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By K. Hasselwander, K. Knabel

"A significant area of Outotec’s business involves fluidized bed roasting. With several decades of experience, more than 300 reference plants and strong R&D capabilities, the company provides several industries with optimum processing solutions. Applications include oxidation and sulfation of sulfides found in copper, pyrite and zinc concentrates. Gold production and de-arsenifying roasting are also within this scope. This paper describes the latest furnace developments and includes novel trends. Moreover, hot and wet gas cleaning systems are examined focusing on unit operations related to the removal of components such as dust, SO2 for sulfuric acid production, fumes, halides, Hg, hydrocarbons, nitrous oxides and metals.INTRODUCTIONGenerally, when defining roasting processes, it can be stated that the respective primary pyrometallurgical reaction is exothermic, of gas-solid nature and relates to a value solid product. These processes are a key focus within Outotec’s scope and include: (i) dead roasting (ii) sulfating roasting (iii) partial de-arsenifying roasting and (iv) two-stage, de-arsenifying roasting.Dead roasting involves the oxidation of a given sulfide, thus allowing for a subsequent leaching process, and has been applied to producing ZnO. Dead roasting of pyrite has also been extensively utilized with a primary goal of producing sulfuric acid. In contrast, sulfating roasting involves converting a sulfide to its sulfate, enabling a selective sulfation of components, such as Cu or Co, and their separation from ferrous components during leaching (produced sulfates are soluble). Partial roasting involves partially oxidating the metal sulfide to its oxide with the simultaneous production of gaseous As4O6, which is handled during gas cleaning. The solid product, containing hardly any As, is rich in S and can be fed to a respective smelter (e.g. in the case of Cu). Alternatively, if the production of oxide is required, a dead roasting step is added after the partial roasting step, with the overall process considered as two-stage roasting."

Jan 1, 2012

By P. Harvey

"Following initial discovery in 1991, BHP Billiton Diamonds Inc. opened Canada’s first diamond mine, the EKATI Diamond Mine (EKATI) in the Northwest Territories on October 14, 1998. Four short years later, on November 29, 2002, saw the opening of North America’s first underground diamond mine, the Koala North mine. Nestled between the original Panda open pit and the new Koala pit, which is in the early stages of production, Koala North represents the only underground kimberlite mining venture in Arctic conditions outside the new underground mines being developed by ALROSA in the Yakutsk region of eastern Russia. Extensive underground kimberlite mining has been practiced in the Republic of South Africa for much of the 20th century and continues today.Underground mining represents a key component of the long-term business plan for EKATI. As various open pits reach their economic limit, continued recovery of high-value ore at depth is dependent upon the ability to productively mine the kimberlite pipes by underground methods. As a function of its location, size, and value, the Koala North pipe is ideally positioned to host the first underground mine at EKATI. Koala North is designed and approved as a learning mine, from which to gain valuable experience in preparation for the potential mining of other larger, higher value pipes by underground methods in the development, the Koala North mine is well into its production ramp-up phase and currently producing at around 1,200 t/day from the first two production levels."

Jan 1, 2005

By Rob Boom, Yasuyuki Tozaki, Greg Traquair

The objectives of the business case are to examine a proposed metallurgical project and answer fundamental questions about project feasibility, risks, opportunities, and value. A business case fulfills these basic functions: estimates economic value; helps to understand competitiveness; serves as a risk management tool; and serves as a communication tool. A business case evolves with the project life cycle, and supports the gate reviews at the end of each phase of engineering, through to project construction and operations. A business case must be holistic, including all elements of scope that can impinge on project risk and value.

Jan 1, 2015

By Ainul Akhtar, Steve Cockcroft, Daan Maijer, Carl Reilly, Lu Yao, Jun Ou

A coupled thermal-fluid flow-multicomponent model has been developed to aid in understanding the melting/dissolution behavior of solid Al-rich Material (TiAl) in a liquid titanium pool produced by an electron beam. The model is capable of accounting for the significant phenomena present affecting heat, mass and momentum transport including thermal and compositional buoyancy and Marangoni forces, Darcy attenuation, evaporation, melting and solidification, and the associated release or absorption of latent heat. The modeling results have indicated the compositional fluid flow driving forces (compositional buoyancy and Marangoni forces) contribute significantly to the melting/dissolution process. The model is waiting for validation against empirical data.

