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By C. V. Deutsch, O. Babak, J. G. Manchuk

High levels of geological heterogeneity occurring over relatively short distances pose a challenge to the unconventional open-pit techniques used in oil sands mining. There is strong motivation to mine selectively and minimize dilution and loss; however, the large equipment and high mining rate used to meet production targets tend to reduce selectivity. A numerical model is developed to account for geological complexity, mining equipment, regulatory criteria, and other operational parameters. This framework is used for more accurate forecasts, optimization of equipment, and other operational decisions. An example demonstrates the approach in light of Alberta Energy Regulator criteria.

Jan 1, 2014

By H. Hitchen

THE object of this paper is to present the various facts that l1ave been revealed during lengthy investigations into the performance of all types of ropes on different hoisting installations. It then goes on to suggest means by which most of these findings could be usefully employed to obtain more economical rope lives with increased safety. SHAFT HOISTING ROPES Four basic designs of ropes are now employed for hoisting duties: (1) Six-strand, round strand ropes with fibre cores. (2) Six-strand, triangular strand ropes with fibre cores. (3) Non-rotating, multi-strand ropes. 0) Locked coil ropes. Round Strand Ropes (Figure 1) Very solid and reliable ropes can be obtained with this simple geo-metric design of strand. 1'1?iangula1? Strand Ropes (Figure 2) Owing to the fact that the wires in the strands are bent over a triangle, they do not seat quite so solidly as when they are bent over a circular core wire, as is the case with

Jan 1, 1963

By Mika Muinonen

"Dewatering of nickel concentrate at the INCO Thompson integrated mine-metallurgical site takes place within the smelter plant. The eight original 60 foot diameter cable torque thickeners of which four were operational and eight Dorrco internal drum filters have been replaced with a single Outokumpu high rate thickener and a single Lasta pressure filter. The modernization has resulted in a filter cake which has a more stable and lower moisture content. Control of the entire dewatering process has been improved and costs have been reduced.Typical filter cake produced from the Dorrco filters during processing of high tonnages of Birchtree mine ore was ~20% moisture vs. ~13% moisture for concentrate produced from the Thompson mine ore. The high moistures were correlated with the amount of fine magnesium silicate gangue in the concentrate. As Birchtree ore processing rates have increased, this filter cake moisture became unacceptable because of material handling problems and the impact on furnace metallurgy. The Dorrco filters were replaced with the Lasta filter in 2003 that has consistently produced filter cake at ~11% moisture.This paper summarizes the piloting, design, installation and commissioning of the modernized dewatering circuit.INTRODUCTIONThe Thompson integrated nickel processing facility was built in 1958 and originally consisted of a mine-mill-smelter and, soon after, a refinery.Nickel concentrate is pumped from the mill as a dilute slurry directly to the smelter facility ~200 meters along an unheated pipe trestle. Originally, nickel concentrate was de-watered using up to 8 conventional 60-foot diameter thickeners and 8 internal vacuum drum filters."

Jan 1, 2006

By P. A. Riveros, J. Binvignat, V. M. McNamara, D. Koren

The recovery of cyanide from a gold mill solution containing high levels of copper (400 mg/L to 900 mg/L) using the AVR process was evaluated. It was determined that acidification to pH 2 to 3 provides a suitable balance between HCN generation, copper precipitation and acid consumption. A short pilot plant campaign showed that ~75% of the feed WAD cyanide was recovered while the remainder precipitated along with copper upon acidification. The acid consumption averaged 3.5 g H2SO4 per litre of solution. The copper precipitate, consisting mostly of CuCN and CuSCN, was readily separated from the solution by gravity. The volatilization of HCN in countercurrent packed columns averaged 98.7% efficiency. Reabsorption of HCN was practically 100% in NaOH solutions and slightly lower in a lime slurry. Basic volatilizer design parameters applicable to a large-scale operation were determined, including the Henry’s Law constant and the mass transfer coefficient of HCN gas.

