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By Helen W. Lang

This report describes a monitoring system applied by the Bureau of Mines to provide rapid, continuous determination of the main constituents of exhaust gas during the Bureau's approval schedule testing of diesel engines for under-ground use. Commercially available continuous analyzers with strip chart readout are employed for nitric oxide (mass spectrometric), carbon dioxide (nondispersive infrared), methane (NDIR), carbon monoxide (NDIR), and oxygen (polarographic). Good correlation is obtained between the continuous instrumental results and those obtained by batch chemical and gas chromatographic methods.

Jan 1, 1969

By James S. Browning

The Bureau of Mines conducted laboratory batch and pilot plant flotation tests to determine the technical feasibility of recovering commercial-grade mica from a California micaceous schist. Best results in the laboratory batch tests were obtained using sodium carbonate and sodium silicate for pH control and quartz depression, and a combination of fatty acid and cationic reagents as the mica collector. In continuous pilot plant flotation tests, an alkaline fatty acid-cationic method recovered about 70 percent of the mica in a concentrate analyzing 95.6 percent mica.

Jan 1, 1965

By J. H. Holden, C. C. Shale, G. R. Strimbeck, W. S. Bowie

Electrical characteristics of positive corona are presented for air in a 2 - in - diam electrostatic precipitator operating under dynamic conditions at temperatures of 600 ° to 1,500 ° F and pressures of 0 to 80 psig . Results show that current - voltage relationships depend solely on air density . Comparison of data on positive corona with previously published data on negative corona demonstrates a higher sparkover voltage and a wider range of operability for positive corona at temperatures above 375 ° F. The possibility of achieving higher voltages with positive polarity as indicated by these experiments implies several advantages for the use of positive corona in precipitators to allow better removal of suspended material from hot gases . Based on the physics of an ion in an electrical field , a theoretical equation is derived to define current - voltage characteristics of positive corona in terms of air density . Constants for the equation are evaluated from Calculated current - voltage values at different air densities agree reasonably well with experimental data .

Jan 1, 1964

By L. Mark Irwin, R. A. Marsyla

The objective of this laboratory investigation was to develop a mattesmelting process for the recovery of copper from industrial smelter dusts . Experimentation was conducted on three samples of Cottrell precipitator dust from a northern Michigan smelter with variations in the following conditions : Temperature , charge composition , pelletization , and moisture content . Based on chemical analyses of the furnace slags , poorest recovery of copper was effected in smelting dry charges regardless of composition . Some improvement was noted with uniformly moistened charges and still more with pelletized (but dry) mixes , but best results were obtained from smelting moist , self - fluxing pellets . Under favorable conditions , experiments yielded furnace slags with an average copper content of only 0.15 percent , which is well below that of industrial copper reverberatory slags .

Jan 1, 1963

By Stephen P. Holt

In the fall of 1946 and spring of 1947 the Bureau of Mines put down five inclined diamond-drill holes totaling about 3,100 feet of bore to test for the possible eastward extension of the Royal Princess ore deposit in Jo Daviess County, Ill. Attention of the .Bureau was first directed to this property by the Illinois State Geological Survey. The history of production of the Royal. Princess mine and reports as to the size and nature of the deposit were considered justification for investigating the trend of the mineralization. This report describes the work done by the Bureau of Mines and presents the data obtained.

Jan 1, 1948

By R. J. SHAW

Oil shale has been defined as, "a compact, laminated rock of sedimentary origin yielding over 35 percent of ash and containing organic matter that yields oil when distilled but not appreciably when extracted with the ordinary solvents for petroleum." The oil-yielding organic matter in oil shale, commonly called kerogen, decomposes upon application of heat to form bituminous materials that are soluble in organic solvents and may be extracted from the inorganic residue. However, separation usually is accomplished by continuing the heating and thereby cracking the primary bitumens to gas and oil, which distill, leaving a carbonaceous material on the mineral residue. It has been suggested that this conversion takes place only at relatively high temperatures - 750°F or higher. On the other hand, other workers have found that transformation may take place to some extent at temperatures as low as 400°F. In either a solvent extraction or a destructive distillation process for separating organic material from the inorganic portion of oil shale, the quantity of heat required to raise the temperature of the oil shale sufficiently to induce a satisfactory rate of conversion of kerogen to oil is important in determining the design of an economical process. Likewise, the quantity of heat recoverable from a spent shale is important in determining the overall heat balance of the process. Published data on the specific heat of American oil shales are meager. Gavin and Sharp present data for two samples of Colorado oil shale, one from near DeBeque and one from Parachute Creek, and for a sample of spent shale over a temperature range of 68°F to 1940°F. McKee and Lydor present data on the specific heat of two samples of oil shale from near DeBeque, Colorado. Additional thermal data on various grades of oil shale over a wider range of temperature are needed in order to apply sound engineering practices to the design of equipment for processing oil shale.

