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By L Casari

A study of samples from three sectors of the mine, which was worked from Roman times to 1991, revealed different textures, mineral associations and distributions of trace elements in the sulphides. In the last decade before closure, grades of sphalerite concentrate were in the range 51.67-53.30% Zn and 2.21-2.86% Pb and of galena concentrate 69.43-71.62% Pb and 4.70-8.36% Zn, while the estimated by-product germanium content of sphalerite concentrates sold was 300-400 g/t. Passing the different run-of-mine materials through the same concentrator flowsheet produced middlings and tailings during the preconcentration processing. Separate and alternative treatment of run-of-mine products would have yielded improved recoveries of sphalerite and galena and better values of by-product germanium and cadmium

Jun 18, 1905

By Z. H. Khan, A. K. Saha, D. D. Akerkar

The possibility of extracting nickel from a low-iron, highly siliceous nickel ore of Indian origin using roast reduction followed by an ammonia leaching process has been examined. The ore used in the investigation contained 0.82 wt% Ni, 6.20 wt% Fe3O4, 12.04 wt% MgO and 60 wt% SiO2. Phase changes in the constituent minerals on heating were studied by differential thermal analysis which revealed endothermic peaks at 110 and 695 degrees C and an exothermic peak at 810 degrees C. Significant process variables in studies of roast reduction include the amount of reductant, the temperature of reduction and chemical kinetics. Maximum nickel extraction was achieved by reducing the ore with 10 wt% fuel oil at 750 degrees C. The reduced ore was given a preconditioning treatment in concentrated ammonium hydroxide solution to oxidise most of the metallic iron and was then leached in aqueous ammoniacal solution at ambient temperature to dissolve nickel. This gives 88.5% extraction of nickel as soluble ammine complexes.

Jan 4, 1992

By T. A. A. Quarm

The concept of a continuous zinc smelting process which employs submerged combustion of coal char for both heating and reduction is described. An estimate of the results of smelting a marmatitic zinc concentrate indicates that both the operating and construction costs would be lower than those incurred in processes now in commercial operation. The results of smelting a complex zinc-copper concentrate are also estimated, but no simple commercial process exists with which they can be compared

Dec 1, 1971

By Winmill T. F.

(Paper presented at the Institution of Mining Engineers' general meeting held in London on 8th June 1916.) The conclusions reached in this paper may be summarized briefly as follows: (1) The method of estimating moisture in coal by determining the loss in weight of a sample heated to 105°-110° Cent, in an air-bath for an hour is untrustworthy, the results so obtained being too low. (2) Dried coal has a very considerable power of absorbing moisture, and a sample, after being dried, must be protected instantly if it is to remain free from moisture. (3) A fairly accurate estimation may be made by heating the coal in a current of dry air at 105° to 110° Cent., and collecting the moisture evolved. (4) In cases in which it is proposed to use the dried coal for any further experiments, the drying must be done in the absence of oxygen, and this can be done simply and quickly by the vacuum method now described

Dec 1, 1916

By M. W. Davies, P. N. Smith

The activity of MnO has been measured in the system CaF2-MnO at 1773 and 1873 K and in the system CaF2-CaO-MnO at 1773 K by the method of equilibration with platinum. Large positive deviations from ideal solution laws have been found, but these became less as the lime content rose. The loss of a volatile component made activity measurements impossible in the CaF2-AI203-MnO system, but the boundaries of a two-liquid region have been measured at 1773 K.

