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By A. A. Lavrinenko

There are discussed the possibilities of using of flotation tailings of platinum-copper-nickel sulfide ores of the Norilsk region for the preparation of backfill mixture instead of a specially produced rock and binder materials to reduce the cost of stowing operations and impact on the environment. It is shown that due to the presence in the tailings of flotation up to 10% of sulfide sulphur, which reduces the strength of the fill materials, and more than 1 g/t PGM it is necessary the preliminary extraction of the sulfides in the product for further processing that give an opportunity to reduce the losses of valuable components. It is shown that by the flotation of the current tailings it is possible to extract 91% of sulfide sulphur, 60% of palladium and 30% platinum in 17% sulfide concentrate containing 2.1 g/t palladium, and to reduce the sulphur content in the tailings up to 0.7%. Due to the easy oxidation of pyrrhotite, there is recommended fractional delivery of the collector with a total consumption 200 g/t. There are discussed results of the flotation study with an additional collector of PGM (sodium diizobutyditiophosfinate), which one show the possibility to increase extraction of platinum on 45%, as well as extraction of sulphur and palladium. For the flotation of sulfides and PGM from the current tailings there is recommended a combination of collectors for primary flotation and only butyl xanthate using in control operations. The possibility of using sludge fraction of the current tailings as a component for the preparation of the combined cementing materials after exposure of sulfides is analyzed. It is shown that the efficiency of the flotation of sulfides from this fraction can be enhanced using selective flocculants. There are discussed the advantages of implementation of completely hydrophobic butadiene-styrene copolymer in comparison with partially hydrophobic polymers. There is discussed an efficiency of the mechanochemical treatment of old tailings in turbo mill and sulphuric acid to remove oxide films from the surface of pyrrhotite before its flotation. Due to the pretreatment operation there is achieved increasing of sulphur extraction and after the introduction to the flotation circuit three control operations there is produced the fill material with sulphur content 2.5%. Keywords: tailings, copper-nickel ore, pyrrhotite, butyl xanthate, sodium diisobutyl dithiophosphinate, selective flocculation, butadiene-styrene copolymer, mechanochemical treatment

Sep 1, 2012

By D. Johann, E. Zanetti, I. A. S. Brum, P. M. Zancan, A. F. Castro

"This study was done from a sample of coal mined at the Vale-Mozambique mine, located in Moatize district, Tete Province. The aim of this work is to analyze the reagent system in the flotation of coal fines belonging to the Upper Chipanga layer (UC). Among coal processing methods, flotation stands out as one of the most important for the concentration of this material, in particular in the treatment of fine particles. The total feed of the Vale-Mozambique processing plant is 8,000 tph of coal, where 10% of this feed corresponds to the fine fraction that feeds the flotation circuit. The material used in this study had a particle size of 96% smaller than 0.25 mm. The reagents used in the flotation tests were betacol and diesel oil as hydrophobizing agents and MIBC as frother. The range of betacol concentrations in the first test phase was 200 g/t to 500 g/t, and in the second phase 200g /t to 500g /t while diesel oil and MIBC were kept constant at 300 g/t. The immediate analysis followed the Brazilian standards NBR 8289, NBR 8293, NBR 8290; and NBR 8299. The results showed that it is possible, from a feed with ash content around 22.84%, to obtain products with levels below of 10% ash, with a mass recovery around 50%. The recovery of carbonaceous matter was also evaluated and presented positive results. Complementing this study, the effect of H2O recovery was evaluated and it was observed that for the concentrations of betacol the recoveries ranged from 6 to 9%, and for diesel oil plus MIBC were 4 to 7%.INTRODUCTION Considering the increase in population and energy consumption as humanity has been living along the last decades and the consequent demand for non-renewable natural resources, it is clear the challenge of the mineral industry in the search for new technologies and improvement of the existing ones. This challenge is justified by the need for better industrial results and to meet the market specifications, taking into account the reduction of deposits with higher contents and the need for beneficiation of more complex ores, lower levels and lower release granulometry. Usually in these situations, processes already well-established as the gravimetric (Sampaio and Tavares, 2005) have not good results."