Jan 1, 1998

By R. M. Graves, C. B. McKenzie, D. Barbour, D. W. Desnoyers

"Abstract -The prospective Tulks volcanic belt hosts five significant massive sulfide deposits, Tulks Prospect, Tulks East, Jack's Pond, Daniel's Pond and Victoria Mine, as well as numerous showings and indications throughout its 70 km outcrop length. Regionally, the 498 Ma sequence consists dominantly of felsic pyroclastic rocks and flows with interbedded mafic volcanic units and fine­ grained sediments, commonly graphitic. Contemporaneous granitoid rocks occur in the south half of the belt. Rocks usually display a strong NE-SW, steeply dipping, penetrative foliation and other shear-related high-strain fabrics. Facing directions are normally northwest, although there is local evidence of folding. Sulfide bodies and their alteration systems are deformed and shape-modified in the style of ambient strain.The Tulks, Tulks East and Jack's Pond prospects appear to occupy a similar stratigraphic level, on or near the contact between a thick felsic pile and an overlying broad, conductive package of graphitic sedimentary rocks. AU are pyritic deposits with well-developed footwall alteration systems. The Tulks prospect comprises four polymetallic lenses totalling 750 000 t. Three lenses constituting more than 6 000 000 t of sulfide mineralization are indicated at Tulks East but only the 210 000 t ""B"" lens contains significant base metals. Jack's Pond consists of a very extensive, zoned alteration complex in which four lenses of massive to semi-rnassive pyrite + chalcopyrite are known.The central part of the system, characterized by Mg chlorite and carbonate, is enveloped by pervasive sericitization and capped by intensely silicified and pyritized volcanics. The sulfide lenses are interpreted as part of the footwall zone and are beneath that part of the system most likely to host polymetallic massive sulfides.Daniel's Pond differs from the other prospects in such fundamental ways as metal content, associated alteration and structural setting. The deposit comprises strongly tectonized, Ag-rich, Zn-Pb mineralization distinguished by a pronounced Ba-As-Sb signature. Mineralization is confined to a narrow, north-south high-strain zone which separates unstrained mafic volcanic rocks to the east from well-foliated felsic rocks. The deposit Jacks an extensive alteration halo and at its north end is associated with a lens of barren, undeformed massive pyrite.The Victoria Mine deposit, the most cupriferous of the five, is related to a moderately dipping structure that separates well-foliated Tulks volcanic rocks from an overlying, Jess deformed volcanic­ sedimentary sequence that may be as young as 462 Ma. The structure is also the locus of black chlorite, dolomite and quartz alteration. Structurally remobilized precursor sulfide mineralization is one possible source for the deposit."

Jan 1, 1993

By E. L. Martheleur

Introduction In October, 1945, the Coal Division of the Institute appointed a Committee on The Use of Electricity in Coal Mines, with the following terms of reference: ?To study under which conditions in each deposit the use of electricity can be brought closer to the coal face and which types of electrical machinery can be recommended?. It was not until the beginning of this year (1946) that the Committee had a chance to convene and .discuss the conclusions which are embodied in this report. Mr. McLeod, as Chief Electrician of the Dominion Coal Company, is intimately concerned with that Company's installations, and Mr. McIsaac, as Electrical Inspector of Coal Mines for Nova Scotia, is well acquainted with installations in all coal mines in the Province. The knowledge of both has been very valuable in helping to draft this report.

