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By Philippe Angers

This article analyzes the social acceptability process of a mining project located in an existing city. It will explore how the principles of sustainable development have been integrated in the project of the Canadian Malartic open pit mine held by the Osisko Mining Corporation, and the corporate social responsibility (CSR) initiatives proposed to strengthen the social acceptability of the project. This mine is located on the ancient south quarter of Malartic and has required the displacement of hundred of houses and five institutions. The location and the inherent social impacts generated by the relocation of the citizens of the south quarter makes this case particularly interesting to understand social dynamics in an era of environmental consciousness. These major constraints of the mine generate high expectations within the urban population with regard to the social and economic benefits it will receive from the project. In a context where society demands higher CSR from the corporation, Osisko is closely followed regarding their actions toward the sustainable development principles to see if they respect the environment and the desires of the community. From the beginning, the company had to be a model of sustainable development in various aspects reflected by the manifold interest of the population. To understand the endeavor made by the company to fulfill the demand of CSR, we will analyze how the company understood sustainable development principles and what CSR initiatives Osisko company put forward. We will explore the involvement of the company in various social aspects like employment, employee satisfaction, and the level of commitment to non-discrimination policy in employment, notably with the native populations. We will also take a closer look at the relationship built by the company with the community and the level of commitment with the various stakeholders of the community. In this way, we will be able to seize the level of involvement of the company in the fulfillment of the principles of sustainable development toward a higher CSR, and to specify the trajectory adopted to build social acceptance.

Aug 1, 2013

By R. Bashir, J. F. Hatley

ABSTRACT Northern Saskatchewan boasts some of the world’s largest known high-grade uranium deposits. The successful mining of these deposits cannot be accomplished without overcoming technical challenges, however, which include high grade of the uranium ore, specialized mining methods to deal with groundwater at high pressures, and poor ground conditions. This paper discusses the various mechanisms of inflows at three of Cameco Corporation’s sites in northern Saskatchewan. The risk of inflows is quantified in terms of unique challenges due to hydrogeological conditions, rock mass integrity, and uncertainty in geological conditions. Strategies in the case of an inflow are also briefly described.

Jan 1, 2013

By J. D. Jones

The geographic occurrence of economic mineral deposits presents a variety of problems in modern tailings disposal operations. This paper presents case histories in several sectors of the mineral industry as well as the several stages of operations planning required for new designs, system expansion, reactivation of abandoned systems and upgrading to present environmental standards.

Jan 1, 1978

By Magella Pelletier

"IntroductionDepuis une vingtaine d'année, les nombreux travaux de géochimie effectués par l'industrie privée et les milieux gouvemementaux ont permis:• de découvrir de nombreuses zones minéralisées a valeur économique;• d'identifier et de vérifier certains patrons de dispersion géochimique au-dessu s de secteurs minéralises déjà connus;• de favoriser le développernent des techniques analytiques;• de forcer le développement d'une mise en carte des résultats d'analyse, qui soit plus adéquat afin de permettre une meilleure interprétation géochimique.L'une de ces cartes géochimiques qui permet le mieux de mettre en valeur les données analytiques et qui fut instaurée au debut des années 80, est la carte d'interprétation géochimique par pondération.Cette carte numérique semi-quantitative, qui est construite à partir des données de base et de l'importance des éléments indicateurs pour une substance donnée, permet d'identifier et de définir des zones possédants de fortes probabilités pour la recherché de sources minéralisées."

