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By G Bournival, Y Saavedra Moreno, S Ata

Flotation frothers are heteropolar molecules that are preferentially adsorbed at the bubble interface to enhance the flotation performance by promoting the formation of small and stable bubbles. Frothers have different characteristics that can be used to classify them. A classification framework has been recently presented by Saavedra Moreno et al (2022) to classify non-ionic frothers by conducting a principal component analysis (PCA) and a hierarchical clustering analysis (HCA). However, for the purpose of the present research, only five frother characteristics, including molecular weight (MW), hydrophile–lipophile balance (HLB), critical coalescence concentration (CCC), the minimum Sauter mean diameter (DL), and foam stability index (DFI) were used in the PCA and HCA. All those characteristics were evaluated for a two-phase system in the absence of particles. Realising the important role that particles play in froth stability and behaviour, the effect of hydrophobic particles on the presented frother classification framework was investigated in this study. Four frothers with different characteristics, methyl isobutyl carbinol (MIBC), 1-pentanol, tri (propylene glycol) (TPG), and tri (propylene glycol) methyl ether (TPM), were chosen. The experiments were carried out in the presence and absence of silica particles esterified with 1-pentanol. It was evident that the results for 1-pentanol, TPM, MIBC, and TPG in the three-phase system agreed well with the frother classification presented for the two-phase system as frothers were clustered in the same groups. The findings from this research support the use of the frother classification system presented in two-phase system to select a specific frother for a particular application without the necessity of conducting laborious experiments in a three-phase system.

Aug 24, 2022

By Manlapig EV, Mackinnon IDR, Laudr DW

Orebodies at Ok Tedi contain a number of different fluorine bearing minerals. Some of these minerals report to concentrate and are responsible for the presence of the penalty element, fluorine, within the concentrate. Previous analytical work has tended to examine geological samples for content, rather than determine the metallurgical behaviour of the different mineralogical species. This investigation utilised X-Ray Diffraction combined with Scanning Electron Microscope / Electron Microprobe to identify the fluorine bearing minerals in flotation test products. Seven fluorine bearing minerals were identified, viz., talc, phlogopite, amphibole (tremolite and actinolite), sphene, apatite, biotite and clay. Talc was found exclusively in the skam ore type. Phlogopite and amphiboles (tremolite and actinolite) were found to occur in both skarn and porphyry ores, while sphene, apatite, biotite and clay were found only in the porphyry ores. Of the fluorine bearing minerals observed, only talc exhibited natural hydrophobicity to any significant degree. Phlogopite and the amphibole minerals were found to be hydrophillic, whilst the remaining minerals occurred in insufficient quantities to determine the flotation behaviour. Ok Tedi copper concentrate fluorine content prior to skarn ore treatment in the mill (typically 350ppm) was previously identified as deriving from phlogopite, while talc was believed to be the source of intermittent high concentrate fluorine contents when skarn ores were treated. This paper provides supporting evidence for this belief, and reports the nature of fluorine bearing mineral flotation behaviour.

Jan 1, 1997

By B Arthur, K Sexsmith, D Hockley, S D

At the proposed Crandon Project, mill tailings would be depyritised for upland disposal. The resulting pyrite concentrate would be disposed of in the underground workings as a cement-amended paste backfill. In the long term, the underground workings would be flooded and the potential for the paste backfill to generate acid would be limited. However, while the mine is operational, there is potential for oxygen ingress to the backfill that may lead to sulfide mineral oxidation and acid generation. A series of humidity cell tests were completed to assess the potential for groundwater contamination. To assess effects of surface area on oxidation, the humidity cell tests were conducted on moulded cubes of paste backfill. The tests were terminated at different intervals, and the cubes were dissected and examined mineralogically. Various leach extraction procedures were also used to assess the progress of oxidation and secondary mineralisation within the paste backfill. The test results showed that: the cement amendment significantly contributes to acid neutralisation and results in a lag in excess of one year before the onset of acidic conditions (in comparison to less than three weeks for the pyrite concentrate); the depth of oxidation in the paste backfill is restricted to about 1 mm after 107 weeks of testing; and secondary minerals form a distinct ærindÆ at the surface of the paste backfill. The results indicate that acid generation in the backfilled stopes would be minimal. The importance of including the surface area effect in the testing (ie using moulded cubes) is clearly demonstrated.