Jan 1, 2018

By Silvia França, Hudson Couto

"In this paper, an alternative beneficiation process was developed to recover nickel minerals from low-grade weathered ores. The studied sample, 0.3% Ni grade, is essentially composed of nickel sulfides (pyrrhotite and pentlandite); magnetite and silicates (mostly talc and amphibolites) are the primary gangue minerals. The particle size distribution was controlled using a grinding operation to avoid producing an excess of fine particles by overgrinding. The sample underwent a grinding step for the fine degree of liberation. The slimes (-20 ?m) were removed via two desliming stages in hydrocyclones (diameters of 1.5" and 2"); the ground material, which was classified in a range of (-150+20) ?m, was processed by column flotation in three different stages: rougher flotation for magnesium silicates, rougher flotation for sulfides, and cleaner flotation for sulfides, using pilot flotation columns (2" and 6" in diameter and 20 ft high). The goal of using the preliminary magnesium silicate flotation step was to remove hydrophobic minerals (mostly talc) that would float naturally with the sulfides, which would decrease the Ni grade in the concentrate, as well as to reduce the MgO content because this compound is considered harmful in metallurgical processes when a grade greater than 9% is used. The final concentrate obtained in the cleaner flotation step reached up to 2% Ni and 7.0% MgO. The global and flotation recoveries in the process were approximately 30% and 60%, respectively, due to the losses of Ni during the desliming process. Despite this low global recovery, the adopted beneficiation process can be considered an interesting alternative to produce nickel concentrate from tailings or waste materials."

Jan 1, 2014

By B. K. Mohapatra

Small manganese ore bodies in south Odisha, India occurs both as stratiform and stratabound ore bodies. These two ore bodies show contrasting mineralogical, petrographical and chemical characteristics. Stratiform type of Mn-ores consists of manganese, iron and silicate- phases in approximately same proportion. In contrast, stratabound ore bodies contain a high proportion of manganese oxides, silicates and phosphorus phases. Phosphorus is found within apatite in the stratabound ore bodies while in the stratiform ore it occurs as an adsorbed state with iron phase (goethite). Both ore bodies are low-grade (17-23% Mn) therefore do not have a market value. However, the stratabound ores are enriched in phosphorus (P2O5: >1%) compared to the stratiform ores. Both the ore types were processed through gravity, magnetic and roast reduction followed by magnetic separation techniques. The strata bound ore could be upgraded to 33% Mn from a feed of 23% by combination of dry and wet magnetic separation methods. But the phosphorus content also suits up (P2O5: 1.2%) in the processed product making it unsuitable for further use. The stratiform ores do not respond to either gravity or magnetic separation because of close association of manganese with iron phases. However, this could be beneficiated through roast reduction followed by magnetic separation. An ore with 17% Mn content could be upgraded to 40% Mn with a 42% yield and 78% recovery. The goethite, having phosphorus, converts to magnetite and is retained within the magnetic fraction, thereby reducing the concentration of phosphorus in the non-magnetic fraction, which becomes the product. This report demonstrates the influence of ore petrology in determining the up-gradational potential of manganese ore in the southern Odisha, India. Keywords: manganese ore, physical beneficiation, phosphorus rich ore

Sep 1, 2012

By A. Koizhanova

Kumistinskoye gold- and silver bearing ores (Republic of Kazakhstan) as well as standardized test solutions containing gold, silver, copper, zinc and iron were studied. The best results in silver and gold recovery from Kumistinskoye gold- and silver bearing ores were achieved through use of complex cyanide-thiosulfate solutions as compared to individual cyanide solutions and thiosulfate solutions. It was found that such complex solutions substantially step up leaching process herewith increasing precious metals recovery rates. Thermodynamics of studied chemical processes was calculated. Reaction order, kinetic constant and activation energy of gold leaching process through use of cyanide-thiosulfate solutions were identified. We managed to prove that the sorption rates and holding capacity in process of gold anions recovery with anionite AM-2B are comparable to sorption characteristics for cyanide solutions. Keywords: gold, silver, copper, zinc, iron, cyanide-thiosulfate solutions, anionite AM-2B