Jan 1, 1987

By Frank Cappuccitti, James A. Finch, Stéphanie Gélinas

"A colorimetric technique, originally developed for methyl iso butyl carbinol (MIBC) based on the Komarowsky reaction, has been extended to a wide range of common mineral flotation frothers. The procedure, which is briefly described, is shown suited to on-site determinations in a campaign at Kennecott Utah Copper Copperton Concentrator (Rio Tinto). Some observations are described, including: frother (MIBC) concentration evolution down a bank, frother distribution between pulp and froth phases, and loss of frother over time due to adsorption on certain minerals. A possible interference with a fuel oil addition was overcome. MIBC in recycle water was also measured.The ability to monitor frother easily will help interpret gas dispersion behaviour and should permit further optimization of flotation cell hydrodynamics and chemistry. The capability to directly measure should help optimize the type, amount and location of frother addition, and to assess frother recycled with reclaim process water.INTRODUCTIONOwing to the lack of analytical methods, the task of determining frother concentration in plant flotation circuits is not routinely performed. Industrial sites seldom outsource analyses that are both costly and inconvenient, due to the necessity of shipping freeze-dried samples to remote testing facilities. A more direct colorimetric method has recently been demonstrated for the laboratory characterization of common industrial frothers (Gélinas and Finch, 2004). The approach, based on the Komarowsky reaction (Penniman et al., 1936; Coles et al., 1942; Duke, 1947), was previously described by Parkhomovski et al. (1976) for methyl iso butyl carbinol (MIBC). The reaction involves the interaction of the OH group of a higher alcohol, concentrated sulphuric acid, and salicylaldehyde, to yield coloured solutions with intensities that can be analyzed by UV-visible spectrophotometry."

Jan 1, 2005

By Fred C. Delabbio

The successful implementation of a new technology in an underground production mine requires many challenges to be overcome. These challenges include mine hardening of new technology, mitigation of safety risks and hazards, mine operation support, and technology transfer to mine staff. In the end, the majority of these challenges relate to the human aspects of implementation. The approach selected to overcome these challenges must be customized and appropriate for each unique situation. This paper outlines the approach used to address these challenges as part of successful implementation and resulting demonstration of the hydrogen fuel cell locomotive at the Placer Dome (CLA) Limited, Campbell Mine. This technology demonstration at Campbell Mine is critical for determining technical, regulatory and implementation aspects to be incorporated into future fuel cell prototypes such as the LHD project.

May 1, 2003

By A. van As, J. McGaughey, M. J. Mol, R. Tosen

Geotechnical monitoring is a key element of the successful management of a block cave mine. The interrelationships between production and various monitoring datasets are often not realized due to a lack of data integration and appropriate 3D visualization. Timely delivery of information to ensure best cave management practices is only possible with an integrated cave management system. At Rio Tinto, a state-of-the-art cave management system (CaveCAD) has been designed and developed in cooperation with Mira Geoscience to integrate and analyze vast datasets and report this as instructive information regarding the current \u201cstatus\u201d of the cave.

Jan 1, 2014

By J. R. Tickner

"Gold is conventionally analyzed using fire-assay or other destructive chemical methods that impose significant sample preparation, OH&S, and skilled labour requirements. Developed over the past 15 years by the CSIRO, PhotonAssay provides a new approach. A high intensity, high-energy x-ray source is used to activate atoms of gold and other elements in bulk mineral samples. The resulting activity is counted to automatically, accurately and rapidly determine metal grade. Samples weighing 0.5–1.0 kg can be measured in a few minutes with minimal preparation. As the method is matrix-agnostic, traditionally hard-to-assay materials such as highly refractory ores, carbon pulps and copper concentrates require no special treatment. We present the status of commercial PhotonAssay systems being developed by Chrysos Corporation. The first unit with a throughput of up to 80 samples per hour is to be deployed in an Australian assay laboratory in late 2017; smaller systems suitable for providing real-time assay directly at the mine-site will be progressively rolled out from mid-2018. Performance results from extensive testing using both mine-sourced and standard reference materials are presented, demonstrating the sensitivity and accuracy of the method. Implications for replacing conventional gold assay in exploration, mining and processing operations are discussed.INTRODUCTION Accurate methods for assaying ore grade are essential throughout the exploration, mining and mineral processing value chain. The discovery and evaluation of new ore deposits, reserve and resource definition, mine operations planning, ore processing, metal accounting and product quality evaluation all rely on accurate measurement of the valuable metal content of bulk materials. The analysis of gold presents particular challenges, stemming from the very low concentrations at which commercial operations run (often part-per-million (ppm), or equivalently one gram-per-tonne levels or below), and the highly heterogeneous nature of many gold deposits. These challenges mean that any analytical method must have high sensitivity and be capable of measuring large-mass samples. The most widely used quantitative analytical method for gold is fire-assay (Hoffman, Clark and Yeager 1998). An initial ore sample typically weighing several kilograms is dried, crushed and pulverized to allow a small sub-sample (10–50 g is common) to be representatively drawn. The sub-sample is mixed with flux, litharge (lead oxide), a reducing compound and other reagents. The mixture is fired at a temperature of 1000–1200°C until molten. After cooling, the slag is removed and the lead button containing any gold present in the sample is remelted in a porous cupel. The lead is absorbed into the cupel, leaving a gold prill which is either weighed directly, or dissolved in acid and analysed via atomic absorption spectroscopy (AAS) or inductively coupled plasma spectroscopy (ICP or ICP/MS)."