Dec 1, 1971

By Zhengya Lu, F. Lawson

The surface tensions of lead and lead alloys with very low concentrations of silver, tin and copper were measured by the sessile-drop method. The enrichment of silver and tin in the surface of liquid lead alloys at temperatures close to the freezing-point of lead was confirmed, which may explain the unusual behaviour of small amounts of silver and tin in lead bulllion during the sulphur-drossing step of the refining process. From the limited data available copper also appears to concentrate at the surface of the liquid alloy

Dec 1, 1991

By M. L. Schmulian

"The Windarra nickel deposits display many of the characteristics that typify Archaean volcanic peridotite-associated nickel sulphide ores of Western Australia. The Fe-Ni-Cu sulphide mineralization, which comprises dominantly disseminated sulphides, occurs at the base of a differentiated ultramafic volcanic pile grading upwards from massive meta-peridotitic flows to thin, locally spinifex-textured meta-picritic units. The entire mafic-ultramafic belt has been subjected to mid-amphibolite- facies metamorphism. The ore-bearing ultramafic is immediately underlain by dominantly sulphide-facies banded iron formation (BIF), which commonly contains nickel sulphides adjacent to its contact with mineralized ultramafic. BIF-hosted ores are formed both by physical remobilization of ultramafic-hosted sulphides and by migration of Ni and Cu into pre-existing iron sulphides.At Mt. Windarra the mineralization comprises eight steeply dipping, steeply plunging elongate oreshoots, which display a marked parallelism with major and minor fold structures in the underlying BIF. Seven of the shoots occur at or close to the base of the ultramafic pile, and are hosted by at least three overlapping flows. The zone of overlap occurs at the northern end of each flow, where picritic ultramafic, representing a dominantly liquid portion of the flow, occupies the basal contact. A gross south- north ultramafic flow direction is inferred. The eighth shoot occurs in a stratigraphically higher position within the ultramafic sequence.At South Windarra at least two overlapping mineralized flows occupy the basal contact, the ore zone having a strike extent three to four times its downdip extent. There is no obvious structural control to the mineralization."

Jan 1, 1984

By P. Danson, D. A. White, S. Bashir

Composite ion exchange materials made of SnO2, TiO2 and MnO2 can be used to remove radioactive contaminants from nuclear waste streams. In several cases their selectivity and capacity are enhanced by mixing hydrous silica into the matrix. MnO2-SiO2 materials are especially useful for a number of reasons, such as their selection of heavy elements over caesium. Distribution constants and determinations of exchange capacities show that in many instances the properties of the composites are better than those of the oxides alone, while the presence of a chelating agent has been found to reduce the uptake of nuclides considerably. Methods are being developed for the bulk manufacture of the materials. Further work on sorption mechanisms is required to explain anomalous results, particularly the variation in exchange capacity for different elements and the ability of the oxides to sorb colloidal material in alkaline solution.

Jan 8, 1992

By N. T. Moxon, D. Mead, S. B. Richardson

A laboratory and theoretical study of air decks was carried out to assess the effects of the size and location of air-decks on fragmentation. The degree of fragmentation was found to depend on both factors. As the size of the air-deck increases the degree of fragmentation is reduced relative to a full column charge. However, the reduction is relatively small until a critical size is exceeded. The critical size depends on the strength and structure of the surrounding material. A critical air-deck length of 30-35% of the original explosive column was determined for the model materials used in the study. A theoretical explanation of the results was derived based on pressure decay rate relationships. The location of the air-deck also influences fragmentation. The interaction and oscillation of the two shock fronts from the top and bottom charges mean that mid-column air-decks produce better fragmentation for the same air-deck length and explosive loading as top-column or bottom-column air-decks.

