Search Documents

By A. Visnapuu

High-grade synthetic rutile has been produced in the laboratory from domestic ilmenite concentrates by a new carbonyl process. The ilmenite was first reduced to convert the iron oxides to metal and then treated at temper-atures over 1000 C in high-pressure carbon monoxide (CO) to convert the iron to the pentacarbonyl. Rapid carbonylation was achieved in the presence of small quantities of selected promoters. Maximum iron removal occurred at temperatures between 110° and 130° C at CO pressures from 1,000 to 1,400 psig. Iron pentacarbonyl appeared as liquid and vapor in the reactor and could be removed by gravity flow and vapor transport. More than 90 pct of the iron was extracted in 2-hr experiments at pressures of 1,000 psig and above. The Ti02 product is porous owing to the removal of the iron, has the rutile crystal structure, and is suitable for chlorination. Waste disposal problems associated with the process would be minimal because the iron pentacarbonyl can be decomposed to produce iron powder or pellets for sale and CO for recycling.

Jan 1, 1973

By J. E. Zeilinger

This Bureau of Mines study was conducted to determine the sulfur reduction potential attainable when washing fine-size coal on a spiral concentrator. Crushed samples of Middle Kittanning and Bakerstown bed coals washed on the spiral provided pyritic sulfur reductions of up to 90 percent for the plus 200-mesh material. Pyritic sulfur reductions on the minus 200-mesh material seldom exceeded 30 percent; consequently, this material would require further treatment. The capacity of the spiral was 2 tph per unit when washing l4-mesh by 0 coal. The ability to remove pyrite combined with the higher-than-expected capacity makes the spiral worthy of consideration as a rougher-cleaner in new fine-coal desulfurization circuits.

Jan 1, 1976

By Robert P. Vinson

The Bureau of Mines investigated the presence and extent of methane accumulations in mine roof cavities using a full-scale mine model. Methane was released at a constant rate into the roof of a cavity built onto a 700-ft wind tunnel. Two box-shaped roof cavities were used in the study: one had a volume of 114.7 cu ft; and the other had a volume of 57.3 cu ft. Methane concentration was measured at 28 sampling points in the cavities using 21 different combinations of gas emission rates and air velocities. Brattice hung in the cavity helped reduce methane concentrations without auxiliary ventilation. It was also found that the effective ventilation rate increased by a factor of 40 in the large cavity and by a factor of 20 in the small cavity when air velocity was increased from 100 to 600 fpm.

Jan 1, 1978

By C. A. Wilson

The Bureau of Mines started a continuing program to investigate and evaluate analytical techniques to assist governmental agencies to select simple, rapid, reliable methods for crude oil spill identification. Six crude oil samples were analyzed to evaluate gas-liquid chromatography, atomic absorption spectrophotometry, infrared spectoscopy, sulfur and nitrogren determinations, mass spectrometry, nuclear magnetic resonance spectroscopy, and ultraviolet spectrophotometry. Samples were studied from the following selected fields: El Morgan, Egypt; Duri, Indonesia; Minagish, Kuwait; Bachaquero, Venezuela; Gach Saran, Iran; and Prudhoe Bay, Alaska. These samples were chosen to represent high-production fields that are likely to be involved in oceanic transport. Over 50 years of Bureau of Mines analytical research on petroleum served as the basis for evaluation of the experimental results to determine which of the methods are effective techniques to identify crude oil spills. Gas-liquid chromatographic analysis, atomic absorption spectrophotometric analysis, and sulfur-nitrogen determinations are recommended as the most useful of the techniques investigated.

Jan 1, 1975

By A. V. Petty

In accordance with its objective to maximize minerals recovery from secondary domestic resources, Bureau of Mines conducted research on recycling chrome refractory wastes. Since 20 pct of the U.S. demand for imported chromite is used in the production of refractories, primarily for the steel, copper, and glass industries, samples of used chrome-containing refractories from copper converter and reverberatory furnaces were investigated to determine their potential for recycling. The samples were beneficiated using a combination of wet magnetic separation, flotation, and leaching techniques, and the concentrates were reformed into briquets for refractory evaluation. Small refractory test specimens produced from the beneficiated concentrates gave modulus of rupture values at 1,350° C comparable to those of commercial mag-chrome brick of similar composition; however, grinding the waste refractories to at least minus 65-mesh was required in order to liberate the metallic copper. Most of the copper was easily recovered using conventional beneficiation techniques, but the finely ground chrome concentrate would require briquetting, calcining, and crushing to produce a coarse grain suitable for recycling into secondary mag-chrome refractories.