Jan 1, 2003

The mining industry is quite often faced with declining selling prices for its products in the face of rising prices for the input cost resources that it uses. Blasting is a key activity within the mining system and has a vital role to play within the Mine to MillTM concept. It is therefore important that blasting makes a positive contribution to mine profit and productivity. There are several variables involved in considering the profitability and productivity of blasting. The rock types and structures, the bench height, the blast hole drill rig specifications, hole diameter, spacing and burden, explosive loading and initiation and blast size fragmentation. Productivity accounting is a methodology which is used elsewhere to give additional insights into the productivity and pricing factors that drive the financial performance of a business. Miners know intuitively that productivity and pricing influence costs and profit, but only with productivity accounting can the dollars involved be calculated. Drilling and blasting are part of a chain of unit operations in a mine. For an owner-miner, drilling and blasting would be considered as cost centres and a productivity accounting cost model approach would be relevant. On the other hand a contractor is likely to consider drilling and blasting as a profit centre, in which case a productivity accounting profit model approach would be appropriate. Both of these will be explained. The paper provides a basic outline of deterministic productivity accounting and demonstrates its application to blasting. Drilling and blasting data from a mine was obtained for a two-month period. The change in productivity and prices was calculated to obtain the dollar contributions from them towards the change in cost. It was determined that although there had been productivity dollar gains these were offset by larger pricing dollar losses, the net effect being that total drilling and blasting costs increased. The productivity accounting analysis gives the facts and the mine is in a position to establish priorities based on knowing the dollar contributions of each input used.

Jan 1, 2001

By Mutton B. K

Hilton Mine is being developed as an integrated component of the Mount Isa operation, to achieve continuity of silver/lead/zinc production well into the next century. The mine has a chequered history from its discovery in 1947 through several periods of intense development activity, each of which has been curtailed due to the further development of the Isa Mine operation. This era has now passed; to sustain increased production rates at Mount Isa, there is a requirement for Hilton ore in 1989. The decision was made in 1983 to accelerate the programme of Hilton development by installing skip hoisting facilities in the main service shaft (P49), to facilitate the development of the mine to pre-production status. The Hilton development plan provides for the mining of selected orebodies, a broadening of the underground exploration drilling programme, and the establishment of significant mine infrastructure. Several technical challenges have been identified as important. The Hilton orebodies, although occurring in the same rock type as Isa Mine, are more faulted, jointed and intersected by intrusive dykes. The ore is more variable in terms of ore continuity, boundaries, grade and metal distribution and the mineralogy more complex. As a consequence the development of this project consists of a co-ordinated programme of mine exploration and development, rock mechanics investigations and metallurgical research and development work. Production will commence in 1986 at a rate of 1000 t/day using mechanized cut and fill techniques. It is planned to introduce sublevel open stoping and by 1996/97 the production rate will be 2.5 million t/yr.

Jan 1, 1986

By Wood CJ, Davis JJ, Askew H

A dynamic model of a dense medium circuit has been developed and tested against plant data. The model shows the response of the circuit to both controlled (changes in specific gravity set point or changes in circuit coal feed rate) and uncontrolled changes (changes in raw coal moisture, loss of raw coal feed) in operating conditions. The model is built up from dynamic models of the individual sumps, pumps, pipes, splitters, magnetic separators and automatic controllers in the circuit. The model can be used for design of automatic control loops and for investigation of possible process modifications such as changes in water addition points. This paper describes the model construction, the testing of the model against actual plant data and gives some examples of its use in investigating plant response to changes in operating conditions.

Jan 1, 1978

By Miles M. J, Sandy D. A

It has long been known that drilling and blasting operations have a direct influence over productivity and costs of subsequent operations. If mine management is to effectively optimise blasting operations, good information is required on the operating costs of each of the affected operations, together with knowledge of how they are influenced by blasting. In practice it is not possible to do enough repeats of a full scale production blasting experiment to make a statistically significant analysis of the results. By monitoring each blast and subsequent operations in as much detail as possible, enough data will be available to effectively measure the effect of blasting on costs. This gives management an insight into the blast performance and is the first step towards optimisation. An Integrated Blast-related Cost Reporting System has been developed at the Rossing Mine Open Pit, which calculates the total mining cost for each blast. In assessing the total mining cost for each blast, use was made of an.integrated planning and management information system to collect relevant production variables, current operating costs and survey data. An automatic image analysis system was employed to measure the fragmentation of the blasted material in the back of haul trucks. A shovel monitoring system is also under development for use in assessing the muckpile diggability and, in conjunction with an appraisal of shovel component reliability, to estimate the maintenance cost under various digging conditions.

