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By R Atmuri, W Liang, R Prasad, Y Liu, E Wingate

Yellow phosphorus (YP) has been commercially produced since the 1920s. First in the USA by the Tennessee Valley Authority (TVA), next in Russian (Kazakhstan) in the 1950s, and finally in China in the late 1970s and early 1980s. There are operations in Vietnam and Sarawak on a smaller scale. YP has become very in vogue due to its use in the production of lithium iron phosphate battery cathode precursor materials by the Chinese and other western battery manufacturers. The YP is also used to produce purified phosphoric acid and higher grades of acid using a thermal oxidation process after smelting. This paper will look at the basics of the smelting including slag chemistry, alloy chemistry and offgas chemistry. The paper will look at the design of the furnaces used in the YP production process as well as the downstream recovery of phosphorus from the smelter off-gas stream to YP. The next part of the discussion will focus on the operations of a YP smelter with regards to control of the furnace to optimise phosphorus recovery to YP. Will discuss tapping cycles for alloy and slag with a view to optimal phosphorus recovery. The discussion will close out with a review of operational challenges in the smelter and a brief description of the downstream conversion of YP to high purity phosphoric acid.

Aug 21, 2024

By K L. Silversides

Shales form distinctive peaks in natural gamma downhole logs, which are used to manually identify the location of ore boundaries. These shales form important lithology markers that can potentially be automatically identified using Gaussian processes. This approach is trialled using data from a typical iron ore mine in Western Australia which contains the Marra Mamba sequence of the Hamersley province.The method uses Gaussian processes (GPs) with a single length scale squared exponential covariance function. A library of 8 m sections, where natural gamma measurements were taken at 10 cm intervals down the hole, was used to train the GP model. This library was iteratively improved and was tested using natural gamma logs that were not included in the library. Areas that were misclassified or were not clearly classifi ed were added to the library. The new library was then used to train the model and improve the results. The trials used a double gamma peak from the NS3 and NS4 shales at the boundary between the Newman 1 and Newman 2 ore zonesin the Newman member and the AS1 and AS2 shales at the base of the West Angelas member. The results show that both boundaries can be identifi ed with an accuracy of over 99 per cent. The classification has the highest accuracy on undeformed shales. This method provides a fast, accurate and objective identifi cation of shale and ore boundaries and can potentially replace the current manual detection.

Jul 11, 2011

Natural Gas has been available in New Zealand for twenty years. During that time the gas share of the energy market has grown and now natural gas forms a significant part of New Zealand's energy scene, helping consumers to achieve a higher standard of living, and reducing dependence upon imported oil.Natural gas is now used for petrochemical manufacture and power generation in addition to direct supply to consumers.As concern for the environment continues to build, natural gas will have an increasingly important role to fill in these markets. This paper sets out the background to the development of natural gas in New Zealand and identifies the current markets. It then looks at those matters which are likely to influence the role of natural gas in the 1990s.

Jan 1, 1990

As the oxide reserves in an oxide/sulphide deposit are exhausted transition to the treatment of sulphides should be investigated in detail and well before processing the sulphide ore commences. The investigation should be broad based to consider all treatment options and not restricted entirely by the existing process plant treatment method. These options may include cyanidation, flotation, roasting, bacterial leaching or gravity treatment and are chosen on the basis of various testwork responses. Experiences in laboratory testing of sulphides and treatment of sulphides at various operations are discussed. This includes the treatment of copper/gold sulphides, CIP treatment of sulphides and treatment of marcasite ore in a conventional CIP circuit.

Jan 1, 1989

Over the last thirty years production of heavy minerals from Australian deposits has dominated the world market. The main incentive has been to suoply the raw material for titanium dioxide based pigments. These ~ninerals include ilmenite, rutile, leticoxene and more recently, synthetic rutile. Inevitably the viabilit/ of developing placer type deposits has seen influenced by other heavy minerals present, such as zircon and monazite, but these have been of secondary importance. For most of the sixties and seventies, Australia supplied the 'najority of free world rutile and zircon, and a large proportion of the ilmenite. With the run-down of rutile- rich reserves in eastern Australia, the emphasis has s:iifted in several countries, including Australia, to fill }the gap with i l Wen i to and its derivatives, leucoxene, synthetic rutile and titanium rich slag. over the next 15 - 20 years, as high grade beach placers in Western Australia are mined out, less traditional sources for mineral sands products will be opened up. Low grade placers (particularly those dominated by ilmenite) will be reassessed in Australia, U.S.A., Africa and Asia, and exploration will shift from beach and dune environment, to heavy mineral concentrations in alluvials, lake deposits and continental shelf deposits. At the same time, production of anatase and bastnaesite will be expanded, as required, from the huge resources contained in carbonatites in 3razil, U.S.A. and China.