Jan 1, 1946

By Neil Campbell

"The gently-dipping Devonian dolomite beds south of Great Slave lake in northern Canada are nearly every-where concealed by a cover of glacial drift and muskeg. Nevertheless, in 1898 or earlier, four small outcropping areas of dolomite, richly mineralized with lead and zinc sulphides, were discovered. Exploration work performed here up to the end of 1930, included intensive trenching and drilling of the showings, together with mapping and wide-spaced drilling in the surrounding region. This work proved that the discoveries are isolated pockets of mineralization much too small to be commercially valuable by themselves. No evidence of orebodies elsewhere was reported.Meanwhile, mapping by the G.S.C. in the Shield far to the east disclosed major Precambrian faults, some of which can be projected southwesterly (under a cover of Paleozoic sediments) to the vicinity of Pine Point. During the period from 1940 to 1947, consideration was given, by The Consolidated Mining and Smelting Company Ltd., to evidence of a theoretical possibility that, although apparently dormant in Paleozoic times, these faults may have provided a structural control and a source of ore-bearing solutions in some post-Devonian period. From this, it was postulated that the breaks might have created, in the overlying dolomite, a linear array of orebodies concealed by overburden but lying in a belt of considerable length and in a position predictable within practical limits. A program of drilling designed to test and exploit this specific concept was conducted from 1948 to 1955.he drilling within the new, theoretically-defined search area resulted in the discovery of many lead-zinc ore-bodies, none of which was exposed at the surface. Some of these are large and (as indicated by 1965 production records) very rich. They are situated 1 to several miles distant from, and apparently not connected to, the earlier-known surface discoveries. The drilling also disclosed that the ore, which consists of disseminated sphalerite and galena replacements together with colloform sphalerite and coarse galena cavity fillings, occurs mainly at certain stratigraphic horizons within a large, coarsely-recrystallized dolomite barrier reef. Considerable fracturing and folding was found. It has been suggested that reef development was influenced by post-Precambrian tectonic movements associated with the old faults in the basement complex. The ore may have been deposited by solutions moving from distant sources to favourable structural and chemical environments in or related to the reef.In more recent exploration performed in the course of preparing for mining production, the rate of ore discovery within the same general geological context has been greatly accelerated by the use of new geophysical techniques and drilling equipment. Reserves of 21.5 million tons, averaging 4 per cent lead and 7.2 per cent zinc, were reported in 1965, and production from open pits at the rate of approximately 248,000 tons of concentrates per year is in progress"

Jan 1, 1966

By H. Kudelka

Copper electrowinning at Duisburger Kupferhuette was introduced in March 1975. The electrowinning plant has a capacity of 10,000 mT of copper cathodes a year. The cuprous oxide feed material is an intermediate product of the treatment of the leach solutions, originating from chloridizing roasting of pyrite cinders. This material is characterized not only by a wide spectrum of accompanying impurities, but also by an unusually high level of precious metals. As the priority set was the production of high-purity cathodes. there was a need for developing a process which would be suited to treat complex leach liquors . The process adopted consist s of an oxidizing leach in spent electrolyte, followed by two- stage purification, By this means. a low- acid pregnant copper electrolyte is obtained free of elements detrimental to copper quality. Electrowinning is carried out at a current density of 200 A / m2 in the presence of 10 g/l zinc. The electrowon copper has a conductivity of at least 101.4% lACS and a softening temperature not exceeding 200°C, which makes it a suitable product for continuous casting and dip ?forming.