Jan 1, 1981

By David K. Ingram

The development of large open surface fractures over mined-out coal longwall panels is the focus of this U.S. Bureau of Mines report. The research concentrates on defining the fractures characteristics and their controlling variables. The investigation was conducted at two mines in south-central West Virginia. All but one of the fractures are subparallel to the trend of the underlying longwall panel. One fracture is perpendicular to the trend of a longwall panel. Overall length of the fractures ranges from 60 to 900 ft. In cross section they are V-shaped, ranging from a couple of inches to 25 ft in width at the surface, but narrowing as they increase in depth. Fracture depth varies from a few inches to over 50 ft into bedrock. A vertical fracture or joint plane was observed in the bedrock at several open zones along the fractures. All of the fractures vary in elevation and do not parallel surface contours. The fractures are aligned with local joint trends, they correlate with longwall development, and they are situated in an increased tensional area over the mined out longwall panels. These observations indicate that the fractures are tensional openings along preexisting joint planes possibly triggered by longwall mining.

Jan 1, 1989

By Walter W. Fisher

A kinetic investigation of copper cementation in a revolving drum was undertaken by the Bureau of Mines to explore the effects of a porous copper deposit attached to the iron surface and a fluidized slurry of copper particles surrounding the iron precipitant. The rate of cementation was found to be significantly enhanced by the increased cathodic areas provided by a porous copper deposit or the presence of a fluidized bed of copper particles contacting the iron precipitant. The cementation rate was found to be retarded by increased ionic strength, low pH, and the presence of oxygen. The cementation reaction was first order with respect to precipitant surface area. Copper cementation on iron is visualized to occur by two basic mechanisms. Precipitation may occur through a series of shorted electrochemical cells, whereby cupric ion precipitates on a growing cathodic copper deposit, or, deposition may occur via a fluidized cathode of copper particles contacting the ion precipitant.

Jan 1, 1976

By Isaac A. Zlochower, Kenneth L. Cashdollar

The Pittsburgh Research Laboratory of the National Institute for Occupational Safety and Health conducted a study of the explosibility of various metals and other elemental dusts dispersed in air, with a focus on the experimental explosion temperatures. The data are useful for understanding the basics of dust cloud combustion, as well as for evaluating the explosion hazards in the minerals and metals processing industries. The dusts studied included boron, carbon, magnesium, aluminum, silicon, sulfur, titanium, chromium, iron, nickel, copper, zinc, niobium, molybdenum, tin, hafhium, tantalum, tungsten, and lead. The dusts were chosen to cover a wide range of physical properties - from the more volatile materials such as magnesium, aluminum, sulfur, and zinc to the highly "refractory" (very low volatility) elements such as carbon, niobium, molybdenum, tantalum, and tungsten. These flammability studies were conducted in a 20-L chamber, using strong pyrotechc ignitors. The experimental data obtained included the minimum explosible concentrations, maximum explosion pressures, and maximum explosion temperatures. A unique multiwavelength infrared pyrometer was used to measure the temperatures. For the elemental dusts studied, all ignited and burned as air-dispersed dust clouds except for nickel, copper, molybdenum, and lead. The measured maximum explosion temperatures ranged from -1 550 K for tin and tungsten powders to -2800 K for aluminum, magnesium, and titanium powders. The measured temperatures are compared to the calculated, adiabatic flame temperatures. In general, the dusts whose experimental temperatures were closer to the adiabatic values were those with the finer particle sizes, those that were more easily vaporized, and/or those that were intrinsically more reactive.

By John P. Gooch

The Bureau of Mines wrote a computer program which calculates the saturation curves and condensation characteristics of gaseous mixtures consisting of binary organic vapor and air. The program employs an algorithm which assumes an equilibrium mechanism for condensation, and the degree of fractionation obtained is predicted on the basis of relative volatility. The program incorporates a feature which allows the user to examine the fractionation resulting from condensation as a function of the size of the temperature increments over which condensation is assumed to occur. If a single. temperature interval between the dewpoint of the mixture and the outlet temperature of the condenser is assumed for the calculation, the results obtained will be those resulting from a single equilibrium condensation. If the condensation is assumed to occur over a number of temperature increments, the results obtained will approach those predicted by the Rayleigh equation as the magnitude of the temperature increments approaches zero. The results from calculations performed on vapor mixtures from organic heavy liquid solutions used in beneficiating potash and brucite ores are presented. The liquids are solutions of dibromomethane in trichloroethylene or perchloroethylene. The results show the degree of liquid recovery which is possible by cooling mixtures of organic vapor in air. Compositions of the vapor range from 10 to 95 percent air, and assumed condenser exit temperatures range from 110° to 50° F.

