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By A. R. Farkoosh

Al-Si based alloys have been recently used by automotive industry for highly stressed engine applications. Due to severe working conditions of the engine parts, existing alloys hardly endure high pressures at high temperatures. This necessitates alloy modifications to enhance the elevated temperature performance. In this study, the effects of trace nickel additions on the microstructural and mechanical properties of A356+0.5Cu alloy have been investigated at different aging conditions. Electron probe microanalysis (EPMA), scanning electron microscopy (SEM) and X-ray diffraction (XRD) are used to study the microstructural changes. Aging curves have been obtained by hardness measurement. It was seen that the presence of additional nickel introduced many complex intermetallic phases within the microstructure which led to improved high temperature mechanical and aging response.

Jan 1, 2011

By J. Font

The RAF or copper fire refining process at the Caletones smelter of CodelcoChile consists of several pyrorefining stages that successively lowers the levels of S, Fe, Pb, As, Sb, Te, Se and to some extent 0 in the copper melt, allowing the production of high quality fire-refined copper of 99.93 % purity (RAF copper). This chemical feature of the RAF copper is only achieved by quite long processing times, and a considerable consumption of fluxes and fuels in the RAF vessels. The main goal of this study was to improve the RAF process performance by thermodynamic considerations and industrial scale tests, i.e., an in situ approach for the process as featured by intensive sampling, characterization and subsequent modifications. Thus, both theoretical and industrial data were derived, and based on kinetic and thermodynamic evaluations, a higher operational standard was achieved for the RAF process. These new operational practices allowed enhancing the overall economic of the RAF process, by reducing the time and operational costs, and consequently increasing the availability of the vessels.

Jan 1, 2007

By R. Salimi

Tricalcium aluminate hexahydrate (TCA) is used as filter-aid for security filtration in the Bayer alumina process. TCA is typically produced on-site by mixing Bayer liquor with slaked lime. Specific properties are required from the TCA to ensure adequate filter throughput, lifetime and importantly effective reduction of solid/colloidal impurities from the solution. The effect of reaction time on morphology and particle size distribution of tricalcium aluminate was studied for a batch experiment at simulated process conditions. It was found that reaction time plays a critical role on the morphology, crystal structure (diameter and crystallinity) and particle size distribution. In the early stages of the reaction, nucleation dominates the crystallization process followed by growth dominated by agglomeration up to a mean particle size of 10 µm. The particle morphology shifted from an irregular shape to more spherical throughout the course of the reaction.

Jan 1, 2014

By N. Erarslan, M. Serati

"This paper attempts to provide a simple analytical solution for the calculation of the stress tensor induced in a two-dimensional elastic ring of a brittle material subjected to general loading on either its internal or external curved surfaces. Airy stress functions and Michell’s expression in polar coordinates are used, and parametric studies are performed to investigate the influence of loading angle and the geometrical aspect ratio of the ring on the maximum induced tensile stress. INTRODUCTIONA proper and accurate estimation of the tensile strength of a given material is a crucial step in many engineering projects; in particular in rock cutting, since rocks are much weaker in tension than in compression or shear. Both direct and indirect laboratory techniques such as the direct uniaxial pulling test, the Brazilian indirect tensile test (also known as the split cylinder test), and the ring test have been proposed and developed to estimate rock tensile strength. Among these, the ring test, initially suggested by Ripperger and Davids (1946), has become particularly appealing for its ease of sample preparation and its unique breakage mechanism in almost a pure tensile mode. Unlike the Brazilian test in which high shear stresses developed in the vicinity of the contact could interfere with the tensile breakage of the disc specimen, a tensile failure starts away from the loading platens in a ring test (Hobbs, 1964)."

