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By G Bournival, Y Saavedra Moreno, S Ata

Flotation frothers are heteropolar molecules that are preferentially adsorbed at the bubble interface to enhance the flotation performance by promoting the formation of small and stable bubbles. Frothers have different characteristics that can be used to classify them. A classification framework has been recently presented by Saavedra Moreno et al (2022) to classify non-ionic frothers by conducting a principal component analysis (PCA) and a hierarchical clustering analysis (HCA). However, for the purpose of the present research, only five frother characteristics, including molecular weight (MW), hydrophile–lipophile balance (HLB), critical coalescence concentration (CCC), the minimum Sauter mean diameter (DL), and foam stability index (DFI) were used in the PCA and HCA. All those characteristics were evaluated for a two-phase system in the absence of particles. Realising the important role that particles play in froth stability and behaviour, the effect of hydrophobic particles on the presented frother classification framework was investigated in this study. Four frothers with different characteristics, methyl isobutyl carbinol (MIBC), 1-pentanol, tri (propylene glycol) (TPG), and tri (propylene glycol) methyl ether (TPM), were chosen. The experiments were carried out in the presence and absence of silica particles esterified with 1-pentanol. It was evident that the results for 1-pentanol, TPM, MIBC, and TPG in the three-phase system agreed well with the frother classification presented for the two-phase system as frothers were clustered in the same groups. The findings from this research support the use of the frother classification system presented in two-phase system to select a specific frother for a particular application without the necessity of conducting laborious experiments in a three-phase system.

Aug 24, 2022

This paper is written as a supplement to that of Edwards, Baker and Knight on "The Geology of the Wonthaggi Coalfield" 1, the West Area pit being in an early developmental stage at the time of their paper. The thin seams to the west of Dudley Basin 2 had beenknown for many years but it was not until 1935 that it became necessary to work them. The West Area Pit came into production as Dudley Area Pit approached exhaustion in 1937. From available information it was estimated that early work would be in a 36in. bottom seam. The present top seam was not included in the reserves, but it was to be extracted where it proved thick enough for economical working.THE SEAMSEdwards, Baker and :Knight (1944) had insufficient information to correlate positively the West Area seams with those in the Dudley Basin. Their opinion was, however, that they were a westerly extension of the Bottom Seam. Since then the driving of the present north-east heading towards No. 4 Bench McBride Tunnel has established that the West Area seams are those worked as Bottom Seam in the Dudley Basin. West Area Top Seam is a seam that occurred above the Bottom Seam in the Dudley Basin. Only sporadic attempts have been made to work it in Central Area, because 30in. was considered an economic minimum height until recent times. This seam should not be confused with Top Seam, Dudley Basin, which lies some 300ft. above the bottom seam measures and except in isolated areas over deeper workings has been eroded away in West Area.

Jan 1, 1953

This paper briefly discusses the negotia- tion of the more important provisions in agree- ments for exploration and mining rights with Pacific countries. LAND RIGHTS Land rights are complicated and sometimes controversial in many of the Pacific countries. In some countries, a company will have to deal with land owners directly; in others, the government will act as intermediary. Inevit- ably, a company will have to deal with both. Mining companies need to be sensitive to the culture and particular interests of the land owners and of their history in defending their rights. The issues are too complicated to be dealt with here. Some mining companies have spent, and will continue to spend, considerable time trying to understand them. It will " require patience, perseverance, sensitivity and unflagging optimism. The better advised companies will ensure that their local repre- sentatives get to know the land owners, under- stand their concerns, and will pursue a policy of keeping them informed on a regular basis of all of the company's activities and proposed activities. Good community relations are the keystone for good mining operations in the Pacific. Most countries will require the submission of an environmental impact statement so that they will know in advance what effects a pro- posted mining operation are expected to have on the environment and how it is intended to deal with them. They will also want to approve the company's environmental reclamation and rehabilitation plan. Let's face facts right away - mining, by its very nature, is not going to improve the environment. There will be waste discharges, emissions and deposits. They will affect the land, air and water and hence human, marine and animal life and vegetation. There will be sounds and odours and the esthetics of mining operations, though perhaps pleasing to geolo- gists and mining engineers, will not please Others.

