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By David Hoadley, Kenneth R. Maser, Ashok B. Boghani, James E. Billar, D. Randolph Berry, Mackenzie Burnett, Robert H. Trent

1, Introduction This report is submitted in fulfillment of the requirements of USBM Contract No. J0255017, "Development of Emergency Escape Systems Guidelines for Underground Metal and Nonmetal Mines" Under this contract the history of past mine fires was studied. Representative metal and nonmetal mines were surveyed and escapeways, refuge chambers, life support, and emergency hoist requirements were studied to determine the problems in complying with the proposed regulatory standards and their enforcement by MESA Mine Inspectors. In addition, a computer program was written to evaluate mine evacuation performance. The completed program is included in the appendix. 1. 1 Historical Review of Metal and Nonmetal Mine Fires Early records of mine fires are poorly documented because there was no statutory provision for reporting fires to the Bureau of Mines. The survey of representative mines during the course of this contract indicated that many small fires still go unreported even though they are now required to report all fires A recent report survey approximately 80 disasters in metal and nonmetal mines, (6 ) Table I is a summary of some of these fires. Historically most metal and nonmetal mine fires have been caused by electrical problems. Spontaneous combustion and the use of welding equipment are the other major causes of mine fires(14) Although not documented, many mine personnel agree that 30 percent to 40 percent of underground metal and nonmetal mine fires have their origin from cigarettes and other smoking related materials. The number of fires related to spontaneous combustion is decreasing and equipment fires are on the increase. The reduction of spontaneous combustion fires can be attributed to the use of sandfill in more mines and the increase in equipment fires to the increased use of LHD equipment.

Jan 1, 1976

By Edward D. Thimons

Because of the high number of accidental methane gas ignitions in metal and nonmetal mines, the Bureau of Mines searched for a simple guideline that would allow mine personnel to evaluate the methane hazard in a given mine. Air samples were collected by the Bureau in 53 metal and nonmetal mines and analyzed for trace evidence of methane gas. Samples were collected in the returns and at the working faces. Those mines classified as gassy by the Mine Safety and Health Administration had a significantly higher average methane concentration than those classified as nongassy. Of the 9 gassy mines sampled, 7 had methane concentrations above 100 ppm, whereas only 1 of the 44 nongassy mines had a concentration above 100 ppm. The 100-ppm concentration may be used as a simple and convenient guideline for forecasting the methane hazard in a mine, whether or not the mine is classified as gassy. There was no consistent correlation between commodity mined and methane concentration, nor was there a correlation between mine depth and methane concentration. Neither of these factors can be considered a guideline for predicting methane hazards.

Jan 1, 1979

In laboratory tests using reconstructed soil columns, rubber latex showed good sealing efficiency when applied at a rate equivalent to 4000-5000 pounds per acre. Results of field testing, however, were inconclusive. The ideal situation in which latex would coagulate in a narrow zone two to three feet below the surface by reacting with acidic or metallic constituents of the soil was not attained. Rather, the latex was deposited progressively as it passed through the soil (most of it remained in the top foot), the rate of deposition being dependent on soil structure and composition as well as on properties of the latex such as particle size and emulsion stability. Latex stability appears to be a more critical property than latex particle size in controlling penetration. Addition of excess anionic or nonionic surfactants to latex improved its penetration into the soil. A styrene-butadiene (SBR) rubber latex of 2400 Å average particle size with high mechanical stability gave the best balance of penetrating ability and sealing capacity in laboratory tests and this was confirmed in tests on a 5 x 5 foot test plot at Lanse, Pennsylvania. This latex was subsequently applied to three one-quarter-acre plots at Lanse by sprinkler irrigation, and compared to adjacent areas that were sprinkled with water only. Soil moisture measurements did not enable us to judge the effectiveness of the seal because differences between sampling positions were greater than differences between treated and untreated sections, but permeability tests showed that water flow was much slower (90-99% reduction) within the top ten inches of soil in the latex- treated sections. This sealing effectiveness was reduced after wintering. There was no deleterious effect on the vegetation as a result of sprinkling the areas with latex. A laboratory study conducted in a 5 x 5 x 5 foot box containing uniform reconstructed soil from a New Jersey source suggests that latex penetration into the soil in the field occurs mainly through natural macro openings and not through the capillaries of the soil structure. Dilute solutions of ammonium hydroxide or sodium carbonate (with no latex present) were found to seal effectively in laboratory soil columns as well as in field applications. However, since these chemicals are water soluble, the seal is temporary. Raw material costs of latex at the application rates used in the field testing are in the order of $1000 per acre. Equipment and operating