Jan 1, 1986

That gold will dissolve in sodium hyposlphite solutions is known from the lixiviation of silver and gold ores.The gold will dissolve only in small quantities. According to Stetefeldt, if gold leaf is treated for a time with sodium hyposlllphite solutions of varying strengths solution takes place in every instance, the deviation in quantity being very slight.In order to form hyposulphite double-salts, the gold must become oxidised, the oxygen being derived from the air absorbed by the solution. Consequently, it is the quantity of free oxygen in the solution by, which the reaction is determined, as for one equivalent of gold dissolved one equivalent of caustic soda is set free.

Jan 1, 1901

By K J. Lownie, T Rafferty

The in situ testing of mine ventilation fan systems has been a contentious issue for many years. Site testing was generally undertaken by adapting standards that were developed for the laboratory testing of fans using standardised airways. The deficiencies inherent in this practice have been widely recognised by informed practitioners, and this led to the first stand-alone document specifically intended for the in situ testing of large fans (ISO 5802:2001 Industrial fans - Performance testing in situ).This paper describes the structure of the International Standards organisation and the processes that are followed in the course of preparing such a standard.The application of ISO 5802:2001 is briefly outlined together with how test data is assessed for compliance with the suppliers guarantee. This paper must be read in conjunction with ISO 5801:2007, ISO 5802:2001 and ISO 13348:2007.CITATION:Lownie, K J and Rafferty, T, 2013. A review of ISO 5802:2001 industrial fans - performance testing i n situ, in Proceedings The Australian Mine Ventilation Conference , pp 149-154 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 1, 2013

By I Ritchie, G Lane, C Morley, D Yataco

Marcobre SAC (Marcobre) is developing the Mina Justa project in Peru. The project has a lower grade oxide orebody overlaying the higher grade sulfide orebody. The oxide ore is treated by acid leaching; consumption of acid is high and is managed by vat leaching rather than the more conventional heap leaching process.The leaching process uses ore crushed to 100% passing 8 mm to optimise copper recovery. Acid consumption generally increases with a higher proportion of fines. Marcobre is investigating a three-stage crushing circuit with high pressure grinding rolls (HPGR) in the third stage, instead of the more conventional four-stage cone crushing circuit. The use of HPGR can result in higher fines production due to the higher compression forces in the crushing zone. This paper reports on the outcomes of the test work completed by Marcobre in 2016 and 2017 to manage fines production and compare the use of HPGR with conventional crushing on a high acid consuming ore.At moderate pressing forces, a HPGR crushing circuit appeared to produce similar size distributions to cone crushing. On average, both the copper recovery and the acid consumption in subsequent vat leaching were higher with HPGR crushing than with cone crushing.CITATION:Lane, G, Morley, C, Yataco, D and Ritchie, I, 2017. Are there differences in size distribution when comparing conventional crushing and HPGR?, in Proceedings MetPlant 2017, pp 60–72 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Sep 11, 2017

In the retreatment of an old tailing dump containing five per cent of lead principally as lead sulphate, the lead sulphate was floated with liquid Aerofloat reagent after sulphidising with phosphorous pentasulphide in an acid circuit. A zinc middling product was removed by flotation before recovering the lead. Concentrate products were sundried in surface dams.INTRODUCTIONDuring the period between 1917 and 1928 the Junction North Broken Hill Mine N.L. deposited several tailing dumps on its leases, which were acquired by North Broken Hill Ltd.in 1931. One of these dumps lay alongside a main road close to a residential area. The high metal prices prevailing in the post-war years (1945 onwards) provided a strong incentive for retreating this dump and transferring it to a less objectionable site.SAMPLING AND TESTINGIn 1946 a sampling and testing campaign was instituted which culminated in 1949 in a decision being made to erect a tailing retreatment plant adjacent to the dump.The dump was sampled with a 3 in. post hole auger using extension lengths of -! in. pipe for drilling to 30 ft. The dump material was fine and moist and core recovery was excellent. Hole depths ranged from 14 ft. to 30 ft., with an average dump depth of 20 ft.Individual samples were prepared from successive 9 ft.lengths of core and each sample thus obtained was, submitted for sizing and assay.The sampling showed that the dump contained approximately 380,000 tons of fine tailing assaying:

Jan 1, 1956

By C Czerny, T Elkington, L Lorenzen

The Dutwa Nickel Project is a nickel laterite atmospheric leach project located in Tanzania that has been under development by African Eagle Resources plc (2012). A bankable feasibility study (BFS) has been progressed to evaluate mining of the resource (107 Mt at 0.92 per cent Ni) followed by hydrometallurgical processing on-site to make a mixed nickel-cobalt intermediate product. The unique relatively high silica contents in the Dutwa deposits, as opposed to limonite, which is more commonly occurring in nickel laterites, presented the possibility for beneficiation of the ores to enhance the leach feed nickel grades and provide economic benefits in terms of operating and capital cost efficiencies.Geometallurgical relationships, based on the results of an extensive variability metallurgical test work program for beneficiation and leaching, were developed for the BFS, which resulted in an improved understanding of ore classifications within the deposit and their responses. The geometallurgical information obtained has been instrumental in making key preliminary techno-economic decisions, such as forecasting whether or not mined material should be beneficiated and was ultimately used to drive the mine plan towards the prioritisation of areas within the deposits that delivered the best cost efficiencies and overall project economic outcomes.CITATION:Elkington, T, Lorenzen, L and Czerny, C, 2013. The use of geometallurgical relationships in process route selection and mine plan optimisation for the Dutwa Nickel Project, in Proceedings The Second AusIMM International Geometallurgy Conference (GeoMet) 2013 , pp 207-216 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Sep 29, 2013

By Bartrop S. B

Mount Isa mine has a long history of successful exploration since discovery 70 years ago. Remaining reserves, although substantial, exist in a scheduling framework which involves long-term production from new ore sources with attendant technical risk and major capital investment. Current exploration aims to incrementally increase reserve tonnage to maintain existing production levels as well as to provide a buffer for potential start-up delays from new ore sources. Exploration also aims to increase the net present value of the operation by discovering new major orebodies around the Mount Isa and Hilton mines.

Jan 1, 1993

By S B. Martin, M P. Simpson, J L. Mauk

The Martha deposit in Waihi, New Zealand, is a giant adularia-sericite epithermal gold-silver deposit that formed 6.0 to 6.1 Ma, and has produced over 6.4 Moz gold and 39.9 Moz. Fluid inclusion analyses were undertaken on a limited number of vein samples from Martha. The results from this eight week student project are preliminary but agree with previous studies. There is little variation between primary and secondary inclusions and between different vein types, except that homogenisation temperatures of the inclusions in sphalerite grains are on average 20¦ to 30¦C higher than the average quartz vein values. Overall the temperatures of homogenisation ranged from 182¦ to 258¦C and final ice melting temperatures ranged from 0.0¦ to 2.8¦C. Unusual black inclusions were also found associated only with the ginguro bands. Some of these appear to be solid sulphide inclusions but others are not so clear.

Jan 1, 2007

By Perring CS, Barnes SJ

The nickel exploration boom of the late-1960s and early-1970s led to the discovery of numerous komatiite-hosted nickel sulphide deposits, associated with variably serpentinised bodies of olivine-rich cumulates. Subsequent research has shown the importance of volcanological processes to understanding the genesis of these deposits. Crucial developments have come through consideration of the fluid dynamics of magmas and magma-crystal mixtures, through observation of the dynamics and geometry of modern day basaltic lava flows, through application of theory and experimentation on the kinetics of crystal growth from magmas, and most importantly from extensive detailed field mapping of komatiitic sequences in the Yilgarn Block and elsewhere. From these studies has emerged a new integrated view of the volcanological setting of komatiite-hosted deposits, and a recognition that a complete continuum of deposit types exists. Nevertheless, komatiite associated magmatic nickel deposits generally fall into two overall types based on the nature of the sulphide ore. In the first type the bulk of the ore is either massive Fe-Ni-Cu sulphide or a variable mixture of massive sulphide and an ore characterised by olivine crystals in a continuous matrix of sulphide occupying between 30 and 75 per cent by volume of the rock (called Matrix Ore). Nickel grades of massive sulphide ore range from 2 - 20 wt% and those of the matrix ore generally fall in the range 1 - 5 wt% (average 2.5 wt%) Ni/Cu ratios of the sulphide fraction are generally >10.