Jan 1, 1987

In response to requests from the iron ore mining industry, the Commonwealth Scientific and Industrial Research Organisation (CSIRO) Division of Mineral Physics has developed a number of bulk analysis techniques in which analyses are obtained directly from ore samples weighing many kilograms or from ore located on conveyor belts.Because penetrating neutron and gamma radiation is used, measurements are obtained from a large volume of ore, which ensures thal the analyses are represelllative of the bulk.Two different gamma-ray techniques have been developed to measure iron ore grade. The first is based on backscallering of 60CO gamma rays, while the second involves measurement of the annihilation radiation which arises when the ore is irradiated wilh 226Ra gamma rays. Both techniques measure the iron concentration with an accuracy (1 s) of better than 0.4% Fe.A thermal-neutron irradiation technique using a 252Cf neutron source has been developed for the simultaneous determination of iron and the aluminium impurity (expressed as AI2O3) in iron ore fines on a conveyor bell. Because the conveyor speed must not exceed about 0.05 m/s, if good accuracy for AI2O3 is required, an auxiliary analysis bell is required Lo avoid inLerference with normal ore processing. Dynamic trials have demonstrated that accuracies of 0.6% Fe and 0.1% AI2O3 can be obtained.

Jan 1, 1985

Both as an energy source and as a raw material, natural gas is playing an increasingly important role as a catalyst for the development, continuation and rebirth of mining projects in Australia. Pipelines are the vital link in making natural gas available to a region and to individual mines. This paper will cover the role of pipelines in supplying mining projects in Australia, the development and status of the Ballera to Mount Isa gas pipeline and the future prospects for gas pipelines in the Carpentaria Mineral Province.

Jan 1, 1998

With mining development on hold and other underground works in a slowdown, the develop- ment of nuclear waste repositories takes center stage on the American rock engineering scene. Three repositories for commercial spent fuel -- in salt, tuff, and basalt -- are in the phase of site characterization and conceptual design, and one pilot project for defense high-level waste in salt is under construction. A repository design for crystal line rock has recently been postponed. Because of strict quality assurance requirements throughout design and construc- tion, and because of the need to predict and ascertain in advance the satisfactory perfor- mance of the underground openings, much intellectual energy has been expended to analyze underground openings in the unusual circumstances of the repository environment. In the long term, these efforts will lead to an improved understanding of rock behavior and improved methods of underground analysis and design. For the shorter term, a formalized ground control plan was developed, the princi- ples of which may be applied to other types of projects. This paper summarizes the status of underground design and construction for nuclear waste repositories and presents some details of the ground control plan and its individual elements.

Jan 1, 1987

I am honoured and very pleased to have been given the opportunity this evening to say a few words of thanks not only on behalf of all the guests but especially for the delegates and accompanying persons attending the 13th Congress of the Council of Mining and Metallurgical Institutions. Firstly, I would like to congratulate Sir Hamilton Whyte,KCMG for his most interesting address. In his far ranging talk, when he showed knowledge of widely diverse subjects, I had a brief fear that he was going to be talking about the details of support methods in deep level mines, or how to avoid flotation problems in multi-metal mines. Although he did not go that far, he touched on subjects which have arisen this week - long term planning and secure supply of minerals at acceptable prices. The dire predictions of the Club of Rome have been debunked with a far more elastic supply of minerals having been proved. Combined with the importance of a falling birthrate in some parts of the world, this will lead to many changes in the future, when hopefully governments will take the long term view rather than look at the next budget or the next election. Maybe some of them are not too lazy to do this for all of us. However as a fellow Ukranian, I feel that he might have been called something different if he had been in Australia. Sir Hamilton, thank you for your talk. Once upon a time - and this is not a fairy story - there was a cobbler who had two sons; one very bright who became a professor of mathematics; the other, dim, who became a millionaire shoemaker. Asked for the secret of his success, the millionaire attributed it to a vital piece of economics which his father had imparted, "Be content with small margins on a large turnover." "So", said the millionaire, "I make my shoes for $2 a pair and sell them for $5. I am very happy with the three per cent profit."