Jan 1, 1971

By Michael J. Brnich

Since 1991, Pittsburgh Research Center (PRC-formerly part of the Bureau of Mines) researchers have recorded extensive interviews with 30 individuals who are experts in the area of mine emergency response. These individuals, who have an average of 35 years of mining experience and 29 years of mine emergency response experience, related stories and observations from events that they experienced during their combined 850 plus years in mine emergency response. The purpose of this effort was to gather information that could be passed on to both today?s and tomorrow?s mine emergency responders to train and guide them in handling future events. This is the first of two articles which report the responses that these experts gave when asked how they think people who may have to respond to a future mine emergency should be trained. During the interviews they discussed how training should be conducted, who should be trained, and what topics should be included. This article will cover the first two areas: what training methodologies would be most effective and who needs to participate.

Jan 1, 1997

By T. W. Goodman, J. Cervik

The Bureau of Mines conducted studies to compare the effectiveness of the cross-measure borehole system with that of surface gob holes on two successively mined retreating longwalls in the Lower Kittanning Coalbed. Only the cross-measure system was in operation on panel A; on panel B, both systems were in operation. In addition, the cross-measure bore-holes on panel B were drilled parallel to the face, whereas those on panel A were drilled at a 45O angle with respect to the longwall axis. The studies show that the cross-measure system captured 71 pct of the methane generated by longwall mining on panel A. On panel B, the sur- face gob hole dominated over the cross-measure system for about 700 ft (213 m) after it was intercepted. Beyond that point, the cross-measure system dominated. About 93 pct of the methane generated on panel B was captured by the two systems. Cross-measure boreholes that were drilled parallel to the face were as effective as boreholes oriented 45" with respect to the longwall axis. In addition, they are shorter and require less drilling time. Comparison between observed gas pressure differentials in boreholes and calculated values indicate that boreholes can be shortened further to 140 ft (43 m). Additional studies are needed to verify these calculations.

Jan 1, 1986

By Donald P. Schlick

This report presents a representative cross section of methods success- fully used to ventilate continuous-miner places as well as various factors that should be considered when selecting auxiliary ventilating equipment. Line brattice can direct fresh air to the active face reasonably well, provided that adequate area for installation is available. Continuous mining equipment, however, often restricts clearances to such an extent that proper installation of line brattice is impossible. Consequently, in many instances face ventilation is inadequate; therefore, many methods of auxiliary ventilation for continuous-mining equipment have been developed and have been discussed in this study.

Jan 1, 1963

By Kevin Michael, David C. Byrne

In previous issue of Spectrum (October 1999, 16/4), a system of measuring the attenuation provided by insert-type hearing protectors was described, That report described experiences using the FitCheck (Michael & Associates, Inc.) system in a pilot project involving the steel industry during 1998.[ ]

By J. R. Allsup

The Bureau of Mines studied the characteristics of simulated coal gas as an automotive fuel in two multicylinder vehicles in a standard and high-compression-ratio engine configuration. While using simulated coal gas fuel, increasing the engine compression ratio improved the fuel economy and vehicle performance but increased hydrocarbon emissions by 40 pct. photochemical reactivity of exhaust hydrocarbons was found to be extremely low using the coal gas fuel. An oxidizing catalyst used with the simulated coal gas fuel eliminated all but trace amounts of carbon monoxide and reactive hydrocarbons in the exhaust. Spark gap geometry and firing voltage were varied and, within the range tested, had little effect on vehicle performance and emissions using simulated coal gas fuel.