Jan 1, 2015

By M. Al Mukhtar, D. Hoxha, X. Brunetaud, D. P. Do, C. Auvray, L. Michel

"Mechanical behavior of rock joints is often the key factor governing the response of complex structures constructed in fractured rock masses such as underground openings or of objects assembling various stones blocks such as historical building walls or damaged marble statues. This paper aims at developing a theoretical model to describe the behavior of fresh joints based on the description of their morphology. The main idea of the model is to establish a link between the effective contact surface of joints and the frictional coefficient. Beginning from a chosen level of joint surface description where a joint is considered as “smooth”, the model describes the added friction with respect to the increase of the contact surface of the joints and the distribution of stress in these contacts. The model developed initially for asperities with regular geometry is firstly compared with existing models and then applied on fresh artificial joints. For that, healthy artificial joints have been characterised using in one hand classical CNL shearing tests and in another hand the morphology of joints. The joints surfaces are digitized before testing using a high resolution laser scanner (Konica Minelota Vivid 910) allowing to obtain a precision up to 10µm. From these scanned surfaces the morphology of joints is characterised on the profiles running in the direction of shearing and a mean value of friction is calculated using the developed model. This calculated value is then compared with that obtained from CNL shearing test and a good approximation is notedINTRODUCTIONThe role of the mechanical behavior of rock joints on the overall response of fractured rock masses is well established in many fields of engineering activity going from the stability of underground constructions (Souley M, Hoxha D, Homand F 1999), rock slope stability (Einstein H.H. Veneziano D., Baecher GB., O’Reilly K.J, 1983, Jaeger 1971), various rehabilitation of masonry construction, damaged stone artworks restoration (Michel L., Do D.P, Coignard B, Hoxha, 2014) and so on. In the same time the characterisation of the behavior of joints and their modeling is nowadays a dynamic field of research or/and investigations and many alternative approaches have been proposed (Barton, N.R. and Choubey, V. 1977, Tatone, S.A. Bryan, Grasselli Giovanni 2010, William C E. 2007). While empirical relations of shear strength with various parameters of the joint morphology are the most used in practice because of their simplicity (Barton. and Choubey, 1977, Barton 1973, Bandis S., Lumsden A. C. and Barton N. R. 1983) many other models of joint strength are developed based on mechanistic considerations (Haberfield CM, Johnston IW. 1994), multiscale approaches (Yang Z.Y., Di C.C., Yen K.C. 2001, Fardin N., O. Stephansson, Lanru Jing 2001) or micromechanical ones (A. Serrano, C. Olalla, R.A. Galindo 2014) to mention just a few of research trends on rock joints modeling."

Jan 1, 2015

By A. Mortazavi, H. Nasab

"The storage of petroleum products on surface is associated with difficulties and limitations. Accordingly, a viable alternative is to excavate underground space in rock and provide a safe way for oil storage. Soft rocks such as salt domes provide good conditions from environmental and operational points of view. The potential for high-volume storage and low permeability are encouraging aspects for oil storage in salt domes. The complicated shape of oil storage caverns, the complicated behavior of salt rocks, and boundary conditions associated with large underground openings are important challenges in the design of oil storage caverns. The aim of this paper is to delve into the stability and deformation mechanisms of storage caverns created in salt domes. A parametric study of effect of the cavern size, orientation, and depth is carried out as a function of ground stress regime. The stress field and deformation mechanisms are calculated for each case aiming at providing design guideline.INTRODUCTIONOne of the most popular soft rock that is used for underground oil storage is salt rock (halite). Salt rock has particular characteristics which makes it suitable for oil storage. Salt rock has several advantages for oil storage, these are: high production rate, high degree of availability, short filling period, high level of safety and low permeability [1]. The low permeability is due to the fact that halite deforms in a plastic manner over a wide range of pressures, temperatures and rates of deformations. This property prevents joints or gaps opening up in the formation, thus preventing the escape of liquids and gases. The state of stresses around the cavern in salt domes depends on the depth of the cavern (initial stresses and rock mass temperatures are increasing with depth), the in-situ stress state within the rock mass, and the internal oil pressure in the cavern. Furthermore, the salt creep behavior and the cavern geometry are influencing stress redistributions during loading and unloading phases.Rock mass structure, cavern geometry, material behavior and cavern operation patterns require complex physical models to describe the load-bearing behavior of the geomechanical structure. The determination of stress, strain and deformation in the rock mass due to cavern construction and operation are complex problems which can be evaluated employing numerical tools such as the Finite Element Method (FEM) or Finite Difference Method (FDM). In this study, the finite difference method was used to evaluate the behavior of oil storage cavern in salt rock."

Jan 1, 2015

By O. Espinoza Ortega, S. Song

A process scheme has been devised to improve the silver recovery and the grade of concentrates from the scavenger concentrate of a silver ore flotation circuit. Based on modal analysis studies it was found that silver sulfide minerals in the scavenger concentrate were associated as simple binary particles and finely disseminated in sulfide and non-sulfide gangues. Fine grinding of the concentrate improved the grade-recovery curve of silver to a very limited extent owing to heterocoagulation between liberated fine silver sulfides and coarse particles of gangue. This heterocoagulation phenomenon was prevented by grinding the concentrate in the presence of the dispersing reagent sodium hexametaphosphate. The silver grade-recovery curve was improved by practicing. before the conventional flotation step, a selective aggregation step for the fine silver sulfide particles using the non-polar oil kerosene, the sulthydryl collector Aerophine 3418 and conditioning the pulp under strong agitation conditions.

