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By G. H. Keith

The Bureau of Mines determined the mechanism(s) involved in observed anomalous changes in mechanical properties of vanadium-base alloys. Tensile properties of electrorefined and commercial-purity vanadium-base alloys containing up to 5 atomic percent molybdenum or titanium were measured between 77° and 673° K. Snoek oxygen and nitrogen peak heights were measured to determine the changes in dissolved interstitial content caused by increasing quantities of solute. In addition, changes in lattice parameter were followed wit: precision X-ray techniques. Softening, observed in alloys containing titanium, is explained by the formation of a second-phase titanium compound with oxygen or nitrogen. However, because of partitioning of titanium between compound formation and solid solution formation, about five times the stoichiometric amount was required for complete reaction. Addition of 1 percent titanium drastically lowered the strengthening due to strain aging, at 673° K, and 2 percent titanium essentially eliminated it. All alloys were ductile at 77° K. Variations in the tensile properties of the molybdenum-containing alloys are explained by variations in the amounts of interstitial impurities present. The molybdenum did not react with these impurities and had no effect on strengthening due to strain aging. Commercial-purity vanadium alloys containing more than 2 percent molybdenum were brittle at 77° K.

Jan 1, 1969

By Mary A. Barrett

The Bureau of Mines conducted a laboratory-scale investigation of grouting mixtures containing iron or aluminum to determine the existence of health or explosion hazards, due respectively to oxygen depletion or hydrogen emission. Mixtures containing iron created an oxygen deficiency in less than 24 hours and released small amounts of hydrogen; a health hazard could occur but only under extremely unfavorable conditions. Mixtures containing aluminum released little hydrogen and consumed little oxygen; however, if improper on-site mixing yielded high local metallic aluminum concentrations, enough hydrogen might be released to produce an explosive atmosphere in a confined space.

Jan 1, 1969

By Clarence O. Babcock

Model pillars of limestone, marble, sandstone, and granite with length-to-diameter (L/D) ratios of 3, 2, 1, 0.5, and 0.25 (0.286 for granite) were tested to failure in axial compression to determine to what extent an increase in end constraint increased compressive strength. Adjustable steel rings, mechanically tightened about the ends of test specimens to create a radial prestress of 3,000 or 5,000 psi prior to the application of axial load, increased end constraint more than was possible in previous tests using solid steel rings. (Solid rings, epoxy-bonded to the ends of dogbone specimens, increased compressive strength compared with that of straight specimens without ring constraint.) During the loading cycle, additional end constraint was produced by lateral expansion of the specimens against the rings. The effect of the end constraint was to increase the compressive strength 55 to 58 percent for the shorter pillars of dogbone shape compared with the compressive strength of straight pillars with the same L/D ratios without ring constraint. Most pillars with L/D ratios of less than 2 were made stronger by end constraint. Pillars with an L/D ratio of 3 did not benefit significantly from end constraint. When the results from compression testing of straight specimens of rock in the laboratory are used to design mine pillars in situ, the pillars will be larger than necessary if the horizontal compressive stress is several thousand pounds per square inch greater than that resulting from the weight of the overlying rock alone. The L/D ratio can be increased by a factor of 1.76 for ratios in the range 0.25 to 3 and still provide the same compressive strength. The safety factor applied with straight specimen test results should also be acceptable for use with constrained pillar test results.

Jan 1, 1969

By Robert W. Ageton

The Bureau of Mines is currently conducting a comprehensive study to evaluate all aspects of recovering gold from large, low-grade deposits in the Golden Sunlight area, Whitehall mining district, Jefferson County, Mont. Prior to World War II this area produced significant quantities of gold. The study includes geologic mapping, diamond drilling, assaying, computer analysis of assay data, metallurgical research and ore testing, mine and mill planning, and an economic evaluation of all factors bearing on the establishment of a producing gold mine. Preliminary evaluation of the deposit indicates about 31 million tons of submarginal gold resources. American Exploration and Mining Co. (AMEX) has assisted the Bureau in this project by providing drill site preparation, control assays, and geological aid for the Bureau's exploration work and by furnishing comprehensive assay information of the property and copies of base and geologic maps. This report presents the geology and mining history of the area, together with a summary of Bureau work in progress.

