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By Anne-Laure Bonnet

Les connaissances acquises au cours des dernières décennies sur les gîtes de métaux de base et précieux intensément métamorphisés (p. ex. Vokes, 1991; Cornell et al., 1992; Zaleski et Peterson, 1995) ont permis d?élaborer des guides d?exploration pour de tels gisements dans les terrains de haut-grade métamorphique (Spry et Scott, 1986; Rubin et al., 1993; Hand et al., 1994; Spry, 2000; Spry et al., 2000). Un transfert de ces connaissances à la cartographie des vastes terrains gneissiques non différentiés de la province de Grenville permet d?affiner l?approche cartographique nécessaire pour reconnaître les systèmes hydrothermaux métamorphisés en terrains vierges et peu diagnostiques puis d?en discriminer les divers halos d?altération (Corriveau et al.,1996, 1997, 1998, 2003; Williamson et al., ce volume). Cette approche prend en compte les « empreintes métamorphiques » observées sur le terrain, telles que les variations des assemblages minéralogiques, du mode et de la composition des minéraux métamorphiques, pour reconnaître des roches présentant une composition inhabituelle caractéristiques de protolites altérés par hydrothermalisme. Ces empreintes citées cidessus sont facilement reconnaissables dans les terrains de haut-grade où la recristallisation induit un grossissement des grains qui permet de déterminer la nature et le mode des minéraux dès les levés de terrain. Cette approche raffine la compréhension des terrains de haut-grade métamorphique et illustre que leur complexité (i.e. polyphasage de la déformation et du métamorphisme) n?est pas forcément une limite à leur exploration. Elle a donc été utilisée systématiquement lors des levés de terrain réalisés dans le cadre d?un projet de l?Initiative géoscientifique ciblée de RNCan. La zone cartographiée se situe le long de la marge sudest du Groupe de Wakeham dans le secteur est de la Province de Grenville. Deux régions ont été plus particulièrement étudiées, celle du lac Musquaro (SNRC 12K10, 11 et 14) et la région côtière comprise entre Kégashka, La Romaine et Baie des Loups (SNRC 12K1, 2, 3 et 7) (fig. 1).

May 1, 2003

By Sammy Bansah, Komla Dzigbodi-Adjimah

Abstract-Ghana, a major West African gold-producing country, took a crucial step in 1986 to allow private participation in mining ventures that had hitherto been state controlled and starved of funds. This decision has led to a three-fold rise in gold production with substantial local and foreign capital once again flowing into exploration and mining projects. Though the rise in gold export is due primarily to increased production from large mines such as Ashanti Goldfields Corporation, Billiton Bogosu Gold, Tebrebie Goldfields and Ghana Australia Gold that work primary lode gold deposits on quartz veins and Banket conglomerates, a fair amount of gold comes from placer gold mining from which two new mines have been developed at Kwabeng and Bonte during the current gold boom. Also, placer gold mining is important locally because the lower capital outlay required for its development enables many entrepreneurs to operate small concessions and provide employment for a large pool of unskilled labor. Placer gold exploration and development in Ghana is labor-intensive. Pitting is the most used method although few employ the mechanized ("Banka") drilling. The advantages and disadvantages of the two approaches in the local setting are discussed. The gravel is normally sluiced and the gold recovered by amalgamation. The drawbacks to successful placer gold exploration in Ghana have been attributed to lapses in execution of exploration programs (Dzigbodi- Adjimah and Arhin, 1993; Dzigbodi-Adjimah and Gawu, 1994). However, the failure to recognize and set time frameworks and financial limitations for the various stages of placer gold exploration have spelt the doom of some projects. It is critical that the characteristics of the placer gold deposit be determined by efficient and cost effective means. A planned exploration supported by adequate flow of funds saves costs and leads to success. This article discusses the current Ghanaian situation and presents proposals from case studies for planning and budgeting placer gold exploration programs for use in similar settings.

