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By L. X. Li

Coking coal producers often encounter variations in clean coal quality when mining multiseam deposits containing coals with different washability and coking properties. This paper describes how, for a single coal property, an initial clean coal specification with an ash content of 8.5% on an air-dried basis (ADB) and a free swelling index (FSI) of 5.5 can be improved to a specification with 7.5% ash content ADB and an FSI of 6. This is accomplished by sorting coal seams into two groups for processing and blending. A preliminary economic model demonstrates how this improvement enhances economic returns through a beneficial factor.

Jan 1, 2014

By T. Prietl

Metallurgical vessel linings are multilayered, consisting of refractory bodies, insulation materials, joints, and additional space to control for thermal expansion. A unique biaxial hot testing press (BHTP) was installed at the RHI Refractories Technology Center Leoben, Austria to enable the three-dimensional behaviour of complex vessel lining segments to be investigated under simulated service conditions. Using the BHTP, the heat up and thermo-mechanical behaviour of magnesia chromite brick lining segments with and without mortar filled joints were examined. The results obtained during the initial heat up provided validation of CFD modelling of the lining system. In addition, after the heat up and under steady state conditions, the lining behaviour during deformation-controlled compression and relaxation was examined. These analyses generated important data regarding the stiffness, joint compressibility, and brick damage of the lining segments after cyclic loading and unloading as well as the benefits of using mortar joints in the lining. These investigations were performed in collaboration with the Christian Doppler Laboratory for Secondary Metallurgy of Nonferrous Metals, University of Leoben, Austria. The BHTP has been operational since November 2004 and is providing information regarding the thermo-mechanical behaviour of different lining segments.

Jan 1, 2007

By C. Samuelsson, G. Carlsson

Characterization of dust from Boliden Mineral AB’s copper-plant in Sweden was carried out using chemical analysis, X-ray diffraction analysis, energy dispersive analysis and wave length analysis using electron microprobe equipment. Dust from four different locations was characterized: the electrostatic precipitator (ESP) after the roasting furnace; the ESP after the copper smelting furnace; from the copper converter ventilation bag house filter; and from the bag house filter collecting dust from the settling furnace and tap gas ventilation. The results showed that the dust is composed of small solid and/or liquid particles from the furnace reactor which have been transported with the process gas to the dust collecting devices. This portion of the dust is mechanically formed. It also contains compounds that have been vaporized in the process and then condensed from the process gas at lower temperature, chemically formed dust. The proportion of mechanical and chemical dust varies with the process generating the dust.

Jan 1, 2001

By A. E. McIlhinney, I. E. Puddington, C. E. Capes, A. F. Sirianni

"Two main problems are associated with the removal of pyritic sulphur from coals. The first is due to the fine state of dissemination of pyrite, which requires grindin1 to a very fine size to accomplish liberation. The second problem is caused by the similar surface chemical characteristics of coal and pyrite, which complicates separatio11 methods based on this property. In the work described here, the problem of fine particle size was overcome by using the selective oil agglomeratioa method developed at the National Research Council of Canada. Recovery of more than 90% of the combustible values was possible, even with particles only a few microns in diameter. Experiments using conventional chemical depressants for pyrite met with little success. It was found, however, that pyrite may be rejected during coal agglomeration through treatment with the iron.oxidizing bacteria, thiobacillus-ferrooxidans. The conditions for maximum pyrite separation are described and possible mechanisms by which the bacteria act are discussed."

Jan 1, 1973

By E. M. Córdoba

The effect of the Fe3+ lFe2+ redox couple on the chemical and biological dissolution of chalcopyrite was studied. All the tests were carried out in stirred flasks with 100 mL of a ferric/ferrous sulphate solution, in the absence or in the presence of bacteria (iron- or sulphur-oxidizing) and at low (35 DC) and high (68DC) temperature. The initial redox potential was controlled between 300 and 600 m V Ag/ AgCI and silver was used as chemical catalyst. The results showed that the oxidizing action of ferric ion on the chalcopyrite was controlled, in all cases, by nucleation and precipitation of jarosites on unreacted particles. The tendency of Fe3+lFe2+ solutions towards equilibrium favours the activities of both ions to be equal. Consequently, the dissolution rate was faster at relatively low redox potentials (between 400 and 500 mY) than at high values (600 mY). In this sense, the presence of ferrous ion in the system is a key factor to control hydrolysis and precipitation of ferric ion. Unlike jarosite, the elemental sulphur produced during dissolution of chalcopyrite was porous and did not act as a diffusion barrier.