Jan 4, 1993

By J. E. Rouse, D. L. Buchanan

"During the emplacement of the Bushveld Complex in the Potgietersrus area magma reacted with the original floor rocks— Archaean granite or Malmani dolomite and overlying Penge handed ironstone or sedimentary rocks of the Pretoria Series. The complex sequence of sulphide-rich mafic rocks that formed along the contact is known as the Platreef. Associated with the sul­ phide mineralization are important concentrations of platinum-group metals, copper and nickel. Xenoliths of Malmani dolo­ mite have been incorporated into the Platreef and previous work has suggested that anhydrite is likely to have been present in the dolomite. The sedimentarv-derived sulphur thus introduced into the magma exercised an important control on the forma­ tion of the sulphides.Petrographic studies on the Platreef rocks from the Tweefontein area indicate that the original magma reacted with the banded ironstone to form iron-rich pyroxenites. In the Turfspruit area, to the south, the footwall rocks consist of sediments of the Timeball Hill Series. Original argillaceous rocks have been metamorphosed to cordierite-, corundum- and spinel-bearing hornfelses. Graphite was present in the contact zone in both the Tweefontein and Turfspruit areas. Anhydrite-bearing hornfels rocks are also present on Turfspruit.The Platreef rocks that overlie the corundum- and spinel-bearing hornfelses on Turfspruit are peridotitie, and pyroxenites are present in areas underlain by cordierite-bearing hornfels. The absence of orthopyroxene in the peridotite is probably indicative of low silica activity in the original magma. The pyroxenites have, however, undergone silica contamination from the underlying more siliceous cordierite hornfels.Carbon isotope studies indicate that the graphite in the Tweefontein and Turfspruit samples represents organic material orig­ inally associated with the footwall sediments. Sulphur isotope determinations on the anhydrite-bearing floor rocks indicate that this phase is clearly of sedimentary origin and was probably derived from an evaporitic unit within the carbonate sequence. This provides firm support for a model of ore genesis that involved the introduction of additional sulphur into the Bushveld magma. Isotope studies on sulphides associated with the banded ironstone and graphite indicate that these units were not the source of additional sulphur. Experimental studies predict, however, that a magma contaminated with iron- and carbon-rich material would have a high sulphur-carrying capacity. Where additional sulphur is available the magma would achieve saturation early in its crystallization history and precipitate an immiscible sulphide phase. Experimental work has also shown that sulphide precipi­ tation can be triggered by the introduction of salic material into a magma close to sulphur saturation. This mechanism probably played a role in the control of the sulphide mineralization in the Turfspruit area."

Jan 1, 1984

By E R. Hassall

Discussiong the importance of minerals and mining, impacts on the environment and remediation, and the need to foster interest in science among young people.

Jan 8, 1997

By A. L. W. Lips, B. P. J. Stevens, T. J. R. Bareley, E. Rothery, S. H. White

B.P.J. Stevens contributes a further response to the authors' earlier lengthy reply regarding their paper published in Trans.IMM B, vol.104, 1995, p.B1-B17, contending that despite the positive contribution clarifying their interpretations they perpetrate some misquotations, attempt to rewrite history and fail to understand the New South Wales Geological Survey's stratigraphic interpretation of the Broken Hill area. The paper's authors, in their further response, robustly defend their views, insisting that Stevens tends to misquote or take out of context what they have written and reiterating their findings that Zn is tectonically stacked above Pb at the north end of the orebody, that the written development of the stratigraphic interpretation is as they have stated, that shearing has attenuated or removed fold limbs in the Broken Hill block and that the 1:100 000 stratigraphic map reveals that magnetic anomalies are oblique to and truncated by the Geological Survey's interpreted stratigraphic boundaries

Jun 19, 1905

By E. A. C. Chamberlain

New techniques for the continuous sampling and analysis of mine air are expected to replace traditional methods used for the early detection of spontaneous combustion. It has been established that the rate of evolution of carbon monoxide is the earliest indicator of incipient spontaneous combustion. Two methods of continuous monitoring of this gas are available and are now in use in the UK collieries. The first is the UNOR infra-red gas analyser, which is flameproof and may be used underground; the second is a system of tube bundles, which permits air to be drawn from any critical point in a colliery and analysed on the surface. Each system has its advantages and disadvantages but both provide the colliery manager with far more information on the condition of his pit than could previously be obtained by spot sampling and laboratory analysis. This paper describes the two systems presently in use and assesses likely future developments.