Jan 1, 1995

By Sammy Bansah, Komla Dzigbodi-Adjimah

Ghana, a major West African gold-producing country, took a crucial step in 1986 to allow private participation in mining ventures that had hitherto been state controlled and starved of funds. This decision has led to a three-fold rise in gold production with substantial local and foreign capital once again flowing into exploration and mining projects. Though the rise in gold export is due primarily to increased production from large mines such as Ashanti Goldfields Corporation, Billiton Bogosu Gold, Tebrebie Goldfields and Ghana Australia Gold that work primary lode gold deposits on quartz veins and Banket conglomerates, a fair amount of gold comes from placer gold mining from which two new mines have been developed at Kwabeng and Bonte during the current gold boom. Also, placer gold mining is important locally because the lower capital outlay required for its development enables many entrepreneurs to operate small concessions and provide employment for a large pool of unskilled labor. Placer gold exploration and development in Ghana is labor-intensive. Pitting is the most used method although few employ the mechanized (“Banka”) drilling. The advantages and disadvantages of the two approaches in the local setting are discussed. The gravel is normally sluiced and the gold recovered by amalgamation. The drawbacks to successful placer gold exploration in Ghana have been attributed to lapses in execution of exploration programs (Dzigbodi-Adjimah and Arhin, 1993; Dzigbodi-Adjimah and Gawu, 1994). However, the failure to recognize and set time frameworks and financial limitations for the various stages of placer gold exploration have spelt the doom of some projects. It is critical that the characteristics of the placer gold deposit be determined by efficient and cost effective means. A planned exploration supported by adequate flow of funds saves costs and leads to success. This article discusses the current Ghanaian situation and presents proposals from case studies for planning and budgeting placer gold exploration pro-grams for use in similar settings.

Jan 1, 1995

By M. Leroux, C. J. Martin, S. R. Rao, J. A. Finch

"The effect of nitrogen on the flotation separation of sulphides from complex ores from Brunswick Mining and Smelting (New Brunswick) and Mattabi Mines (Ontario) was investigated. The most significant finding was enhanced pyrite floatability after as little as 3 minutes nitrogen conditioning. This was used in a novel sphalerite/pyrite separation process developed on the Brunswick ore. After aeration and Cu/Pb bulk flotation in air using xanthate the slurry was nitrogen conditioned, xanthate added and the pyrite floated in nitrogen. As an example up to 70% pyrite recovery with about 20% sphalerite recovery was achieved. Sphalerite was recovered from the pyrite tailings and the pyrite concentrate by copper-activation, raising the pH to 10 and floating in air. About 65-70% recovery at 35-40% Zn grade was achieved compared to 25% Zn grade by the conventional route. The process offers a promising alternative to current practice which seeks to depress pyrite at all stages. A possible mechanism of the effect of nitrogen is presented. INTRODUCTIONUse of gases other than air in froth flotation has been reported from time to time. [Podobnik and Shirley, 1982; Lin and Metzer, 1975]. Of all the gases, nitrogen would appear to hold the greatest practical promise because of its easy availability and chemical inertness. It is used in froth flotation in chalcopyrite-molybdenite separation [Redfearn, 1983]. The use of nitrogen in polysulphide chalcopyrite. this case is mainly to reduce the oxidation of a compound (Nokes reagent) used as a depressant for There is no reported use of nitrogen in the flotation of other sulphide minerals."

Jan 1, 1988

By M. H. Ali

Codelco, a multi-process primary copper producer, is undertaking a full life cycle inventory (LCI) of all its commercial products based on copper and molybdenum. During this work, many questions have surfaced regarding the contribution of process unit design to specific aspects of a product's LCI and, more importantly, how such designs could be improved using a life cycle perspective. Management strategy efforts were undertaken to improve the LCI footprint, however it was found that the corrective actions were almost impossible to apply at the operation level in plant, given the ongoing timing pressures of extractive mining, and costs saving priorities. Additionally, it was found that most of the important comparative differences between operations had structural reasons. In this circumstance, the LCI practitioner group from 1M2, and the environmental managers from Codelco, decided to shift its efforts to place the critical LC1 aspects to the design process of future developments. Hatch Associates has developed unique tools in their Sustainable Plant Design (SPD) package that compliment and enhance LCA methods; these effectively drive sustainability into the heart of the design process. By using LCA and SPD in a project design phase, you cannot only address potential hotspots, but also decide on materials, location and size of certain facilities to optimize for energy efficiency. Moreover, you can avoid the shifting of environmental burdens upstream or downstream within the plant and finally it is extremely useful in identifying opportunities for greenhouse gas reduction.