Jan 1, 2014

By D. A. Nelson, Wedding. R. E.

"A planned production increase of 1.25 million tonnes per year at Domtar's salt mine in Goderich, Ontario required an increase in the underground mine ventilation system from 320,000 to 700,000 scfm, The design of the expanded facility included the addition of a 22-foot-diameter shaft to augment the existing production and service shafts.A preliminary review of the ventilation requirement s indicated that in order to pr ovide good economic design for the expanded system, a comprehensive ventilation survey of the existing system was required. The survey was completed in the latter part of 1980, and subsequent engineering design and equipment selection proceeded throughout 1981.This paper presents the methods used to carry out the survey. Particular attention is given to the numerous challenges presented in determining air flows in the large 45-ftwide by 43-ft-high airways. Emphasis is placed on practical field survey techniques.A mathematical model of the ventilation system using a computer program is described, and the application of this program to provide design data and assist in equipment selection is discussed. Economic sizing of airways and fan selection are analyzed considering horsepower and operating costs.IntroductionThe Goderich Mine of Sifto Salt Division, Domtar Inc., is located on the eastern shore of Lake Huron in the town of Goderich, Ontario, and has been operating since November 1959. The salt is extracted by a modified room-and-pillar method, and the workings advance at a rate of 1.5 miles per year by undercutting, drilling and blasting. The surface mine area consists of a 12-acre site in the Goderich harbour, at the mouth of the Maitland River, and the underground property consists of approximately 2,700 acres lying mainly under Lake Huron."

Jan 1, 1983

By K. D. Hester

This paper will review the metallurgical aspects of the completed expansion program at Quirke, and the current rehabilitation and refurbishing program at Panel. During the Quirke program, completed at the end of 1977, the plant capacity was increased from a nominal 4,500 to 7,000 short tons per milling day. The expansion of crushing, grinding, neutral thickening and filtering, leaching, partial neutralization, sand-slime separation, sand washing, C.C.D., clarification, ion exchange, mine water treatment, and tailings neutralization and pumping will be considered. The application of Enviro-Clear thickeners in the mine water treatment circuit and in the C.C.D. will be briefly reviewed. An automatic grinding and classification circuit for limestone will also be covered. The refurbishing program underway at Panel will be discussed. The Quirke and Panel plants will be contrasted and compared. In particular, reference will be made to environmental considerations. The innovative system for producing yellow cake at Panel, LAMIX, will be considered as well as the proposed treatment system for Panel tailings.

Jan 1, 1979

By B. Galy, L. Giraud

"This paper compares Canadian provincial mining safety regulations regarding the use and testing of cage safety catches, including a brief history and evolution. Regulations are similar across provinces, with only slight variations. Currently, the “Ontario-type” safety dog is the most commonly used safety catch in Canada. Performance estimation of the compensation mechanism for different safety-dog shapes and tooth angles show this shape works well and has consistent braking results, but the best efficiency is obtained for initial tooth angles greater than 10°. Miner safety is questionable for lightly loaded cages, an issue that should be addressed technically and legislatively.RÉSUMÉ Le présent article compare les diverses réglementations de sécurité minière concernant les parachutes des cages dans les provinces canadiennes ainsi que les essais qu’ils doivent subir. Il semble que les réglementations soient semblables à travers les provinces avec quelques légères différences ou divergences. Un bref historique des parachutes et de leur évolution est présenté. De nos jours, le parachute de « type Ontario » est le plus fréquemment employé à travers le Canada et il présente des résultats de freinage uniformes. Une estimation de la performance du mécanisme de compensation pour les diverses formes de taquets de sécurité et les divers angles des dents montre que cette géométrie fonctionne bien; cependant, la meilleure efficacité est obtenue pour des angles de dents supérieurs à 10°. La sécurité des mineurs est mise en jeu pour des cages faiblement chargées et ce point devrait être traité du point de vue technique et du point de vue législatif."