Nov 1, 1947

By K. K. Kelley, L. B. Pankratz, W. W. Weller

Mullite is a substance of prime importance in ceramic technology . Despite this fact , its thermodynamic properties have received little attention . A Bureau of Mines literature survey disclosed the absence of lowtemperature heat capacity data , the absence of an experimental entropy value for 298.15 ° K , and the lack of heat content data beyond the temperature range from 298° to 576 ° K. Data supplied in this Bureau report fill these gaps in the thermodynamic knowledge of mullite . According to equilibrium phase studies of Aramaki and Roy ,3 the mullite phase melts congruently at 2,123 ± 15 ° K , and the equilibrium crystallinephase composition extends from Al Si2013 to Al6.8 Si₂ Q4.2 . The results in this report are for the stoichiometric composition , Al Si¿Qз . • Heat capacity measurements were made over the temperature range from 50 ° to 298 ° K , and the entropy at 298.15 ° K was evaluated . Heat content measurements covered the temperature range from 298 ° to 1,800 ° K. Heat content

Jan 1, 1963

By D. D. Fischer

Recovery and separation of molybdenum and rhenium from a process solution was accomplished by a technique developed by the Federal Bureau of Mines involving a combined solvent extraction and activated carbon adsorption procedure. The processing sequence required treatment of the solution with S02 to reduce the chlorate ion and adjust the pR prior to solvent extraction of molybdenum and rhenium with a tertiary amine. Molybdenum and rhenium were stripped from the organic phase with an NH40H solution, and the strip solution was then passed through activated carbon to preferentially adsorb the rhenium. After washing entrained molybdenum from the column with a brine solution, rhenium was eluted with an MeOH-H20 mixture. The activated carbon was regenerated with water. Molybdenum was recovered as (NH4)6Mo7024 by evaporating the column effluent. Rhenium in the column eluate was reextracted with a tertiary amine, stripped from the organic phase with dilute NH40H, and recovered as NH4Re04 by evaporating the strip solution. The final (NR4)Re04 product contained < 80 ppm impurities. Sodium sulfate was crystallized from the first solvent-extraction raffinate by lowering the solution temperature to 0° C. Precious metals contained in the original process solution were adsorbed onto the activated carbon.

Jan 1, 1975

By H. C. Fuller

Depletion of iron ore in the Nation&apos;s large deposits has directed attention to other sources. One of these is the titaniferous iron ore of the Iron Mountain, Wyo., area. Tests were made to determine the feasibility of smelting this ore, which contains about 20 percent titanium dioxide (Ti02), in an electric-arc furnace to produce pig iron. Initial tests, which were made in a 30-pound-capacity induction furnace, demonstrated that the iron could be easily reduced to metal and that limestone was a suitable and effective flux. Larger scale tests then were made in a 50-pound-capacity electric-arc furnace to obtain the more detailed information necessary for the planned continuous operation of a still larger arc furnace. The principal facts determined by preliminary batch-smelting studies were that (1) 9 pounds of limestone flux was required for each 100 pounds of ore smelted, (2) expensive coke was not required because coal proved to be a satisfactory reductant (near stoichiometric carbon was optimum), and (3) overreduction, which produced a viscous slag, must be avoided.