Jan 1, 2017

By I. A. Menshikh, S. A. Kotov, N. L. Shinkarkin

All the cycle for conversion of natural and reprocessed uranium of ROSATOM’s “TVEL” Fuel Company is concentrated at the Siberian Chemical Plant. Conversion capacities are located on two sites, i.e. the Radiochemical Plant, which refines feedstock, and the Conversion Plant, which produces uranium oxides and uranium hexafluoride. Liquid radioactive waste arising in the process, after pretreatment, is transferred to a dedicated national operator for underground disposal. Environmental strategies pursued by the Fuel Company involve the introduction of process solutions intended to eliminate liquid radioactive waste and convert it into a solid phase. In the 5–7 years coming, work will be performed to refurbish and upgrade conversion facilities of the Siberian Chemical Plant that will principally change its radioactive waste management scheme. This paper describes the current waste management scheme and sets out planned schemes for management of natural and reprocessed uranium waste, which will be implemented in the refurbishment of conversion facilities of the Siberian Chemical Plant. The new technologies for the management of liquid radioactive waste from uranium conversion described in the present paper have an undeniable advantage over the current technology mainly due to significantly less environmental harm.

Jan 1, 2020

By J. G. Bennett

Coal consumption has increased globally by 57% over the last ten years. Underground mining typically provides coal of the highest calorific value and accounts for the greatest proportion of production. Despite a negative environmental image and indeed impact, this industry appears likely to thrive on the global scale for many years to come. Such mining consumes large amounts of electricity with implications for carbon dioxide emission at power plants and emits substantial quantities of the powerful greenhouse gas methane. In response to this significant carbon footprint, the European Union has funded research to examine the potential for a range of improvement technologies in a project entitled Low Carbon Mine Site Energy Initiatives (LOWCARB). Coal properties related to seams and mines, together with longwall characteristics, provide the basis for research into modelling optimally efficient methane drainage with a view to assisting mining as well as maximising electricity generation at surface and hence oxidation of the methane. Possible systems for the oxidation of very low concentration methane in ventilation air, which contributes the greatest greenhouse gas impact due to the volumes emitted, have been studied and modelled. Simulation and investigation of intelligent optimisation of electricity demand patterns provide the basis for reducing the demand peaks at mines and hence the cost and ultimately the carbon footprint of a mine, while specific investigations have been undertaken into ventilation efficiency at an unusually challenging mine and simulation of mine water pumping in order to develop an innovative method to monitor pumping systems efficiency. For post-mining use, the potential of disused shafts for compressed air energy storage to improve the operation of future electricity grids with high renewable energy penetration by reducing peak generation capacity requirements has been studied. While underground coal mining will always by definition be related to a significant carbon footprint, this paper provides an overview of a set of initiatives that can make a positive environmental impact while controlling costs across a huge global industry.