Jan 1, 2016

By H. Soto, P. Lacombe, R. del Villar

"During the summer of1989, Les Mines Selbaie, with the cooperation of Université Laval initiated a research project to evaluate the column flotation technology for its concentrator near Joutel, Quebec. The experimental work involved both a 5 cm by 11 m laboratory column and a 45 cm by 10 m home-made pilot unit Amenability tests were conducted using both units on various streams of the plant. Results showed that columns are not suitable for the copper cleaning circuit because the loss of precious metals, associated with the rejected pyrite, overcome the improved copper metallurgy. On the other hand, column testing at the zinc circuit showed improved zinc selectivity.Scale-up testing was', therefore, conducted on the first zinc cleaner concentrate using the laboratory-size column. The influence of variables such as porous parger grain size, wash water flow rate, airflow rate and froth depth values on column performance was' first assessed. Scale-up parameters were then determined using the optimal operating conditions from the previous tests. Simulation facilitated the determination of the most convenient plant-scale column arrangement.A number of conclusions concerning the experimental determination of scale-up parameters are also presented."

Jan 1, 1993

By S. P. Jekielek

"This paper describes the automation of a mine hoist ore loading pocket using a programmable controller. It provides an introduction to programmable control, and outlines the various modes and operating sequences of the loading pocket. A comparison is made with previous equipment to illustrate the increased flexibility, reliability and diagnostic functions that are gained.IntroductionLoading pockets have evolved from a couple of manually operated air cylinders to entirely automated systems. Early pockets were usually formed in rock, with loading and discharging regulated by air-operated gate s. Interlocks, added to this arrangement, prevented simultaneous operation of the gates and ensured proper hoist position . As the loading pocket advanced, it was recognized that gravity feed posed problems, often becoming plugged or letting water run through into the shaft. A belt conveyor was employed, eliminating the se problems and resulting in greater loading control. Weighing the combination of transistorized logic modules, replaced many relay systems. This elimination of moving parts and contacts increased reliability and reduced maintenance costs.As semiconductor technology progressed, there were major breakthroughs in miniaturization and reliability, and as a result the programmable controller was introduced. Programmable controllers first appeared in the automotive industry in the late 1960's. A system controller was required to replace the large relay panels in operation at that time. The use of digital integrated circuitry enabled these programmable controllers to automate processes with hundreds of inputs and outputs. Advances in electronics reduced production costs , making controllers for smaller application s viable . This development is on-going, each generation introducing controllers with greater capabilities for a wider variety of systems. equipment was the next step in loading pocket development, and dependance on much of the manual control was reduced . The complete system was first automated using relay panels. Solid- state devices were later introduced, and static control,"

Jan 1, 1980

By S. G. Enns, E. W. Yarrow

"Situated about 200 km southeast of Juneau, Alaska, within the lower Stikine River region of northwestern British Columbia, the Galore Creek porphyry Cu-Au deposits are hosted by Upper Triassic to Lower Jurassic alkaline volcanic rocks and comagmatic syenite intrusions. Early and late breccias are also locally important host rocks for mineralization. Of the twelve identified Cu-Au deposits, the most important are the Central zone, Southwest zone and the Junction deposits with a combined resource of 284 million tonnes at 0.67 % Cu.The composition of the intrusive rocks is predominantly silica-undersaturated, alkaline, and metaluminous. Four intrusive suites are identified from field, petrographic and petrochemical data. Variation within suites or lineages can be explained by alkali feldspar fractionation. An oscillation between porphyritic and equigranular intrusions is suggested by the sequence of different intrusive lineages. The youngest intrusive phase is silica-saturated.A complex succession of intrusive and hydrothermal events is demonstrated at Galore Creek, with the most intense alteration and mineralization developing early in its history. In the Central zone, early Ca-K-silicate alteration, dominated by garnet, biotite, Kfeldspar, and anhydrite grades outward into K-silicate alteration. Both are locally overprinted by retrograde sericite± anhydrite± carbonate (SAC) alteration. The most intense Ca-K-si/icate alteration, a magmatic-hydrothermal breccia, and an early syenite intrusion are all coincident with copper mineralization in the core region of the Central zone. However, higher grade mineralization in the zone, exceeding 1 % Cu with more than 0.5 g/ t Au, is typically associated with intense biotite-rich, K-silicate alteration primarily hosted by altered volcanic rocks. The highest gold grades, commonly exceeding 1 g/t, are associated with bornite-rich mineralization situated in the northern and southern parts of the Central zone.Mineralization in the Southwest zone occurs as disseminated chalcopyrite within a late, diatreme breccia and adjacent K-feldspar porphyry. In the other satellite deposits, disseminated chalcopyrite and bornite occur in volcanic rocks with alteration that is similar to the Central zone."