May 23, 1905

By T. Piirainen, T. Alapieti

"The Koillismaa layered igneous complex is the result of igneous activity that occurred 2436±5 m.y. ago. Its crystallization took place in three separate but connected magma chambers, the total volume of which is estimated at more than 2000 km'. These chambers were located partly in a feeder system within Archaean granitoids and partly in an unconformity between these grani­ toids and Early Proterozoic supracrustal rocks. The composition of the parental magma that initially filled the chambers is thought to have been that of a relatively MgO-rich tholeiite. Sulphides and platinum-group minerals are mainly concentrated in the marginal series of the western part, where they are encountered over a distance of 25 km. This marginal series is an originally nearly horizontal series of rock types that displays a reversed differentiation trend, grading inwards from gabbroic to ultramafic rocks, followed bv rocks of the layered series. The chilled margin is not encountered anywhere in its original position at the contact, probably as a consequence of magmatic erosion, but remnants are to be found in the form of elongated xenoliths. Partly melted siliceous fragments from gneissic country rock typical of the lower part of the marginal series indicate pronounced contamination.Chalcopyrite, pentlandite and pyrrhotite±pyrite are the predominant sulphides. The accessory sulphide minerals include covellite, violarite, marcasite, mackinawite, sphalerite and argentian pentlandite. Platinum-group minerals are represented by froodite, michenerite, merenskyite and sperrylite. Other accessories that have been identified are electrum and native copper and gold. The mean of the Cu/(Cu+Ni) ratio in the mineralizations is 0.67 and Pt/(Pt+Pd) 0.31.It is suggested that the sulphide phase was formed in the marginal series as the solubility of sulphur in the basic magma was lowered by contamination, possibly assisted by some other factors. The sulphur isotope data support the juvenile origin of the sulphur."

Jan 1, 1984

By D. F. Ball, P. R. Dawson, J. T. Fitton

Report of discussion at December, 1970, IMM general meeting (Chairman: M. J. Cahalan, President) and contributed remarks on the paper published in Transactions/Section C (Mineral Processing & Extractive Metallurgy), vol. 79, September, 1970, pp. C189-96, plus the authors' replies. Contributors included Cohen E., Hope B., Wasse D.G., Shakespeare A.G., Burwood D.S., Jones H.A., Dartnell J., Carter G.C., Henderson T.A., Relf G. and Clark S.W.

Dec 1, 1971

By Ruddle R. W.

Solid mattes are generally held to be either (a) eutectiferous mixtures of the component sulphides Cu2S and FeS or (b) mixtures of complex sulphides. This chapter shows that liquid mattes consist essentially of a homogeneous phase in which iron, copper and sulphur are present. The amount of sulphur is generally less than that required to account for all the metals as stoichiometric sulphides; mattes cannot therefore be regarded as mixtures of FeS and Cu2S. Some iron oxide may be dissolved in the sulphide phase and magnetite is often present as a second phase. If the sulphur content of the matte is reduced the composition enters the miscibility gap in the ternary system and either an iron- or copper-rich solution (depending upon the composition of the matte) separates as a new phase. On solidification any one of four phases (iron, copper, Cu2S and FeS solid solutions) may crystallize as primaries. The remainder of the matte solidifies as a ternary eutectic. It is possible that iron oxides enter into this eutectic. Knowledge of the ternary Cu-Fe-S system is far from complete and nothing is known of the quaternary system Cu-Fe-S-O