Jan 1, 1990

By Stanton G

The Department of Mapping and Surveying (DMS), the Australian Key Centre in Land Information Studies (AKCLIS), the Department of Industry Development (DID) and the State Government Computer Centre (SGCC) are testing a regional information network in northern Queensland. Several study sites have been chosen by different groups of participants. The members of each common-interest group share their data for the site. They can also access datasets supplied by other organisations that are not directly involved in the particular study being undertaken. The participants include state government departments, local authorities, fed- eral organisations and the private sector. The participants communicate with computer systems in Brisbane via Q-Net. Q-Net is a pilot State government tele- communications network, established by the Department of Industry Development. Q-Net uses the communications sat- ellite AUSSAT 1 as the primary instrument of data transfer. The Q-Net network is a star system, with a Master Earth Station in Brisbane acting as a hub for radial earth stations, located throughout Queensland.

Jan 1, 1987

By La Brooy S R, Fenton K

A low grade copper flotation tailing from Telfer containing 1.2% Cu as chalcocite and cuprite and 5 gt-t Au was leached with ammonia, cyanide and ammonia-cyanide mixtures to extract copper and/or gold. Direct cyanidation extracted both copper and gold but consumed about 30 kgt 1 NaCN. Pre-leaching the tailing with an aerated ammonia solution containing 28 kgt 1NH3 and 17 kgtl(NHa)2S0a at pH 10 readily extracted up to 95% Cu in about 6 hours under optimum conditions. However pH and total ammonia concentration were critical factors. Subsequent cyanidation ex- tracted 80% Au using 6 kgt NNaCN. Ammonia-cyanide mixtures werefound to selectively leach gold over copper depending on the concentration and relative proportion of NH3 and CN. The best composition for leaching up to 80% Au from Teller tailing was 1.6 kgt t NaCN and 1.1 kgf 1 NH3 in the presence of 0.3 kgt t Cue+. Such a mixture left only 50 mgL-1Cu in the final solution after precipitation of some of the initially dissolved copper.

Jan 1, 1991

We operate a 50 cubic metre per hour mobile alluvial tin mine on small scattered deposits in the Irvinebank area. Wash is loaded by a Cat. 950 front end loader into the bin of a screening section and screen undersize is pumped to a separate jig unit. Both units are rubber tyre mounted and are shifted once a month when the haul distance gets to about 150 metres. The shift takes about 8 hours.The screening section is sited close to the face with a ramp for dumping in and a one metre drop for the screen oversize which is removed by the loader.A reciprocating plate feeder with variable rate hydraulic drive, feeds wash onto a horizontal 1.2 metre x 2.2 metre two deck Kinergy screen. Minus 10 millimetre undersize is pumped by a Warman 6/4 sand pump with a 37 kW variable speed Reeves Motordrive to the jig unit.The jigs are placed 20 to 70 metres away so that tailings will run back into previously mined ground. Reject stone is used to impound the sand and mud, allowing the water to filter through and return to the feed water pump.An MTE trapezoidal module is used as a primary jig. Hutch product is pumped to an eight cell clean-up jig which we developed ourselves along MTE lines. It has a trapezoidal shape and sawtooth stroke provided by cams. Clean tin is taken from the first four spigots. These consist of clear plastic tubes fitted with taps so that there is no water loss except when the tin is drawn off. Fine concentrate from the last four spigots is put over a curvilinear table which sits on a steel base packed with earth.