Jan 1, 1995

By A. Singh

Two alloys Mg96.9Zn2.7Ho0.4 and Mg93Zn6Ho have been processed by direct extrusion at 300°C and 200/230°C to produce various microstructures containing icosahedral quasicrystalline phase with different grain sizes. The alloys were mechanically tested in tension and compression. The mechanical properties were related to the grain size and microstructures studied by transmission electron microscopy. The extruded alloys showed a mixture of nano-sized icosahedral and monoclinic Mg4Zn7 phase, as well as icosahedral phase particles a few hundred nanometers in size distributed in the matrix. Coarse icosahedral phase particles several micron in size also remained after extrusion. The alloys Mg96.9Zn2.7Ho0.4 and Mg93Zn6Ho extruded at the same temperature of 300°C produced very different grain sizes of 15 and 3 µm, respectively. The alloy Mg96.9Zn2.7Ho0.4 extruded at 200°C and Mg93Zn6Ho extruded at 230°C produced grain sizes of 0.7 µm and 1.5 µm, respectively. Both the alloys showed yield stresses of about 300 MPa in both tension and compression with elongations of about 18%. Hall-Petch parameters are calculated for the alloys.

Jan 1, 2006

By J. R. Welsh, D. J. Palmer, O. M. G. Newman

"The use of calcine for selective zinc precipitation requires specialist knowledge to achieve satisfactory flowsheet design. Calcine from the bed of a fluid roaster is preferred, and factors such as the size distribution of ground calcine, the stoichiometric ratio of the calcine precipitant to the initial dissolved zinc concentration and the moisture content of the resultant filter cake are parameters which require critical attention. Extensive testing in a fully-integrated electrolytic zinc plant pilot plant has demonstrated that properly designed selective zinc precipitation plants using calcine as the precipitant are reliable operating units.The advantages of using calcine instead of limestone for selective zinc precipitation include a decreased cost of reagents, as well as avoiding the formation of by-product gypsum.Process simulation modelling has demonstrated that the use of calcine in this context has widespread application in the design of zinc plants with superior impurity and water balance control characteristics. A particularly powerful approach involves closed circuit washing. In this mode, filtrate from the selective zinc precipitation step is used to wash a zinc plant residue such as jarosite, and the resulting filtrate is returned to the selective zinc precipitation section. IntroductionThe Selective Zinc Precipitation (SZP) Process, developed and patented by the Electrolytic Zinc Company of Australasia Limited (EZ) may be used to achieve simultaneously, water balance and impurity control in an electrolytic zinc plantO,2). Impurities which may be controlled by the SZP process include chlorine, magnesium, manganese, potassium and sodium.In the SZP process, basic zinc sulphate is precipitated from a zinc sulphate solution by either limestone, lime or a compound containing zinc oxide, usually calcined zinc sulphide concentrate (calcine) or alternatively zinc oxide fume .The solids containing basic zinc sulphate are separated, typically, by filtration and returned to the zinc plant circuit as a neutralizing agent. The zinc depleted solution can either be discarded, or used to wash residues, thereby achieving water balance and impurity control (Fig. I)."