Sep 1, 2012

"The most common agglomeration technique in iron and steelmaking is sintering, which requires the use of iron ore/concentrate mixtures, limestone and dolomite as fluxes and coke as fuel in order to produce the required melt at high temperature to cause agglomeration of the particles. Sinter feed blends containing high proportions of magnetite concentrate are difficult to granulate and to produce granules of high permeability, and sufficiently robust quasi-particles for successful sintering operations. Since the granulation of iron ore sinter feed requires no use of a binder, the added fluxes play a vital role in holding the granule particles together until they sinter. The fluxes also help to improve the granule quality and control slag composition in the blast furnace. It is well-known that the particle size distribution of the fluxes affects the granulation effectiveness and green bed permeability which determine the productivity, physical and metallurgical properties of the granules and sinter. Hence it is necessary to understand the role of flux particle size on granule properties so as to improve the granulation of iron ore sinter feed blends containing high magnetite concentrate. In this study, laboratory granulation experiments have been carried out on iron ore sinter feed blends containing high proportions of magnetite concentrate at different addition levels of limestone and dolomite mean particle sizes, to understand the influence of limestone and dolomite particle sizes on granulation rate processes and granule properties.INTRODUCTION Increases in iron ore production to meet the global demand for iron and steel products has led to the depletion of high grade iron ores and thus the current utilisation of low grade iron ore fines and concentrates. However, sinter, pellets and the lump are the required feed types used in the blast furnace. The high basicity sinter is the main iron bearing feed accounting for 70-85% in the blast furnace due to its good metallurgical and mechanical properties that allow high productivity, efficient processes and low production cost (Adam et al., 2017)."

Jan 1, 2018

By E. L. Chanturiya

During the mineral processing of pyrites sulphide ores of some deposits of Russia loss of gold with tailings and pyrite concentrates amounts up to 40%~90%. The problem of selective allocation of gold-bearing pyrite is crucial. There are 4 mineralogy-technological groups of pyrite determined in copper-zinc sulphide ores, based on the increase of contents of gold in pyrite. The gold associated with group 4 pyrite contents of 85% the total mass of gold found in the pyrite. The flotation behaviour of the enriched fractions of pyrite (98%), of the allocated from the ore of Gay deposit, were studied essentially in various conditions ?? and the charge of Butyl xanthogenate of potassium (ButX). Some products of selective pyrite flotation were investigated by methods of scanning electronic microscopy, energy-dispersive and X-ray spectral microanalyses, definition of specific resistance and thermoelectric moving force.

Jan 1, 2014

By Andrey V. Yevdokimov

The results of the test work on gold leaching using high strength of cyanide solution in the presence of activators are presented. The major physical and chemical relationships of gold leaching were determined. Intensive cyanidation results of gravity concentrates with various material compositions using an activator are given. Process design criteria for intensive cyanidation unit were developed on the base of pilot plant test results. Keywords: gold, activators, intensive cyanidation, gravity concentrates

Sep 1, 2012

By B. A. Kutlin

29% of the total ore mined in the Russian Federation for copper production is finely disseminated copper-zinc-pyrite ores of the Ural Region. Physical and chemical characteristics of pyrite copper-zinc ores make for difficulties in obtaining high indices during processing. At present, the authors have elaborated the technology to improve the quality of copper concentrates up to 20.0% for the ones obtained during pyrite copper-zinc ore processing (based on the example of the ore mining and processing enterprise ?Uchalinsky GOK?, Russian Federation). There are examples of use of fair-sized pneumo-mechanical flotation machines by modernization of processing plants. Keywords: copper-zinc-pyrite ores, Ural region Russian, selective flotation, pneumo- mechanical flotation machines

Sep 1, 2012

By William Skinner, Jonas Addai-Mensah, Keith Quast, David Robinson, Jason Connor