Jan 1, 1986

By Bhattacherjee A, Makesh S

Mechanised sub-level stoping is one of the most widely accepted stoping practices followed in base metal mines in India. As a general practice, blast-scheduling of rings in these stopes is done either heuristically or randomly which leads to a high fluctuation in ore grade when drawn and delivered to the mill. In this paper, dynamic programming has been investigated as an optimisation technique for optimal blast-scheduling of rings. A microcomputer based dynamic programming algorithm has been developed in C language which runs under the UNIX environment. A case study based on Indian mine data is presented to demonstrate the application of the dynamic programming concept and use of the developed software. It is concluded that dynamic programming can be used as a production planning tool in Indian mines practicing sub-level stoping and following heuristic/random approaches for blast-scheduling of rings.

Jan 1, 1995

By Chugh Y. P

A generalized void diffusion model for subsidence prediction has been developed based on theoretical concepts and physical principles. The general form of the model is a three-dimensional differential equation. With a few assumptions on the characteristics of overburden strata overlying typical room-and-pillar mining or longwall mining systems, specific solutions for the differential equation were obtained. A brief description of these solutions and their applications in the United States and China are presented in this paper.

Jan 1, 1992

Although forty-seven years have passed since the by-product coke oven made its successful commercial appearance, it is only during the past fifteen or twenty years that this system of coal carbonisation has advanced rapidly to its present position ofabsolute supremacy.Early designs of by-product ovens proved more or less faulty, and the coke produced was so inferior to coke made in beehive ovens that there was a natural hesitancy on the part of coke producers to invest large sums of money in installations of by-productovens of doubtful utility-more especially in view of the fact that beehive ovens could be erected cheaply and operated by non technical labour for the production of high-grade coke under the most variable conditions of trade.Surely and steadily designers brought forward by-product ovens of improved type, coupled with more efficient apparatus for the recovery of by-products, but still the industry lagged, due almost entirely to the insistence on the part of coke users that the qualityof ordinary beehive coke was vastly superior for metallurgical operations to the best coke produced from by-product ovens. So deep rooted was this prejudice that only the passage of time could eradicate it. That it has successfully done so is strikingly illustratedin the following statistics:

Jan 1, 1928

By S Hapugoda, J R. Manuel, M J. Peterson, A Poliakov, E Donskoi

The occurrence and deportment of manganese in a number of ferromanganese and Mn-bearing iron ore samples from supergene-upgraded deposits, as well as from magnetite banded iron formation (BIF) and magnetite skarn deposits, was characterised in order to provide a basis for improved understanding of the processing characteristics of different ore types and investigate the potential for development of a robust geometallurgical classification for Mn-oxide ores. An understanding of the Mn mineralogy in mixed Fe-Mn deposits is necessary to inform any attempt to separate the Fe and Mn during beneficiation and to understand and predict the behaviour of lump and fine ore products during processing.A suite of analytical techniques was utilised, including hand sorting of lump ore particles, optical microscopy, X-ray fluorescence (XRF)/inductively-coupled plasma mass spectrometry (ICP-MS) chemistry, X-ray diffraction (XRD), scanning electron microscopy (SEM)/electron probe microanalysis (EPMA) and gas and solid phase pycnometry, in order to elucidate manganese mineralogy, mineral chemistry and mineral textures. Manganomelane group minerals (eg cryptomelane, hollandite), pyrolusite and lithiophorite were the most common manganese oxides in the samples examined. From the microprobe work, there was evidence of probable substitution of Mn, as well as Al and Si, into the structures of goethite and hematite. Manganomelane minerals were often intimately associated with goethite, in particular, and a clarification of this association and the associated Si and Al impurities is fundamental for improved understanding of beneficiation and sintering behaviour of Mn-oxide ores. Due to the poor or very fine crystallinity of some supergene manganese deposits and of some Mn oxide minerals, in particular the extent of overlapping peaks and their variable mineral chemistry, XRD was a problematic technique to equivocally determine Mn mineralogy.For lower-grade, earthy, poorly microcrystalline ores the mineralogical and textural association between mixed Mn, Fe and Al (¦ Si) phases was also critical. The deportment and potential separation of these elements in these deposits, especially Al, was complex, as they were characterised by forms of æhydrousÆ cryptomelane with higher levels of Fe-Al-Si substitution, as well as intimate intergrowths of ochreous-earthy goethite (probably aluminous in part) with cryptomelane, lithiophorite and/or kaolinite.Trace amounts of alkali elements in ferromanganese deposits were considered likely to be preferentially structurally associated with Mn oxides, while lateritic deposits with significant amounts of lithiophorite could contain elevated levels of deleterious impurities; Co and Ni in particular.A combination of solid and gas phase pycnometry proved to be a useful technique for broadly discriminating hematitic, goethitic and mixed Mn oxide-goethite lump particles based upon differences in their envelope and apparent densities. Based upon these preliminary results and ongoing Raman spectroscopy work on manganese deposits sensu stricto, Raman spectroscopy is a technique considered to have promise during targeted research to better link the optical and compositional properties of ferromanganese ore particles. CT-scan (computed tomography scan) analysis could also be combined with Raman spectroscopy and pycnometry to link mineral composition, mineral texture, ore particle textures and particle porosity/permeability to the high-temperature processing behaviour of lump and fines products.CITATION:Peterson, M J, Hapugoda, S, Manuel, J R, Donskoi, E and Poliakov, A, 2013. Textural characterisation of manganese minerals to improve the geometallurgical characterisation of ferromanganese and iron ores, in Proceedings Iron Ore 2013 , pp 281-300 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 12, 2013