Jan 1, 1986

In order to satisfy environmental and mine operational requirements it is becoming increasingly important to minimise ground blast vibrations at certain locations. These locations are often in soil or on large resonant structures such as grain silos, highway bridges or even the walls of an open pit. A soil monitoring exercise was carried out to evaluate the common practice of coupling vibration detectors to the ground using spikes. At a series of locations in an operating quarry the spiked array response to single blastholes was compared with that of an accelerometer array attached to a calibrated embedded mount. The results clearly showed that the spiked arrays over-estimated the true ground vibration by 46.5 per cent on average, with a maximum observed error of 99.2 per cent. These errors are considered too large for compliance monitoring where accurate vibration levels are required for comparison with prescribed limits. Although spike coupling is convenient, its use for compliance monitoring should be viewed with caution. Unfortunately, however, many manufacturers supply their detectors as spiked arrays. A structural monitoring exercise was also carried out to evaluate the vibration response of a grain silo, highway bridge and a pit wall to the initiation of single blastholes. In this case accelerometers and standard geophones were firmly attached to the bridge which resonated at low frequencies. The results clearly show that, due to their limited low-frequency response, the geophones typically measured only half the true vibration level as measured by the accelerometers.

Jan 1, 1995

The mining industry is quite often faced with declining selling prices for its products in the face of rising prices for the input cost resources that it uses. Blasting is a key activity within the mining system and has a vital role to play within the Mine to MillTM concept. It is therefore important that blasting makes a positive contribution to mine profit and productivity. There are several variables involved in considering the profitability and productivity of blasting. The rock types and structures, the bench height, the blast hole drill rig specifications, hole diameter, spacing and burden, explosive loading and initiation and blast size fragmentation. Productivity accounting is a methodology which is used elsewhere to give additional insights into the productivity and pricing factors that drive the financial performance of a business. Miners know intuitively that productivity and pricing influence costs and profit, but only with productivity accounting can the dollars involved be calculated. Drilling and blasting are part of a chain of unit operations in a mine. For an owner-miner, drilling and blasting would be considered as cost centres and a productivity accounting cost model approach would be relevant. On the other hand a contractor is likely to consider drilling and blasting as a profit centre, in which case a productivity accounting profit model approach would be appropriate. Both of these will be explained. The paper provides a basic outline of deterministic productivity accounting and demonstrates its application to blasting. Drilling and blasting data from a mine was obtained for a two-month period. The change in productivity and prices was calculated to obtain the dollar contributions from them towards the change in cost. It was determined that although there had been productivity dollar gains these were offset by larger pricing dollar losses, the net effect being that total drilling and blasting costs increased. The productivity accounting analysis gives the facts and the mine is in a position to establish priorities based on knowing the dollar contributions of each input used.

Jan 1, 2001

Tectonic subsidence plots have been calculated for well, extrapolated-well and significant off-well (seismically-based) locations in the Vulcan Sub-basin and adjacent highs (western Timor Sea). The subsidence curves have been normalized to a common datum, the distinctive "near top Permian" marker, and corrected for sediment compaction, palaeobathymetry, eustatic sea-level change and loading effects.Four principal phases of post-Permian basin development are recognised and quantitatively described by integrating the results of the sub-sidence analysis into the regional (e.g. recent Ocean Drilling Program-derived) framework of the tectonic evolution of the North West Shelf. They are1. the Triassic-mid Jurassic Westralian Superbasin intracratonic phase,2. the late Jurassic-early Cretaceous North West Shelf rift phase,3. the mid Cretaceous-Palaeogene North West Shelf subsidence phase, and4. the Neogene-present Timor collision phase. Rapid Triassic tectonic subsidence occurred in an intracratonic setting, possibly subsequent to aborted late Palaeozoic rifting. Intracratonic sub-sidence mechanisms such as deep crustal metamorphism and/or intrustion and regional tectonic compression are invoked in addition to any post-rift thermal subsidence which may have occurred.