A review of the laboratory- and pilot plant-scale physical separation techniques for the beneficiation of nickel (Ni) laterites shows limited efficacy. To date, the only upgrade technique adopted commercially, prior to hydrometallurgical processing of Ni laterites, is the removal of a barren, coarse size fraction in the feed by classification. In the present work we investigated two low grade (~ 1%), goethite-rich Ni laterite ores’ upgrading by magnetic separation, attritioning/coarse, (lower Ni-grade) gangue rejection and flotation techniques. Low intensity (0.1T) dry magnetic separation at ambient temperature of raw samples and those pre-heated at temperatures up to 450 °C showed evidence of pay metal Co and Mn bearing asbolane and/or lithiophorite minerals pre-concentration in the magnetic fractions. Ni distribution, however, did not show any noticeable magnetic upgrade but followed the weight distribution. Other ore pre-treatment methods (e.g., desliming and sulphidisation) followed by froth flotation with anionic and cationic reagents also led to noticeable (~35%) Ni upgrade. This is due to the deportment of Ni across several gangue host mineral phases (i.e. Fe oxide/hydroxide and a range of silicate/aluminosilicate minerals). From chemical analysis, after disaggregation of ~ 1% Ni grade feed ore, coarse (-600 + 38 µm) and fine (-38 µm) fractions of ~0.6% and 1.3% Ni grades respectively, were also produced, suggesting that a significant upgrade in Ni content can be achieved by rejecting the + 38 µm fraction with the loss of <40% of the Ni. The ore mineralogy, particularly the complexity and high number of un-liberated Ni-bearing phases, greatly compromises physical separation methods for these ores, with the possible exception of screening after disaggregation of the fines inherent in the run of mine ores.

Jan 1, 2014

By V. Runkana, N. K. V. Nadimpalli, S. Sahu

"IsaMill™ has been in operation in the recent past for fine grinding of low grade ores to extract non-ferrous minerals. IsaMill™, typically, consists of a series of uniformly spaced identical disks mounted on a rotating shaft which is encased in an outer shell. The mill offers high energy efficiency for fine grinding and an inherent scalability. But, it encounters certain operational challenges such as non-uniform distribution of grinding media coupled with high wear rate of the disks and solid walls of the mill at specific locations—which adversely affect the mill performance. To circumvent these operational challenges, design modification of the disks through heuristics, by introducing a reduced diameter disk (RDD) at specific locations, is a common practice in industry. But there is no systematic scientific study in this regard. In the current work, we developed a discrete element method (DEM) based model and simulated for the IsaMill™ operation to study the effect of RDD on the efficiency of the mill and wear rate of the solid walls and disks. Since the first set of disks experience the high wear rate due to the high loading of the charge, the RDD was introduced at the first two disks. The simulations were performed at different diameters of the RDDs and at different media loadings. The performance of the mill was analyzed based on the power consumption, the wear rate on disks and the distribution of media particles inside the mill. Besides, the performance variables such as mean velocity of media particles and total impact energy provided useful insights into the milling operation. It was observed that the reduction in disk diameter yields lower wear rate of the disks at the cost of decrease in power draw at a constant high media loading. Whereas, when the media loading was decreased, the amount of wear and power drawn was comparable for both the most reduced and least reduced disk diameters. Therefore, there is an optimum choice of RDD for a given mill loading to maximize the mill performance while reducing the wear rate of the disks."

Jan 1, 2018

Results of the study of chloride ion concentration effect to osmium-187 sorption from wastewater of copper smelter with use of foreign anionites of different basicity and structure are presented in the work. It was found that the increase of chloride ion concentration in the wastewater helps to increase recovery of osmium using anionites regardless of their nature. The ways to intensify the process are proposed. The method for osmium elution from the anionites with potassium iodate solution was developed. It was shown that the method lets to recover up to 99% of osmium from the anionites. Recommendations for selection of eluents for better recovery of osmium from the anionites were elaborated. Keywords: wastewater, osmium, anionite, sorption, chloride ions, eluent, recovery