Jan 1, 1961

By W. W. Adams, V. E. Wrenn

"Production of explosives in the United States during the calendar year 1936, as represented by reports of sales by manufacturing companies, totaled 391,604,500 pounds, an increase of 27 percent over the amount produced during 1935. This quantity included 81,698,375 pounds of black blasting powder (granular and pellet), 262,047,106 pounds of high explosives other than permissibles, and 47,859,019 pounds of permissible 5/ explosives.The manufacturers' reports to the Bureau of Mines classify the sales of explosives according to five main classes of work in connection with which the explosives were used.Coal mines used 87 percent of the total amount of black blasting powder sold, bituminous-coal mines 79 percent, and anthracite mines 8 percent; coal mines also consumed 98 percent of all permissible explosives and 9 percent of the high explosives other than permissibles. The coal-mining industry consumed 16 percent more explosives in 1936 than in the preceding year, the increase at bituminous mines being 21 percent and that at anthracite mines 4 percent.Metal mines used 29 percent of the high explosives other than permissibles and less than 1 percent of the black blasting powder and permissible explosives. The total quantity of the three classes of explosives used in metal mining in 1936 was 36 percent more than the quantity so used in 1935."

Jul 1, 1937

By K. C. Dean

Time and motion studies were made by the Federal Bureau of Mines on the hand and machine dismantling of scrapped auto starter motors, generators, and alternators for recovery of copper, aluminum, and iron. The studies showed that an individual with power handtools and convenient access to a hydraulic press, power bandsaw, acetylene torch, and power lathe could, in an 8-hour day, disassemble about 100 starters, or 150 generators, or 30 alternators. The scrap copper yield would be 280, 390, and 45 pounds, respectively, and the iron yield would be about seven times the copper weight. About 100 pounds of aluminum would be obtained from the alternators.

Jan 1, 1976

By William K. Tolley

The U.S. Bureau of Mines (USBM) is investigating hydrometallurgical processing techniques to recycle metals from semiconductors and other advanced materials. Cadmium and tellurium were recovered from mixed CdTe/CdS scrap produced in the manufacture of thin-film photovoltaic devices. Selective cadmium dissolution was achieved using oxygen-pressure leaching in dilute sulfuric acid. Leaching the scrap for 90 min at 110° C in 2.2NH2S04 under 400 psig 02 yielded 97% Cd extraction; however, cadmium content of the residue ranged between 4% and 7%. Soluble iron was added to the lixiviant to catalyze oxidation of the CdS component. Tellurium and sulfur remained in the leach residue primarily in the elemental form. The iron and tellurium were removed from the cadmium-rich leach liquor by adjusting the pH to 5.3. The cadmium was recovered as cadmium sulfate crystals by evaporating the solution. Alternative leaching and purification schemes are discussed.

Jan 1, 2010

By Lawrence W. Scott

The performance of RETIMET metal foam as a flame arrester on explosion-proof enclosures was investigated by the U.S. Bureau of Mines both in laboratory tests and at the U.S. Mine Safety and Health Administration&apos;s (MSHA&apos;s) Approval and Certification Center, Triadelphia, WV. The objective of this research was to develop a permissible pressure vent for use on lightweight, vented, explosion-proof enclosures. In laboratory tests, four grades of RETIMET, a stainless steel foam material, were evaluated: (1) 45 NC-7, (2) 45 NC-13, (3) 80 NC-7, and (4) 80 NC-13. Explosive gas mixtures were prepared by a dynamic flow system. Ignition was by a low-voltage arc. Each grade of RETIMET metal foam successfully arrested the flame front in all methane-air tests. To evaluate RETIMET metal foam on large, commercial size enclosures,a multi compartmented enclosure was designed and tested in MSHA&apos;s explosion gallery in Triadelphia, WV. Extensive explosion testing revealed that a minimum vent-area-to-enclosure-volume ratio of 11.33 in2/ft3 is required to keep internal pressure rises below 3 psig. The RETIMET metal foam functioned satisfactorily in all tests as evidenced by the absence of external ignitions.