Jan 1, 2007

By S. Kapusniak

Specialist Machine Developments (SMD) is a design and manufacturing company involved in the design of Remotely Operated Vehicles (ROV?s), ploughs, trenchers and mining machines for use in submerged environments. Established in 1971, the company has made over 500 vehicles for subsea use. These range in size from small remotely operated swimming vehicles with a weight of less than a tonne to heavy duty seabed crawling machines with a weight of up to 310 tonnes (in air). Primarily, these machines have been designed for offshore vessel-based applications, but the machines are equally suited to other submerged mining applications onshore. Many onshore deposits can technically and theoretically be mined using currently available submerged mining ROV technology. Similar equipment to that in use subsea could easily be fast-tracked into use to extend the life of opencast mines facing severe hydrological problems. It could also easily be used to mine vertical ore-bodies where the stripping ratio has become uneconomical due to increasing depth. In some cases mining ROVs could even be suitable for use as the primary extraction method for a new mine. Exploration and extraction techniques used in oil and gas gradually developed and moved from land to offshore in the middle of the last century. Are we about to witness a similar shift with other minerals? This paper describes the design concepts of submerged mining equipment, targetted subsea mineral deposits, the suitability of submerged mining ROVs for onshore deposits, limits to their application and parallel research and development activities which will help to accelerate the use of such equipment in the emerging submerged mining sector.

Aug 1, 2013

By Song (Bruce) Li

This paper presents a three-tier web-based GIS application that uses Java Server Page (JSP), Java Servlet and relational database to manage performance monitoring and reporting in the oil sands mining industry. It is a real-time Earth Structure Performance Monitoring System (ESPMS), which allows the user to record and store instrumentation monitoring readings as well as technical observations and instrumentation installation documentations into a complete relational database. The ESPMS introduces the advantages of precise field record keeping, due diligence, security, consistency and completeness while at the same time simplifying the task of reporting. ESPMS combines web-based Geographic Information System (GIS) mapping and data management to facilitate the collection, organization, retrieval, reporting and communication of the vast amounts of monitoring data related to mining and tailings engineering associated with site investigation and construction information. ESPMS utilizes web-based GIS technology to incorporate referenced aerial photographs, Energy, Mines and Resources (EMR) maps or AutoCAD drawings as a base map for the monitoring site. It dynamically creates and administers all instrumentation monitoring locations and reading frequencies. It enables the user to collect and manage the data associated with an unlimited number of reading events. It provides the designer with real-time monitoring data (what, why, when, how), thereby allowing them to make early adjustments to design protocols or procedures, or to take remedial action(s) regarding the subject earth structure under construction or after completion. It provides more cost-effective reporting and data sharing through the Internet. It improves security on data entry and eliminates unauthorized data changes. It allows better integration of graphics and illustrations with numerical data files. It is capable of managing the continually expanding workload resulting from new and larger structures in the oil sands or other mineral mining industries. The ESPMS facilitates easier data gathering for preparation of as-built and after-built or regulatory reports, etc. It enables quick location of the interested instruments and summarization of the performance of the instruments. It enables one to visualize performance data and QA/QC construction test results spatially on any given cross-section. Data can be exported to MS Excel for detailed analysis and to evaluate the stability of the earth structures.

May 1, 2004

By D. C. Fraser

"Geophysical Engineering and Surveys Limited of the Keevil Mining Group have routinely conducted ground surveys with VLF-EM receivers for the past two years. Both Crone's Radem and Ronka's EM16 have been used.VLF-EM dip-angle data often yield complex patterns which require considerable study for a proper interpretation. A method was developed which allows field operators to transform the noncontourable dip angles into contourable data, producing conductor patterns which are immediately apparent to exploration personnel untrained in VLF-EM interpretation.VLF-EM contoured data generally peak very close to the top of a conductor, thereby allowing drill holes to be spotted accurately. However, the data generally should not be used alone to select drill targets because structures may be sufficiently conductive to yield strong anomalies. Thus, magnetic and/or vertical-loop EM correlations may be considered as necessary criteria for drilling.VLF-EM surveys can replace IP surveys in certain environments. For example, the Restigouche orebody in the Bathurst camp of New Brunswick yielded a VLF-EM anomaly as distinct as that obtained by IP, although the body did not respond to vertical-or horizontal-loop EM. However, the cupriferous breccia pipes of the Triba mine near Batchawana, Ontario yield strong IP anomalies but not VLF-EM anomalies, illustrating that disseminated ore targets should be sought with IP rather than with VLF-EM."