Sep 1, 2012

By V. E. Dementiev, V. I. Kulikov, G. I. Voiloshnikov, Yu. O. Fedorov

"The report presents the summary of the JSC Irgiredmet’s activities in the field of preconcentration of ores. As of 2018, the Institute has almost 40-years’ experience in this area. Over the years, Irgiredmet has done a lot of work – from development to implementation of new technologies of ore piece sorting and concentration based on X-ray radiometric separation (XRRS). INTRODUCTION Preconcentration has been a challenging issue of the mining industry over the last decades. The implementation of this technology can significantly increase mining efficiency. The main application of preconcentration is improvement of mined ores quality, however new and more complex issues have arisen with the evolution of the technology. Irgiredmet has started to develop an efficient preconcentration technology for gold-bearing and rare-metal ores 40 years ago. The X-ray radiometric method widely used at that date as a method of elements determination in geology and geophysics become the ground for this work (1). Since that time, the Irgiredmet Institute has developed and significantly improved the technology of piece ore sorting, or XRRS (2-5), that is currently also known as the X-ray fluorescence method. The progress of the XRRS development achieved by Irgiredmet in cooperation with Rados LLC, Tekhnoros LLC (Krasnoyarsk), Rados-Service LLC and CJSC Tekhnogen (Ekaterinburg) has proved efficiency and applicability of the XRRS technology for processing a wide range of minerals and solving of various technological problems (7-9) compared to other radiometric methods (6). Furthermore, obtained results are supported by numerous studies, trials and implementations. The significance of ore preconcentration for greenfield and brownfield projects determined the establishing a new subdivision of Irgiredmet, the XRRS Technology Center (XRRS TC), that has provided the Institute with a completed range of processing technologies, from preconcentration to producing final products. Over the past few years, the XRRS Technology Center has carried out studies and testing of a numerous (more than 100) projects, mines and deposits of gold-bearing ores, rare metal ores (Be, Ta, Nb, W, Mo), base metal ores (Cu, Sb, Zn, Pb), ferrous metal ores (Fe, Ti, Cr), rough diamonds and coal. The XRRS Technology Center performs various specific studies and testing not only in Russia, but as well as in Kazakhstan, Georgia and Mongolia. Mines and companies from Chile, India, China, Iran and other countries also take an active interest in the XRRS technology."

Jan 1, 2018

By B. A. Kutlin, S. A. Ropeyko, N. A. Yurlova

"The aim of NPO RIVS research and practice activities is to minimize impact of the mineral processing plants (MPP) on environment by using new concentration methods, high-technology equipment, implementation of engineering solutions directed to reduce emission of polluting substances (PS) into atmosphere, application of low-waste technologies, decrease of water withdrawal from a surface water or groundwater source for process needs. In our studies environmental safety of mineral flotation is provided through technologies using highly selective chemicals, that leads not only to reducing reagent consumption, and production of saleable products of high content of extracted minerals, but also to reducing pollutant emissions, decreasing supply of surfactants (SAA) in natural geosystems, primarily, in ground and surface waters. Decrease of water withdrawal from a surface water or groundwater sources for process needs can be achieved by using closed circuits and waste water treatment for further use in process operations, recycled water conditioning to obtain optimum quality parameters for process operations of concentration. Concentration in water (wet processing), tailings dewatering and semidry and dry (filtration cake) stockpiling in tailing ponds, efficient dust-collecting systems contribute to pollutant emission reduction. Use of mineral wastes – concentration tailings as a source of valued components, facilitates efficient use of natural resources and reduces wastes and its impact on natural ecosystems due to smaller areas of damaged lands during waste products disposal. Process and engineering solutions of NPO RIVS that allow diminishing impact of MPP on natural environment (NE) have been implemented in mining and processing complexes of Russia, Kazakhstan, Ukraine, Kirghizia and Mongolia. Compliance with environmental safety requirements contributes to enhancement of mineral processing and sustainable mineral development.INTRODUCTION Mining and processing complexes have a significant impact on environment as a result of extraction and recovery of mineral resources, landscape changes, waste disposal and, as a consequence, pollution of soils, surface and underground water sources. Therefore, the aim of the operation of the mineral processing enterprises in its research and practical activities is to reduce impact on environment due to new beneficiation technologies, high-technology equipment, implementation of engineering solutions directed to reduce emissions of polluting substances (PS) into atmosphere, use of low-waste technologies, decrease of water withdrawal from a surface water or groundwater source for process needs. Compliance with the requirements of environmental safety encourages advancement of mineral processing technologies and sustainable mineral development. Concentration in water, tailings dewatering and semidry and dry (filtration cake) stockpiling in tailing ponds, efficient dust-collecting systems contribute to pollutant emission reduction. Use of mineral wastes – concentration tailings as a source of valued components, facilitates efficient use of natural resources and minimizes waste formation and its impact on natural ecosystems due to reduction of damaged land areas during waste disposal."