Jan 1, 2010

By Liming Yuan, Charles D. Litton

This paper presents experimental results for conveyor belt flame spread from tests conducted in a small-scale tunnel. The purpose of this study is to investigate the effects of belt type, ventilation velocity, belt surface-to-roof distance and ignition source power on the flame spread properties. The tunnel used was 4.9 m long by 0.46 m square with the ventilation velocity ranging from 0.7 to 3.2 m/s. The ignition source was an impinged methane jet burner with heat output ranging from 7 to 21 kW. The belts tested included non-fire resistant rubber belts, fire-resistant rubber belts, fire-resistant neoprene belt and fire-resistant PVC belt with belt samples measuring 0.23 m wide by 2.5 m long. Experimental results show that with a ventilation velocity of 1.02 m/s all conveyor belts could be ignited, and that with sufficient ignition source power, flames spread the full length of the belt sample. The data showed a coupling effect of the ventilation air velocity and the belt surface-to-roof distance on the flame spread rate. For instance, flames could not spread with a ventilation velocity higher than 1.52 m/s and a surface-to-roof distance of 0.22 m. The use of the measured CO/CO2 ratio as an indicator of combustion stoichiometry is also discussed.

By John Nagy

Results of initial research by the Bureau of Mines are given on the dust explosion hazard of float coal and on the related factors of occurrence, rate of production, sampling techniques, transport, and deposition of float coal. Tentatively, it is suggested that where float coal deposits prevail, a mini-mum of 80 percent incombustible be maintained in the top 1/8-inch layer to neutralize the explosion hazard of the surficial coal deposit.

Jan 1, 1965

By J. E. Pahlman

The Bureau of Mines performed research on a fluid-bed magnetic roasting process for nonmagnetic taconites that utilizes low-rank coals and lignites as reductants and fuels. Roasting tests on a Michigan nonmagnetic taconite were conducted at 600° to 725° C with lignite or subbituminous coal as reductants. Partial combustion of the reductant reduced the amount of heat externally applied to the reactor to maintain the desired reactor temperature. Cleaned, dried reactor top gases were recycled to recover a portion of the reducing potential in these gases without adversely affecting concentrate grade and iron recovery. Highest iron recoveries for magnetic concentrates were obtained at a roast temperature of 650° C with lignite and at a roast temperature of 725° C with subbituminous coal. Magnetic concentrates were obtained that were comparable with commercial concentrates.

Jan 1, 1976

By Henry Kreisinger, John Blizard

This preliminary statement presents some of the results of tests carried out at the Lakeside Station of the Milwaukee Electric Railway and Light Co. , by the fuel section of the U. S. Bureau of Mines , in cooperation with the research department of the Combustion Engineering Corporation of New York . The object of these tests was to determine the thermal efficiency , ease of operation , and other particulars of a boiler equipped with specially designed furnace and burners for burning powdered coal . The boiler tested haş 13380 square feet of heating surface , and is one of eight boilers equipped with the Lopulco powdered coal system supplying steam to two 20,000 -Kw . steam turbines in the largest power house burning powdered coal . Twenty- six tests were run at rates of heat transference varying from 4000 to 8000 B.t.u. per square foot of boiler heating surface , and the mean thermal efficiency attained was about 84 per cent , based on the gross calorific value of the fuel as fired . The efficiency varied little with the rate of steaming , and its high value is accounted for by the small loss from incomplete combustion and the small amount of excess air which varied from 5 to 36 per cent . The coal burned had a gross calorific value of about 11500 to 12800 B.t.u. per pound , contained 2 to 5 per cent moisture , 33 to 36 per cent volatile matter and 9 to 13 per cent ash, and was so ground thaf 89 to 95 per cent would pass through a 100- mesh sieve . The ash had a softening point of 2150 to 2450 degrees F. , but did not fuse together at the bottom of the furnace because it was partly protected from the flame radiation by means of a series of water tubes connected to the boiler which were placed between the fumace bottom and the flame, ..