Aug 1, 2013

By L. van Hijfte, A. Piché

"Drilling and blasting are fundamental operations in the mining cycle and constitute an important component of the mining costs. Problems associated with improper drilling and blasting practices can create losses of several millions of dollars per year. For this reason, a Blasting Technology program was initiated in 1984 at the Noranda Technology Centre (NTC). In this paper, advances made at NTC in drill and blast technology are reviewed. Impacts of drilling and basting for Noranda are assessed in terms of dilution and ore losses. Future challenges are addressed. IntroductionUp to 1997, Noranda was a diversified natural resources company that operated in three sectors: mining and metallurgy, forest products, and oil and gas. The company employs more than 33 000 people in operations and sales offices around the world. Today, Noranda has returned to its roots in mining and metallurgy. The new vision of Noranda is to be dedicated to the responsible and profitable development of mineral resources around the world for the benefit of its shareholders. In so doing, Noranda will continue to be deeply committed to the environment, health, workplace safety, cost competitiveness and return on capital. Technology is an integral part of Noranda’s success strategies. For this reason, the Noranda Technology Centre, formerly known as Noranda Research Centre, was founded in 1963. Since then, it has undergone four expansion phases to keep up with the increasing needs of the businesses. Today, NTC employs more than 220 specialists who work in partnership with different Noranda companies to identify, develop, and transfer technology to the operations, as well as to explore new sectors of activity."

Jan 1, 2000

By J. Girard, V. Aubé, M. Barakate, S. Bellec, M. R. Eddahabi, Y. Chaik, M. Deshaies

"The activated carbon used in the carbon-in-leach (CIL) process to absorb gold is subject to breakage. This carbon breakage can be minimized, but it will always be necessary to deal with fine carbon particles, known as carbon fines. These fines contain a significant amount of gold and mining operations generally struggle with the treatment of this product. Since IAMGOLD’s Essakane mine is located in Burkina Faso, shipping carbon fines out of the country was not considered a viable solution due to the logistical burden and legal procedures in place. A benchmarking study demonstrated the complexity of treating carbon fines on site. IAMGOLD partnered with the host government to find an innovative approach to economically recover the gold locked in these fines. This paper describes the new circuits commissioned in July 2016 built to improve carbon fines collection, incinerate the carbon fines and leach the gold in the ashes produced by incineration. These new circuits successfully demonstrate that it is possible to extract more than 94% of the gold content in the carbon fines. This is profitable for the company as it improves the overall mill recovery rate by 1.0% to 1.5% and significantly decreases gold inventory build-up on site.INTRODUCTION The activated carbon used in the carbon-in-leach (CIL) to absorb gold is subject to breakage. This breakage can occur in the CIL tanks, the stripping circuit, the regeneration process or anywhere throughout the pumping and handling processes of carbon through the circuit. Fine carbon particles are invariably created and, because of their small size, present a large specific surface which favors gold absorption (Hilsher et al., 2014). At the very beginning of operations at Essakane, the carbon fines were recovered by means of a thickener and a filter press, but the circuit was undersized and inefficient. Subsequently, a decantation basin was used to settle the fines before the thickener. The settled fines were shovelled from the basin into bags. All these bags were stored in the backyard of the plant. The average tonnage of carbon fines recovered monthly was 23.5 tons with a gold grade at 1938 g/t."

Jan 1, 2017

By CIM Mineral Resource, Mineral Reserve Committee

These Leading Practice Guidelines for Mineral Processing (LPGMP) were prepared by the Sub-Committee on Leading Practice Guidelines for Mineral Processing. The Sub-Committee reports to the Executive Committee of the Canadian Mineral Processors (CMP) which is a Technical Society of the Canadian Institute of Mining, Metallurgy, and Petroleum (CIM) and incorporates those members of the CIM who are concerned with the processing of mineral deposits. The LPGMP covers the involvement of mineral processing professionals, referred to as Practitioners in this document, in providing inputs to the estimation of Mineral Resources and Mineral Reserves and providing technical content for internal reports as well as public reports on mineral projects as required under National Instrument 43-101 Standards of Disclosure for Mineral Projects (NI 43-101). The LPGMP supplement the CIM Exploration Practice Guidelines (2018) and the CIM Estimation of Mineral Resources and Mineral Reserves Practice Guidelines (2019) which are referenced in Companion Policy 43-101CP to NI 43-101 and recognized internationally. The LPGMP consist of 3 sections: • Principles of Process Support in Mineral Resources and Mineral Reserves Estimation; • Appendix A – Use of Supporting Studies in Process Evaluation and Assessment for NI 43-101 Documentation; • Appendix B – Glossary of Terms Relevant to the LPGMP. The LPGMP deal primarily with the description of leading practice as it applies to the mineral processing and extraction of base metals, precious metals, and other mineral products by the application of mineral processing technology. Other commodities may be considered with future updates of these guidelines. It is expected that this is a ‘living’ document and that these guidelines will develop in the future to address the requirements of the mining industry, investing public, and mining professionals involved. Clarifications and changes to these guidelines will be done under the guidance of the Executive Committee of the CMP.

