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By R. Q. Honaker

A significant problem in ultrafine particle classification is the significant amount of submicron particle by-pass to the coarse particle stream. In classifying cyclones, submicron particle by-pass to the underflow stream can be reduced by decreasing water recovery. Past studies have shown that a reduction can be realized when the feed solids concentration is increased or the apex diameter is reduced. However, both adjustments tend to increase the particle size cut point and negatively affect classification efficiency due to the impact on slurry rheology. The addition of a viscosity modifier to the feed stream of a classifying cyclone improved the classification performance and decreased the particle size cut point over a range of feed solids concentrations. The detailed test program investigated the use of the modifier in conjunction with varying apex diameters to identify conditions that minimize ultrafine by-pass. With small apex sizes, roping conditions were readily eliminated by the addition of viscosity modifiers. The addition of the modifier had no deleterious effect on froth flotation performance, which commonly serves as a downstream separation process. The fundamental and practical benefits of viscosity modifiers in classification processes are discussed in this publication.

Jan 1, 2006

By Y. Tanaka, M. Maeda, S. Suzuki, C. Tokoro, T. Kato, K. Muto

Boron (B) co-precipitation was investigated with ettringite to establish a cost efficient method of removing B from acid mine drainage. For 25 mg/L of B solution, most appropriate pH for B removal was pH 11.5. The most appropriate amount of reagent for B removal within Japanese effluent standard (10 mg/L) was B:Al:Ca:SO4 = 1:3:9:4.5, which corresponds to the composition of Ettringite (Al:Ca:SO4 = 2:6:3). The effect of silicate, carbonate and temperature on efficiency of B removal is important as groundwater and hot spring water are often contaminated. When silicate and carbonate are present, more Al and Ca salts are needed for B removal since some aluminum and calcium precipitate with silicate and carbonate as kaolinite and calcium carbonate. These precipitates do not contribute much to B removal. As the temperature raised, the most appropriate pH for B removal decreased. B removal became less efficient as monosulfate precipitated more rapidly as ettringite.

Jan 1, 2015

By Thomas Clark

This report presents a review of the distribution and exploration potential of platinum-group elements (PGE) in Québec; it is based on published and unpublished analytical data. This qualitative evaluation of the PGE potential, whether in PGE-dominant deposits or in Ni-Cu-dominant deposits with co-product PGE, is based on interelement ratios such as Ni/Pd, Cu/Ir, Cu/Pt, and Cu/Pd. Good PGE targets, i.e., deposits associated with magmas fertile in PGE, are identified. Less favorable PGE targets, i.e., deposits associated with PGE-depleted magmas, are also mentioned. The importance of exploring for deposits similar to those at lac des Îles and East Bull Lake (Ontario) is emphasized.

May 1, 2001

By V. I. Ryaboy, V. P. Kretov, I. V. Ryaboy, E. D. Shepeta

This paper studies the features of known and newly synthesized dialkyldithiophosphates and reagents with thioamide groups when separating copper-containing and arsenic-containing minerals in the flotation of skarn-scheelite-sulphide ore at the Primorskaya concentration plant. The optimization of dialkyldithiophosphate collectors was based on the study of their surface activity at the liquid-gas interface and estimated hydrophobic abilities. The flotation experiments show that the selectivity of action of the reagent increases with an increase of its surface activity and a reduction of hydrophobic ability when separating chalcopyrite and arsenopyrite. IMA-225-5 was proposed as a more efficient dialkyldithiophosphate collector, which increases the recovery of copper by 2.8% compared to the industrially used collector IMA-I413. Selection of the optimal structure for reagents with thioamide groups (derivatives of thionocarbamate and thiourea) was carried out according to their acidity and the presence of hydrophilic particles in their structure. Calculations were performed depending on the pH of the solution of chalcopyrite to determine the optimum reagent sorption and to further optimize the structures of these reagents. The tests with reagents with thioamide groups show an increase in copper recovery by 3-4% together with a significant increase of arsenic content compared to IMA-225-5. As a stronger collector with thioamide groups, it was recommended to use sample 234, which belongs to the thiourea derivatives. IMA-225-5 was recommended for industrial tests at the Primorskaya concentration plant. Thus, this study has shown that using dialkyldithiophosphate is more appropriate if it is necessary to increase the selectivity of separation of copper-containing and arsenic-containing minerals, and using reagents with thioamide groups, or their combinations with dialkyldithiophosphates, is more appropriate if it is necessary to increase the recovery of copper or the quality of copper concentrate with less selectivity of the process.