Jan 1, 2007

By Dave M. Jakelski, Gerhard W. Heinrich, Peter F. Wells, Daniel F. Suarez, Jamie B. Beauchamp

"A need for increased copper concentrate production and for less nickel contamination in that concentrate at Falconbridge's Strathcona Concentrator during 1993 required the installation of a third flotation column and improvements in the operation of the existing circuit. Innovations in wash water distributor and launder design were fundamental in achieving objectives on a new 3 meter diameter column. Minnovex plug-type spargers were tested on a 2.1 meter diameter column in order to reduce maintenance requirements. The paper details the measures taken to enhance column flotation circuit performance and the results obtained.IntroductionFalconbridge's Strathcona Mill receives 10% of the ore feed from a rich copper zone in the Strathcona mine. This ore typically grades 7% copper and 1 % nickel and, because of its high copper content, it is processed in a separate circuit ('C' circuit) which consists of conventional grinding, rougher flotation with the concentrate being treated with lime to pH 12.3 and cyanide followed by column flotation. The columns are operated with mechanical flotation scavengers and the scavenger concentrate is returned to the column feed. Testwork conducted in 1991 showed that the original flotation column (Column 2) could only produce 5.5 mtph of concentrate with less than 0.5% nickel (Figure 1).Between 1991 and spring of 1993, production was increased at times by open circuiting the scavengers. Metallurgical improvements were obtained by improving the wash water distributor of Column 2 and by wash water sprays in conventional cells (1 ). However, the scavenger concentrate assayed 0. 7 -0.8% nickel and was not acceptable for long term operation. When Copper ore production targets were significantly increased for 1993, it became clear that an additional flotation column was required. The new flowsheet employs mechanical scavenger cells on the column tails as in Column 2 circuit (Figure 2). A -parallel configuration was chosen as pulp solids fraction has been shown to be a critical variable and the second column in series would receive a lower density feed."

Jan 1, 1994

By D. Harrington

Ventilation of underground workings consists in establishment of such control of air currents that the underground workers may work in safety, with maximum comfort and efficiency, and without impairment of health; and requires that the mine openings may be made subject to such control of air flow as to remove from these workings at ordinary times harmful gases and dusts, and that, at time of emergency, such as fire or explosion, there may be maintained as much or as little air flow as may be desired covering portions of the mine or the mine in its entirety. Control of air flow is the keystone of any ventilating structure, and this very essential feature is obtainable only by the installation of mechanically-operated fans, together with other;. ventilating devices such as doors, over-casts, regulators, etc. Every mine, large or small, coal or metal, should from the outset be equipped with a fan. While much has been written about natural ventilation and many claims made that in specific mines there is sufficient natural air flow, there are few if any mines, coal or metal, where natural ventilation supplies anything like adequately safe or healthful conditions for underground workers even at ordinary times; and at a time of mine fire or explosion, mines depending upon natural ventilation are practically helpless, and certainly are decidedly dangerous to those unfortunates forced to be in them. While ventilation has practically always been deemed an integral part of coal mining, metal mines have rarely paid much, if any, attention to air circulation until forced to do so by occurrence of some untoward condition or accident. Yet metal mines actually have as great need of efficient circulation of air as have coal mines. The coal mine must remove the dangerous explosive gas, methane, also fumes from explosives and, in occasional places, other gases such as carbon dioxide or nitrogen.