Nov 25, 2022

By E. Talebi, P. Roghanchi

"This study aims to discuss personal and behavioral parameters contributing to heat-related accidents. To study the prevention approaches, it is essential to look at the various factors at the individual, management, and industrial levels. Qualitative risk analysis methods are used based on the public data in the USA to find the impact of the environmental and behavioral parameters on the heat stress and heat strain of mine workers. The effects of individual factors such as worker experience, age, fitness, lifestyle, acclimation, and more are illustrated. The significance of factors such as the roles of the mine management and regulatory agencies are addressed.INTRODUCTIONOccupational hazards in mining industry endanger the health and safety of the workers and productivity loss for mining companies. Among those hazards is the exposure to excessive heat that has adverse effects on the health of mine workers. The intensity of heat load is a significant factor in fatal and non-fatal heat-related accidents. Severe environmental conditions combined with a high level of activity in the mining industry increases the vulnerability of individuals to health and safety hazards (Ngwenya, Oosthuizen, Cross, Frimpong, & Chaibva, 2018). Lack of regulations and legislation addressing the heat issue in the mining industry (i.e., underground and open pit mines, processing plants) also raises widespread concerns.Along the climate change, various sources contribute to the overall heat load at a mine site (Hanna, Kjellstrom, Bennett, & Dear, 2011; Kjellstrom, Lemke, Hyatt, & Otto, 2014). In underground mines, the majority of heat comes from different sources such as geothermal gradient, equipment, auto compression, groundwater, and blasting (Maurya, Karena, Vardhan, Aruna, & Raj, 2015). On the surface, however, the majority of heat load can be sourced to solar energy. The exposure to excessive heat might result in heat-related illnesses, fatigue and fainting, loss of concentration, performance reduction, and production loss (Kocsis & Sunkpal, 2017; Roghanchi, 2017). The severity of the effects depends on duration and level of exposure and the response of an individual to heat stress. The response of an individual is influenced by different factors including age, gender, fitness, lifestyle, experiences, and past medical history."

Jan 1, 2019

By G. C. Hambleton

"The author has had wide experience in the reclamation of coal from coal mine waste dumps in the United Kingdom.The paper includes such topics as the processing decision and factors affecting processability; method of testing and appraisal; test data interpretation; historical influences in apppraisal; special contaminants and processing difficulties; methods of treatment; review of systems in use and their comparative economics; over-all system economics including excavation, handling methods, recovery system and shale disposal; effluent treatment; environmental considerations; alternatives to processing for coal recovery; light aggregate and cement usage; burned shale heaps; land reclamation; shale deposition for encouragement of vegetation by natural or artificial means; use of tailings fines; the environmental argument for action."