Jan 1, 2016

By Neillm Alastair S.

"This paper looks at what has happened in the past decade in the rare earth industry, particularly for those companies outside China trying to develop alternative projects to the Chinese dominated supply chain. The rare earth industry has gone through a metamorphosis over the past decade. The industry was basically unknown outside China until overnight it became the next hot topic on the financial streets of Canada and Australia. Suddenly various junior miners shifted from uranium and other out-of-favor commodities to rare earths as funds were easy to access from an investment community that did not understand the complexities of the space. The initial funding was done on traditional junior mining metrics of grade and deposit size. This has morphed over time to:1) Lights versus heavies2) Making a concentrate3) The importance of separation4) Off-take agreementsAt the peak of the market frenzy certain flagship operations were built using the “Not Made in China” moniker. Unfortunately certain errors were made during implementation, which are finally coming to the surface and making the rest of the pack wondering what will happen next. A review and update of some of the mistakes made and lessons learned will be discussed.BACKGROUNDAbout ten years ago awareness started to form around the rare earth industry and various groups recognized that because of the closure of Molycorp, Mountain Pass, and the dominance of China, there was a risk of uncertainty of reliable supply. This was not news for those active in the industry like Rhodia (now Solvay), the Japanese, South Koreans and other key consumers but to others it was like a light went on and rare earths became the new “.com” trend for investment banks, investors and some mining companies looking for the next hot topic.In the late 1990’s Molycorp accounted for around 20-25% of the world’s supply of rare earths, mostly lights (La, Ce, Pr and Nd), with small amounts of heavies from other sources. Then environmental issues forced the closure of the operation at Mountain Pass. Within six months China had increased production to plug the gap in supply. Around that time China was developing a strategy to leverage their position in rare earths and implemented a series of regulations to increase the value added component of rare earths inside China."

Jan 1, 2016

By Walter Greaves

THIS paper describes a series of tests performed at the Hollinger mill during the past four years, in which both metal and rubber-lined pumps were used for pumping sand and slime. While conditions will not be the same at other mills, it is felt that the information gained from the tests should be of value to other operators and of assistance to them in selecting the most efficient size of pump and kind of lining for economical operation. For the successful operation of pumps with rubber linings there are certain conditions, which, if recognized at the outset, will save the operator a good deal of work and trouble. First is the necessity of keeping sharp pieces of steel, or anything that might cut the lining, out of the pumps. This can be effected by placing screens in the proper locations. Second is to recognize the fact that the rubber lining of the shell, and the rubber cover of the impeller, are subjected to very different conditions. The shell lining, :being at rest and well supported by the metal case, has a relatively easy job compared ? with the impeller covering, which is subjected to centrifugal force and has a tendency to tear itself away from the metal core. Also, the pulp travels through and past the impeller at a high velocity. These two factors, centrifugal force and velocity of the pulp, would appear to set a limit to the speed at which, for a given set of conditions, it is economical to run a rubber-covered impeller. Therefore, a pump should be large enough for the work to be done. To get the best mechanical efficiency, it must be operated somewhere near the limit of its capacity, but this may not give the best overall cost, because the saving in power, due to the high efficiency, may easily be lost through excessive wear on the lining. It would appear that this condition is more critical in a rubber-lined pump than in one lined with metal.