Jan 1, 1923

By N. S. Dalal, X. Shi

"SUMMARYElectron spin resonance (ESR) measurements provide direct evidence for the involvement of the glutathionyl radical, as well as an isolable Cr(V)-glutathione intermediate in the Cr(VI) glutathione redox reactions. These results indicate a new mechanism for the reduction of Cr(VI) by glutathione in relationship to cellular environment and suggest that synergistic reactions of Cr(V) and GS· might be responsible for the (unexpected) increase in the Cr(VI)-induced DNA-strand breaks at high glutathione levels.INTRODUCTIONWhile the reduction of Cr(VI) by glutathione (GSH) is thought to be a critical' step in the pathogenesis of the Cr(VI)-exposure related carcinogenesis1- 4, the exact reduction mechanism is not yet understood. The following reaction steps have been suggested :(A) Initial step:Cr04 2- + GSH - GSCrOa - (1)(B) At high GSH levels:GSCroa- + GSH - Cr( IV) + GSSG (2)(C) At low GSH levels: GSC rO a - - Cr ( V ) + GS ·(3)Thus far, however, in these reactions, the GS· radical has eluded spectroscopic detection, while the evidence for the Cr(V) formation has been reported positives as well as negative2·. Her~ we present spin-trap ESR evidence for the formation of the GS· radical, and a definitive ESR detection of an isolable cr(V)-GSH intermediate in Cr(VI)-GSH reactions.MATERIALS. AND METHODSESR spectra were obtained at X-band (-9.7 GHz) using a Bruker ER200D ESR spectrometer. The magnetic field was calibrated with a self-tracking NMR Gaussmeter (Bruker, Model ER035M) and the microwave frequency was measured with a Hewlett-Packard (Model 5340A) frequency counter. The spin probes, a-(4-pyridyl-1-oxide) -N -tert-butylnitrone (4-POBN) and 5,5-dimethyl~1-pyrroline-1-ox1de (DMPO) were purchased from Aldrich, K2Cr201 from Fisher and used without further purification. All experiments were done at room temperature."

Jan 1, 1989

By J. I. Paige

The effect of fluoride inclusions on the properties of titanium produced from the Bureau of Mines developed induction slag melting process is of concern to members of the titanium industry. The objective of the research was to determine the effect of CaF2 inclusions on the properties of titanium and its survival rate during melting. The data were obtained from single induction-slag-melted ingots prepared with the normal addition of 4 pct and also with 2- and 1-pct additions of CaF2 slag. The results of this effort showed that the mechanical properties of single-induction-slag-melted Ti-6Al-4V alloy exceed the minimum values specified in Aerospace Materials Specification for Titanium Alloy Bars and Forgings AMS4928H, but these materials are much more notch sensitive in fatigue than normal Ti-6A1-4V alloy titanium. First and second vacuum-arc remelts of single-induction-slag-melted ingots fragmented and increased the number of inclusions, while reductions in the amount of flux resulted in an upward trend in the spatial distance between pores in an x-y plane.

Jan 1, 1988

By Christopher Van Dyke, Knox Van Dyke, Lixin Wu, Jaime Gutierrez

"I. INTRODUCTION(SILICA, THE LUNG, INFLAMMATION, AND FIBROSIS)Inhalation of respirable-size silica (0. I to 5 µm in diameter) deposits the particles in the deep spaces of the Jung where oxygen is exchanged. The resulting pattern of inflammation is substantially different compared to that observed from other inhaled substances such as carbon, polystyrene titanium dioxide etc. 1 Following the inflammatory reaction the body attempts to isolate the damage by walling off the area via fibrosis. 2 The unique nature of the inflammatory response to silica makes it logical to infer that fibrosis is a later-stage manifestation of the initial inflammatory damage. In addition to the inflammation extensive lysis and cellular death particularly to macrophages and neutrophils, can occur, depending on the dose of silica.' The ingestion of significant amounts of silica by macrophages and neutrophils produces an inflammatory sequence which activates the lipoxygenase pathway of arachidonic acid metabolism and produces platelet activating factor (PAF) and leukotrienes (LT).4·5II. CALCIUM IONOPHORE MIMICS SILICA TOXICITY IN VITROPhagocytic cells exposed to silica in vitro produce PAF and LT. This response is reminiscent of phagocytic cells exposed to the calcium ionophore (A23 l 87) in the presence of ionic calcium.6-8 A23 l 87 forms a complex with free ionic calcium which passes through cellular membranes, thus transporting calcium inside the cell. The increased intracellular calcium concentration triggers the production of small amounts of prostaglandins large amounts of LT. PAF and. depending on dose cellular death (see Figure 1 ). Could silica cause LT production and cellular death by a similar mechanism? How could silica - an inert solid - act in a similar fashion as a soluble stimulant? Clearly the negative SiO2 and OH- surface of silica can bind calcium ions9 and therefore could theoretically act as a solid-state ionophore releasing bound calcium inside of cells following phagocytosis."

Jan 1, 1998