By Toguri JM

A solid electrolyte technique has been used to measure the activity of cobalt in liquid cobalt-gold alloys containing between 0.085 and 0.50 mole fraction of cobalt, and for temperatures from just above the liquidus to around 1550 K. The system exhibits positive deviation from ideality, both in the activities of cobalt and gold, and in the enthalpy and excess entropy of mixing. The results agree with previous measurements using a Knudsen cell - mass spectrometer technique, but differ from those reported for a gas equilibration method. The data have been used to calculate the activity coefficient of cobalt oxide in silica saturated iron silicate slags and to express the solubility of cobalt in such slags as a function of cobalt activity and oxygen pressure.

Jan 1, 1984

By H Fukaya T Miki, J Gamutan

Molybdenum disilicide (MoSi2) is a promising material for thermal applications due to its excellent heat and oxidation resistance. It can operate at temperatures of up to 1800°C as furnace heating elements and protect refractory metals such as molybdenum from rapidly reacting with air to form volatile molybdenum oxides at elevated temperature. In this work, the feasibility of forming MoSi2 on a molybdenum substrate by hot dipping in a silicon-saturated molten metal bath was investigated. This method is simple, predictable and can be used to coat large components and complex parts. It was found that tetragonal MoSi2 can be successfully synthesised on the surface of the substrate after dipping for 15 mins at 1000°C using molten tin (Sn), bismuth (Bi) and copper (Cu) baths. The growth of the MoSi2 layer was fast within the first 15 mins and then gradually slowed down with time. After dipping for 60 mins at 1000°C, the thickness of the MoSi2 layer were measured as 441.5, 19.5 and 13.1 μm for the copper, tin, and bismuth baths, respectively. The MoSi2 coating synthesised in this study provided oxidation resistance at 1150°C by forming a protective SiO2 layer on the surface. The SiO2 layer prevented the sample from rapidly oxidising by inhibiting direct contact between the molybdenum substrate and oxygen in the atmosphere. Compared to conventional methods, the proposed hot dipping method produces a MoSi2 layer more rapidly and at much lower operating temperatures. This makes it a more attractive option for coating large and complex components, with the potential to enable the use of MoSi2 in a wider range of applications.

Jun 19, 2024

By McNabb KE, Ward B, Dyer G

Roof conditions at Southern Colliery, the second longwall mine to be established at German Creek, were found to be much stronger and more massive than at the earlier longwall mine on the lease. Investigations were made to ascertain the level of face support required for longwall extraction under the changed geological conditions. Geotechnical information was provided from drillholes and highwall exposures. Downhole geophysical logs, notably the sonic velocity log, were used to obtain a distribution of the major lithological units over the mine area. A representative type section of the strata and geomechanical properties was compiled to form the basis for numerical modelling. Two-dimensional finite element methods were used to predict strata movements and chock loads under cantilevered roof conditions. The model incorporated a 6.3 in thick roof beam either bonded or detached, with either a 2 in or 5 in overhang. The solid rib, immediate roof, chock support and goaf were modelled as distinct parts, in addition a front abutment stress profile, derived from three-dimensional displacement-discontinuity analysis, was superimposed on the model.

