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By T. Bednarski, T. McCallum, L. Moya, B. Gay

"Molybdenum recovery by solvent extraction has gained interest partly due to advances in concentrate leach technology. Historically, both molybdenum and rhenium have been produced using amine-based extractants with the ability to co-extract both metals. Alternatively, a phosphinic acid-based extractant (CYANEX® 600) can be used depending on the flow sheet. CYANEX® 600 selectively extracts Mo leaving Re in the raffinate, which is a valuable feature in plants which require rejection of the rhenium from the molybdenum circuit. CYANEX® 600 piloting results are reviewed and compared to commercial experiences with an amine-based extractant. INTRODUCTION Molybdenum is most commonly found as molybdenite (MoS2) in primary porphyry deposits (about 59% of global reserves) and copper porphyries (about 39% of molybdenum reserves)[1]. Recovery from molybdenite traditionally involves flotation (concentrates typically containing 85 – 95% MoS2) followed by roasting to produce MoO3. Solvent extraction is also used to recover molybdenum from acidic aqueous solutions resulting from scrubbing of roaster and smelter off gasses and leaching of molybdenite (uranium ores). Molybdenum is also frequently found in low concentrations in copper leach inventories[2]. More recently, pressure oxidation has gained interest to treat molybdenite concentrates. Molybdenum Chemistry The chemistry of molybdenum is complex with a series of extractable species existing dependent on the pH and oxidation state as shown in Figure 1.Under strongly basic conditions, molybdenum primarily exists as MoO42- while under strongly acidic conditions MoO22+ becomes the predominant species. In between, a number of isopolymolybdates such as Mo7O246- and Mo8O264- are dominant. Equations (1) – (3) demonstrate some of the proposed molybdenum equilibrium reactions[1]."

Jan 1, 2017

By H. Russell, N. DePriest, J. D. Quaranta

Valley-fill structures built of blasted rock overburden from Appalachian mountaintop surface mines pose many reclamation challenges. The steep mountainous terrain, short valley lengths, and straight stream channel profiles create significant challenges to implementing fluvial geomorphic landform design in terms of both form and function, and from a safety and constructability perspective. The fluvial geomorphic landform design approach balances erosive and resistive forces by considering long-term climatic conditions, soil types, slope profiles and vegetation types. Commercial geomorphic landform design software tools do not specifically analyze the stability and factor of safety for the computer-designed landform slopes. This research investigated slope stability parameters and factors of safety between a traditional valley-fill design with a geomorphic landform alternative. Slope stability assessments were performed on two profile geometries. Finite-element modeling of a permitted valley-fill and a geomorphic design alternative indicated that slope angle and internal angles of friction associated with the gradation of the overburden greatly affected the designed factor of safety for both designs. The geomorphic designed slopes yielded the highest factors of safety out of 14 models analyzed with all cases having factors of safety over 2.0. The high factors of safety are attributed to shallow slopes and beneficial surface and internal drainage.

Jan 1, 2014

By K. E. Harrison

The acid rain legislation has passed into law. This new law has caused the power generation community to investigate alternative methods to obtain compliance with the new legislation. One thing all of the power companies have concluded is the answer is not easy. Do we switch fuels to burn all low sulfur compliance coal? Maybe possibly only partial desulfurization by means of a dry sorbent system? Or, finally, maybe a wet scrubber system? Whatever the choice, the power community needs to investigate all of the alternatives. In 1988, ICF Kaiser Engineers, Inc. (ICF KE) responded to a request by the U.S. Department of Energy for the engineering development of advanced physical fine coal cleaning. ICF KE responded and was awarded a contract to conduct a multi-task program to develop an advanced flotation system to eliminate pyritic sulfur and retain as much energy as possible. ICF KE assembled a team that included members of industry, academia, and industry research organizations to conduct this multi-task program. The program includes sixteen (16) tasks. This team had personnel to help solve some of the anticipated problems and to provide industry prospective on the viability and commercial potential for any concepts proposed. The primary team consists of a major coal producer, Babcock and Wilcox, Eimco Process Equipment Company, and Virginia Polytechnic Institute and State University.