Jan 1, 2004

By Erik Q. Dahl

The strength of green and sintered pellets during reduction under various conditions in a laboratory kiln has been investigated. Equipment and test methods are described, together with the results obtained. The strength of sintered pellets drops sharply when the reduction starts, and goes through a minimum at the 70 per cent oxidation level. At more advanced reduction, the strength increases with increasing metallization. Successful use of green pellets as kiln feed requires that more attention be paid to the pellet preparation than is necessary when producing pellets for separate sintering. In particular, the ores have to be ground to a greater fineness. The initial strength of green pellets is low. Below the 70 per cent oxidation level, however, the strength of these pellets is about the same as the strength of sintered ones. Additions of such materials as silica, limestone and anthracite coal; within reasonable limits, affect the strength only slightly.

Jan 1, 1966

By A. Zhecheva

A commercial titanium alloy Ti-6Al-2Sn-4Zr-2Mo has been gas nitrided in this work, in pure nitrogen atmosphere in order to improve its surface properties. The nitriding was performed at two different temperatures, 950 and 1050°C, and for different periods of time. The influence of the initial surface roughness on the diffusion process and on the surface properties of this material was studied. The influence of the processing parameters of gas nitriding on the surface roughness, phase modifications and the microstructure of the nitrided layers has been analyzed using atomic force microscopy (AFM), X-ray diffraction and optical microscopy. Microhardness profiles were obtained on cross-sections of the samples after gas nitriding applying a Knoop indenter.

Jan 1, 2004

By J. P. Jylhä, A. Jokilaakso

The Outotec Flash Smelting process is widely used in primary copper production. A layer of slag on top of matte (copper–iron sulphide melt) creates a barrier through which matte droplets descend. Droplets of different sizes settle through the layer at different rates, which increases possibility of copper losses as smaller matte droplets may be removed with the slag. In this work CFD-DEM (computational fluid dynamics – discrete element method) coupling was used to simulate matte droplets settling through the slag during slag tapping. Discrete droplets and slag flow were simulated with DEM and CFD, respectively. This new approach enables tracking and solving movement and interactions of individual droplets. User-defined models were created to take coalescence and reaction kinetics into account. Coalescence created larger droplets, while the reactions decreased droplet size and increased its density. Drag caused funnelling effect, which pulled droplets towards the centre line of the descending cluster. This research is the only study known by the present authors in modelling liquid-liquid systems with the CFD-DEM coupling. Simulating coalescence and chemical reactions for discrete droplets enables more realistic simulations. However, CFD- DEM simulations are computationally resource intensive already without additional models, so a full scale industrial settler modelling still waits for further increase in computer performance. INTRODUCTION Flash smelting is a method used in copper and nickel production. In the flash smelting process, oxidation of sulphides in a concentrate is used to release energy needed to smelt the feed. In the process, copper matte is formed. Matte has copper content in the range of 55 – 70% (Sridhar, Toguri, & Simeonov, 1997), the rest is mainly sulphur and iron but has still many other impurities (Taskinen, Seppälä, Laulumaa, & Poijärvi, 2001). Oxidized iron forms iron-silicate slag while SO2 is collected for acid production (Davenport & Partelpoeg, 2015). The Outotec flash smelting furnace (FSF) can be divided in four major component: concentrate burner, reaction shaft, settler and uptake. Concentrate, flux and oxygen enriched air are injected into the reactor through the concentrate burner. The mixture then reacts in the reaction shaft forming matte and slag, which are collected in the settler, while off-gases flow out of the reactor through uptake for heat and dust recovery, and SO2 collection for H2SO4 production. The matte and slag form separate layers due to immiscibility and density difference. Raw material feed is continuous, but the matte and the slag are tapped periodically. A flash smelting furnace is depicted in Figure 1.