Jan 1, 1972

By James L. Konchesky

Crushed coal, consisting of a wide range of sizes, was effectively blended by recycling it through a bin equipped with a particle distributor. Vertical blending was accomplished by simply recycling the coal; it was not significantly influenced by the horizontal blending that was achieved by the distributor. The method was effective, even though the coal was wet and possessed poor flowing characteristics. Recirculation appears capable of providing uniform blends of solids that can be more efficiently processed. Recirculation also appears useful, preceding packaging operations, to insure for blending of solids into specification products. Continuous measurement of the bulk density of the coal by a gamma ray meter proved to be an effective monitor of vertical blending effectiveness.

Jan 1, 1972

By James V. Kelly

During the spring and summer of 1947, the Bureau of Mines conducted an investigation and core-drilling program in the vicinity of the Rodham mine, approximately 4 miles north of Shullsburg, Wis. This work was undertaken as a part of a general study of the zinc and lead-producing area of southwestern Wisconsin. Work in the Rodham-mine area was done to investigate further a mineralized area frilled in part by the Puritan Exploration Co., a Delaware corporation, with offices in Galena, Ill. Some significant lead-bearing samples were obtained, but no continuous ore body was disclosed as a result of the Bureau of Mines work.

Jan 1, 1949

By W. A. McKinney

A sample of oxidized copper ore from a large deposit located in Pinal County, Ariz., about 50 miles northeast of Tucson, was treated by the Federal Bureau of Mines in a small-scale continuous pilot plant by a procedure which comprised acid curing complemented by water leaching and countercurrent decantation washing in a series of drag classifiers. A feed was prepared by pugging minus 1/4-in, ore with concentrated sulfuric acid and about 10 pct, of eater, followed by curing in batches for about 24 hr. The cured ore was fed continuously to a leach drum, where it was mixed with advance solution from the countercurrent washing system to dissolve the sulfated copper. The pulp was thickened and washed in four Esperanza-type classifiers, using a flocculating agent to obtain rapid settling and thickening. The leached ore pulps thickened satisfactorily in the drag classifiers when about 0.8 lb. of a polyacrylamide flocculant per ton of dry feed was used. Clear overflow liquors were obtained, and classifier rake products containing about 60 pct. solids were produced, As much as 90 lb./hr. of ore was treated in the plant, with a recovery of 60 pct. of the total copper or 80 pct, of the acid-soluble copper when 2 tons of water per ton of feed was used in washing. The acid consumption was 4.3 lb./lb. of copper recovered. On the basis of the maximum feed rate employed and the effective pulp-settling area of the classifiers, a total of 1 sq. ft. of pool area was required per ton of dry feed per day for the thickening and washing operations. The washing efficiency in the test was 95 pct.

Jan 1, 1960

By W. G. Pariseau

The U.S. Bureau of Mines has been conducting a series of rock mechanics investigations at the Lucky Friday Mine in the Coeur d'Alene Mining District of northern Idaho. The present study uses rock deformation measurements to validate and calibrate a geomechanical model of the experimental Lucky Friday underhand longwall (LFUL) stope on the 5,100-ft level of the Lucky Friday Mine, Mullan, ID. The calibrated three-dimensional, finite-element model and measurements of rock mass displacement show a correlation of 0.795. The calibration reduces rock mass modulus to 14 to 17 pet of laboratory values and rock mass strength (with an energy rule) to 37 to 41 pet of laboratory values. This model suggested that stress-related ground control problems would be encountered west of the stope where the vein makes a right-angle turn and then splits. Rock burst activity was concentrated in this area during mining of the LFUL stope.