Jan 1, 1992

By D. J. Fitzpatrick

The paper reviews current mining subsidence research at The Department of Mining Engineering, University of Notting- ham. Special attention is being devoted to prediction of ground movements between the mining horizon and the surface using physical and computer-based models. The paper presented discusses linear and non- linear finite element methods and compares results with those from physical models and field observations. Special attention is focussed on the determination of the effect of caved zones on overlying and underlying geological structures. The paper presents data from comparisons with U.K. case histories.

Jan 1, 1986

By P. Zhang

Phosphate mining in Florida generates approximately 100,000 tons/day of phosphatic clays (slime). This waste slime not only creates one of the most difficult disposal problems in the mining industry, but also causes tremendous loss of P2O5. About 20-30% of the phosphate mined end up in phosphatic clays. Recovering the phosphate from this waste is difficult for two main reasons: 1) the slime is extremely fine in size, and 2) clay minerals account for almost half of the material. A half dozen dispersants were evaluated for keeping the clay minerals suspended for subsequent separation from non-clay minerals by either settling or cycloning. The separation efficiency and economics are discussed.

Jan 1, 1998

A case study of a systematic approach to grinding circuit steady-state optimization is presented. After overall review of the flowsheet, two circuits were prepared for detailed testing. Functional performance analysis was chosen as the primary modelling system, and on this basis a quality assurance program for data gathering was implemented. A number of circuit design and operating variables were experimented with statistical analysis of plant test results revealed relationships previously unquantifiable by any other modelling technique. Improvements in classification system and mill grinding efficiencies were demonstrated and significant energy cost savings thus realized.

Jan 1, 1998

By H. P. Ehrlinger

The Illinois State Geological Survey added Minerals Processing to its capabilities in 1966. Subsequently, the Minerals Processing Team and several Geologists collectively thought what neither would have thought of separately. The results included a number of projects. discussed here are: 1) The Utilization of the Fines from Kitty Litter as a Bonding Agent for Iron Ore Pellets; 2) Separating Plant Waste from a Commercial Silica Sand Producer into two marketable products, including a closely sized Silica Sand; 3) Marketable Feldspar Sand and Silica Sand from Dune Sands near the Kankakee River; and 4) A Method for Making Metallurgical Grade Fluorspar more desirable as Blast Furnace (Steel) Feed.

Jan 1, 2003

By Viktor Lishchuk, Olof Martinsson, Tobias E. Bauer, Elena Haller

Freely accessible and non-confidential real-life geological data sets from mineral deposits are desirable for the wide range of applications in research and education. However, publicly available statistical data are limited in their number and quality—they contain reduced information about geological, geophysical, geotechnical, chemical, mineralogical, and other relevant properties of deposits. This makes such data insufficient for scientific purposes. However, the amount of geological knowledge obtained for a variety of deposits in the past allows the construction of an idealized synthetic ore body model using analytical approach. Such a model could be used for education purposes and testing basic scientific theories, e.g., visualization of deposit structure; teaching sampling strategies; testing new algorithms for mine planning; or comparing geostatistical modeling methods. This paper presents an analytical approach to simulate volcanic massive sulfide (VMS) deposits and shows how synthetic deposit model can be constructed and further used for studying sampling with drilling and simulating folding and faulting.

Jan 14, 2021

By Brendan Donnelly, Lasitha Piyathilaka, Jung‑Hoon Sul, Sanghyun Jeong, Benjamin Probyn

Premature failure of armoured face conveyor (AFC) chains due to corrosion is a significant proportion of the unplanned downtime experienced on longwall equipment. The AFC chains are constantly in contact with water and wet coal. The premature failure issue of AFC chains has become more prominent since the introduction of longwall top-coal caving with its additional AFC. Reverse osmosis (RO) is a popular water treatment method for reducing salinity and dissolved solids, but its impact on the corrosion of the AFC chains is unclear. This study has been commissioned to investigate the direct effects of RO water on the corrosion of AFC chains. An immersion test was carried out using AFC chain steel submerged in two water samples: untreated dam water and treated water from an RO treatment plant. Elemental analysis was conducted for both water samples, and four corrosion indices were measured for both water samples. The RO water more vigorously dissolves calcium carbonate scales leading to increased corrosion of the AFC chains although the dam water has much higher levels of calcium, chloride, sulphate, sodium, and magnesium. Bicarbonate ions are the main alkaline factor of water that provides the buffering capacity to acids. Decreased alkalinity without balancing other ions in water causes high corrosivity and decreased scaling tendencies.