Jan 1, 1996

By R Bose, M Bovell, G Cheong

Grinding media is a major consumable in mineral processing and therefore decreasing costs associated with its consumption is regularly considered a key goal for the minerals processing industry. Grinding media manufacturers have historically developed steels with improved wear life for their products as a way of delivering incremental media quality improvement. This has included increasing carbon levels from low-to-medium carbon steels up to the eutectoid carbon composition of 0.77% where the relationship between higher carbon and better wear performance is well understood. Producers today will regularly use grades in excess of 0.8% to further improve wear performance particularly for rolled grinding media.This paper first introduces the demonstrated relationship between this increased carbon content and improved wear resistance along with metallurgical rationale behind the high carbon production process and limitations. To test the performance improvement associated with the higher carbon steel grade, a series of Marked Ball Wear Tests (MBWT) were carried out. This paper also explores the relationship between ball properties, test methodology and wear performance and concludes by correlating increased carbon grade with a reduced consumption rate of between 3.1% and 6.1% in the tests conducted.CITATION:Bovell, M, Bose, R and Cheong, G, 2018. Improved forged grinding media performance with carbon content greater than 1.0%, in Proceedings 14th AusIMM Mill Operators' Conference 2018, pp 559–570 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 29, 2018

By X Y. Ma, X G. Tian, P F. Zhang, T B. Zhao, Z H. Li, Z Y. Fu

This study analysed the fracture characteristics and movement process of goaf roofs under the condition of gangue backfilled mining, based on the engineering conditions of Tangshan Mine F5001 gangue backfilled working face. The inclined borehole detection method is adopted to conduct long-term and fixed-point detection of the roof stability. The distribution characteristics of mining-induced cracks in the roof are described quantitatively based on the crack density, and a similar model test method is used to assist the analysis of the roof movement under the control of gangue backfilled mining using stress sensors and digital speckle deformation field monitoring. The results show that under the condition of gangue backfilled mining, structural cracks in the roof typically appear at the boundary of rock strata. The appearance of cracks is related to the rock strata where they are located. Structural cracks appear in the form of single cracks ahead of the working face and develop into structural cracks in the goaf. The roof movement of the coal seam develops in five stages: fracture incubation, crack extension in advance, dense fracture development, steady fracture expansion, and roof stability. Separation forms the primary component of the roof subsidence, accounting for more than half of the subsidence value. The separation generally extends over a long distance along the strike, and vertical crack-intensive areas appear in the roof above the cut-off and stop line. The findings of this study provide a theoretical basis to support designs of backfilled mining and upgrading of hydraulic supports in working faces.

Nov 29, 2022

Gekko Systems Pty Ltd have developed the Python Underground Processing Plant for the concentration of gold and sulfide ores. The Python plant has an established flow sheet including fine crushing, screening, gravity separation and flotation which aims to concentrate the valuable minerals (gold/sulfides). The aim of the plant is to achieve high valuable recovery into a mass yield of 10 - 30 per cent to reduce the amount of material that is needed to be taken to downstream processing. This paper examines the test work protocol for testing an ore to assess its suitability for the Python flow sheet. This paper will discuss the test methods employed to determine crushing requirements, continuous gravity recovery and flotation performance and how the results relate to Python design for the comminution, gravity and flotation circuits. Results from past test work will be discussed.

Aug 1, 2010

By G Balog, T Ormerod, D Cox

This paper discusses the methods utilised by the technical team to identify and quantify the SLC risk factors, the modifications to mine design and scheduling, and the changes to the planned risk management practices. The paper also describes the future work currently planned by the OZ Minerals technical team to quantify the various risk factors in terms of space, time and magnitude. This may better inform the future mining practices within not only the Carrapateena province but also the wider Gawler Craton.