Jan 1, 1933

By K. Adham

Both the dry and the wet fluorination systems require hydrogen fluoride (HF) for the process of uranium conversion to uranium hexafluoride (UF6). The dry methods depend on the electrolysis of HF to generate the fluorine (F2) required for the high temperature pyro-fluorination. The wet methods require aqueous HF in water solutions for the low temperature hydro-fluorination (Argonne, 2019). This paper uses the available HF safety guidelines and industry information to discuss the issues of transportation, storage and utilization. Health effects and environmental considerations are reviewed. Safe practices for handling the HF (both as anhydrous and as aqueous) are considered. Proper selection of different materials of construction are discussed, for both the anhydrous and the aqueous HF.

Jan 1, 2020

By Corby G. Anderson

"Laboratory testing using industrial electrowinning solutions was performed to determine the best Faradic cell efficiency for copper cathode recovery. The variables tested were solution flow rate, recycle ratio, reagent addition combinations of guar and thiourea, and addition amount of acid mist suppressant CAL FAX DBA-70. The ideal flow rate was determined to be 37.85 litre/min. Additionally, the ideal recycle ratio was determined to be 10:1. The reagent addition scheme from testing which showed the highest efficiency was with 680 g/tonne guar of cathode copper won and with 135 g/tonne thiourea of cathode copper won. These values for reagent addition only reflect the best efficiency and should not be assumed to be the best reagent concentration for copper purity. The amount of foaming agent that showed the best efficiency was the test with 2 ppm of foaming agent. Again this amount of reagent is based on efficiency and should not be taken as the amount of reagent that does the best acid mist suppression. Additional proprietary surface characterization work indicates these additives may have enhanced the cathodic reduction surface morphology of some noble minor impurities. Subsequently, these operating parameters were introduced into the plant operation and proved successful after their implementation.BACKGROUNDCopper electrowinning has become a dominant technology for the production of marketable high grade copper cathode products. The literature is robust with applications, optimizations, additives and developments in this field (e.g., Classens & Harris, 1990; Pfalzgraff, 1999; Tozawa, Su, & Umetsu, 2003; San Martin, Otero, & Cruz, 2005; Houlachi, Edwards, & Robinson, 2007; Romero, Avila, Fester, & Yacher, 2007; Marsden, 2008; Beukes & Badenhorst, 2009; Vainio & Weatherseed 2009; Bender, 2010; Joy, Staley, Moats, Perkins, Uhrie, & Robinson, 2010; Khouraibchia & Moats, 2010; Moats, 2010; Rutledge & Anderson, 2015).Tests of forty hours duration and at room temperature were performed for this project using samples of actual industrial electrowinning solutions. These industrial solutions were comprised of 60 g/L Cu plus 65 g/L Ni, 3 g/L Fe, and 30 g/L free sulfuric acid. Other confidential minor impurities were also present including some solubilized precious metals. The testing apparatus utilizing stainless steel anodes and cathodes is illustrated in Figures 1 and 2."

Jan 1, 2016

By J. Kempken, R. Hagmann, C. -P. Reip, W. Hennig

The CSP technology symbolizes a highly productive process for the cost-effective production of steel grades with a range of sophisticated properties comprising both the inner quality of hot strip, its surface formation as well as the relating technological characteristics. Thanks to extensive development work undertaken during the last 15 years, the range of steel grades that can be produced was continuously expanded and the process technology optimized. The present paper describes the ongoing development work concerning the production of higher-strength, microalloyed pipe steels. The resulting hot strip, due to the associated thickness and the potential pipe diameters, is particularly suited for being processed to HFI-welded pipes. Based both on ferrite-pearlite as well as very fine-grained, ferrite-bainite hot-strip microstructures, strength levels of up to grade API X80 can be realized. It can be demonstrated that hot strip produced in a CSP plant has very good toughness values at temperatures down to -60°C and can even make application with required sour-gas resistance possible.