Oct 16, 2023

By William C. Cassun

The important role of pit slope design in the overall economics of open-pit mining ventures has long been recognized and well documented.1 2 Any economic analysis of a pit slope design must reflect the trade-off between the benefits and the increased risk of slope failure inherent in steeper slope angles. The conventional practice in pit slope design is based on the factor of safety analysis.' The approach uses average values to arrive at a deterministic solution to slope stability. Past analyses based on this approach generally have had several drawbacks: 1. The risk from slope failure could not be quantified. 2. Only relatively simple pit wall geometries were considered. 3. The analyses were performed solely for the benefits of steeper slopes, seldom discussing the potential costs of slope failures. 4. Analyses were seldom considered in a year-by-year mine planning context. Recognizing that average values do not reflect the uncertainty in geomechanical parameters, a probabilistic philosophy to slope design has evolved. 4,5 However, this approach had not been fully developed to include complex slope geometries and mine planning consideration. In order to develop an integrated, pit slope design procedure, a research project was initiated at the University of Arizona during 1973 in conjunction with the Canada Center for Mineral and Energy Teleology. This research resulted in the development of a probabilistic design procedure. The remainder of this paper gives an overview of the probabilistic design procedure and a discussion of the requirements for the benefit-cost analysis of a pit slope design. Finally, the results of a case study undertaken at an operating mine are given.

Jan 1, 1977

By William C. Dixon

Since the mid 60's, several haul cycle simulation programs have been developed. However, most of these programs are believed to employ the continuous, rather than the discrete, event-oriented simulation approach to determine the haul cycle times. This paper describes the recently developed haul cycle simulation approach where time is advanced in varying amounts only as the system changes occur. This approach results in greater computational accuracy and increased computational efficiency. The program is written in FORTRAN and requires equipment performance curve and haul road profiles as input. Unique program capabilities include the handling of switchbacks and intersections. The program uses a master data file concept in which various haul road profiles found during the mine life can be simulated all in one job submission. The results of the model validation using the actual time study data provided by an open pit mine operator near Tucson, Arizona, are also described in this paper.

Jan 1, 1978

By Guodong Li, Chenlin Wang, Zibiao Yu, Bo Xu

Abandoned coal mines have many underground space resources, such as roadways, shafts, and gobs. Among them, abandoned roadways are the best gas storage space for underground compressed air energy storage (CAES). However, CAES caverns have high air pressure and strict sealing requirements. Therefore, the stability and sealing of abandoned roadways under high internal pressure must be analyzed. Afterward, the suitability of abandoned roadways used for CAES caverns should be evaluated. In this study, the numerical simulation software FLAC3D was used to calculate the stress, deformation, plastic zone volume, and pore pressure of surrounding rock in an abandoned roadway under 10 MPa internal pressure. The influence of buried depth, surrounding rock grade, and in situ stress state on roadway stability and the effect of surrounding rock permeability on roadway sealing were analyzed. Results showed that the stress, displacement, and plastic zone volume of surrounding rock were affected by high internal pressure when the buried depth was less than 300 m, but high internal pressure had little effect on them when the buried depth was more than 300 m. The suitable range of buried depth was more than 300 m. The optimal choice of surrounding rock grade was I and II, followed by grades III, IV, and V. The optimal choice of in situ stress state was σH > σh > σv, followed by σH > σv > σh and σv > σH > σh. The sensitivity of the stability evaluation parameters was ranked in descending order as follows: buried depth, surrounding rock grade, and in situ stress state. When the surrounding rock permeability was less than 1 × 10− 14m2, the 24-h air leakage rate of the roadway was less than 1%. The suitable range of surrounding rock permeability was less than 1 × 10− 14m2.

May 23, 2023

By S. K. Kawatra

Outokumpu Electronics has designed a new on-line coal slurry ash analyzer, based on an instrument developed at Michigan Technological University. The primary goal was to build an accurate instrument at the lowest possible cost. The instrument determines ash content from measurements of x-ray backscatter, iron Ka fluorescence, and low-energy y-ray absorption. It is capable of measuring the ash content with a standard error of 1.1% ash over an analysis range of 9-21% ash and 7-22% solids. The analyzer was tested on coals from United States, Poland, Great Britain and the USSR.