Jan 1, 1977

By C. R. Julian

THE large pyrites ore-bodies, the underground mining of which is to be described, are situated at Rio Tinto in the Province of Huelva in Southern Spain. The situation of the different ore-bodies with relation to one another is shown in Figure 1. It will be seen on the plan that the strike of the ore-bodies is approximately east and west. The geology of the district has been very fully described by Dr. D. Williams (1), so that for the purposes of this paper it will be sufficient to give briefly the salient features o each of the two larger ore-bodies which are being mined by underground methods at the present time. (a) San Dionisio.-This ore-body is the largest single deposit in Rio Tinto, having on its upper levels a length of 3,500 ft. On the upper levels the average width is approximately 200ft. but in places on the lower levels there is a width of 900ft. of un broken pyrites. Diamond-drill holes, without running out of ore, show the ore-body to persist to a depth of at least 1,600 ft. The ore-body in the upper part lies between slate and porphyry walls, but in depth is enclosed in porphyry walls. (b) South Lode.-Faulting is considered to be responsible for the break in the solid ore between South Lode and San Dionisio. On the upper levels, the South Lode ore-body has an unbroken length of 4,000 ft. The massive pyrites has a maximum width of 300ft. and an average of about 100 ft. Ore has been proved to a depth of 1,000 ft., at which depth the ore-body is much reduced both in length and breadth. This ore-body, to the depth at which it has been proved, lies entirely between slate and porphyry walls. The South Lode and the San Dionisio ore-bodies are mined both by open-cast and by underground methods. There is evidence that these mines have been exploited intermittently during the last 3,000 years; but, as is to be expected, no records are available of the tonnage mined prior to the time of purchase by the present company.

Jan 1, 1940

By L. M. Pidgeon

MAGNESIUM metal, with a specific gravity of 1.73, is two-thirds the weight of aluminium and one-quarter that of steel. It is the lightest metal which is stable in the atmosphere. Before the war it had begun, though somewhat slowly, to take a place among the established metals. In 1939, magnesium production on this continent amounted to some 3,000 tons per annum and was confined to one company. At that time, Germany produced perhaps 20,000 tons. The advent of war, however, increased the demand to fantastic heights and introduced production problems of unprecedented magnitude. By the end of 1943, North American production is expected to reach 300,000 tons per annum (1), an increase of one hundredfold. Such a rate of expansion has not been witnessed previously in the history of metallurgy. It has given the metallurgist an opportunity to try new production methods and to learn in a short time what might otherwise have taken many years. The metallurgy of magnesium is still in its formative years and at this time widely different production methods are in operation side by side. This paper will discuss these methods in so far as information is available for publication at this time. A general description of the new Canadian industry will be included.

Jan 1, 1944

By A. J. Stapleton

"The Copper Mountain mine of Gaspe Copper Mines, Limited was brought into production in January, 1968.This paper describes the organization, scheduling and control of maintenance of large open-pit equipment, including 8-cu.yd shovels and 85-ton electric-wheel haulage units. The facilities for repair as well as maintenance are also described, including repair shops and field repair equipment. Maintenance costs are discussed and particular reference is made to tire inspection, records and costs."

Jan 1, 1969

By M. Kumral, E. Dilhuydy, B. Ozdemir

"In-pit crushing and conveyor (IPCC) systems have become increasingly popular in the mining industry as an alternative to truck-and-shovel systems. Deciding whether to haul waste rock by truck or IPCC represents an important gap to be investigated in semi-mobile IPCC systems. A cost analysis is presented to evaluate the feasibility of crushing and conveying waste material in IPCC systems, along with sensitivity and risk assessments through Monte Carlo simulation. Although the capital expenditure is higher, results showed waste crushing will be feasible in deep pits and over long mine life and haul distances.RÉSUMÉ La popularité des systèmes de concassage et de transport dans la fosse minière (IPCC, de l’anglais In-pit crushing and conveyor) n’a cessé de croître dans l’industrie minière ; ils constituent en effet une option intéressante de remplacement des systèmes par camions et pelles mécaniques. Le choix entre le transport des stériles par camions ou par IPCC est encore difficile à faire et devra faire l’objet d’une étude approfondie au niveau des systèmes d’IPCC semi-mobiles. Une analyse des coûts est présentée pour évaluer la faisabilité du concassage et du transport des stériles par les systèmes d’IPCC, de même que des évaluations de la sensibilité et des risques par le biais de la simulation de Monte Carlo. Si les dépenses en immobilisations s’avèrent être plus élevées, les résultats ont cependant montré que le concassage des stériles sera envisageable dans des fosses profondes ainsi que sur une longue durée de vie et de longues distances de transport. INTRODUCTIONThe mining industry is currently facing many challenges such as low commodity prices, increasing environmental concerns and regulations, lower grades, deeper mines, and greater waste-rock quantities. As a result, the profitability of mining operations has decreased, with many mines stopping or suspending operations, and many new projects being postponed. Mining companies have therefore focused on improvements and innovations to increase the cost effectiveness of operations, for example, increasing production capacity to take advantage of the economies of scale (Crowson, 2003) and decreasing the unit operation cost. Changes in production capacity force mining companies to evaluate alternative material handling systems.During the past few decades and within material handling systems, significant improvements have been made to truck performance and capacity. Consequently, operating expenditures (OPEX) associated with fuel and maintenance have risen swiftly. In a mining operation, truck hauling systems now represent 40–50% of the capital cost and approximately 45% of the OPEX (Tutton & Streck, 2009). Additionally, material transportation costs are expected to increase due to longer haul distances arising from deeper and larger mines (Fleet et al., 2015). Finally, large fluctuations in fuel prices result in high risks associated with truck OPEX. According to the United States Energy Information Administration (2015), the cost of crude oil—the largest component of the retail price of diesel fuel—increased from US$24.31/barrel in 1986 to US$46.92/barrel in 2016, peaking at US$151.72/barrel in 2008 (Macrotrends, 2016)."