Jan 1, 1988

By C. Matthews, A. Vo

"Australia is one of the world’s leading exporters of bulk commodities and the extensive use of sampling equipment is key to the successful management of each mining operation. At the process plant, without a full understanding of the feed, product and tails, it is impossible to fully optimise the performance of the plant, such that the metallurgical balance is often open to error. At the port, a statistically correct, bias free and compliant sampling system is crucial to ensuring exported minerals are reflective of their true value and to avoid penalties. Over the last decade, as a result of the iron ore boom, there has been high demand for reliable, representative and standard compliant solids sample systems in Australia. This paper reviews several solids sampling applications at Australian mine sites, the challenges and experience gained and how the implementation of reliable representative sampling systems has provided better understanding of plant process performance, improved plant control and overall benefits to the operations.INTRODUCTION Mining is the primary contributor to the Australian economy with Australia ranking in the top 4 in economic resources for 21 primary industrial minerals in 2016 (Britt, et al., 2017). Australia is one of the world leaders in the export of the majority of its commodities including gold, copper and iron ore (Britt, et al., 2017). Therefore, a suitable and standard compliant sampling system is essential for evaluating plant performance and content verification. At the mine and at the port, the larger iron ore miners in Australia have developed stockpile models to predict the grade of their ore down to individual blocks of the stockpile. This allows the miner to create the right blend of material for sale to their customers and ensures they are not underselling their product or at risk of penalties for impurities or low grade. As an example, the average difference between the benchmark 62% Fe and low grade 58% Fe fines at the time of this report averaged US $30/tonne according to the Metal Bulletin Iron Ore Index. At a shipload of 180kt this would be a variation of US $5.4M. Whilst this is an extreme example, it highlights the economic importance of producing the correct grade product and a recognised representative sample of said product."

Jan 1, 2019

By W. Curlook

"A review is presented of a growing number of imperatives, some self-imposed, some imposed by society, which the mining and metals industry faces in carrying out its business. These imperatives bear on all activities from the exploration phase, through engineering, design, plant construction and operation, to decommissioning.IntroductionThe mining and metals industry must learn to cope with, i.e. manage, a growing number of imperatives. Some of these, such as the need for responsible stewardship of natural resources, the requirement to respect laws and regulations, the need to provide for safe and healthy workplaces, and the need to provide appropriate returns to investors of capital , have been with the industry for a long time (fable I). But the industry now faces additional imperatives that are growing in number and in importance (fable 2):• There is the growing concern about the impact of operations, not only on the workplace environment and the external environment, but also on the need to monitor not only the chemical concentrations in various effluents but to also monitor the effects of such emissions on the environment; i.e. there is a growing concern about the ""net"" consequences of operations.• There is the need for on-going improvement in productivity and safety to compete and survive in a global economy. The global business environment has become paramount.• There is the imperative to failsafe all designs, equipment and operational procedures, and having done that to provide for containment of unavoidable spills, and to have ready and in place systems for emergency response.• There is the need, indeed the imperative, to involve all employees in various quality improvement programs.• There is the imperative to face up to ""virtual elimination/zero emissions""; and• One must have waste management plans in place to cope with the need to reduce, reuse, and recycle; and• There is the need for decommissioning plans for all operations, for the restoration of business habitats to their original states (or better). Indeed, one must engage in the decommissioning exercise from day one, i.e. right from the time of design and commissioning."