Jan 1, 2018

By Dmitriy Makarov

The paper presents the modeling and analysis of oxidation of pyrite copper-zinc ore samples from the Letnee, Yaman-Kasy and Valentorskoye deposits. It is found, that the oxidized samples contain copper and zinc sulfates that are leached under the sample and water contact. It is shown, that sulfide floatability is decreased by the longer-term oxidation.We advise to improve nonferrous metals recovery by joint leaching and ultrasonic treatment of oxidized compounds. Study of the geotechnological processes of non-ferrous metal extraction, on the basis of two copper-zinc ore deposits shows, that heap leaching is of little use for the ores of the Letnee deposit. Leaching results for the Yaman-Kasy ore showed more promise.

Sep 1, 2012

By Y. Y. Emelianov

The results of the test work of four treatment options of three refractory gold-pyrite and gold-arsenic flotation concentrates are presented. These concentrates were obtained during the concentration of primary ores of large gold deposits. It was found that ultrafine grinding of refractory flotation concentrates did not increase the recovery of gold during subsequent cyanidation. The elimination of sulfur and arsenic during oxidative roasting is 99 per cent. 88-93 per cent of gold is recovered by cyanidation from calcines. After biooxidation of the flotation concentrates with a mixture of strains Acidithiobacillus thiooxidans and Acidithiobacillus ferrooxidans 88-91 per cent of gold is recoverable by direct cyanidation. The recovery of gold from flotation concentrates by pressure oxidation is 88-99 per cent. These results suggest that gold recovery is important but the following strategies would have an impact on a plant performance and would be considered when developing an option to treat refractory ores: capital and operating costs, ore reserves, mine location, infrastructure and qualified staff. Keywords: gold, flotation concentrates, recovery, cyanidation, roasting, biooxidation, pressure oxidation

Sep 1, 2012

By Maurício Torem, Gabriela Huaman, Antonio Merma

The purpose of this review paper is to succinctly present the most significant works related to Mineral Processing and Environmental Bioremediation and developed by the Mineral and Environmental Technology Group (METG) of the Materials Engineering Department of the Pontifical Catholic University of Rio de Janeiro (PUC-Rio). In mineral processing it was emphasized the use of the Rhodococcus opacus bacteria as a bioreagent in the bioflotation of some mineral samples (magnesite, calcite, hematite, quartz and apatite). The adsorption of the bacterial cells on the mineral surface can be due to specific and/or non-specific interactions, which will depend on several factors, as their surface charge and hydrophobic character. The zeta potential evaluation of the mineral particles before and after interaction with the R. opacus cells showed that the biomass modified the zeta potential profiles of the minerals, which confirm the adsorption of bacterial cells on the mineral surface. Moreover, the bacterial cells adsorbed caused a change in the mineral flotability which is related to a change in their hydrophobic character, thus, the mineral bioflotability was found to be dependent on the pH and the bacterial concentration. On the other hand, the environmental bioremetiation assessed the biosorption potential of three metal ions (lead, copper, and cobalt) by four different biomass Streptomyces lunalinharesii, Rhodococcus opacus, Rhodococcus ruber and coconut shell powder. For this purpose, biosorption process was characterized under different operating conditions such as initial pH and biosorbent dosage. The Freundlich and Langmuir isotherm models were applied to the equilibrium data obtained at different concentration.