Jan 1, 1990

By Leach B. G

A geostatistical study was made of diamond drill hole intersections within 18CC stope block at the C.S.A. Mine, Cobar, N.S.W. The stope block is located in 18CC orebody which is a massive sulphide - multiple vein, Copper-Zinc type, lacking clear definition on gangue mineralogy, base-metal assays and total sulphide considerations. Of the variograms constructed for inter- section width and copper, lead and zinc grades and accumulations, only zinc displayed behaviour amenable to model fitting and kriging procedures. Zinc grades were calcu- lated for sub-blocks comprising the total stope block and comparison with equivalent grades determined by traditional methods showed them to be generally less extreme in the highest and lowest grade sub-blocks. The total-block grades derived by the two methods were almost the same. It is suggested that the failure of copper to show variogram continuity might reflect the difficulty in defining the actual 18CC orebody, a proposition which is supported by the poor continuity in the variogram of horizontal width. In the case of lead the poor continuity may be due to the frequent manner of occurrence of galena as coarse grained patches of limited extent. The results of the study, did not provide a convincing reason to depart from the traditi- onal methods of grade estimation at the C.S.A. Mine.

Jan 1, 1979

Thermal Processing of Petroleum Fly Ash for Vanadium Recovery

Sep 13, 2010

Background BHP Iron Ore Pty Ltd is one of the major iron ore producers in the Pilbara Region of North Western Australia. The company manages three separate joint ventures; the Newman, Goldsworthy and Yandi joint ventures and two 100 per cent owned operations, Yampi and Jimblebar. The Newman operations constitute a mine site at Newman and a 426 km railroad to Port Hedland where there is an ore processing/port site. The Goldsworthy operations currently constitute a mine site at Shay Gap/Nimingarra, a developing mine site at Yarrie, a decommissioned mine site at Goldsworthy and an ore processing/port site at Finucane Island (Port Hedland). The Yandi operations include mining and processing facilities at site and a spur line to join the Newman Hedland railroad. Jimblebar operations are scree and bedrock mining near Newman and include mining, processing and a spur line to Newman where it joins the Newman-Hedland railroad. The Yampi operations constitute a mine/port site at Koolan Island (which is presently being decommissioned). The combined BHP Iron Ore operations produce approximately 46 Mtpa of iron ore. This paper will concentrate on the processes developed and applied for the decommissioning of the Goldsworthy site. The Goldsworthy site is on the northern boundary of the Pilbara Region and adjacent to the western extremity of the Great Sandy Desert. It is located approximately 110 km east of Port Hedland (see Figure 1). The area is generally of low relief with isolated low ranges. The mine site being within the Mount Goldsworthy range area. The geology of the area is essentially Archaean granite with Archaean banded iron formation becoming dominant within the ranges. The chief soils are hard alkaline red soils. The vegetation is essentially shrub steppe with the main hummock grass species being spinifex (Triodia sp). The climate for the region is semi arid tropical. The temperature ranges from a mean low of 15¦C in winter to a mean high of 40¦ in summer. Rainfall is episodic, occurring mainly throughout the summer as a result of tropical depressions or cyclonic activity. The average annual rainfall is approximately 300 mm and annual evaporation may exceed rainfall by up to 2500 mm. Goldsworthy Mining Ltd commissioned the Goldsworthy site in 1965/66. Goldsworthy was the first iron ore operation and associated town site in the Pilbara region. The mine development peaked in 1977 with the town population reaching 1400 people. In 1982 mining ceased and the mining operations were relocated to Shay Gap, 80 km east of Goldsworthy. The Goldsworthy town continued as the base for the railing operations between Finucane Island and Shay Gap. BHP Minerals acquired Goldsworthy Mining Limited in 1990. The population for the town of Goldsworthy at this stage was around 450 people. An assessment of the Goldsworthy site operations concluded that it was uneconomic to continue the operation of the site. The decision was made to transfer the base for railing operations to Port