Jan 1, 2005

By Frederic Benard

THE Ontario Refining Company, Limited, wholly-owned subsidiary of The International Nickel Company of Canada, refines the entire blister copper output of the latter's Copper Cliff smelter. Prior to 1936, the blister was cast in 460-lb. cakes at the smelter, loaded on open cars, and transported by rail to the refinery, a distance of approximately 1 1/4 miles. Here the cakes were transferred to the plant narrow-gauge system, charged to furnaces, and re-melted. This procedure necessitated the operation of holding furnaces and casting machines at the smelter -extensive re-handling-and melting down of a cold charge at the refinery. Transfer of the copper in molten form direct from converters to anode furnaces promised a considerable reduction in costs, and this possibility was investigated. As a result, a portable holding furnace, or hot-metal car, was designed and constructed. It was placed in operation in July, 1936, to be followed a year later by three additional units of slightly modified design. Figure 1 shows the original car, and Figure 2 the lacer type. With four cars in service, operations were placed on an all 'hot-metal' basis.

Jan 1, 1938

By S. E. Jackson, L. J. Cabri

Quantitative determination of gold at sub-ppm concentrations in sulphide minerals is an important component of deportment studies for sulphide-gold deposits. Laser Ablation Inductively Coupled Mass Spectrometry (LA-ICP-MS) analysis is preferred for this application because it rapidly and cost-effectively provides spatially resolved (<20 pm), low ppb concentration data for gold and other elements in mineral grains. Recent advances in LA-ICP-MS analysis include the development and application of elemental mapping. Raw signals from multiple line scans or lines-of-spots are deconvoluted and calibrated to generate elemental maps which provide detailed information on spatial variations of gold and other elements within and between grains.

Jan 1, 2011

By C S. Walker

This paper analyzes the physical, operational and economic site conditions which were conducive to the design of a diesel-electric power plant wherein the over-all use of the thermal energy of the fuel exceeds 80 per cent. The heat energy supplied to the diesel engines is recovered in power generation, vapour phase cooling, waste heat boilers, air to exhaust gas heat exchangers and lubricating oil coolers. Electric boilers are also integrated into the plant design to enable the ratio of electric power output to heat recovery to be varied to suit the seasonal and daily variations. The criteria relative to thermal and electric power design requirements are discussed, and the design details of some parts of the plant which conform to these criteria are illustrated. Some data in regard to the actual operation of the plant over a short period are also included. Introduction THE Cantung mine (Canada Tungsten Mining Corporation) is located some 180 miles north-east of Watson Lake, Yukon Territory. It is situated on the upper reaches of the Flat river at an elevation of about 3,700 feet.

Jan 1, 1965

"The Hardy Cross algorithm offers a reliable method of solving network systems of fluid flow and has become widely used for solving water and ventilation flow networks. A limitation is that computational iterations and time to solve a network rises rapidly with the size of the model and modern detailed ventilation networks have typically grown to thousands of airways. Non-linear matrix solving methods can offer improved performance, however these are more complex and may be unstable if initial estimates are poor. This paper presents improvements that can be applied to the traditional Hardy Cross algorithm to greatly reduce iterations and solving time for large ventilation models. INTRODUCTION The Hardy Cross algorithm (Cross, 1936), was originally developed to solve water flow in city and urban pipe networks. Using principles of Kirchhoff’s electricity current laws, Hardy Cross developed an iterative algorithm for solving non-linear equations associated with network water flow. Traditional network analysis research refers to the various members of system networks as branches, nodes and meshes. This terminology has been changed in this paper to airways, junctions and loops respectively which are terms more familiar to engineers in mine ventilation. When Kirchhoff’s laws are applied to fluid networks, the following assumptions can be made: •The sum of fluid flows into a junction must equal the sum of fluid flows out of the junction.•The sum of pressure losses around any loop through a network system must be equal to zero.An iterative solution can therefore be achieved by initially guessing flow in a network, calculatingthe pressure losses around the network loops (Figure 1), and applying flow corrections using Newton’s method for each loop if the sum of the pressure losses does not equal zero. To solve the system, a loop must be defined for every segment or series of segments between a junction of 3 or more airways.The Hardy Cross algorithm has been used extensively for ventilation network analysis since the introduction of the first electronic computers (Tien, 1997), however numerous other variations and methods have since been developed through the use of matrices to solve the required system of nonlinear equations. Commonly used algorithms such as the Newton Raphson method (Brown, 1969), the Gradient method (Todini & Pilati, 1988), the Linear Theory method (Gupta & Prasad, 2000), and Coupled Network Solver (G. Danko, 2008) have found general use in fluid flow network solvers (Rossman, 2000). Despite poor and sometimes unpredictable convergence performance however, the Hardy Cross algorithm still has unique properties that make it attractive for ventilation models. Some benefits are:"