Jan 1, 1939

By K. Huang, L. Pan

"Darcy’s law has been used extensively to model cake filtration. It is a macroscopic model, in which particle size dominates the kinetics and cake moisture. In the present work, a capillary flow model has been developed from first principles to study the effects of microscopic parameters such as capillary radius, boundary layer slip, disjoining pressure, and surface tension that may be important for dewatering ultrafine particles. Laboratory-scale pressure filtration tests show that dewatering kinetics is strongly dependent on capillary radius, which in turn is influenced by surface hydrophobicity, surface charge, and length scales of particles. The model parameters determined from laboratory-scale filtration tests show that use of a hydrophobizing reagent can greatly improve fine particle filtration due to increased slip and decreased capillary pressure. The kinetics of dewatering kaolin clay is fastest at a pH where the layer-structured particles coagulate with a face-to-edge orientation. The capillary flow model developed in the present work may be useful for designing filters and optimizing operating conditions.INTRODUCTIONIn 2014, Canada produced 2.2 million barrels per day of crude oil from the oil sands resources in Alberta, which is expected to grow to 3.2–4.0 million barrels per day by 2030 (CAPP, 2013). One of the challenges to meeting these projections is the tailings management. At present, the industry uses ?77 km2 of the lands to construct tailings ponds. Significant amounts of the tailings disposed to the ponds are silts and clays that are slow to settle and consolidate, creating problems for reclamation. It is, therefore, the objective of the present work to develop a filtration model that may be useful for developing advanced dewatering technologies that can address the tailings management issues.Darcy’s equation is the governing law for filtration. It was derived as an empirical model by H. Darcy in 1856 while he was studying fluid flow in sand filters (Hall, 1956). Since then, many investigators derived it from first principles. It relates superficial fluid velocity to the pressure drop across a porous medium of known permeability. In filtration, the latter can be related empirically to particle size using the Kozney equation (Yoon, 2005)."

Jan 1, 2016

By Baisheng Nie, Longlong Yang, Tao Yang, Wenjie Jia

"Gas adsorption in coal is an exothermic and physical process. Temperature might change during the dynamical process. In order to get the temperature variation of gas adsorption process, the experiment system which can test the temperature variation and analyze the thermal effect was established. Gas adsorption experiments under different conditions were done by using the test system. The results show that temperature increases during the adsorption process. It is an exothermic reaction process. Also, the temperature variation and the variation gradient increase with the increasing of equilibrium pressure. The temperature variation value is smaller if the experiment temperature is higher. The paper will provide basic experimental data for explaining gas adsorption mechanism better.INTRODUCTIONChina is the largest coal producer in the world while it also has the most serious coal mine disasters. According to the statistics, there are nearly a thousand coal mines in China including more than 110 the key state-owned mines risking to happen coal and gas outburst. Hundreds of coal and gas outburst occur each year which often causes serious casualties and economic losses (State Administration of Work Safety, 2007). With the continuing exploitation of the coal resources, the depth of the Chinese coal mines increases about 100 meters every year which causes the situation of gas accident becoming more and more serious (Xie et al., 2006).At present, the real mechanism of gas adsorption, desorption and the diffusion process in coal and the influence factor of it are not so clear. And because of the limit of prediction method and the technological level caused gas accident prevention theory and technology not so valid."

Jan 1, 2015

By China University of Mining & Technology, Yuemin Zhao, Bo Zhang, Liang Dong, Zhenfu Luo, Chenlong Duan

"In China, approximately 65% of coal reserves are in the west region, where water shortage is a serious problem: high-efficiency dry coal beneficiation technology is desired. Using magnetic powder and fine coal as heavy medium, and using air as the fluidizing agent, a novel air dense medium fluidized bed separator is proposed for coal preparation. Coal can be efficiently separated according to density in the fluidized bed, where bed density is steady. The separator is highly reliable, the circulation quantity of heavy medium is low, and the gas distributor cannot be easily easily. The world’s first industrial modularized dry coal preparation plant was built by China University of Mining and Technology. Dry coal beneficiation technology was first used to produce low-ash coal. Results of industrial production show that the ash content of clean coal is 3.46%, the probable error E value is 0.055 g/cm3, and the organic efficiency is over 90%. The advantages of the modularized dry coal beneficiation system are the high separation accuracy, the simple process flow, the low operation cost, low energy consumption, and so on. This technology provides a new effective method for coal separation in acid region and coal tending to sliming.INTRODUCTIONCoal is the most important primary energy source in China, where coal output reached 3.68 billion tons in 2013 and represents approximately 68% of the primary energy consumption. Coal has made a great contribution to the development of the Chinese national economy, but it also brings serious environmental pollution. However, approximately 65% of coal reserves are in the arid west region in China where water shortages present a challenge for wet coal preparation technology. In addition, the abundant lignite resource, because it is easy to mud in the water, should not be treated with the wet separation method. Therefore, it is critical to develop highly efficient dry coal preparation technology to meet the demand in arid areas. Further, water resource shortages are a global problem, thus the development of efficient dry coal preparation technology in has potential application in other water-short countries like South Africa, Brazil, India and Turkey."