Jan 1, 2017

By Andrew Matyas

"During the summer of 1968, the author was employed in the Research Department of Dominion Foundries and Steel, Limited, Hamilton, Ontario. Over the years, Dofasco has been conducting a program for developing more efficient control of its basic oxygen steelmaking process. The author was thus able to obtain a variety of viewpoints from both research engineers and furnace operators. He also had access to extensive literature dealing with BOF control schemes underway at other major steel producers. This paper describes the present state of developments in BOF steelmaking control.The necessity for efficient BOF control is pointed out. To appreciate the variables to be controlled, a brief outline of process fundamentals is included. Technical aspects of present methods of practical control are examined in detail; the relative merits of dynamic over static control models are emphasized. Finally, it is shown how an effective dymic-optimizing control scheme serves as the basis for closed-loop computer control of the process."

Jan 1, 1970

By L. H. Cole

Introduction The increasing importance of the gypsum industry in Canada is evidenced by the fact that the production has increased from 473,129 tons valued at $809,632 in 1909 to 1,205,846 tons valued at $3,622,007 in 1928, an increase of over 155 percent in quantity, and of 347 percent in value, in the 20-year period. Although the export trade in crude gypsum still forms a large proportion of the industry, it is gratifying to see that the home consumption is steadily increasing, and while the percentage of the crude gypsum mined that is manufactured into the calcined products in the country is only 16.8 per cent, its value is practically 50 per cent of the total gypsum production of the whole country. It is to be hoped that each succeeding year will see an increase in the amount manufactured in Canada, and, with the steady growth of the country and a serious endeavour to capture a part at least of the world market in gypsum products, the outlook for the industry is decidedly promising. The value of gypsum as a commercial commodity has been known from the time of the early Egyptians; in fact its value for certain purposes has been known so long chat the date of the discovery of its peculiar properties is unrecorded.

Jan 1, 1930

"Option pricing is used in finance for valuing options to buy (or sell) shares at some future date because it provides a convenient framework for quantifying values subject to uncertainty. As one of the main sources of uncertainty in mining is the price (sales) of the metal, this approach can also be used for valuing mining projects.The first part of this paper reviews options and option pricing; the second part presents the approach developed by Brennan and Schwartz (1985) for using option pricing to value natural resources. Several applications of this methodology have been published; these are described. From a mining point of view, the assumptions made by Brennan and Schwartz are too simplistic. The weaknesses are discussed with a view to improving an apparently promising new way of assessing the value of projects. IntroductionThe collapse of the British merchant banking group, Barings, has highlighted the risks that can be incurred by speculators and arbitragers in the futures and options markets. But this negative attention on futures and options should not make us forget their positive aspects. They can provide producers and consumers of metals with more predictable sales prices. The introduction of the new traded average price options, TAPOS, by the London Metal Exchange in January 1997 is a response to this need. Equally important, the theory that the finance industry has developed for valuing options provides an interesting framework for valuing mineral projects as well. While this paper was being revised, the South African gold mining house, JCI, announced that it was using a methodology based on option pricing for valuing the mineral rights to deeplevel gold resources (see Box 1)."