Jan 1, 2019

By The Hollinger Mill Staff

ALTHOUGH cylindrical grinding mills have long been used, there is wide divergence of opinion as to what constitute best operating conditions. Questions such as mill diameter, diameter-length ratio, revolutions per minute, type and size of grinding media, volume of charge, circulating load, pulp level, pulp consistency, liner design, and size of feed, have all been given serious consideration by competent scientific investigators as well as by operators. While many laboratory and plant tests have been made that would seem to justify certain definite conclusions, there is a dearth of definite data giving actual results obtained when a grinding mill working between fixed limits is operated at its maximum capacity under varying conditions as to ball load, circulating load, speed, etc. In tests conducted recently at the Hollinger, extending over a period of thirteen months, to determine the best operating conditions for a ball-mill 6 ft. 6 in. diameter inside the liners, some very interesting facts have been ascertained. This paper is presented in the desire to make public the results of these tests and not with the idea that the last word has been spoken in regard to grinding. We feel, however, that these facts justify certain definite conclusions and hope that, by the fullest and frankest criticism and discussion, the essentials necessary for the correct design and operation of grinding mills will become better known.

Jan 1, 1937

By O. E. Andrew

THE object of this paper is to present a brief summary of the dust control system in use on the 3,825-foot level at the jaw crusher station, Lake Shore mine. During the years 1936 and 1937, dust survey reports were presented to the management showing that high dust concentrations were being created during operating periods. At that time, however, this crusher was running only an hour or so each shift, and it was felt that no large capital expenditure for dust control equipment could be justified. In order to afford some protection to the operators, a number of respirators then on the market were .tested and the &apos;Comfo&apos; respirator was adopted for use by the crusher-men. In 1938 this crusher began to handle a large share of the total mine tonnage and the hours of operation were increased. Further dust sampling showed increased dustiness with the longer operating time. It was also realized that the operators suffered considerable inconvenience if they wore their respirators throughout the shift. If the respirators were not worn, then dangerous amounts of dust were being inhaled. The fact that the crusher station was situated on the 3,825-foot level limited the means that could be employed to eliminate the dust hazard. At that rime there was not available the 5,000 c.f.m. of fresh air which would be required to sweep out or dilute0 the dust, and there was also no way of disposing of the contaminated air without passing it on for other men to breathe. Thus it became apparent that a self-contained dust disposal system would have to be installed.

Jan 1, 1941

Pillars are used in various forms in underground mining. For several decades pillar design has been an issue in both soft and hard rock underground mining. The major use of pillars is in room-and-pillar type mining. Pillars are critical structures in the production levels of block cave mines. With most mines leaning towards the use of block caving for ore extraction today, pillar design has become even more important. Empirical pillar design is popular. The use of numerical modeling is becoming more common in the design of underground mine pillars. A critical review of both the empirical and numerical modeling approaches to the design of underground mine pillars reveal some fundamental flaws. In general, pillar design approaches often assume the pillars are vertical, and are subjected to pure compression. Pillar failure criteria are then based on this assumption. Most papers on numerical modeling for pillar stability assessment use vertical pillars. This paper shows that where pillars are not subjected to pure compression the empirical pillar design approaches are inadequate, and that when using numerical models for the assessment of pillar performance, more care is needed in the determination of the average pillar stresses. The practice of relating field scale pillar strength to laboratory scale intact rock strength determined from conventional laboratory compression tests in empirical design equations is misleading when pillars are inclined or subjected to compressive and shear stresses. New data is added to the hard rock empirical pillar stability chart, and it is shown that it is misleading to conclude that failure of pillars with width to height ratios greater than 2.3 should not be anticipated. New empirical pillar design charts are presented for pillars at various degrees of inclination for different ko-ratios.