Jan 1, 2014

By Kunihiko Yamaguchi, Gjergj Dodbiba, Toyohisa Fujita

Usually magnetic separation is performed to separate ferromagnetic, paramagnetic and diamagnetic particles by controlling magnetic field strength. In this research the wet high gradient magnetic separation at various kinds of magnetization of medium has been investigated to separate different kinds of magnetization of paramagnetic mineral particles from each other. Most of week paramagnetic particles are captured at high magnetic field using superconducting magnet. If the magnetization of fluid is larger than that of paramagnetic particle, the paramagnetic particle cannot be captured in the direction of magnetic field. The paramagnetic particles of different magnetization such as hematite, chromium oxide, perovskite and rutile are separated in different magnetization of fluids. These particles are present in the incinerated bottom ash. The separation is useful to recover titanium oxide from bottom ash and the removal of chromium of bottom ash is important to reuse the bottom ash as cement. The used fluids are paramagnetic liquids dissolving paramagnetic salts and the water based magnetic fluid dispersing the stable ultrafine magnetite. The dispersion condition of particles related to zeta-potential of the suspension feed is also important to separate effectively by controlling pH

Jan 1, 2014

By A. V. Bogdanovich

In diamond ores processing, final waste tailings size, rejected to dump, is one of the most important parameters. On one side, it is necessary to minimize losses of diamonds, whose size exceeds 1 mm, on the other side ? to provide for the plant high throughput and sufficiently low capital and energy costs, which is in greater part connected with disintegration process. Extensive laboratory, pilot-scale and commercial-scale dressability studies of different types of diamond ores have been performed at JSC ?Mekhanobr Engineering? in recent years. With that, special consideration was given to determination of the required ores? disintegration size that would provide for a high recovery of diamonds. In diamond ores processing, in order to exclude breaking of large diamonds, stage disintegration is used with regrinding of light fractions and heavy fraction X-ray fluorescent separation tailings. On account of rather weak bonds of diamonds with enclosing minerals, in crushing and grinding of diamond ores, selective disintegration takes place, with aggregates? breakup along plane surfaces of least bonding, which facilitates liberation of diamonds and their transition to free state. Heavy components losses with different sizes of final dump tailings were studied in processing of large samples. It was established, that in order to almost completely exclude losses of heavy components over 1 mm size, light fractions had to be ground to 2.5-3 mm size, while X-ray fluorescent separation heavy tailings of -15+3 mm size do not contain diamonds larger 1 mm in aggregates, and their regrinding does not increase total recovery of diamonds. On the basis of the conducted studies, relationships regarding heavy components and diamonds losses with respect to diamond ores final disintegration size were obtained, providing for more rational organization of the ores disintegration and processing flow sheet. Keywords: diamond, waste tailings size, disintegration process, recovery of diamonds

Sep 1, 2012

This paper presents a theoretical investigation on the ionic equilibrium of Fe(III)?Ni(II)?H2SO4?H2O system. A non-ideal speciation model is developed to calculate the concentration distribution of iron and nickel species in a mixed ferric and nickel sulphate aqueous solution over the pH range from 0 to 4 and temperature from 25 to 100°C. A series of speciation diagrams for iron and nickel species is plotted with the effects of ionic strength and temperature on the equilibrium constants being taken into account. The ionic strength-dependent equilibrium constant is treated through a semi-empirical Vasil&apos;eV equation, which is based on an extended Debye?Hückel theory. A Helgeson model is applied to extrapolate the equilibrium constant to elevated temperature. The ionic equilibrium reactions are described by a group of numerical equations containing the temperature and ionic strength-dependent equilibrium constants, which are solved by the Newton-Raphson method. The speciation model is also applied to estimate the hydrogen ion activities and corresponding pH values. The calculated pH values are in agreement with the experimentally measured pH, and are compared to literature data and pH values produced by the Visual MINTEQ® program (a computer code for the calculation of chemical equilibrium in natural aqueous system). This investigation provides a deep insight into the ionic equilibrium behavior of a mixed metal sulphate aqueous system which commonly occurs in hydrometallurgical processing. Keywords: speciation, chemical modelling, thermodynamics, iron, nickel

Sep 1, 2012