Jan 1, 1972

By M. Board, R. Pakalnis, S. Seldon, R. Brummer

The Kidd operation mines roughly 10 000 tpd of copper and zinc ore from underground and employs about 700 personnel. In the late summer and fall of 1997, major movements in the proximity of the east wall of the Kidd open pit had been observed. The Kidd pit had been mined from 1965 to 1977 to depths of 260 m (850 ft), followed by subsequent mining by underground methods to current depths in excess of 1830 m (6800 ft). The No. 1 Mine (2600 Level to pit bottom) is approximately 90% extracted, with most of the remaining reserve between 2000 and 2500 levels. Although initial concerns centred on the stability of the pit walls, the potential ramifications of the movements to the underground were recognized and measures were implemented to ensure the safety of personnel as well as to minimize the potential damage to existing operations. In late October, damage to underground operations was observed as deep as the 2000 Level. In the final assessment, the global mobilized mass was a “wedge”-shaped hangingwall block extending from surface to about 610 m (2000 ft) below surface. The “wedge” boundaries are defined by a fault and shear zone which have continuous lengths in excess of 1070 m (3500 ft); its base by shearing through the host rock mass; and its eastern face by deep tension cracks (Fig. 1). Mined and filled excavations at the western face of the “wedge” allowed mobilization of a mass in excess of 30 M tonnes. Movements in excess of 75 cm (30 in.) per day were recorded on the surface stations that preceded the complete shutdown of operations on October 29, 1997. The evaluations in the days following the shut-down were centred on mitigation of immediate and future possible negative impacts on infrastructure and mining of the remaining No. 1 Mine reserves while ensuring the safety of the operators. This effort required the rapid assessment of the potential damage of the block movement on underground infrastructure, stope access, drainage and ventilation, as well as airblast potential due to the falling of a large block into the pit near the ventilation intake at the base of the pit. These assessments were presented in a previous paper (Seldon et al., 1999). In total, the lateral movement of the block on the ground surface was over 4.3 m (14 ft). This paper describes the detailed studies performed to understand the failure mechanism and to assess the impacts on future mining in No. 1 Mine.

Jan 1, 2000

By Tiziana Apuani

The study refers to an area of about 70 km2, extended in the Italian Central Alps along the the San Giacomo Valley where different civil and mining works are present The regional geological setting is related to the Pennidic Nappe arrangement, characterized by the emplacement of sub-horizontal gneissic bodies resulting from the Mesoalpine isoclinalic folding of crystalline basements, emplaced throw East, and separated by matasedimentary cover units. The investigated geological rocks, belong to the ?Tambò?Unit, overlapped by its meta-sedimentary cover and by the ?Suretta? Unit. The tectonic contact gently dips to the E?NE. The valley, furrowed by the Liro Torrent, follows a N?S striking tectonic lineament, almost parallel to the nappe contact. A number of more then 70 sites, distributed in the studied area, were chosen and detailed structural and geomechanical field surveys were performed to characterize the rock masses, its intact rock and discontinuities. The procedure identifies the number of joint sets, their representative orientation, the set spacing, the type of movement, the amount of dilatation, the degree of alteration, the roughness coefficient, the presence and nature of infill. Rock mass quality indexes, such as the Rock Mass Rating (Bieniawski, 1989) or the Geological Strength Index (Hoek et al. 2002) have been evaluated in each surveyed site. The work is a contribute in assessing how the geometrical and geomechanical properties of the rock masses can be regarded as regionalized variables. The spatial distribution of these properties is a function of the geological and structural phenomena at which the rock masses have been subjected. The presented geostatistical analysis regards the spatial variation of the orientation of the most representative joint set.

May 1, 2009

By A. C. Gagnon, H. Saroglou

"The focus of this paper is on the analysis of geometrical discontinuity properties for the rock mass located within an open pit mine located in Western Africa. Discontinuity data were collected using various techniques including oriented core logging, borehole televiewer surveys, surface pit wall mapping and photogrammetry. The geological setting was initially studied prior to the data analysis to produce threedimensional ground models of the regional and mine site geology along with block diagrams illustrating predicted fracture patterns. Stereographic and statistical discontinuity data analysis of the geometrical properties of the rock mass was subsequently performed to identify unique structural domains throughout the open pit area. The discontinuity data collected throughout the studied open pit area were primarily discontinuity orientation, frequency and spacing and the investigation focused on the reasons for observed differences between the various data collection techniques. Stereographic analysis was used to assess the preferred geometry of discontinuities filtered by lithology, data collection technique, borehole, discontinuity type and pit wall (footwall or hanging wall). The observed fracture pattern is explained adequately by the geological setting. The need for accurate ground models for the design of open pit slopes is highlighted.INTRODUCTIONThe Tasiast Mine is an open pit operation located in north-western Mauritania, approximately 300 kilometres north of the capital Nouakchott. The Tasiast mine, which is owned and operated by Kinross Gold Corporation (Kinross), began commercial operations in 2008. The Tasiast mine is located in an area characterized by flat desert terrain within the western reaches of the Sahara Desert region. The current mine site includes mill buildings, shop facilities, waste dumps, tailings facilities and two main open pit operations (Piment and West Branch). The West Branch pit is the focus of this paper. The current open pit plan for West Branch indicates a final pit measuring approximately 2.5 km long by 1.4 km wide and 510 m deep."