Jan 1, 1971

By E. McLaren, J. Sanftenberg, C. Cameron, H. Dello Sbarba

"A Ventilation on Demand (VOD) system has been optimized and maintained at Glencore’s Nickel Rim South Mine (NRS) in Sudbury, Ontario, Canada for the past seven years. The system monitors and controls air quality and quantity through real-time, dynamic automation of primary fans, secondary fans, automated airflow regulators, and air monitoring instrumentation with VentSim™ CONTROL, a VOD software. This paper will focus on the implementation of testing procedures and system maintenance methods. Overall, the results show a consistent reduction in energy usage.INTRODUCTIONThe Ventilation on Demand (VOD) system at Glencore’s Nickel Rim South (NRS) mine in Sudbury, Ontario, Canada, involves the control of two 2,980 kW centrifugal surface exhaust fans with Variable Frequency Drives (VFDs), three 335 kW vane-axial surface intake fans with VFDs, 21 automated airflow regulators, six automated dampers, seven automatic doors and 198 underground auxiliary fans with ON/OFF starters. Additionally, the system monitors airflow at 48 locations, carbon monoxide (CO) at 40 locations, nitrogen dioxide (NO2) at 21 locations, and dry bulb and wet bulb temperature at 21 locations. The VOD system is also integrated with a tagging and tracking system to modulate the ventilation system automatically and in real time according to the presence and position of the personnel and vehicles. The tracking system comprises of 75 vehicle tags with diesel status and hydraulic status (ON or OFF), 440 personnel tags, and 200 tracking zones. Finally, it also involves the configuration and updating of 55 level plan and interactive procedures and 24 daily scheduled events. NRS currently uses VentSim™ CONTROL, Ekahau Tracking and PI Datalink to control, monitor, and configure their VOD system."

Jan 1, 2019

Agenda ? Introduction ? Inmet?s Operations and Closed Properties ? Inmet?s SECA Philosophy ? Inmet?s SECA Framework ? The Business Case for TSM ? Inmet?s TSM Reporting ? Inmet?s 2004 TSM Performance ? Opportunities for Improvement ? What Have We Learned From The TSM Process So Far? ? Summary Introduction ? Inmet has evolved into a strong TSM supporter ? Inmet is confident that TSM can be successfully and cost effectively implemented by smaller companies ? Inmet?s reporting on economic, environmental and social performance was raised significantly in our 2003 Annual Report ? a signal our commitment to good performance and improvement in these areas ? Our 2004 Annual Report has been further enhanced with the inclusion of our TSM performance

Apr 1, 2005

By J. A. Russell

MR. M. W. Boom: I would like to congratulate Mr. Russell on his fine paper. One very good point which has always appealed to me is the smooth working of a steam hoist as compared with electrical. He does not mention the steam hoist at Springhill which has been working there for a good many years. MR. S. R. NEWTON: I have read with a great deal of interest the paper presented by Mr. Russell on the development of haulage engines in the mines of the Dominion Steel & Coal Corporation. He is to be congratulated on having produced a comprehensive article showing, step by step, the various improvements that have been made over the years in the design of such engines. I am quite in accord with Mr. Russell's statement that the positive tooth clutch can have too many teeth, and also that the method of driving a sliding clutch hub of any design should be by means of a hexagon or octagon on the shaft. Where the clutch hub does not of necessity slide on the shaft it can be pressed on and keyed to the shaft in the normal manner. With regard to the 'Cramp' internal-expanding jaw-type clutch, while it is true there are more moving parts than with the clutch consisting of a ring with internal cut teeth and a driver having a fewer number of teeth as .described by Mr. Russell; there are compensating advantages to the internal expanding jaw-type of clutch. The V shaped profile of the teeth permits of engagement of the clutch with very much less 'jockeying' of the drum. This is particularly the case in vertical-lift mine hoists, where it may be necessary to engage and disengage the clutching mechanism at frequent intervals.

Jan 1, 1944

By D. MacGREGOR, VERA TUREK

The St. Canul and Ste. Scholastique orthoquartzite sanrjstone deposits are located within the Potsdam Formation near Montreal. The sandstone lies on Precambrian basement and is Cam/3rian to Ordovician in age. The Potsdam Formation shows two distinct stages of development. One created a deepwater facies represented by impure, limey or shaley sandstone; the other produced a shallow facies composed of grey, highpurity sandstone. The shallow-water orthoquartzitic sandstone at St. Canul is being mined and beneficiated by lndusmin Limited. The operation manufactures a wide range of silica products and supplies industrial areas of Quebec and Ontario with material for the glass, foundry, silicon carbide and ceramic industries.

