetration rate improvements ranging from 15 to 50 pet were obtained when core drilling through a variety of coal measure lithologies. Drilling cost analysis indicates that the small added cost of using the polymer is more than offset by the savings that result from demonstrated increased drilling penetration rates, which translate into drilling cost savings of about 10 to 30 pct. This report also gives chemical analyses of a variety of coal measure rocks and some corresponding local drilling water samples, obtained from a wide geographical base, along with threshold concentrations of PEO required to effect the improved drilling performance in these rocks. From these data, the threshold PEO concentrations needed to ensure improved drilling performance can be estimated for any coal measure rock suite. Proper techniques for mixing PEO solutions are also presented.

Jan 1, 2010

By D. L. Yopps

In research conducted by the U.S. Bureau of Mines, platinum-group metal (PGM) flotation concentrate from the Stillwater Complex, MT, was subjected to biooxidation using Thiobacillus ferrooxidans in an effort to break down the sulfide minerals and liberate the associated PGM's for subsequent chemical leaching. Bacterial preleaching oxidized up to 94 pct of the sulfide present, destroyed the PGM-bearing pentlandite [(Ni,Fe)9S8] mineralization, and dissolved most of the nickel in the concentrate. Cyanidation at 80° C proved to be the most attractive chemical leachant, removing 34 pct of the platinum, 76 pct of the palladium, 94 pct of the rhodium, and 97 pct of the gold from the biooxidized concentrate. Research also indicated that increased sulfide oxidation during the preleach phase led to improved PGM recovery in the subsequent chemical leaching phase.

Jan 1, 2010

By P. Comba

The U.S. Bureau of Mines investigated a hydrochloric (HC1)-calcium fluoride (CaF2) leaching procedure to treat domestic manganese (Mn)-bearing silicate resources. The proposed process is an alternative to high-temperature and energy-intensive extractive techniques. Single-stage leaching with a stoichiometric amount of HCl and a F-Mn mole ratio of 0.2 extracted 96 pct of the Mn when the leach conditions were 50° C, 3 h, and 35 pct solids. Ninety-eight percent of the Mn was extracted during countercurrent leaching at similar conditions. A process flowsheet was developed that incorporated HC1-Cab leaching, excess leach acid utilization, fluoride (F) recycle, and Mn recovery. When the domestic manganese silicate ore was processed, 98 pct of the Mn was extracted, 99 pct of the Cab was reclaimed, and a leach residue was produced that passed the Environmental Protection Agency (EPA) Extraction Procedure (EP) Test for nonhazardous waste.

Jan 1, 2010

Laboratory tests were conducted by the U.S. Bureau of Mines to determine respirable dust reduction effectiveness of and interaction between face airflow and water sprays for a continuous miner. Increases in exhausting face ventilation from 3,000 to 9,000 cfm, in waterflow from 15 to 35 gpm, and in water nozzle operating pressure from 80 to 200 psi were evaluated. Results indicated that airflow had the greatest individual impact on reducing dust levels, with concentrations at return and operator sampling locations reduced by as much as 57% and 99%, respectively. Regression modeling was utilized to predict dust concentrations over the range of values tested for the control parameters. Interactions between the control parameters were significant and often defined an optimum level where further increases in that parameter failed to produce additional dust reductions. Increasing airflow to 8,400 cfm, waterflow to 25 gpm, and water pressure to 140 psi typically reduced dust concentrations at operator and return locations. Application of a control parameter above these levels can provide additional dust reductions if used in conjunction with appropriate levels of the other two control parameters. Otherwise, higher operator dust levels may result and can be attributed to increased rollback and/or airflow turbulence.

Jan 1, 2010

By P. D. Kovscek

The performance of a novel prototype kerf-cutting impact mining machine was evaluated under a cooperative agreement between the U.S. Bureau of Mines and RAMEX Systems, Bellevue, WA, while operating under conditions typical of normal tunnel entry development. Selected operating parameters were monitored concurrently to determine baseline operating conditions and to study relationships between operating parameters. Using the data obtained, the specific energy requirements of the impact mining machine were calculated and compared to specific energy requirements of tunnel boring machines cutting in rock having similar hardness. Tests results indicate that the kerf-cutting impact mining machine can provide a mechanical means for mining very hard rock that cannot be effectively mined using commercially available mechanical excavators.

Jan 1, 2010

By Gwendolyn D. Hood

The U.S. Bureau of Mines developed a dewatering technique for treating wastewater that was tested on waste slurry from a commercial tile company in Alabama. Raw wastewater samples were pretreated with 10 Ib calcium chloride and 10 lb Wyoming bentonite per 1,000 gal of slurry. After pretreatment, polyethylene oxide (PEO) at dosages varying from 0.05 to 0.20 lb per 1,000 gal was mixed with the waste slurry, forming strong, tough floes that were separated from the clarified water using a trammel. The flocculated slurry was dewatered to a consistency that could be handled for subsequent disposal in a landfill. The clarified water quality was equivalent to that of the company's present treatment system.

Jan 1, 2010

By K. E. Hjelmstad

During an underground mine fire, air can be rapidly depleted of oxygen and contaminated with smoke and toxic fire gases. Any delay in warning miners could have disastrous consequences. Unfortunately, present mine fire alarm systems, such as stench, audible or visual alarms, telephones, and messengers, are often slow, unreliable, and limited in mine area coverage. Recent research by the U.S. Bureau of Mines has demonstrated that ultra low frequency electromagnetic signaling can be used for an underground mine fire alarm. In field tests of prototype equipment at five mines, electromagnetic signals from 630 to 2,000 Hz were transmitted through mine rock for distances as great as 1,645 m to an intrinsically safe receiver. The prototype system uses off-the-shelf components and state-of-the-art technology to insure high reliability and low cost. When utilized, this. technology would enable simultaneous and instantaneous warning of all underground personnel, regardless of their location or work activity, thereby increasing the likelihood of their successfully escaping a mine disaster. This report presents the theoretical basis for through-the-rock ultra low frequency electromagnetic transmission, design of the prototype transmitter and receiver, and the results of in-mine tests of the prototype system.

Jan 1, 2010