Jan 1, 2019

By D. Satish Kumar, D. Mazumdar

"95% bulk mixing times in three different size water model ladles of a 140 T cylindrical shaped , dual plug ( located diametrically opposite at mid bath radius position) stirred, industrial ladle were determined experimentally with and without an upper buoyant phase. Based on dimensional analysis and a regression of the experimental data and, it was shown that in the inertial and gravitational force dominated flow regimes, 95% bulk mixing times for a slag-less situation can be described via:[equation]Parallel to this, a large number of experiments were also carried out in one of the water models (D=0.30m) to quantify the influence of an upper buoyant phase on mixing. These indicated that mixing time, operating variables and thermo-physical properties of the upper phase liquid can be correlated via a dimensionless relationship of the type:[equation]in which, Q is the ambient gas flow rate, L is the depth of liquid , (AL) is the slag layer thickness and 6 and t are respectively the surface tension and viscosity of the upper phase fluid The dimensional analysis, regression of experimental data as well as the adequacy of the proposed correlations are discussed in the text."

Jan 1, 2004

By Ram Song, Yohei Harada, Shinji Kumai, Kazuho Otsuka

"Recently, vertical-type high-speed twin-roll casting (HSTRC) has been developed. The HSTRC shows extremely high cooling rates over 1,000 K/s even at the mid-thickness area. The fabricated strip has many metallurgical characteristics; super-saturation of alloying elements, fine solidified structure, and homogeneous distribution of fine constituent particles. In Al-Mn based alloys, the Mn alloying element can be supersaturated in the a-Al matrix and also form Mn-containing constituent particles during solidification. The Mn supersaturation and the distribution of primary/secondary particles in cast products affect the metallurgical behavior in the down-stream processing and can improve mechanical properties of the final products. In this study, Al-Mn based alloy strips were fabricated by HSTRC with various Mn contents. The solidified microstructure, constituent particles and its distribution, and Mn solubility were investigated in the as-cast condition. Due to the high cooling rate of HSTRC, fine constituent particles were homogeneously distributed, and coarse intermetallics were not observed. Mn solid solubility was estimated by electrical conductivity. The estimated Mn solubility was equivalent between strip surface and mid-thickness area.INTRODUCTION Al-Mn based alloys, as non-heat treatable wrought aluminum alloys, are widely used in packaging and heat exchanger for automobile industry. Besides Mn, Al-Mn based alloys often contain Fe and/or Si as alloying elements or natural impurities. During solidification, Mn can be super-saturated in the Al matrix, and also form Mn-containing constituent particles. Additionally, in the subsequent thermal-mechanical processes such as homogenization, rolling, and intermediate annealing, Mn in solid solution precipitates out of the Al matrix as secondary particles. The size, distribution, type, and the amount of dispersoids including constituent particles affect to texture evolution, recrystallization behavior, and final mechanical properties of wrought Al-Mn based alloys (Huang et al., 2016; Huang & Marthinsen, 2015; Engler et al., 1995; Muggerud et al., 2013). Therefore, controlling the initial level of Mn super-saturation and the distribution of constituent particles are important in the cast Al-Mn based alloys."

Jan 1, 2018

By Robert Dickson

Princess colliery is operated by Old Sydney Collieries, Limited, a direct descendant of the General Mining Association of London, England, which, in the first quarter of the nineteenth century, pioneered in coal mining in Nova Scotia. The coal worked is a 5 ft. 6 in. seam known generally through the Sydney coalfield as the Harbour seam but referred to locally as the Sydney Main. Entry is made by shafts, 680 feet deep, sunk in 1871 on a headland forming the northern entrance to Sydney harbour. From them extend the main roadways of the colliery, a distance of 700 feet to the shore line and a further distance of 14,700 feet in submarine areas to a total length of 15,400 feet. It was the first colliery in Nova Scotia designed to work submarine areas. Lateral development extends across a frontage of 16,000 feet and the submarine area from which the coal has been extracted is slightly over 6 square miles. There yet remains sufficient territory ahead of the workings to assure a future life to this colliery estimated at over 80 years at the current rate of production. In this area the seam dips at 6 to 7 per cent and face workings have reached a depth of 1,690 feet below the sea level. Until 1923 extraction of the coal was by room-and-pillar, followed by the drawing of the pillars. At that date the superincumbent strata had reached a thickness of 1,400 feet, resulting in heavy weighting on the roof and severe side pressure on the coal ribs. In combination with a soft, heaving pavement this created a set of conditions involving great difficulties and expense in keeping open places driven in the solid sufficiently long to permit recovery of the coal in the pillars by methods and equipment then available. The operator was forced to resort to extraction by longwall as the only economical method of winning the coal.