Jan 1, 1992

By Ali Ekrem Aritan

Exposure to hand-arm vibration (HAV) among the labor force in the mining industry can result in permanent vibration diseases such as behavioral disorders, visual impairment, osteoporosis, pain (mostly in the hands, wrists, and shoulders), circulatory system disorders, and malnutrition. In this study, the vibration exposure of excavator operators working regularly in 25 different natural stone quarries was measured. In addition, the relationship between vibration exposure and rock properties was investigated. Gloved and ungloved vibration measurements were performed and revealed that antivibration gloves reduce excavator operators’ vibration exposure by 7.10–25.95%. Samples from each quarry were characterized with rock mechanics tests. The correlations between the hand-arm vibration measurements and the natural stone physical–mechanical properties (uniaxial compressive strength, Shore hardness, Knoop hardness, apparent density and total porosity) were determined to be over 70%. One finding of the study was that the health risk in excavators cannot be reduced sufficiently by the sole use of antivibration gloves. Furthermore, the excavation of any rock with a Knoop hardness above 121 is associated with an 81% risk of HAV. To increase awareness of the danger of vibration exposure for natural stone miners, training programs should be provided, and technical and operational changes should be implemented.

By Yongheng Jiang, Wentong Wang, Haoming Luo, Chuanju Liu, Qianjun Zhang, Sha Guo

Rock burst has always been a major problem in deep underground engineering with high stress, and rock burst strength evaluation has become an important research topic. To effectively predict the rock burst hazard in underground rock mass engineering, a cloud model (CM) rock burst intensity evaluation method based on the CRITIC method and order relation analysis method (G1) was proposed in this paper. First, a rock’s uniaxial compressive strength σc, tangential stress σθ, uniaxial tensile strength σt, ratio of uniaxial compressive strength to tensile strength σc/σt (brittleness coefficient), ratio of tangential stress to uniaxial compressive strength σθ/σc (stress coefficient), elastic deformation energy index Wet, and depth of cover H were selected as evaluation indices of rock burst intensity. Ninety-five groups of rock burst measured data at home and abroad were selected, and the objective weight and subjective weight of each index were calculated by using the CRITIC method and G1 method, respectively. The comprehensive weight was determined according to the combined weighting method of game theory, and the sensitivity of each evaluation index was analyzed. By utilizing a forward cloud generator, the membership degrees of different rock burst grades were calculated, and then the rock burst intensity grades of the samples were evaluated and compared with the evaluation results of the CRITIC-CM method and G1-CM method and the actual grades. Finally, the rock burst classification ability of the model was analyzed. To better verify the accuracy and reliability of this model, the rock burst case of the W39 line in the Chengchao Iron Mine was analyzed by using this model. The research results show that the rock burst evaluation results based on CRITIC-G1-CM are basically consistent with the actual rock burst grade, and the rock burst intensity grade evaluation model has good practicability and reliability.

Sep 1, 2023

By George S. Koch

We evaluate the exploration effort by diamond drilling for zinc in central Tennessee and southern Kentucky through a statistical analysis comparing the Middle Tennessee district with the older Tri-State and Upper Mississippi Valley districts. All of the ore deposits are of the Mississippi Valley type and are similar geologically. Through statistical analyses we attempt to answer these questions: Had the drilling density in the Middle Tennessee district been applied to the Tri-State district, how much of the ore in the Tri-State would have been discovered? Had this drilling been done in the Upper Mississippi Valley district, how much of the ore in that district would have been found? Which of these two older districts does Middle Tennessee more closely resemble in intensity of zinc mineralization? Is more drilling warranted in the Middle Tennessee district? Our data base includes tonnage and area distributions of ore deposits in the Tri-State dis¬trict, sizes of ore bodies and probabilities of their recognition in the three districts, and data for the Elmwood mine in the Middle Tennessee district. Our statistical analysis considers the consequences of drilling holes in the three districts on square grids at coarse, intermediate, and fine spacings. We conclude that the drilling pattern assumed for Middle Tennessee would have found some but not all of the ore in the two older districts. We believe that in intensity of mineralization Middle Tennessee more closely resembles the Tri-State than the Upper Mississippi Valley district, and that more drilling is warranted in the Middle Tennessee district.