Jan 1, 1994

The Canada Centre for Mineral and Energy Technology (CANMET) /Calgary Coal Research Laboratory and the National Research Council in Ottawa established a joint working research group with industry to develop and test various computer models for application in surface coal mining operations in western Canada.The first part of the paper deals with the problems the group experienced during the past two years especially having model specification and requirements defined and understand site management practices.The second part of the paper deals with site specific development of general mine model for TransAlta Utilities' Highvale Mine in Alberta. Described here are the development of an interactive truck/shovel model for their three pit operation, selection and application of dragline model for tandem operation with the extended bench method, criteria for operational model of the five seams operation with selec-tive mining approach.

Jan 1, 1985

By Kelley BC, Filmer AO

The chemical oxidation kinetics of sphalerite by Fe(III) was studied at various temperatures and size fractions in sulphate media. The kinetics of Zn extraction followed a pore diffusion control mechanism with an apparent activation energy of 54-58 kJ mole. This figure, although high for a pore diffusion control process, is consistent with other studies carried out in sulphate media. An empirical statistical model, relating the extraction time to % Zn extraction, average particle size and temperature, is described by log 1 = 12.22 - 0.017% Ext. - 1.76 log D Av t - 2954 T Parallel studies were also carried out investigating the biological oxidation of sphalerite utilizing the acidophilic autotrophic bacterium Thiobacillus Ferroxidans. The effect of such kinetic parameters as pulp density, particle size and Fe(III) on bacterial growth rate and consequently zinc extraction rate, were studied and where appropriate, optimum conditions for bacterial growth were specified. Based on the results of chemical and biological leaching studies, it was apparent that rapid zinc extraction from sphalerite was predominently due to oxidation by Fe(III). The biological oxidation process catalyses the oxidation and regeneration of Fe(III). The proposed combined chemical-biological leach system was simulated in semi continuous fashion. The sphalerite oxidation rates obtained in this system were similar to that predicted by the chemical leach empirical model. 1. Senior Research Metallurgist, CRA Research, Boolaroo, N.S.W. 2. Group Leader-Hydrometallurgy, CRA Research, Boolaroo, N.S.W. 3. Senior Research Scientist, Biotechnology Australia, Roseville, N.S.W. 4. Senior Experimental Officer, Biotechnology Australia, Roseville, N.S.W.

Jan 1, 1986

The objective in design of an excavation in a jointed rock mass is to achieve a prescribed degree of control of rock mass displacement around the excavation. Any excavation in jointed rock usually involves slip and separation along discontinuities as well as translation and ro- tation of constituent rock blocks. Thus, any acceptable model of behavior around an excava- tion must be capable of simulating the force displacement paths followed by the constituent elements, including rigid body translation and rotation. The distinct element method models such behavior by simulating the rock mass as an assemblage of rock blocks which interact through corner and edge contacts. Discontinuities are regarded as boundary interactions between blocks with joint behavior prescribed for these inter- actions. Introduction of structural element logic allows a variety of installed support sys- tems to be modeled. The response of the support to axial, transverse, and flexural loads is based on explicit algorithms similar to those used in the distinct element formulation. This allows large displacements and rotations and general non-linear constitutive behavior for both the support elements and the interface with the rock. This paper describes both the distinct element and structural element formulations and demonstrates several applications involving sup- port interaction with jointed rock.