Jan 1, 1984

By Irvine J. Berscheid

This paper describes a rock drill bit which, although conventional in the processes of manufacture and use on the job, has incorporated into the outer wall or periphery of the insert, where wear is always the greatest, a variable amount of extra metal, distributed in units of height of insert to withstand this excessive wear. Explained are variations of construction, how the extra metal enables the bit to drill more footage, prevent antitaper and the need to gauge grind, increase penetration rate and the length of run per regrind, reduce shank breakage and ma-chine costs, and permit increased production per man-shift, without requiring any change in equipment already on the job. F OR purposes of clarity, reference to bits here means integral rods or multi-winged bits which have their inserts sharpened to a conventional shape. When dull, the insert has worn, on its face, a flat which increases in width as we progress from near the center of the bit toward the outer edge. Very

Jan 1, 1965

A series of small scale tests have been conducted to evaluate the effect of micro-fracture development, imposed by blasting, on the material properties of the rock as well as its resistance to crushing and grinding. The uniaxial compressive strength, tensile strength, Poisson?s ratio, P-wave, Swave velocity, point load test index, crushing and grinding work indices were evaluated for samples without any blasting load and for samples which had received a variety of blast loads ranging from a single impact with low strength detonating cord, to combination of impacts at different times and significant impacts with powder factors close to those used in practical blasts. It was shown that the rock mechanics parameters change even at low impacts, suggesting easier crushing of the rock. Damage values appear to be affected by timing as stress wave superposition affects the damage process. Fragmentation is achieved at higher impact levels while work index modification of the fragments is also observed when high powder factors are used, suggesting improvements in grinding.

May 1, 2003

By Tom Shumka

All mineral processing facilities that use girth gear driven mills need to inspect the gear teeth on a routine basis, whether it is every six months or every three years. The inspection frequency depends upon gear tooth condition, and the objective is to ensure operational integrity of the gear teeth. Conventional methods such as magnetic particle testing, visual inspection, or dye penetrant examinations rely heavily on interpretation. At best, these techniques can determine whether a defect exists, but are unable to provide information on defect severity. This paper describes the use of combined Eddy Current Array (ECA) and Alternating Current Field Measurement (ACFM) to provide a complete survey of all surface breaking indications on the whole gear tooth depth. This method accurately determines the size, length and depth of any cracks found on the surface.

Jan 1, 2012

By D. B. Nazzer

"ANY DISCUSSION of energy today is incomplete without consideration of nuclear energy. In the Maritimes, with plentiful supplies of coal, with relatively easy availabilty of imported oil brought in to the deepwater terminals, with future sources of large supplies of oil and gas anticipated from under our neighbouring continental shelf, and with the Fundy tides, you may question why nuclear energy should be considered. What follows may not give you a specific answer to that question, but it may provide a basis for better understanding. Energy from the sun, from hydraulic sources and from combustion has been available to man from prehistoric times, for thousands of years, but the most sophisticated source of energy, the actual conversion of matter into energy by man, has been developed entirely within the last one-third century, since the discovery of fission in 1939, and the application to generation of electric power has all been done within a generation or less. The pressure of military needs during and after the second world war was largely responsible for the speed of initial development, by funding and focussing the effort needed to develop the basic technology, and in particular materials. The U.S. defence program yielded, for example, the large-scale isotope separation processes for fissile U'35 and for heavy water. The nuclear submarine program yielded zircaloy, a key structural material for the core of the Canadian Candu type reactor."

Jan 1, 1972

"In conjunction with Banick Mercur , Wright Engineers Limited designed the first multi-stage aqueous pressure oxidation system in an alkaline environment in North America. A three-stage slurry heating and slurry pressure let-down with heat recovery was an innovative approach to the problem of high energy cost with the low sulphur content of the ore. The design of this system required solving a number of problems associated with heating and pumping of slurries at pressures up to 3230 kPa and temperatures in excess of 220°C. Wright received an Award of Merit in October 1989, from the Canadian Consulting Engineering Awards Committee in the Process Category for its design of the Mercur pressure oxidation system.The Mercur Mine is located at the south end of the Oquirrh Mountains in Tooele County about 65 miles by road from Salt Lake City, Utah, U.S.A. The original mill was designed to process 5000 tpd of oxidized gold ore in a carbon-in-leach (CIL) circuit. A new ore treatment system was required to treat the substantial quantities of refractory ore reserves which could not be treated economically in the existing mill. The new pressure oxidation circuit makes the refractory ore amenable to gold recovery by oxidation of the sulphides contained in the ore .Wright Engineers Limited was commissioned by Barrick Mercur Gold Mine Ltd ., a wholly-owned subsidiary of American Barrick Resources, to design the pressure oxidation facility. This followed completion of a feasibility study by Wright which showed that the project was technically and economically viable.Work on the feasibility study began in 1986, detail design commenced in February 1987, and was completed in December 1987. Mechanical installation was completed in January 1988, and slurry feed began in February 1988. The plant has operated since June 1988 without major interruption . Wright was responsible for engineering, procurement and construction management for the addition of the 750 tpd pressure oxidation circuit to the existing mill and also had commissioning responsibility.Major unit processes involved in the pressure oxidation facility are ore thickening, three-stage slurry preheating, pressure oxidation and three-stage slurry cooling with heat recovery, stearn generation, propane and oxygen storage and a video graphic display process control system were included in the scope as process anciliaries.The pressure oxidation increases gold recovery from the refractory ore by conventional CIL from as low as 35% to more than 86070. A patent has been granted for the process."