Jan 1, 2016

By Zhiyang Long, Ruiling Xiao

"A mine shaft is one main development method of establishing access in an underground mine. The construction technology of the mine shaft sinking is complicated and large equipment setup on surface and in the mine shaft. The paper briefly reviews a single-line operation method, parallel operation method and mixed operation method as well as the features of the one operation method with the excavation, lining and installation. The special construction technology mainly would include ground freezing methods, full diameter shaft drilling methods, caisson methods, grouting technology and concrete curtain methods as well as other methods. The paper summarizes the shaft sinking numbers and effects by the special construction methods during different periods. The paper states the shaft sinking conditions and the each created record conditions in the coal, metallurgy, non-ferrous metal, hydropower, highway, railway, nonmetallic and other industries. The paper has a prediction on the shaft sinking requirements and development tendency in the future for China.INTRODUCTIONA mine shaft is one main development method of access in an underground mine. In recent years in China the new shaft mines represent 45% of the total number of new mines. With the development of new mining area under construction and the development of deeper mines, the ratio of the mine shaft as access for underground mines will increase. The construction technology of the mine shaft engineering will be complicated, the operation site footprint will be small and the working environment will be more difficult. The mine shaft sinking operation will often be varied by the geological conditions and affected by underground water inflows, seam gas outbursts, geothermal and other natural conditions. The safe construction of the mine shaft sinking will be challenged by all these conditions. Although the mine shaft engineering will only be about 5% of the total mine roadway engineering, the mine shaft construction period often will take over 40% of the total mine construction period. With the progress of modernized mine production technology and the construction of a high production and high efficient mine, the mine transportation roadways mostly would be set in the seam and the engineered amount of the mine rock roadways reduced year by year could cause more prominent long extensions of the mine shaft construction period. Therefore, in order to speed up the construction, to shorten the mine construction period and to realize the investment benefits as early as possible, the technical level of the mine shaft sinking should firstly be improved and the construction speed of the mine shaft engineering and sinking should be speeded up, which would have important significant benefits."

Jan 1, 2019

By Dharmendr Kumar, Pradip, Sivakumar Subramanian, Beena Rai, Venugopal Tammishetti

The separation efficiency in a mineral processing plant is generally assessed and reported in terms of elemental assays constituting the minerals of interest. However, different minerals comprising of same elements behave differently under similar process conditions. Thus, it is imperative to track the mineral composition thank elemental composition of different streams in a processing plant. The availability of automated mineral analyzers such as QEMSCAN and TESCAN in recent times has made it possible. However, due to the high cost and expertise required, their adaptation in day to day monitoring of operations is not yet a common place. X-ray diffraction (XRD) profile fitting (Rietveld Refinement) is another technique which can provide estimates of mineral proportions in a sample. The results of Rietveld Refinement however are affected by coating of fines on coarse particles, method of sample preparation, particle size distribution of sample, elemental substitution in mineral crystal lattice. In the present work, we propose a simple and efficient method for quantitative estimation of minerals in iron ores using elemental assays and thermo-gravimetry analysis data. The minerals (hematite, goethite, gibbsite, kaolin and quartz) are identified using powder XRD analysis. It is also observed that goethite contains Al substitution in the crystal lattice. The samples were analyzed for %Fe, %Al2O3 and %Silica using chemical analysis. The measured Loss on Ignition (LOI) in the sample is contributed from goethite, gibbsite and kaolinite phases. LOI from gibbsite and goethite occur in temperature range 250–350°C and LOI from kaolinite occur in temperature range 400–700°C. According, LOI are determined in two different temperature ranges that are 100–400°C and 400–850°C. We have used the data to successfully determine the mineral compositions of iron ore samples. We have also employed a data reconciliation algorithm on the calculated data for further improvement and consistency of our results. Our method is very convenient for quick estimation of mineral proportions in a sample. The proposed method can also be used for quantitative phase estimation in bauxite ores and red muds.