Jan 1, 1953

By L. G. Billington

"The Agnew nickel deposit occurs in a major linear greenstone belt in the Archaean Eastern Goldfields Province of Western Australia, and has been subjected to mid-amphibolite facies nietamorphism of dynamic style. The largest dunitic ultramafic body in the Perseverance Block is host to the bulk of the nickel mineralization. The Perseverance Ultramafic is mineralogically zoned and has an embayed western margin against a mixed metasedimentarv-metavolcanic wallrock sequence.Three categories of nickel sulphide mineralization are concentrated on this western margin at the thickest part of the ultramafic exposure. Massive sulphides characteristically occur as contact mineralization, internal mineralization and as remobilized concentrations in vein form structures. Disseminated ore constitutes the largest volume of mineralized materials in the deposit and occurs in three separate shoots in en-echelon relation. Weakly mineralized 'cloud sulphide' zones surround and envelop the shoots and persist much further along strike. In the upper mine levels the shoots are truncated by a shear or crush zone, which inhibits geological knowledge to the south but marks a major fundamental structural break.Most of the ore types have suffered supergene alteration and there is a complex variable distribution of the mineralogical facies. The ore types have been metamorphically retextured, but the oreshoots can be characterized by their Ni tenor and some chemical ratios. S/Se values, PGF. and precious metal values are distinctly different from those of other nickel sulphide ores extracted.Despite intense structural and metamorphic modification of the mineralizations, some features support an original magmatic derivation for the sulphides. These include the localization of massive sulphide ore types on one marginal contact within an emhayment structure, the general distribution of disseminated mineralizations located immediately above the massive sulphides and the Ni/Cu, Ni/Co, Fe/Ni ratios of the oreshoots being similar to those of deposits that typify the intrusive dunite- associated class of nickel sulphide deposit. Varying S/Ni ratios between different shoots suggest a revision of the single magmatic intrusion model in favour of a changing composition between successive magmatic episodes."

Jan 1, 1984

By L. T. Matthews, C. E. Loo, R. P. Williams

The behaviour of iron ores and fluxes in the high temperature zone of a sintering bed is extremely complex. Following a review of current knowledge, an attempt is made to define relevant terminology to describe the processes that occur in this part of the bed. A deformation temperature is used to quantify the initial formation of melt, which is produced predominantly by reactions between fine particles in the sinter mix. The subsequent assimilation of larger particles is considered to depend on the reactivity of the melt and the assimilation resistance of these particles. Novel laboratory experimental techniques are used to quantify these parameters. Results demonstrate that the properties of the raw materials used have an extremely important influence on the initial processes of melt formation and assimilation and also on the nature of the sintering reactions and sinter-bonding phases.

Jan 4, 1992

By J. Ostwald, L. T. Matthews, C. E. Loo

Australia has large reserves of pisolitic limonite. Mining recently commenced on the Yandicoogina deposit to produce a high-grade sintering ore. The ore contains about 10 wt% combined water and simulated sintering temperature profiles indicate that progressive dehydration of ore particles occurs in the temperature range 300-700 degrees C. Studies by optical microscopy show that although the dehyrdrated ore particles contain numerous cracks, there is no change in the microstructure of the ore because topotactic transformation to haematite results in the formation of compact masses of very fine-grained haematite microcrysts. When the ore is held at around 1 200 degrees C for 1 min significant recrystallisation of these microcrysts occurs, resulting in the formation of optically visible, micrometre sized haematite crystallites. Studies to simulate the behaviour of ore particles during sintering (as nuclear particles surrounded by a standard adhering fines mixture) show that the recrystallisation process occurs much earlier at temperatures of about 900 degrees C. Further studies indicate that CaO in the adhering fines mixture enhances the recrystallisation of the ore nuclei. The results of the investigation indicate that the pseudo-relict haematite in sinters produced from ore blends that contain significant levels of pisolitic limonite consists of dehydrated goethite that has undergone significant recrystallisation and grain growth, a phenomenon that is facilitated by the presence of lime derived from the sintering melt.

Jan 12, 1992

By D. V. Venugopal, W. W. Gardiner

Spessartine-quartz rocks are manganiferous sedimentary rocks rich in spessartine and quartz which occur in north-central New Brunswick. They represent a recrystallised manganiferous siltstone/chert that is contained in or associated with red manganiferous siltstone (RMS) units. The spessartine-quartz rocks and RMS form part of an Ordovician volcanic and sedimentary succession within the Appalachian-Caledonian orogen which hosts numerous massive sulphides and polymetallic vein deposits. The New Brunswick spessartine-quartz rocks are spatially and temporally associated with stratiform base-metal, precious metal and hydrothermal tin-tungsten deposits. This suggests that spessartine-bearing lithologies and zones can be useful in predictive metallogeny and for the understanding of the stratigraphy and palaeographic setting of the early Palaeozoic rocks of the Appalachian-Caledonian orogen.

Jan 12, 1992