Jan 1, 1989

By Thomas E. Shumka

ASTM E2905 describes a two-part standard for electromagnetic methods for preparation and examination of ring gear teeth in the mining sector for SAG and Ball Mill ring gear drives, including pinions? particularly on the addendum, dedendum, and root areas. This practice addresses the need to detect surface breaking flaws electronically and to have the ability to accurately size any surface breaking cracks found on cast and forged SAG and ball mill ring gear and pinion teeth faster and more effectively than other methods. Eddy-current surface arrays are seeing increasing use throughout the industry for the detection of surface breaking flaws in conducting materials. Example applications include examinations of pipelines, bridges, engines, aerospace structures, and any conducting material for surface breaking flaws including cracks. In addition, model-based methods are being used to size cracks accurately found in the addendum, dedendum, and the root of SAG and ball mill girth gear teeth. As visual interpretation of a surface breaking discontinuity on gear teeth is the normal analysis, the colors and 3D images that are provided with this technique, help with visualization and therefore are absolutely invaluable in such circumstances. This practice will help to standardize the use of this nondestructive testing approach.

May 1, 2013

By T Nakamura, M. Itoh

Most of the used cathode ray tube (CRT) glass in Japan, which contains lead oxide, was exported and recycled in overseas factories of new CRTs. However, domestic treatment and recycling of waste CRT glass has become necessary because overseas CRT factories have shut down and exports of CRT glass have stopped. Some of the waste CRT glass recycled domestically is charged in lead blast furnaces instead of silica flux, because there is no local reproduction route for glass that contains lead. However, the mass of CRT glass that can be treated in this manner is limited because of its high silica content. Consequently, additional treatment methods for waste CRT glass are required so that more can be used as a lead smelting material. In this study, waste CRT glass was treated with hydrofluoric acid to dissolve the silica contained in the glass, and the dissolved lead was recovered by precipitation. Lead metal was recovered by electrodeposition from the prepared hexafluorosilicic acid solution.

Jan 1, 2011

By S. Jordanov

The nature of processes that take place on top of copper bearing grains during the suppression of copper acid drainage from mine tailings was studied on a grain model. Cyclic voltammetry (C.V.) was employed as an experimental technique suitable for indirect measuring of copper leaching. Experiments were done in sulfuric acid (pH=2) at electrodes that progressively approach the real situation during acid main drainage, starting with Cu-metal, then with CuO and finally with CuO covered with CaSO4. Oxidation was found to be the only process that takes place on metallic copper electrode anodically polarized up to 2 V vs. Cu/CuSO4 reference electrode. Dissolution is intensive and reaches up to 50 mA.cm-2. When the same was repeated, but on CuO electrode, anodic currents were some 4 times lower than on the bare metallic surface. This indicates that the electrode material is not completely oxidized to copper(II)oxide and the Cu(O) or Cu(I) residues are oxidized during the anodic polarization. This explains the diminished dissolution. Dissolution is further restricted at electrodes covered with CaSO4. It is some 20 times lower than on the bare oxide electrode. When the second layer of CaSO4 was applied, anodic currents were another 15 times lower. Total decrease of anodic currents when transition is made from Cu-metal to CuO covered with 2 layers of CaSO4 reaches up to 7.500 times. C.V. measurements produced a proof that mechanical blockage is the way how lime prevents leaching of copper bearing grains in immobilization experiments referred elsewhere.

Jan 1, 2007