Jan 1, 2015

By K. Bullock, M. Levesque, G. Lyle, D. L. Millar

ABSTRACT The options for reducing the carbon footprint of energy use in mining fall into three categories of activity: i) reducing demand, ii) improving energy utilization, and iii) adopting low carbon energy technologies. In addition to the environmental imperative, the economic case for these activities gains higher priority as the prices of electricity, gas, and liquid fuels increase. Low-carbon, energy-saving technology options that are available to mining industry companies lead to projects with return rates that must compete alongside other capital-intensive projects considered by mining company boards. Energy projects frequently involve longer payback periods and lower rates of return than those of competing bids for capital, such as new mineral property developments. For energy services companies that specialize in the financing, construction, efficient operation, and maintenance of energy projects, the same returns and payback periods can be considered acceptable or even attractive.

Jan 1, 2012

By J. T. Liu, G. H. Han, W. C. Chai, Y. F. Huang

"In beneficiation process, metal ions could adsorb onto clay mineral surfaces or interact with flotation chemicals, and then result in the flotation behavior changing of desired minerals. Al(III) is the dominating ion existing in the bauxite flotation system. In this research, the adsorption behaviors of Al(III) on two silicate clay minerals (including bentonite and kaolin) were investigated by means of UV-Vis spectra, zeta potential testing and scanning electron micrograph analysis. The adsorption experiment results show that the adsorption capacity of clays for Al(III) ions increases with the initial Al(III) concentration, contact time and solution pH. There are some different adsorption behaviours for two clays. Increasing the clay concentration decreases the adsorption capacity of bentonite, while increases first then decreases for kaolin. Higher temperature favours the adsorption of Al(III) on bentonite but goes against for kaolin. The adsorption capacities of bentonite and kaolin for Al(III) respectively reach 12.48 and 0.875 mg/g at initial solution pH 5. Zeta potential results show that the adsorption of Al(III) on two clays is characterized by electrostatic attraction mechanism.INTRODUCTIONIn beneficiation process, there is inevitably a wide variety of metal ions generated from mineral crushing, mineral dissolution and water chemistry conditions. Metal ions adsorb on the mineral surfaces or interact with the beneficiation agents, affecting the flotation efficiency of desired minerals (DiFeo et al., 2001; Parolis et al., 2008; Shackleton et al., 2012; Shengo et al., 2014). Therefore, it is necessary to have a detailed investigation on the adsorption behaviour of metal ions on clay minerals.Having good ion exchange capacity and negative surface charge, the clay minerals could take up various metal ions from the mineral-water system. Bentonite and kaolin are very common aluminosilicate clays in the mineral processing system. These two clays both hold a permanent negative charge, =X- on the basal surfaces, and a smaller variable charge, =SiOH on the mineral edges (Gu & Evans, 2008; (Gu et al., 2010). Adsorption experiments are usually used to study the adsorption affinity of metal ions for clay minerals (Sen & Bhattacharyya, 2012). The adsorption of Zn(II), Cu(II) and Pb(II) onto natural bentonite showed that the adsorption amounts of metal ions increase with contact time, solution pH and metal ion concentration, but decreases with adsorbent concentration and system temperature (Sen & Gomez, 2011; Melichova & Hromada, 2013). Cr(III) adsorption on bentonite was significantly pH dependent. The adsorption process followed pseudo-second-order model and the equilibrium adsorption was consistent with Freundlich isotherm (Lollino et al., 2015). The adsorption behaviours of Pb(II), Cd(II), Ni(II) and Cu(II) onto kaolin indicated that increasing pH favoured the adsorption of metal ions (Jiang et al., 2010). The adsorption of Cd(II), Cu(II), Pb(II) and Zn(II) onto kaolin showed that an ion-exchange reaction occurred at pH<7.0 and inner-sphere surface complexes were prone to form at higher pH (Srivastava et al., 2005)."

Jan 1, 2016