Jan 1, 2010

By Raymond M. Stateham

Calculations based on data obtained from measurements of smoke from coal-fired powerplants predict that infrared imagers will be useful tools for smoke vision. Infrared imagers operating in the 3-to 5-um spectral region have been evaluated for this purpose. A mine opening 110 meters long was filled with smoke from burning coal, and two men, wearing breathing apparatuses, moved through the smoke to serve as targets. The men were detected and identified at 80 meters.

Jan 1, 1976

By John C. Franklin

A radon survey was made at five different locations in the Twilight mine near Uravan, Colo., to determine chances in radon concentrations in an inactive mine. Data were taken with a continuous monitor set for 1-minute count periods and readings were taken 24 hours a day for 9 days. The 12 readings per station each hour accurately showed how t w radon concentration varied during the day. From the data collected from the intake portal to station 4, the average radon emanation rate was estimated at 18 picocuries per second per square foot (pCi/sec/ft3). A daily cycle in radon concentration was detected that apparently was related to barometric pressure change.

Jan 1, 1976

By J. B. Stephenson

The Bureau of Mines, under an interagency agreement with the Department of Energy (DOE), investigated the feasibility of hardfacing the critical surfaces of valves and similar devices by chemical vapor deposition. The purpose of this research was to increase the wear resistance of these components for use in the abrasive and erosive environment of coal gasification units. Tungsten and molybdenum coatings were produced on nickel-plated carbon steels and stain-less steels by hydrogen reduction of the metal hexafluoride at 325° to 600° C. Titanium nitride coatings were produced on low-carbon steels by the reaction of titanium tetrachloride, hydrogen, and nitrogen at 1,000° C. Titanium carbonitride coatings were produced on low-carbon steels by the reaction of nitrogen, hydrogen, and methane at 900° C. Tungsten, molybdenum and titanium nitride coatings were formed on 6-, 10-, and l2-inch (0.15-, 0.25-, and 0.30-meter) ball valve seats for evaluation in the low-Btu coal gasification pilot plant at the Morgantown Energy Research Center, Morgantown, W. Va.

Jan 1, 1979

By C. B. Manula, R. L. Sanford, R. A. Rivell

PART I. FLOW CHARTS

Jan 1, 1974

By Maria I. De Rosa

The U.S. Bureau of Mines conducted experiments for predicting materials' ease of combustion (smoldering onset, smoldering, flaming, and decomposition rates) by means of submicrometer smoke particle characteristics for the development of a simple test method. The experiments were carried out in an approximately 20-L furnace, with a 10-L/min airflow through the furnace for a 14-min duration, at set furnace temperatures of 150°, 250°, and 1,000° C. The variables studied as a function of time were the onset time of smoke particles, time and duration of maximum smoke particle generation, average concentration of smoke particles, and particles' average diameter, mass weight loss, and furnace temperatures. Results show that the onset time of smoke particles is predictive of materials' ease of smoldering, and the time of maximum smoke particle generation and its duration, coupled with mass weight loss, are predictive of materials' ease of smoldering and flaming (depending on the experimental temperatures), and decomposition rates.

Jan 1, 2010

By B. J. Scheiner

As part of the goal to maximize minerals and metals recovery from primary domestic resources, design factors associated with minimizing current leakage in bipolar cell configurations were studied by the Bureau of Mines as a means of improving the efficiency of bipolar e1ectrooxidation cells. Initial studies that were conducted in a small bipolar cell operating at 140 to 145 volts and 15.4 amp indicated how design factors could be employed to minimize cur-rent leakage around adjacent electrodes during cell operation. Based on these results, a 40-electrode, 108-kva prototype of an industrial-sized cell was constructed and tested for extracting metal values from offgrade molybdenite concentrates. The feasibility of recovering molybdenum and rhenium from the oxidized pulp also was determined. Feed to the process sequence consisted of flotation concentrates containing 16 to 35 pet Mo as molybdenite and 6 to 15 pct Cu. E1ectrooxidation in the prototype cell resulted in 84 to 97 pct Mo and Re extraction with a corresponding energy consumption of 9 to 13 kwhr/1b Mo extracted.