Mar 15, 2021

By P J. Sack, L V Danyushevsky

"An EXTENDED ABSTRACT is available for download. A full-length paper was not prepared for this presentation. Regional-scale exploration for sediment-hosted gold deposits is hampered by the challenge of evaluating the fertility of ancient sedimentary sequences that host these deposits. Recent developments in laser ablation inductively coupled plasma mass spectrometry allow for the evaluation of the gold fertility of sedimentary sequences using chemistry of early-formed sedimentary pyrite. We present a case study from the Selwyn basin area of Yukon, Canada, where significant sediment-hosted gold exploration has been ongoing for the last five years. Data from sedimentary pyrite in some Neoproterozoic shales are anomalous in Au and As compared to a global data set of unmineralised sedimentary pyrite. If at least some of the gold and associated trace elements in sediment-hosted gold deposits are derived from recrystallisation of early sedimentary pyrite, it follows that strata containing anomalous sedimentary pyrite should be more prospective. Based on this premise, our data clearly show that Yusezyu Formation Neoproterozoic shales in the Selwyn basin area of Yukon are a fertile source rock for sediment-hosted gold deposits, while pyrite from Nadaleen formation shales are strongly anomalous in Hg and Tl, but not Au. We suggest that the area warrants continued exploration for sediment-hosted gold.CITATION:Sack, P J, Gregory, D D, Large, R R and Danyushevsky, L V, 2015. Using sedimentary pyrite chemistry to inform regional exploration for sediment-hosted gold deposits – a gold fertility case study from the Selwyn basin area, Yukon , in Proceedings PACRIM 2015 Congress, pp 69–76 (The Australasian Institute of Mining and Metallurgy: Melbourne)."

Mar 18, 2015

By M A. Ward

On 23 May 1977 the Hon Mr George Gair announced an amalgamation of the present Ministry of Energy Resources, the New Zealand Electricity Department and the Mines Department. Hopefully it will prove to be the solution of many national problems in energy planning and policy making, in energy distribution and use, and energy discovery and production. The name of this new giant is the Ministry of Energy which gives a firm indication of its future direction. For those amongst us involved with mineral energy resources the establishment of this new department must be encouraging. For those amongst us who are involved in non-energy side of the mineral industry it is the very opposite. The loss of the Mines Department a year short of its centenary is a loss for the mineral industry without a doubt - but how much of a loss?

Jan 1, 1977

The potential of the developed multi-dimensional analysis system to assist interpretation from large data sets through derived digital mapping models is presented accompanied by preliminary results. The concept learning model is original and its application general. Applications exist in general science, engineering, earth resource management and economics. The developed system incorporates advances in machine learning, neural networks, object-oriented software engineering, knowledge representation and fuzzy logic. ' The specific application presented involves automatic earth resource modelling and assessment involving geological theories of mineral potential. The developed system functions as a new and powerful mineral exploration tool, To date the model has been trialled on an earth resource database and several published data sets. A more general potential application is knowledge discovery within databases. The specific theory that is tested in the experimental results is the nature of the cause-effect relationship between the hypothesised geological causes and the measured effects within a previously published test survey. Also integrated here are a neurophysiological cerebellar model of human learning, a new concept similarity measure for pattern recognition, modelled components to explain human concept formation through knowledge discovery and a means of permanent representation.The implementation is as a new artificial neural network architecture functioning as a hybrid expert system. Understanding of programmed concept learning is extended through the model. Also established is a basis for a new approach to multivariate data analysis. Spatial analysis for decision support is integrated over many dimensions, relationships, data types and data modes. Application of the developed methodology and system adds value to data bases. Discovered knowledge is represented as new generalisations, interpolations, classification hierarchies, aggregations and associations within a dynamic, maintainable and reusable integrated knowledge framework. New digital knowledge products and intelligent access follow. Permanently stored, maintainable, easily accessible and discovered knowledge improves decisions through extended hypothesis testing, spatial data analysis and inferencing, prediction, logical deductions and explanations.

Jan 1, 1995