Jan 1, 1992

By S. V. Ulianov, A. Y. Senchenko, A. A. Shvets, A. V. Aksenov

Development of an efficient technology to process complex ores containing gold and antimony as well as silver is described in the paper. The results from the testwork aimed at the valuables recovery by means of flotation are presented. A process sample of antimonite gold-bearing ore was studied in TOMS institute aiming at development of a technology to process such an ore with generation of antimony concentrate and sulphide gold-containing concentrate. Material composition study indicated that the ore included 5.3% of sulphides: arsenopyrite – 2.4%, pyrite -2.4%, and antimonite – 0.5%. Gold is present as an isomorphic dissemination in arsenopyrite. At sighter testing stage a direct selective flotation flowsheet was chosen to process the ore. Antimonite flotation was activated due to addition of lead nitrate. A single cleaning of a rougher flotation concentrate resulted in antinomy concentrate with 30% Sb content and 71% recovery. Au recovery into antimony concentrate did not exceed 1%. Sb flotation tailings were used to float the remaining sulphides and gold. The resulted sulphide concentrate was characterized by Au content of 20 g/t at about 80% recovery, arsenic content - 10% at ~80% recovery, and sulphur content - 18% at ~81% recovery. The sulphide concentrate can be forwarded to further processing aiming at gold recovery. Given that the concentrate is highly refractory it should be pretreated (bacterial or pressure oxidation, Albion process) prior to cyanidation in order to liberate gold from sulphides. The proposed technology allows one to solve the problem of precious metals recovery from antimonite ores.

Jan 1, 2016

By A. A. Brant

BECAUSE of its simplicity, the dip needle is widely used for locating magnetic rock formations in drift-covered areas. Although it responds only to strong magnetic disturbances, it has the advantage that surveys with it can be carried out rapidly, at relatively low cost, by untrained operators. More accurate surveys can be made with a much more sensitive instrument known as the magnetometer, but this must be operated by a specialist and the resulting survey costs are much higher. Mining men use the dip needle for the location of magnetic ores or mineral deposits associated with magnetic rocks. In certain districts, a survey with the dip needle may aid in solving geological structure. In the Little Long Lac and Crow River gold camps of Ontario, it has recently been used for these purposes. In interpreting the results of a dip needle survey, an understanding of the chief magnetic and mechanical factors determining the dip recorded by the needle is definitely necessary. For example, many observers locate a magnetic body by the highest dip values, apparently unaware that these frequently may not lie directly above the body. It should also be realized that a careful dip needle survey may yield information regarding the dip, breadth, and perhaps depth, of the magnetic body. Moreover, the observer should know when numerous closely-spaced dip readings are necessary, and when the dip may be measured at more widely separated intervals. The purpose of the following article is primarily to describe the factors affecting the registration of the dip needle, with a view to aiding investigators in a more accurate and complete interpretation of their results. To explain the cause of magnetic disturbances (anomalies) and the action of the dip needle, a knowledge of certain fundamental magnetic terms is necessary.

Jan 1, 1938

By Earl Gebhardt

The planning and design of mining panels in the Potash Corporation of Saskatchewan Inc., Lanigan Division mine Block B involved a number of investigative techniques. The techniques utilized to gain insight into the viability of mining included 2-D and 3-D seismic surveys, longhole drilling, exploration wells, photolineament, magnetic and gravity surveys, and actual room excavation.

Feb 1, 1993

By A. Lloyd, Montgomery, J. Jorgesen, W. J.

"Coals are ranked according to their degree of metamorphism or progressive change in the natural series from lignite to anthracite. The reader is referred to ASTM Standard D-388, ""Standard Classification of Coals by Rank"" for a detailed description of the system in use throughout North America including Canada.Fixed carbon and calorific value (expressed in Btu/ lb) calculated to the mineral-matter-free basis have been chosen as the main characteristics from which rank is established. Higher rank coals are classified according to fixed carbon content, lower rank coals according to the calorific value on a ""moist"" mineral-matter-free basis. Certain adjacent groups are differentiated according to their agglomerating (caking) properties. ""Moist"" refers to inherent moisture. Referring to Table 1, coals having calorific values greater than 14,000 Btu/lb on a moist mineral-matter-free basis and fixed carbon of 69% or more on a dry mineral-matter-free basis are classified according to fixed carbon. Coals having calorific values of less than 14,000 Btu/lb on a moist mineralmatter-free basis are classified according to calorific value on a moist mineral-matter-free basis. Agglomerating coals having 69 to 86% fixed carbon on the dry mineral-matter-free basis are classified in the low or medium volatile group of the bituminous class according to their volatile matter content. Agglomerating coals having calorific values between 10,500 and 11,500 Btu/lb are classified in the high volatile C bituminous coal group; nonagglomerating coals in the same calorific value range are classified in the sub-bituminous A coal group."