Jan 1, 1975

Abandoned Mme - A mine that a not producing any mineral and will not continue or resume operation Abatement - The lessening of pollution effects Acidity - A measure of the extent to which a solution is acid Acid Mme Drainage - Any acidic water draining or flowing on, or having drained or flowed off, any area of land affected by mining

Jan 1, 1975

By Gerrit V. R. Goodman, Charles D. Taylor, Edward D. Thimons

Future coal mining systems will be able to cut from crosscut to crosscut where advances could exceed 100 ft. However, limitations arise when ventilating such mining systems. In deep advance mining, there would be no workers at the face to advance ventilation tubing or curtain manually. Traditional methods also provide no means for maintaining face ventilation after the miner backs away from the face. U.S. Bureau of Mines research is studying means to provide effective ventilation at cut depths beyond the current limit of 40 ft. Several innovative ventilation schemes are currently being considered. One such method is the use of a jet fan to ventilate a deep cut. A jet fan is simply a freestanding fan using little or no ducting to direct the ventilation flow. Jet fan testing in a 90-ft entry revealed that higher exit velocities and greater penetration depth occurred when various configurations were used to confine and direct the air flow. Additional testing also indicated that 2,200 cfm of fresh air was delivered to the face 90 ft distant when a check curtain was used to limit entrainment around the fan. Without this curtain, this quantity dropped to only 1,000 cfm This testing indicated that a jet fan was capable of providing ventilation to a distant face area. It also highlighted potential problems, such as recirculation at the fan and reentrainment in the jet flow. Despite these potential problems, jet fans may be adequate for ventilating cuts exceeding 40 ft.

Jan 1, 1992

By John Durkin

Information on vertical magnetic noise in the voice frequency band, both within and above coal mines, is needed for the evaluation of through-the-earth baseband electromagnetic communications at mines where horizontal loop antennas are used. This report discusses the theory of the source of electromagnetic noise, the propagation of this noise to an observation point above a mine, and its interaction with the local earth conductivity structure, which gives rise to vertical magnetic noise. The relationship of surface noise to underground noise is also discussed. Bureau of Mines investigators made surface and underground vertical magnetic noise measurements at a number of coal mines located through- out the United States. These data were modeled through regression analysis to characterize expected noise levels. The results are presented, including results in one-third octaves for use in evaluating the expected performance of through-the-earth communication systems by articulation-index studies.

By Robert R. Stein, Roy C. Bartholomae, William W. Aljoe

This Bureau of Mines report describes in detail the design and operation of a test apparatus for measuring the sound power levels of drills used by the mining industry. The two major components of the test apparatus are a computer-controlled automated drill test fixture (ADTF) and a large (45,000-ft3) reverberation chamber that houses the ADTF. Design specifications and performance capabilities of the ADTF and the reverberation room are given. Initial test results for three types of drills--a pneumatic percussion drill, a hydraulic percussion drill, and a pneumatic rotary drill--are given to illustrate the types of experiments that can be conducted with the test appartus.

By C. I. Pierce

Knowledge of the water content of oil-bearing formations is important in petroleum-reservoir evaluation work. Electric logging provides a means for making reliable estimates of water content if resistivity-saturation relationships representative of the formations are available. Relationships can be determined in the laboratory by a number of methods. This report describes and presents results of a laboratory investigation conducted at the Bureau of Mines Appalachian Experiment Station, Morgantown, W. Va. (1) to evaluate an evaporation method of attaining water saturations in sandstone samples when determining resistivity-saturation relationships and (2) to compare saturation exponents derived from data obtained, using different methods of achieving water saturations. A series of tests was conducted to determine the effect of evaporation on salinity distribution within the core specimen. Results of these tests show that a zone of high salinity was set up at the surface of a sample during evaporation and that long periods were required for the sample to reach resistance equilibrium after evaporation had ceased. Equilibrium time ranged from several minutes to several days, depending on the sample size and the technique used. The high-salinity zone was removed from the sample by using auxiliary porous material in capillary contact with the sample surface during evaporation. Salinity determinations and resistance measurements indicate that, at saturations greater than the minimum interstitial values, the mechanism of flow during evaporation was one of moisture migration mainly as a liquid from the interior of the test specimens to their exterior surfaces. The concentration of the contained brine remained essentially unchanged, except for a narrow zone near the evaporating surfaces.

Jan 1, 1958

By Roy C. Bartholomae

This U.S. Bureau of Mines study found that the performance of the active noise cancellation hearing protector in a reverberant field was mixed. The performance varied when the conditions changed from ideal to nonideal. The active noise cancellation (ANC) component provided substantial additional noise reduction from 125 to 500 Hz for all testing conditions (broadband noise or pure tones both with and without safety glasses). While the ANC under ideal conditions provided additional attenuation from 500 Hz and below, under nonideal pink noise conditions the ANC amplified noise below the 125-Hz third octave band. There was a middle band of frequencies at which the ANC amplified noise levels ranging from 630 to 4,000 Hz. The results for pure tones showed that attenuations were higher but that they followed the same general trend.

Jan 1, 2010