Jan 1, 1969

By Hillary W. St. Clair

This report describes a mathematical procedure for analyzing size distribution data by the method of moments. The method was applied to Andreasen's data on a variety of grinding mill products. It was found that the observed size distributions could be represented by gamma and beta distribution functions over a wide range of sizes. A computer program, written in BASIC, is described for calculating moments, distribution parameters, and the weight fraction in any size range.

Jan 1, 1969

By Carl E. Norman

An investigation of geologic structure on macroscopic, mesoscopic, and microscopic scales was conducted on near-surface igneous and metamorphic rocks in which the existing stress field was determined by in situ methods. A consistent NE-SW orientation of the maximum compressive stress in the horizontal plane at four of five test localities appears due to the intrusion of NW-trending diabase dikes. Structural features at the mesoscopic scale show no consistent directional relationship to determined stress directions. Petrofabric diagrams of open microfractures show preferred orientations, but these are not consistently related to the orientations of larger structural features, such as joints, foliation, or mineralized shear zones. However, at five of six test sites the preferred direction of microfractures occurs nearly perpendicular to the maximum principal stress directions; an anomalous parallel relationship exists at a test site in an intrusive rock body. The results suggest that the open microfracture subfabric may provide a means for gaining information on the directional properties of stress fields. Such information can be obtained from oriented cores taken from holes which exceed the approximate 100-foot depth to which other in situ methods are presently limited.

Jan 1, 1970

By W. R. Hardwick

Nuclear explosive fracturing has been suggested as a method to make hard rock amenable to extraction by a modified block-caving method. To evaluate this possibility, conventional and nuclear blasting practices are discussed, underground mining methods for large deposits and their costs are described, and the cost of fracturing ore with a nuclear explosive and subsequent mining by a modified caving system is estimated and compared with both open-stope and block-caving mining costs. While the direct cost of fracturing the ore in hard rock with a nuclear explosive is less than with conventional explosives, additional costs imposed by the use of nuclear explosives may make their use unattractive for deep mining.

Jan 1, 1970

By K. Robert Dorman

Spray-applied polyurethane foam was used to insulate the walls of heated rooms excavated in permafrost. The experiment was designed to determine whether polyurethane foam can be sprayed successfully on frozen ground under freezing conditions and to measure the effectiveness of the insulation in maintaining--at elevated temperatures for an extended period--a room excavated in frozen ground. Two manufacturers' foams were investigated in the laboratory. Subsequently, one of the foams was employed to insulate two small rooms, one in frozen gravel and one in frozen silt, in an experimental tunnel belonging to the U.S. Army Cold Regions Research and Engineering Laboratory (USACRREL) near Fairbanks, Alaska. Following insulation, heat was introduced into the two rooms. Heat migration across the insulating barrier into the walls, in addition to wall closures, was monitored over an 8-month period. The results show that polyurethane foam can be successfully sprayed on frozen ground in below-freezing temperatures. Given this type of insulation, together with winter cold to supercool the surrounding ground, it should be possible to maintain a shaft or heated room in permafrost for several years.

Jan 1, 1970

By G. G. Campbell

Bureau of Mines research to develop an in situ retorting recovery method for oil shale has involved field testing of fracturing techniques for creating fluid-flow paths in impermeable oil shale. Electrolinking, hydraulic fracturing without and with sand propping, and explosive fracturing with a liquid explosive were tested in a 25-ft-square, five-spot pattern. These wells were drilled into oil shale at 50-to 88-ft depths near Rock Springs, Wyo. Results of the fracturing tests were evaluated by injecting air into a test well and measuring flow rates and flow profiles in adjacent test wells before and after each test. To identify points of air entry (location of fractures) in wells, flow profiles were determined by use of inflatable packers and by continuous logging with an airflow probe developed during the fracturing program. Electrolinking and hydraulic fracturing without sand propping were relatively ineffective; hydraulic fracturing with sand propping created horizontal fractures with desirable flow capacity; and fracture flow capacity was significantly increased by detonation of nitro-glycerin displaced in the natural and hydraulically induced fracture systems.

Jan 1, 1970

By A. J. Barry

A practical method has been developed and field tested which provides an estimate of the bearing capacity of mine roof and floor. The relationship between penetration of the strata and imposed loads is determined by in situ tests. Information of this type is needed to determine the maximum allowable pressure that may be applied by self-advancing supports on roof and floor of a longwall face without causing a punching type of failure.