Jan 1, 2016

By T. Grammatikopoulos, K. Gibbs, H. De Souza, C. Gunning

The mineralogy of any ore body is a key factor in defining ore zones and predicting minerals/metals behaviour during processing. The determination of forms of gold, defined as the different chemical states in which gold is encountered in ore deposits, is critical. The most commonly known form is that of gold minerals and alloys, while other forms of gold have been collectively described in the literature as submicroscopic gold (i.e., less than 1 µm in diameter). Gold mining operations generally deal with very low-grade ores, in the order of a few g/t, in which gold displays complex mineralogy. These difficulties complicate the mineralogical studies and pose challenges for processing and recovering the gold. A comprehensive understanding of the chemical forms of gold is necessary to define gold mineralization and optimize gold metallurgy. SGS Canada Inc. has been using QEMSCANTM and a Tescan automated SEM that are automated mineralogical techniques that provide vast amounts of data for microscopic Au. The data in conjunction with other physical and chemical methods provide a comprehensive delineation of the ore composition and behaviour.

Jan 1, 2011

By S. P. Lowe

Flotation testing of Flin Flon ore was started in the Denver laboratory of Complex Ores Recoveries Co. in March, 1926. There had been a considerable amount of flotation testing previously which had shown possibilities of success, and it was felt that, with the increased knowledge of flotation and the comparatively new reagents then available, flotation held out the best prospects for a successful commercial treatment of this ore. There remained available for this experimental work a small amount of the rejects from a thorough sampling of the mine and some ore from the mine dump.

Jan 1, 1930

By F. Habashi

Lead is an ancient metal, has been produced to-date from its ores exclusively by pyrometallurgical route. The process suffers from high operating cost and excessive pollution problems. Extensive research has been going on since the beginning of the twentieth century to find a non-polluting process for its production and a solution for its complex refining scheme. It has been assumed correctly that the hydrometallurgical route should be the most promising. Pilot plants have been constructed and operated for a reasonable periods, but no process has proved to be satisfactory. As a result, a number of smelters and refineries have been shut down. The present review analyses the situation and suggests that the best route to treat lead sulfide concentrates is by leaching with fluoroboric acid, HBF4, containing ferric fluoroborate, Fe(BF4)3, and electrolyzing the solution in a diaphragm cell - - a process recently invented by Italian metallurgists. In this process, any silver present in the concentrate remains in the residue together with elemental sulfur and can be recovered by known methods.

Jan 1, 2008

By R. Loney, M. Militzer

There is a significant demand for new high strength steels with fine grain sizes for structural applications. One approach in this regard is to develop hot-rolled HSLA steels where refining the microstructure leads to increased strength levels, e.g. 700 MPa yield strength, that can be attained by suitable modifications of chemistry and processing. Here, an HSLA steel is investigated that contains 0.05wt%C-1.65wt%Mn-0.20wt%Mo¬0.07wt%Nb-0.02wt%Ti and approaches the above strength class. The ability to control and predict the mechanical properties of hot rolled steel depends strongly on the thermomechanical processes, which the steel undergoes. The final microstructure and, thus, the properties of the hot-rolled steel are a function of the austenite decomposition obtained during accelerated cooling on the run-out table and precipitation during coiling. The austenite-to-ferrite phase transformation under run-out table conditions has been investigated using a Gleeble 3500 thermomechanical simulator equipped with a dilatometer. The effects of cooling rate and initial austenite microstructure including the degree of work hardening on austenite decomposition kinetics and ferrite grain refinement have been quantified. Results show that grain refinement can be optimized by the presence of work hardened austenite and accelerated cooling. Based on the experimental results, a model is proposed to predict the transformation start temperature and the resulting ferrite grain size for run-out table cooling conditions.

Jan 1, 2004

By E. A. Roux

As the first mine-to-metal zinc operation utilising atmospheric leaching, solvent extraction and electrowinning, Skorpion Zinc faces unique challenges and opportunities. One of these challenges is found in the solvent extraction circuit, in which di-ethylhexyl phosphoric acid (D2EHPA) is used as the organic extractant. Although D2EHPA is an excellent extractant for zinc, it suffers from the co-extraction of ferric iron, which is produced during leaching and by the corrosion of the grinding media. This situation is partially mitigated by iron precipitation in the neutralisation step prior to solvent extraction. Unfortunately, some ferric iron still reports to the solvent extraction process. This leads to a slow build up of iron in the organic phase. Chemical stripping is used to maintain the Fe concentration at an acceptable level. In this paper, the efficiency of the iron removal process is discussed.