Jan 1, 1997

By M. Jackson, R. McDonald, T. Osken, D. Robinson

"The addition of sulphidic materials in the leaching of nickel laterites has several potential benefits that include improvements in the rheological behaviour of the blends, reductions in the sulphuric acid and steam requirements, sweetening of the nickel grade of the combined feed material, and the option of using a range of sulphidic materials. The current study examines the oxidative processing of 30% w/w blends of nickel concentrate and nickel laterite ore at 250oC. In particular, the viability of using low oxygen overpressures was examined for significant amounts of nickel flotation concentrate, up to 12% w/w. Further to this the impact of process water quality, in particular the presence of chloride, upon the kinetics of extraction and the mineralogy of the residue were also investigated. This paper will present the results of preliminary work in this area.INTRODUCTIONThe use of sulphidic ore as a source of sulphuric acid during oxidative hydrometallurgical processing is not a novel idea and can be traced back over forty years (Seidel & Fitzhugh, 1968). A series of patents pertaining to application of this approach for laterite ores can be subsequently found (O’Neill, 1973; Opratko et al., 1974; Rodriguez, 2008a, 2008b; O’Callaghan, 2010; Liu et al., 2011) and a few of articles containing published data (Ferron & Fleming, 2004; Quinn et al., 2009). The use of pyrrhotite tailings as a source of sulphuric acid has also been employed for the leaching of converter slags (Perederiy et al., 2011).It is known that hydrometallurgical operations such as the HPAL plant at Murrin Murrin have added small amounts of sulphides as either transitional (mixed sulphide/oxide) ore or non-smeltable concentrate. This can improve the rheology (Rodriguez, 2009) and provide heat credits. However these plants are generally limited in their ability to add such materials due to their reducing nature and given under highly acidic conditions that the breakdown potential of the titanium used for the autoclave lining is significantly reduced. A suitable oxidant must therefore be present to ensure the potential remains sufficiently high."

Jan 1, 2012

By D. Hodouin

Jan 1, 1978

By T. Mulja, Michel Boily, Anthony E. Williams-Jones, Pierre Pilote

"The Preissac-Lacorne batholith is composed of suites of early metaluminous calc-alkalic gabbroic to granodioritic intrusives, three late peraluminous monzogranite plutons and numerous Li, Be and Ta-bearing granitic pegmatites. The Lacorne pluton is dominated by biotite and biotite + muscovite monzogranites containing abundant Be and Ta-bearing granitic pegmatites (40-80% volume). The pluton is surrounded by swarms of unzoned or poorly zoned spodumene-rich pegmatite dykes. The La Motte pluton is composed of biotite monzogranites, biotite+ muscovite monzogranites and rare muscovite + garnet monzogranites. Li, Be and Ta-bearing pegmatites are less abundant than in the Lacorne pluton and are commonly associated with molybdenite bearing quartz-muscovite-K-feldspar veins. In the Preissac pluton, muscovite + garnet monzogranites and muscovite + biotite + garnet monzogranites are the dominant rock types. The pluton rarely contains granitic pegmatites and these are generally barren. However, numerous molybdenite bearing quartz and quartz-feldspar-muscovite hydrothermal veins are observed.Li, Be andTa-bearing pegmatites display a crude spatial zonation around their parent monzogranites. Spodumene-rich pegmatites are generally unzoned or poorly zoned and are confined to the surrounding metasedimentary or metavolcanic rocks or crop out in the early gabbroic to granodioritic intrusives surrounding the monzogranites. Ta and Be-bearing pegmatites are usually concentrated towards the margins of their parent monzogranites. The highly fractionated nature ofmonzogranites (high Rb/Sr, low K?Rb, Ba?Sr, Zr/Nb ... ), their peraluminous composition (corundum normative and muscovite bearing) and the numerous occurrences of Ta and Be-bearing pegmatite dykes represent important criteria for the exploration of fertile granites."