Jan 1, 1979

By Bruce Cantrell, K. L. Rubow

"INTRODOCTIONMeasurement of the contribution of diesel exhaust to respirable aerosol in mine environments has become increasingly important because of current concerns over the occupational health effects resulting from exposure to diesel emissions. In response to this, the U.S. Bureau of Mines is developing and evaluating new sampling methods for measuring diesel aerosol in underground mines. Two such techniques are being studied by the Bureau, size selective sampling and Chemical Mass Balance (CMB) modeling. These techniques use measurable physical or chemical characteristics of a mine aerosol sample to infer the amount of diesel particulate material contained in the sample.Size selective sampling is being adapted for measurement of diesel aerosol by the Particle Technology Laboratory (PTL) of the University of Minnesota under sponsorship by the Bureau. 1 It is based on the premise that diesel and mineral dust aerosol can be physically separated by size and collected during sampling using inertial impaction. An independent effort by the National Institute for Occupational Safety and Health to develop a size selective sampling technique was also sponsored by the Bureau.The second technique, CMB modeling, is being developed by the Bureau as an alternative measurement technique to referee the results obtained using size selective sampling.3 It compares measured trace element ""finger prints"" of aerosol sources with similar profiles of mine aerosol samples. From these, the portions of the sample contributed by each source can be determined. Results of these investigations in underground coal mines have confirmed that diesel and coal dust aerosol are of different size and can be measured separately using size selective sampling techniques.A major difference in diesel usage among underground mines is the requirement for exhaust gas cooling systems in coal and gassy noncoal mines. Nongassy mines usually employ limited exhaust conditioning in the form of catalytic converters, which have limited effect on primary exhaust particulate. The cooling system in most general use in gassy mines is the water scrubber. This device has little effect on most of the gases but removes particulate material from the exhaust. 5 Because of this, exhaust aerosol characteristics in nongassy mines are expected to be different. To see if size selective sampling techniques can be used in such mines, the Bureau and the University of Minnesota conducted a second study in three metal and nonmetal mines, two nongassy and one rated as gassy."

Jan 1, 1990

By J. A. McAllister

In the course of a study of domestic Manganese resources, 2-ton representative samples of ore were taken by Bureau of Mines' engineers from the Payday claim, Weber County, and the Newcomb-claims, Rich County, Utah. The Payday No. 1 deposit is situated 13 miles northeast of Huntsville, Weber County, Utah. The manganese ore is a. replacement deposit in limestone and consists of manganese oxides imbedded 'in clay and also as the cementing agent consolidating small pebbles and pieces of quartz and limestone.

Jan 1, 1949

By A. W. Khair, M. Ahmad, Gehi. L. D.

"This paper presents an analysis of the effect of the dynamics of bit wear on dust generation. Two surveys have been conducted in order to assess the mechanism and type of bit wear and to evaluate the impact of bit wear on the productivity of the continuous miners. Used bits were collected from the underground coal mines and these used bits were utilized in laboratory coal cutting. The effect of bit wear on dust generation has been quantified and its impacted on dust generation and ventilation system has been exemplified.INTRODUCTION Research has reduced the prevalence of Coal Workers Pneumoconiosis from 15 to 5 percent according to NIOSH reports (Breslin 1982). However CWP still have not been eliminated as a hazard to mine workers. To prevent coal workers from having black lung MSHA has established a very strict standard for coal mine operations (2.0 mg/m3 with silica content equal to or less than 0.1 mg/m3,). There are numerous coal operations still experiencing great difficulty with meeting the 2mg/m3 dust standard. Among these are the longwall sections and continuous mining sections. In order to meet the rising demand of energy and coal, the number of longwall operations and continuous mining operations would have to be increased. Thus a long term research commitment is required to develop basic solutions that are more generic and greater benefit to the mining and mineral industry.In continuous-mining operations, the miners are exposed to the dust produced during the fragmentation of the coal from the face plus the dust produced during loading and transferring of the coal. The fragmentation process generates most of the respirable dust. The amount of dust generated during fragmentation depended on the coal properties, cutting parameters and cutting bit configuration. Bit wear changes bit configuration, therefore, it also affects dust generation. Bit wear can be defined as the removal of material from surface as a result of mechanical action. In soft coal mines bit wear may not be a serious problem but in hard coal seams bit wear is very significant. In addition, as the good coal seams are depleted, the operators are mining thin seams and the seams with rock partings. During cutting these seams operators are sometimes forced to cut roof and floor rock or rock partings which result in more rapid wear of bits."