Jan 1, 1992

By Paine GG

The in-situ retorting of shallow oil shale deposits is an attractive alternative to the material handling problems of conventional open pit mining techniques, which involve removing overburden, fragmenting and transporting the shale to a fixed retort, and finally disposing of the hot spent shale.For in-situ retorting to be successful, the oil shale has to be fractured and the fragmented rock expanded into a void, to allow controlled propagation of a flame front through the in-situ retort. The principles of cratering with explosives have been used to develop a process for the in-situ fracturing of a thin oil shale deposit overlain by a formation of porous rock. The overlying porous rock formation is first compressed by explosive charges to create voids in the porous rock. The oil shale is then fragmented and pushed in to the voids with separate explosive charges. This paper discusses methods of creating voids in porous rocks with minimal surface disturbance, and then methods of obtaining the most uniform fragmentation of the shale. The whole process can be completed, in practice, in one blast. The results of an experimental blast are presented, and possible modifications are then discussed.

Jan 1, 1985

By Johnson N. W, Quast K. B

Over the years there have been occasional references in the literature to the activating effect of cyanide in galena flotation with xanthates. These have usually been associated with the processing of lead-zinc or copper-lead-zinc ores. Bubble contact curves for the pure galena-xanthate system show a flotation edge at pH 10.4 independent of sodium cyanide concentration which was thought due to hydroxyl ion, not cyanide ion.Flotation tests were conducted on samples of Mount Isa lead-zinc ore using varying concentrations of sodium ethyl xanthate and sodium cyanide. At low collector concentrations, galena recovery kinetics improved with sodium cyanide addition, and the higher the cyanide concentration, the higher the galena recovery rate. At higher collector concentrations, galena recovery rate was independent of sodium cyanide addition.For a given collector addition, the lead grade-recovery curve shifted to an improved position with increasing sodium cyanide level. For the same recovery there was an increase in the lead grade with increased sodium cyanide addition, and this increase was most dramatic at high sodium cyanide concentrations.The presence of sodium cyanide during the grinding of Mount Isa ore caused surface passivation of the iron sulphides and possibly the sphalerite.These sulphides, therefore, reacted with less of the oxygen present in the pulp, hence more oxygen was directed to the surface of the galena. This resulted in an enhancement in the total amount of xanthate adsorbed on the galena that is reflected in the improved flotation response of that mineral.

Jan 1, 1990

By D Feng, G C. Lukey, J S. J, R R. Dagastine

An ongoing challenge in the coal industry is pyrite removal using the flotation method for fine particles. The use of a æseparation in frothÆ (SIF) technique to recover coarse particles of up to a few millimetres in size has presented a potential solution. However the commercial success of SIF is still limited due to the poor understanding of the separation mechanism. The particle floatability in SIF is determined by the constructive or destructive stresses resulting from the forces exerted by the particle on the bubble films. Hence, the surfactant properties and the mineral characteristics (eg hydrophobicity, shape, etc) are the key factors that control the interaction between the particle and froth. In the present work, the interaction forces between different particles (ie crushed glass, pyrite and coal) and a single air bubble are measured in a non-ionic surfactant solution (pentaethylene glycol mono n-dodecyl ether, C12E5) using an atomic force microscope (AFM). Experimental results show that the interaction is primarily dependent on the contact angle (ie the degree of hydrophobicity of the minerals). For crushed glass, the transition from repulsion to attraction was observed as the contact angle increased. As the concentration of C12E5 increased, the adhesion force was suppressed due to wrapping effect. For coal and pyrite with much higher hydrophobicity, long-range attraction was observed. The effect of shape factor was only visible at high surfactant coverage where sign of destabilisation became noticeable on the retracting force curve. These results provide a fundamental understanding of the direct interaction forces of a complex real system between an irregular particle of either crushed glass, pyrite or coal and a single air bubble. Theories developed for interpretation and modelling are thus far based upon the study of ideal systems of glass or polystyrene spheres and an air bubble and were incapable of explaining the interactions in complex real systems. The presented measurements were a first approach to the problem of real mineral-bubble interaction in flotation systems. Thus, the results can only best be interpreted semi-quantitatively.

Jan 1, 2005