Aug 1, 2013

By L. P. Chrismas

"IN 1975, Nova Scotia produced 1.8 million tons of coal with a FOB mine value of $47.6 million. Of this total, about 30 per cent or 600,000 tons was coking coal and the remainder was steam and industrial-grade coal. The Nova Scotia Power Corporation consumed 630,000 tons in three generating stations and 570,000 tons were sold to Sydney Steel for making coke for its steel operations. Exports, principally to Great Britain, comprised 370,000 tons in 1975 in addition to the 300,- 000 tons shipped to other provinces for use by cement and pulp and paper companies. In 1975, just over 100,000 tons of coking coal were imported into the province from Alberta. Before 1975, low-volatile coking coal was traditionally obtained from the United States. In 1975, production came from seven individual mines and one project involving reclamation from mine dumps in Pictou County. Of the seven producers, four are owned by the Cape Breton Development Corporation, a federal Crown corporation; the remaining three are small independent mines, but, even though small, they are sizeable contributors to the economies of their local areas. After 101 years of continuous operation, Devco's Princess mine was closed in 1975. The Nova Scotia coal industry, in terms of value, accounted for about half of total mineral production in 1975. The industry provides jobs for 3,000 men and women. It is also significant that in 1975 Nova Scotia produced about 6.5 per cent of Canada's total coal production of 28.3 million tons. Detailed statistics on Nova Scotia's coal industry appear in the Appendix."

Jan 1, 1976

In this study, we develop a detailed model of the likely future carbon footprint of primary copper supply. We develop a peak copper production model, based on a detailed copper resource data set, and combine this with a comprehensive life cycle assessment model of copper mining and milling to predict greenhouse gas emission rates and intensities of Australian and global copper production up to 2100. By establishing a quantitative prediction of both copper production and corresponding greenhouse gas emissions of Australian and global copper industry, we then analysed the emissions intensity of various energy input scenarios, such as business-as-usual, solar thermal electricity and solar thermal electricity with biodiesel. The Australian Government has an aspirational goal for long-term greenhouse gas emissions of an 80% reduction from the 2000 level by 2050. For the copper sector, this means moving from about 12.6 Mt CO2e in 2000 to a goal of some 2.52 Mt CO2e in 2050 (assuming equal emissions reductions across the economy). Based on the energy sources modelled, only the solar thermal plus biodiesel scenario was capable of achieving this goal at about 0.15 Mt CO2e, since the solar thermal alone scenario still includes normal petro-diesel as a major source of emissions. Overall, it is clear that there are abundant resources which can meet expected long-term copper demands, the critical issue is more the carbon (and environmental) footprint of different copper supplies and use rather than how much is available for mining. It is clear that the switch to renewable energy can have a profound impact on the carbon intensity of copper supply, even allowing for increased energy intensity as ore grades decline, and a complete conversion to renewable energy will position the copper sector to meet existing annual greenhouse gas emissions targets and goals.

Aug 1, 2013

By J. Mrozowski, R. Kurowski, A. Chmielarz, Z. Szolomicki

PbSO4 is a commonly encountered component of the materials used in lead recycling (e.g. battery paste) and in by-products of metallurgical processes (e.g. residues from zinc hydrometallurgy, dust from copper smelting). Smelting of battery paste results in SO2 emission and in generation of significant amounts of hazardous ‘white slag’. Those adverse phenomena can be eliminated by removal of sulphur from the paste. Lead-bearing by-product materials are of polymetallic character with usually low Pb content, which makes lead recovery technologically difficult and uneconomic. However it can be successfully achieved by extraction of lead sulphate from solid phase with triethylenetetramine (TETA) water solutions. That compound has capability for selective solvation of a whole lead sulphate molecule. Virtually pure lead carbonate can be precipitated by means of saturation of lead-loaded aqueous TETA solution with carbon dioxide, and complete regeneration of the extractant is achieved by fixing of sulphate ion into gypsum through operation of calcium hydroxide suspension. The paper presents results of the lab and pilot scale studies into process of battery paste desulphurisation and recovery of lead from the residue of zinc calcine leaching.

Jan 1, 2014