Jan 1, 1970

The Bureau of Mines performed cratering experiments in a homogeneous granite to test scaling laws for charge weights of 0.00476, 0.0220, 0.0900, 0.304, and 1.03 lb. Agreement among the data was best when empirical scaling exponents greater than one-third were assumed. Although the analysis showed that the best empirical scaling exponents were 0.37 for crater volume, 0.38 for crater radius, and 0.39 scaling for crater depth, all three crater dimensions could be scaled with a 0.38 scaling exponent.

Jan 1, 1970

By H. D. Jacobs

A process for recovering both iron and manganese from four manganiferous ores of the Cuyuna Range was evaluated. It comprised: (1) Low-temperature gaseous reduction to convert nonmagnetic iron minerals to magnetite and manganic minerals to manganous oxide, (2) acid leaching to extract manganese, and (3) magnetic separation to reclaim iron from the leach residue. Iron recoveries from the magnetic products ranged from 70 percent to 90 percent; manganese recoveries from leach filtrates ranged from 75 percent to 95 percent. Two ores, from the Hillcrest and South Alstead properties, yielded magnetic products considered adequate for use as blast furnace feed. Although good yields of manganese were attained on all ores, appreciable iron accompanied the manganese into solution. Previous work, however, has shown that this iron can be precipitated almost quantitatively under autoclave oxygen pressure with very little loss of manganese.

Jan 1, 1970

By Jack I. Paige

In this Bureau of Mines study, two fluidized-bed reactors were designed, built, and operated, one as a sorber for S02 and the other as a contactor for the regeneration of the sulfur-laden alkalized alumina. The target of 90 percent removal of S02 from a flue gas stream containing 0.3 percent S02 was attained by using a sorbent feed of 10-15 grams per minute into a 5-inch bed depth of alkalized alumina. The sorption unit was operated at about 330° C. Complete regeneration of the laden alkalized alumina containing 5 to 10 percent sulfur was accomplished in approximately 1/2 hour. An excess of reformed propane at about 730° C was the regenerating gas. Attrition losses, a major problem with this sorbent, ranged from 0.9 to 7.9 percent of the inventory. Data from these tests demonstrate, within experimental error, the validity of equations developed from short-term, thin-bed tests related to sorption and regeneration rates.

Jan 1, 1970

By Stephen D. Cramer

A nondestructive procedure for measuring electrodeposit porosity has been developed which records the location and number of deposit defects including pores, pits, and voids. The procedure involves the passage of an X-ray beam through the deposit-substrate system onto suitable film. The defects are recorded as images on the film. Variables studied included intensity and spectra of the X-ray beam, composition and thickness of deposit and substrate, film type and developing procedure, and limits for detecting defects. At an X-ray tube voltage of 40 kv, pores several mils thick were easily detected in copper-nickel specimens more than 20 mils thick. To illustrate the utility of the procedure, the effect of substrate oxidation and of current density on electrodeposit porosity was briefly studied.

Jan 1, 1970

By D. S. Burgess

An investigation of the hazard of spillage of liquefied natural gas (LNG) onto water is described. About 2,000 gallons of LNG were consumed in various tests. The initial vaporization rate of LNG following spillage was found to be 0.037 lb/ft2 sec; when the spill was confined, this vaporization rate was moderated after about 20 seconds by the growth of an ice layer on the water surface; when the spill was unconfined, a coherent ice floe was not observed and the vaporization rate was essentially time independent. The maximum diameter (in feet) of the spreading LNG pool was found to be given by 6.25 Wo 1/3, where Wo is the weight of LNG in pounds, Downwind of a natural gas source, time-averaged methane concentrations were given in good approximation by standard air pollution equations. However, peak concentrations were as much as twentyfold higher than average, adding an additional factor to the assessment of hazard. The effect of layering by the cold vaporized natural gas was similar to the effect of a temperature inversion on normal gases in the atmosphere. Small-scale explosions were observed on pouring LNG onto a water surface; no single explanation seems pertinent to all of the incidents observed.

Jan 1, 1970

By Raymond M. Stateham

Microseismic noise rates and slope movements were measured in an unstable area along the north wall of the Tripp-Veteran pit, Kennecott Copper Corp., Ruth, Nev. Low-noise, wide-band microseismic geophones were located at various points in the wall, and the change in distance across open fractures, resulting from instability, was determined by repeated measurements between fixed points set on each side of the fractures. The microseismic noise rate increased and decreased with corresponding increases and decreases in the rate at which the fractures opened. The microseismic noise rates and changes in width of the fractures show excellent agreement, and the two types of measurements complement each other in monitoring the progress of pit wall failure.