Jan 1, 1979

By A. D. Kalogeropoulos, T. N. Michalakopoulos

This paper deals with the numerical simulation of rock cutting laboratory tests using the discrete element method. The main objective is to provide a method for calibrating numerical DEM models of rock cutting in a systematic way so that realistic results are yielded. The numerical models are developed with the discrete element code Yade, which models rocks as a collection of bonded spheres. The models are calibrated in a four-step process based on the design of experiments method and optimization. The calibrated models are evaluated both quantitatively and qualitatively against actual laboratory cutting tests, in terms of the ratio of the simulated mean cutting force to the actual one and the cutting force time series, respectively. The fully calibrated models showed that the simulated cutting process matched qualitatively the actual cutting force recordings and underestimated the mean cutting force by approximately 3%. It is concluded that well-calibrated numerical simulations of the rock cutting process can provide not only a better understanding of the process itself but also quantitative data regarding the cutting force and energy requirements.

Dec 28, 2022

By J. Morris, R. Sellaro

Petro-diesel is a common collector for coal flotation, but the partitioning of diesel range organics (DROs) in process streams has not been widely studied. Preliminary research suggested that under normal dosing schemes total residual DRO contents in process waters should be limited to the sub-ppm water-soluble fraction (WSF). Further, polycyclic aromatic hydrocarbons (PAHs) should partition proportionately with DROs. The purpose of this study was to confirm these findings in laboratory flotation tests. Total DRO and specific PAH contents were measured in the waters associated with the concentrate and tailings streams. The results show that concentrate waters consistently had higher amounts of DROs than tailing waters. Moreover, the DRO contents in both streams generally increased with increasing diesel dosage. In line with preliminary research, DROs appeared to be limited to the WSF, and PAHs tended to partition proportionately with DROs. Under typical operating conditions, it appears that residual DROs should not present an environmental concern, but conditions should be avoided that allow significant overdosing of diesel.

Jan 1, 2014

By C. J. Bise, M. F. Sindelar

Regulations, such as the MINER Act of 2006, require the installation of redundant and secondary communication systems to assure that contact can be established with coal miners who may become trapped underground as a result of an event such as a fire, explosion or inundation. For half a century, the orientation towards underground communications has been that more complex systems better serve the coal miner. However, if a goal is to provide for an alternative means of establishing communication between the surface and trapped miners underground, then some of the technology employed should be simple, reliable and cost-effective. Coal mines spend hundreds of thousands of dollars on exploratory drillholes to characterize reserves, sometimes decades ahead of mine development. During the pre-mine planning phases, certain exploratory drillholes could be located and then outfitted with a simple communication link that would remain compatible with the continuing evolution of communication systems. Inexpensive links, whose locations would be accurately recorded, would be exposed by continuous miners during mine entry development, thereby allowing an underground phone to be connected to a surface station in the event of an emergency. A latent network of these communication links could be installed for less than $500 each, minimally affecting drilling and grouting operations, and could be designed to be compatible with many communication devices. This research examines methods and materials for incorporating an embedded communication link during pre-mine exploration drilling, addresses significant factors affecting its implementation, and presents a recommended design. Since mine plans are known to change, the objective is to minimize cost so that, if not used, the investment is minimal for a potential secondary means of communication between the surface and underground workings.

Jan 1, 2014

By Miche1 Dagbert

In most open pit operations mining porphyry type deposits, production planning rests on an are reserve inventory block file which is derived from diamond drill hole data. With such a practice, the way by which block values are generated is critical and in the recent years many studies deal with the comparison of different estimation methods for block grades (Mueller, E. (1), Knudsen et al (2) (3), Barnes, (4), Williamson and Mueller (5). Typically in such studies, one selects a bench or a group of benches where there is a "sufficient" number of blast holes (BH) with assay values in each of the blocks (generally 30.5 x 30.5 m (100 x 100 ft) or 15.2 x15.2 m (50 x50 ft). Then the arithmetic mean of the BH values in each block is computed and it is assumed to represent the real block grade against which different estimated values are compared. However it is sometimes observed that the variation of these BH values within a block is high and that their arithmetic average may significantly differ from the real average grade of the block (Barnes (4). The problem of the precision of the mean BH grade in a block has been examined by Williamson and Langlois (6) in an experimental way. They strove to find a better estimate of the average block grade than the mean BH grade but their results were not conclusive. The purpose of this study is to investigate the same problem within the frame of geostatistical models (David (7). Besides practical results obtained with these models, two general points are emphasized and illustrated in the text. First, "good results" are obtained if "good geostatistics" is done (David et al (8).

Jan 1, 1978