Jan 1, 1990

By Ian R. Morrison

"Abstract - The Izok Zn-Cu-Pb-Ag volcanogenic massive sulfide deposit is located 265 km south of Kugluktuk (Coppermine), Nunavut Territory, Canada, in the west-central Slave structural province. The Izok deposit is owned 100% by Inmet Mining Corporation and represents one of the largest undeveloped zinc-copper resources in North America. The Izok deposit is hosted within and near the top of a thick sequence of predominantly felsic pyroclastic rocks of late Archean age. The hanging-wall stratigraphy includes additional felsic volcaniclastic rocks, andesitic and basaltic flows, thin sulfide-rich iron formations, and turbiditic sedimentary rocks. The felsic volcanic rocks are intruded by intermediate dikes and sills, followed by gabbroic dikes and sills. Both intrusive suites are interpreted to be volcanic feeders to the overlying flows. All lithologies are subsequently cut by younger, irregular, granitic pegmatite and diabase dikes. The volcanic and sedimentary rocks are regionally metamorphosed to pyroxene hornfels grade. The massive sulfides occur within a large (kilometer-scale) Na-depleted sericitic alteration zone. The immediate footwall and hanging-wall rocks to the deposit are characterized by zones of muscovite- biotite-sillimanite, lesser chlorite-biotite-cordierite, and locally intense silicification and sodium metasomatism. All lithologies have been affected by younger Ca-metasomatism. As currently defined, the Izok deposit comprises a cluster of five complexly zoned composite lenses: the Northwest, North, Central West, Central East, and Inukshuk lenses. The first four lenses are amenable to open-pit mining, whereas the Inukshuk lens will require underground development. The total indicated mineral resource presently stands at 16.5 million tonnes with a grade of 2.2% Cu, 11.4% Zn, 1.1% Pb, and 60 g/t Ag. Inmet Mining Corporation is presently reviewing the economic feasibility of developing the property."

Jan 1, 2004

By J. E. Dutrizac

The dissolution of low-iron sphalerite, (Zn,Fe)S containing 0.08% Fe, in ferric sulphate-sulphuric acid media was investigated using closely sized fractions of crushed sphalerite crystals and sintered disks made from the crushed crystals. Linear kinetics are observed, and the predominant reaction products are ZnSO4, FeSO4 and elemental sulphur. The leaching rate increases systematically with increasing temperature, and the calculated apparent activation energy is 56 kJ/mol for the sized sphalerite and 54 kJ/mol for the sintered disks. The relatively high apparent activation energy suggests that the rate is chemically controlled, a conclusion supported by the insensitivity of the rate to the disk rotation speed. The rate increases as the 0.22 power of the Fe(SO4)1.5 concentration, and as the 0.22 power of the H2SO4 concentration. However, in the absence of ferric ions, the rate increases more significantly with increasing H2SO4 concentrations, and relatively rapid rates are observed in solutions containing >0.5 M H2SO4. In 0.1 M Fe(SO4)1.5-0.3 M H2SO4 media, the measured rate decreases with increasing sulphate concentrations, added as Li2SO4. The rate of dissolution of low-iron sphalerite is promoted by dissolved copper concentrations as high as 800 mg/L. In contrast, dissolved silver, even in the 0-2 mg/L concentration range, significantly retards the dissolution of the low-iron sphalerite.

Jan 1, 2008