Nov 1, 1995

By E. P. Youngman

The basic mining law of French Morocco is the Edict of 1914, "Danir of Jamary 19, 1914, for the Regulation of Mineral Prospecting and Exploitation in the Zone of the French Protectorate of the Cherifien Empire," which, as the preamble states, was promulgated at the instance of the Director General of Public Works, in consideration of the fact that mines constitute one of the sources of wealth of the Empire. According to a consular report, dated May 18, 1923, by Bradford, men- tioned above, the mining industry of that country, aside from the exploitation of the extensive phosphate deposits, can scarcely be said to exist, but the potential field for mining is promising. However, no large-scale exploitation of the mineral wealth of French Morocco can be hoped for until there is complete pacification of large areas that are still in an unsubdued state or until adequate transportation facilities, scientific prospecting, and large investments of cap- ital are assured. An edict in 1920 (Dahir of January 27, 1920) modified the law mentioned above by declaring the prospecting for and the exploitation of phosphates to be exclusively reserved to the Government. The Dahir o. August 7, 1920, announced the creation of the Cherifien Phosphate Office (Office. Cherifien des Phosphates), a State monopoly charged with the exploration, management, and exploitation of the phosphates of Morocco.

May 1, 1930

By G. E. McClelland

The Bureau of Mines investigated chemical methods for producing high- purity gold from precious-metal-bearing zinc precipitates and steel wool cathodes. Precious-metal-bearing zinc precipitates and steel wool cathodes are unrefined products from conventional cyanidation and heap leaching-cyanidation operations. The zinc precipitates contained 14,40 pct Au and 0.35 pct Ag. The precious-metal-bearing steel wool cathodes contained 20.65 pct Au and 4.84 pct Ag. The precipitates and cathodes were treated with dilute acid to solubilize the silver and/or base metals. The gold-bearing residue was leached in dilute aqua reqia to solubilize the gold. High-purity gold was precipitated from the aqua regia solution with oxalic acid, sulfurous acid, sodium bisulfite, and gaseous sulfur dioxide. The leaching-precipitation experiments recovered 99.9 pct of the gold. The gold precipitates ranged in fineness from 997 to 999 fine. The chemical refining method provides a viable technique for the smaller operator to produce high-purity gold without using pyrometallurgical refining methods.

Jan 1, 1985

By J. J. Drost

This Bureau of Mines investigation studied the effect of thermal treatments upon concentratability of a western Mesabi Range nonmagnetic taconite ore and is a sequel to Bureau of Mines RI 7567. Magnetic tube tests were used to develop the data needed to calculate separation efficiency, the primary measure of concentratability. A horizontal tube furnace was employed to heat treat and reduce the hematitic ore samples. The two variables studied were roasting temperature and cooling method. The manner of cooling, either by slow cooling or quenching in water, produced no significant difference in concentratability. Roasting temperatures employed ranged from 500° to 1,000° C, and a temperature of 650° C effected the best concentratability. The temperature of 650° C correlated with the most effective roasting temperature for grindability.

Jan 1, 1973

By L. B. Pankratz

High-temperature heat-content values of gallium and scandium sesquioxides were measured over the temperature range from 298° to 1,800° K. The results fill gaps in the thermodynamic information for these compounds; no previous similar data existed. The heat-content values were combined with heats and entropies of formation to obtain free energies of formation of gallium and scandium sesquioxides to 2,000° K. The thermodynamic stabilities of the sesquioxides of aluminum, gallium, scandim, and yttrium were compared.

Jan 1, 1963