Jan 1, 1987

By Grant J

In surface mining, significant improvements in efficiency can be obtained through greater control over the formation of the muckpile. By tailoring the muckpile shape and its looseness to the requirements of the excavating equipment savings can be rea- lised through increased production, machine life and reduced maintenance. For instance, one open cut coal mine has recently estimated that a 2001o improvement in its front row throw would realise $320,000/year savings in rehandle costs alone. Previously greater throw has been achieved by increasing the powder factor through increased quantity of explosive or by drill- ing a larger number of holes-both at a significant cost penalty. However a recent series of experimental blasts demonstrated that it was possible to achieve a twofold increase in the distance of throw of a single row blast by simply changing delay timing alone. The Nobel Electronic Delay Detonator was used to provide the timing flexibility and control required for a thorough study of the effect of blast timing on heave. Whilst it is well accepted that the front row of a blast dominates the extent of throw, it was also found that the profile of the blast could be significantly altered. To date, the general consensus has been that the muckpile for- mation from a blast is a function of the blast geometry, the rock type, the explosive and the initiation sequence. Typically the geometry, rock type and initiation system have a far greater impact than the explosive type. This has been demonstrated by many high speed film studies. However the extent of influence via initiation has rarely been fully evaluated, owing largely to the limited control offered by conventional detonators.

Jan 1, 1988

By Culshaw MG, Deaves AP, Bell FG

The accurate prediction both of the water ingress into sub-surface excavations and the nearby groundwater pressures is of fundamental importance to the control of the stability and flooding of tunnels or mines constructed below the water table. Predic- tions are usually based on laboratory and in situ permeability determinations together with observations of groundwater conditions in boreholes. Although established theoretical methods provide a basis for prediction, the actual ingress depends on many factors. The objective of this paper is to explore the geological controls on groundwater conditions, and the available methods of prediction of both groundwater flow and pressure are outlined. Salient points are emphasised by reference to a case history involving the construc- tion of a tunnel in a faulted and mixed sequence of sandstones, siltstones, shales and coals. Water ingress quantities have been monitored for a variety geological and geotechnical conditions including heavily faulted and mine disturbed ground. The overall results are discussed with reference to the relevant hydrological and geologi- cal conditions in terms of the geological structure, lithology and rockmass condition as well as the construction methods.

Jan 1, 1988

By Singh RN

Monolithic packing systems have gained in popularity as a gate side packing method. However, there has been no detailed investigation to assess their underground strength behaviour. This work includes the laboratory and in situ investigation for strength behaviour determined on various monolithic packing materials namely Tekpak-XX, Hydropak-20, Hydropak-30, Astrapak-3R, Flashpak, Thyssen pack and Aquablends. A simple technique for assessing the pack strength was developed at the laboratory by using a penetrometer, of which penetration resistance can be directly correlated with the uniaxial strength of the pack. The in situ strength investigations were made on core samples obtained from three pipes inserted inside the pack, while the penetration test were made on the pack surface. The in situ results indicated that the packing material develops an inconsistent strength on various part of the pack which was mainly related to an inadequate mixing of grouts inside the pack.

Jan 1, 1992

By H Fukaya T Miki, J Gamutan

Molybdenum disilicide (MoSi2) is a promising material for thermal applications due to its excellent heat and oxidation resistance. It can operate at temperatures of up to 1800°C as furnace heating elements and protect refractory metals such as molybdenum from rapidly reacting with air to form volatile molybdenum oxides at elevated temperature. In this work, the feasibility of forming MoSi2 on a molybdenum substrate by hot dipping in a silicon-saturated molten metal bath was investigated. This method is simple, predictable and can be used to coat large components and complex parts. It was found that tetragonal MoSi2 can be successfully synthesised on the surface of the substrate after dipping for 15 mins at 1000°C using molten tin (Sn), bismuth (Bi) and copper (Cu) baths. The growth of the MoSi2 layer was fast within the first 15 mins and then gradually slowed down with time. After dipping for 60 mins at 1000°C, the thickness of the MoSi2 layer were measured as 441.5, 19.5 and 13.1 μm for the copper, tin, and bismuth baths, respectively. The MoSi2 coating synthesised in this study provided oxidation resistance at 1150°C by forming a protective SiO2 layer on the surface. The SiO2 layer prevented the sample from rapidly oxidising by inhibiting direct contact between the molybdenum substrate and oxygen in the atmosphere. Compared to conventional methods, the proposed hot dipping method produces a MoSi2 layer more rapidly and at much lower operating temperatures. This makes it a more attractive option for coating large and complex components, with the potential to enable the use of MoSi2 in a wider range of applications.

Jun 19, 2024