Jan 1, 2006

By P. Mpofu

In this work, the modification of interfacial chemistry of colloidally stable kaolinite clay dispersion has been carried out to improve its flocculation performance and dewatering behaviour. Synergistic action between dispersion pH, hydrolyzable metal ion and high molecular weight polymeric flocculant structure type (anionic polyacrylamide-acrylate copolymer (PAM) and non-ionic polyethylene oxide (PEO)) was found to play a pivotal role in inter-particle bridging, the enhancement of the settling rate and extent of consolidation of the pulps. Flocculation with PEO led to higher settlings rates in acidic than alkaline pH, whilst for PAM, the maximum dewatering rate was achieved in the neutral pH range 6 - 7.5. Upon shear, the PEO flocculated pulps showed dramatic improvement in consolidation to 40 wt%, the extent of which was greater at lower than high pH values. For PAM-based pulps were however, not shear-responsive, lower sediment solid contents of 15 - 23 wt% was observed between pH 3 and 11. Hydrolysable metal ions, Mn(II) and Ca(II), used respectively at pH 7.5 and 10.5 in conjunction with PAM and PEO, significantly enhanced the settling rates and consolidation of the pulps. The findings exemplify the strong links existing between pH-mediated particle surface chemistry. polymer structure-conformation, inter-particle bridging and dewaterability of kaolinite dispersions.

Jan 1, 2004

By M. M. Holgate

"Porosity neutron deflection scales can be derived more easily by cumulative correlation than by the conventional method of plotting corresponding points on a graph. The micro-log can be used as a porosity datum for the neutron log by transforming the permeability cut-off it shows to a porosity cut-off by a permeability-porosity function obtained from core analysis. Porosity footage values calculated in this manner from the neutron log are within 20 per cent of core analysis values."

Jan 1, 1960

By Louis Frost

"1N 1951, the Dominion Steel and Coal Corporation, as part of a programme of modernization in their coal mining operations at Sydney Mines and Glace Bay, Nova Scotia, undertook the development of two large cross-measure tunnels, which were to be used for the purpose of raising the coal from the underground workings by conveyor belts direct to wash plants located on the surface.These tunnels were to reach from the surface to central loading points underground located at a depth of 600 and 900 feet, respectively. They were to be driven on a pitching gradient of 11 degrees to the horizontal, and they were to reach a length of 3,600 feet in the Sydney Mines area and 10,000 feet in the Glace Bay area.The longer tunnel, 19 feet in diameter, was driven a distance of 1,500 feet and, for domestic reasons, bas not yet been •completed. The other tunnel, in the Sydney Mines area, 18 feet in diameter, is steel supported and concreted throughout its entire length. This tunnel has been completed and will be in operation at an early date.The development of this particutar tunnel posed an additional problem, as the rock through which it had to pass was considered to be water-bearing. In the sinking of Princess Colliery shafts in 1866, a great deal of water had been encountered, and it had been necessary, while sinking, to line the shaft with cast-iron tubbing through the water-bearing strata. The shaft had to be lined for a depth of 300 feet at the upper end. It was anticipated that we would meet with difficulty in driving the tunnel through this strata."

Jan 1, 1955

By C. G. Anderson

Industrially proven and applied nitrogen species catalyzed (i.e. NSC) acidic pressure leaching has been utilized to treat a number of ores, concentrates and recycled materials. This versatile technology offers many advantages including low temperatures, low pressures, low capital costs, low operating costs, faster throughput and less costly materials of construction than conventional pressure oxidation. This paper will elucidate the application of this technology for production of gold, silver, palladium, rhodium, zinc, germanium, gallium, cobalt, copper and nickel. Recycled material applications will also be elucidated. In addition, details of an application for treatment of a refractory chalcopyrite copper and gold bearing ore will be presented and pertinent economics discussed.

Jan 1, 2004