Jan 1, 1948

By M. Medraj, M. A. Arafin, D. P. Turner, P. Bocher

In this study, the kinetics of isothermal solidification during TLP bonding of Inconel 625 and 718 superalloys with nickel based multi-component filler alloy BNi-2 have been studied through a combination of direct experimentation and mathematical modeling in order to determine the effect of process variables and, thus, to optimize the process. The predicted isothermal solidification completion times from the boron diffusion model and migrating solid/liquid interface model were in good agreement with the experimentally determined values and, they were found to be significantly less than those of other nickel superalloys with different nickel based filler alloys. Further, significant reduction of holding time was observed with increasing bonding temperature and with decreasing joint gap. No significant grain growth in the base metals has been observed in the temperature range being investigated (1325 - 1394K).

Jan 1, 2006

By J. Petit

"In July 2004 workers at the ABI Smelter in Bécancour (Quebec, Canada) went on strike. Contingency plan were ready to face the situation and plan was done to operate one potline out of three. Two lines were stopped; keeping in mind the restart on cold metal after the strike was over. The subject to be presented and shared includes a summary of work organization including training, schedule of restart, pot cleaning, pot preparation, crash start method, follow up after crash start, safety and environment. This major project has been a very big challenge. It shows that people involvement is a must and the key success. It is then true to say : ""People who believe in success will work and act in order to get there"" and ""People who don't believe in success will act in such a way to fail"" Then both will prove they were right to think their own way ! Sharing such experience can be interesting because it's a true story and people like true stories."

Jan 1, 2006

By Jan Butra

Longstanding mining of copper deposits in the Legnica-Glogow Mining Basin, Poland has accumulated broad experience concerning the impact of geological and mining conditions on seismic and rockburst hazard. Methods of rockburst prevention for deep copper mines have been developed based on gathered data. Methods of rockburst hazard evaluation and rockburst control constitute a set of rockburst prevention measures. Due to their nature and location within the production process, prevention methods can be passive or active. Active methods of rockburst prevention consist of the liquidation of stresses in the areas where they are concentrated through controlled generation of rock-mass tremors and rockburst by blasting works (group extraction blasting, release blasting in the rock mass and pillars able to accumulate the stress, as well as in the roof and floor). Group blasting works as a basic method are very effective in copper mine conditions. Provocation of dynamic events makes it possible to control the timing of their occurrence. In Polish copper mines, all blasting works are made during the absence of miners in the mining fields. Daily distribution of both the number of recorded strong seismic events and volume of energy released, confirm the advisability of using this kind of rockburst hazard prevention. The rockburst hazard prevention methods developed over 40 years of copper deposit extraction are economically reasonable and offer sufficient effectiveness under high rockburst hazard conditions.

Aug 1, 2013

By C. Guo, R. J. Chalaturnyk, M. MacKinnon, J. D. Scott

The Mildred Lake Settling Basin (MLSB) is the largest disposal site for mature fine tailings (MFT) at the Syncrude Canada Ltd. oil sands plant. Over the past years (since 1996), there has been a marked change in the densification behaviour of MFT in the MLSB. Methane-producing microorganisms, known as methanogens, have become very active, and large amounts of biogas (mainly methane) have been produced. Continued field monitoring of the MLSB has provided convincing evidence of the rapid densification process (rapid water drainage from the tailings) at the area with intense microbial activity. This rapid densification has caused pumping challenges in the transfer of fine tailings from the Mildred Lake Settling Basin for the creation of composite tailings. It may also have potential positive effects in accelerating the reclamation of the oil sands fine tailings. A field and laboratory research program was carried out to study the mechanism leading to the rapid densification phenomenon. A review and discussion of the research program is given and some results from the field investigations and small-scale column tests are presented in this paper.

Jan 1, 2007

By G. S. Barry

INVESTIGATIONS to date have shown that, should there be the need or the appropriate economic stimulus, Canada's mineral resources are sufficiently extensive to allow considerable expansion of its non-fuel mineral industry, during the remaining part of this century and possibly beyond (1, 2). The availability of sufficient capital will be one of the critical factors which will determine whether this potential will be fulfilled. The following analysis centers on the capital requirements of the Canadian non-fuel mineral industry under one set of basic assumptions of capacity growth, cost of new and replacement capacity, rates of depletion and depreciation of mines and plant, and the cost of exploration and infrastructure. Mindful of the fact that exploration and development will not thrive in Canada unless a very positive approach is taken, the writers make no apologies for being "optimistic" about long-term production prospects. Furthermore, in the event that world demand does escalate as anticipated and the forecast realistically attainable levels of Canadian production are not reached, then Canada will not have reaped the full range of economic benefits available, and opportunities will have been lost. Projections for Canadian production between 1976 and 2000 are essentially based on the forecast published in the 1974 paper, "Towards a Mineral Policy for Canada - Opportunities for Choice (3), with some updating on the basis of recent developments.