Jan 1, 1971

By Hillary W. St. Clair

This report describes an experimental method for determining parameters for the rate of reaction of CO2 with solid carbon. The method involves the simulation of a flow reactor by a mathematical model based on a hypothetical multistage reactor which permits calculation of the analyses of effluent gas and carbon consumed as functions of the flow rate and duration of the reaction. The method is applied to experimental data on the reaction of coke with CO2 in fluidized-bed and fixed-bed flow reactors. A method is described whereby two parameters may be determined simultaneously. The method involves a reiterative procedure that finds the values of the parameters that minimize the sum of squares of deviation between calculated and observed analyses of the effluent gas.

Jan 1, 1971

By C. Daniel Kealy

Finite-element,, mathematical models that solve LaPlace's and Richard's equations numerically were used to locate the phreatic surface within tailings pond embankments and to define the subsurface flow of water from the pond. Both must be known to design structurally and environmentally safe tailings dams. The permeability distribution within and beneath the embankment, the fluid potential values upgradient and downgradient from the embankment, and the geometry and elevation of an approximately impermeable layer at some depth beneath the embankment were used as computer inputs in analyzing over a dozen finite-element models of tailings dams varying structurally from simple to complex. Results predicted with the finite-element model were confirmed with measurements in a laboratory model of a tailings pond and in the field. Of particular importance to the design of safe slopes, all data indicated that the phreatic surface within a tailings dam is concave upward, a configuration opposite that in most earth dams. The close correlation between predicted and experimental values confirmed the practicability of using the finite-element technique to design safe tailings dams.

Jan 1, 1971

By L. A. Haas

The feasibility of removing sulfur dioxide by carbon monoxide reduction in a fixed-bed catalytic reactor was investigated by the Bureau of Mines. The reduction rate of sulfur dioxide with carbon monoxide was significantly dependent upon the iron and alumina content of the mixed catalyst. Maximum catalytic activity was obtained with about 40 percent iron-alumina mixture with a nominal gas mixture of 10 percent carbon monoxide, 5 percent sulfur dioxide, and the balance nitrogen. The synergistic effect of this catalyst mixture was explained by a dual reaction site mechanism, with both iron and alumina augmenting their specific sites at their interparticle contacts. The catalytic activity also increased with decreasing catalyst pellet size. With O.7-mm pellets, the entire pellet appeared to be catalytically active in a 2-gram catalyst bed. The apparent activation energy of the reaction was 18.3 kcal per mole in the temperature range of 350° to 600° C. Carbonyl sulfide (COS) was produced by the interaction of carbon monoxide and sulfur. The amount decreased with decreasing CO concentration. The ratio of COS formed per SO2 removed reached a maximum at about 400° C. The reaction rate appeared to be independent of S02 concentration in the range of 0.2 to 16 percent. The rate, however, increased directly with the CO concentration in the range of 5 to 20 percent. The presence of CO2 (<15 percent) had no appreciable effect on the rate. However, not over 0.5 percent oxygen could be tolerated. This method appears feasible for removing S02 from waste gas if the oxygen is removed prior to the catalytic S02 reduction process.

Jan 1, 1971

By M. J. Ferrante

The Bureau of Mines investigated the applicability of the freeze-drying technique for preparing dispersion-strengthened tungsten powders suitable for conversion by powder metallurgy into materials which might have improved high-temperature strength. Extruded rods from compacts of tungsten-5 vol pct thoria had at 1,650° C a tensile strength of 30,300 psi and a 10-hour stress-rupture strength of 12,700 psi, These are slightly below those measured for swaged rods of commercial tungsten-3.7 vol pct thoria. Only those tungsten-thoria dispersions containing a stoichiometric deficiency of oxygen yielded a significant strengthening effect. A low-melting eutectic formed in extruded tungsten dispersions containing either zirconia or yttria, which caused a lowering of the tensile strengths. These tensile strengths were only slightly higher than strengths of elemental tungsten made from commercial powder having a particle size of 2.4 microns (Fisher subsieve). Sheet made from this commercial tungsten had a slightly higher tensile strength than tungsten made by freeze drying, but the freeze-dried tungsten sheet had a lower recrystallization temperature, a lower ductile-to-brittle transition temperature, and a higher purity.

Jan 1, 1971