Jan 1, 1977

By E. Heikkinen, J. Suikkanen, T. Siren, J. Valli, M. Hakala

Diametrically faced borehole breakout observations are a fairly good indication of magnitude of the secondary stresses acting perpendicular to the borehole. In cases of low in situ stresses, where borehole breakouts are not observed naturally, it is possible to increase the prevailing stress state around the borehole by increasing the rock temperature. When the temperature is increased sufficiently, thermally induced borehole breakouts will occur. By implementing the temperature increase in boreholes located at excavated tunnels, it is also possible to study the effect of the near-field stresses caused by the excavation. The near-field stress state changes as a function of borehole depth, thus increasing the information available from experiment. To study the feasibility of this proposed low cost method, a Borehole Thermal Spalling (BTS) experiment was executed in ONKALO Underground Rock Characterization Facility, in Western Finland in 2014. The first borehole pilot test with the method was conducted in ONKALO at the POSE niche in already at May 2010, with the second pilot test following in August 2010 at Äspö HRL. The major objective of the experiments was to define the trend of the maximum in situ stress component, while also providing knowledge of the in situ spalling strength of the ONKALO rock mass. The stress state in ONKALO is nearly isotropic in horizontal layer, causing problems for the use of more traditional stress measurement methods. With boreholes heated over long interval, the weakest rock parts are observed to fail, thus providing statistical confidence. For these reasons, continuous test sections have an advantage in ONKALO, compared to spatially limited stress measurement methods such as overcoring and hydraulic fracturing. The BTS experiment is conducted in 9 meter deep vertical boreholes located at the POSE niche, situated -345 m depth below the ground surface. The boreholes used within the BTS experiment are located in migmatitic granite, in an experiment area where the surrounding stress state and the rock strength are fairly well known. The prior knowledge of the stresses is favourable for the experiment, as it requires careful planning and iterations to determine the appropriate heating power domain. Too low heating power will not be sufficient to cause borehole breakout, while too high heating power causes breakout in all directions thus making determination of stress direction hard or impossible. The initial state of the borehole and induced borehole breakouts will be monitored using acoustic televiewer logging (ABI) and optical borehole logging (OBI) imaging techniques. Fracture mechanics modelling is used in planning of the experiment, also in back-analysis to link the observed breakout angle to stress state. Both the pilot test in 2010 and BTS test in 2014 resulted in similar borehole breakout direction. The results are in line with so called EDZ & VT1 stress interpretation, revealed the maximum horizontal component bearing the magnitude of 21.5 MPa, with the trend of 166°.

Jan 1, 2015

By W. S. Dyer

Considerable attention has been paid in recent years to the fire-clay and silica-sand deposits of the Mattagami and Missinaibi rivers and ? to the lignite occurring in them. The fireclay especially deserves this attention; it is of first-class quality; it appears to be widespread; it is the only fire-clay in central Canada, and part of it lies not more than 20 miles west of Coral rapids, to which point steel will be laid this coming spring by the Temiskaming and Northern Ontario railway. Undoubtedly, these clays will rapidly find a place in industry. The fire-clays and the better grades of silica-sand are Mesozoic in age and have been referred to the Lower Cretaceous or Upper Jurassic. Glacial clays and sands and Palaeozoic shales also occur in the same region, but are of little economic value, and will not be dealt with in this paper. Dr. Robert Bell was perhaps the first to discover the clays, since in the Report of Progress of the Geological Survey of Canada for 1877 and 1878 he reported beds of lignite on Coal brook, a tributary of the Missinaibi river, underlain by sticky clay and overlain by glacial drift. In 1880 E. B. Borron (1) discovered an extensive deposit of white sand and clay on the east bank of the Missinaibi river, five miles below Coal brook, and in 1890 (2) he examined the deposit found by Dr. Bell on Coal brook. He recognized that the underlying clays were quite distinct from the glacial clays of the region, and suggested that they might be used for fire-brick if metallurgical operations were undertaken in the region. Somewhat later, J. M: Bell described a deposit of fire-clay and silica-sand on the Wabiskagami river, another tributary of the Missinaibi.

Jan 1, 1928