Jan 1, 1985

By R. W. Lawrence, A. Bruynesteyn

"Pre-oxidation of refractory pyritic concentrates by biological leaching to enhance the recovery of gold and silver in cyan ideation has been investigated. The results of laboratory tests on three concentrates are presented. In all cases substantial increases in precious metal recoveries were obtained following the pre-treatment. For one concentrate, gold recovery of 81% was achieved following an 87% oxidation of pyrite, compared with 24% recovery by direct cyanidation of non-oxidized concentrate. Gold and silver recoveries from the other concentrates were increased from the range 60-78% to over 90% and from 80-86% to over 98% respectively. Operating parameters are discussed and methods of maintaining high oxidation rates are evaluated. Methods of employing this pre-oxidation technique in commercial practice are described.IntroductionMany of the gold and silver deposits now being developed contain precious metals finely disseminated in sulphide minerals such as pyrite. These ore s often present considerable resistance to metal recovery. The ease with which gold may be extracted is usually related to grain size and its manner of distribution within the host mineral. In many cases, a significant percentage of the gold may occur in submicroscopic form, or in solid solution with pyrite, so that even very fine grinding fail s to liberate the metal for recovery by cyanide leaching. Such ores are often termed refractory. Even in cases where liberation by fine grinding is practicable, high cyanide and lime consumption may be experienced due to the presence of specific sulphide minerals, and poor metal recovery may result.Pre-oxidation methods for refractory ore s and concentrates are commonly used to improve precious metal recoveries. Roasting, for example, as a pre-treatment to cyanidation, removes harmful constituents by oxidation or volatilization, and liberates gold from pyrite. In some cases, however, this method of pre-oxidation can result in poorer metal recovery, particularly of silver, due to fusion and the formation of clinker, and the formation of compounds which consume cyanide in the subsequent metal recovery stage. Difficulties in compliance with environmental pollution regulations may also be encountered."

Jan 1, 1983

By H. N. Tran, D. Barham

"A systematic survey of the appropriate literature in terms of phase equilibria and possible reactions involving deposits in Municipal Solid Waste (MSW) incinerators are analyzed particularly with respect to the theoretical first melting points of typical ashes and the possible presence of a liquid phase at the temperature of ash-metal interface. Conclusions are drawn on the basis of the possible presence or absence of various metal chlorides and sulphates in such situations, and their effects on the problems of fouling and metal corrosion. From preliminary results, it would appear that ZnCl2 is unlikely to be present in any molten phase which causes corrosion because it evaporates rapidly from such liquids. It would also appear that PbCl2 and, by inference, ZnCl2 will sulphate at relatively low temperatures if the flue gas contains SO2 and O2.IntroductionMunicipal Solid Waste (MSW) incinerators produce fly ash which deposits on heat transfer surfaces throughout the furnace, leading to corrosion and loss of energy recovery efficiency. Despite a massive amount of research carried out on the subject of corrosion in MSW incinerators, the problem of corrosion of heat transfer metal is still with us, and no definite over-all cause and effect relationship has yet been identified. In order to make a contribution to the eventual solution of this problem, the authors have examined the problem from the beginning, using their knowledge of fouling and corrosion problems in black liquor recovery boilers as a starting point.The incineration of MSW has been used for many years to reduce the volume of material sent to landfill (ash volume compared to raw waste volume), and, in most cases, to recover energy at the same time by raising steam The steam may be ""low- or high pressure/ temperature"" depending on its end use. The higher the steam pressure and temperature, the greater seem to be the problems with corrosion of heat exchanger metal, presumably because the metal must withstand higher surface temperatures.The chemical and physical composition of MSW is extremely variable, not only on a regional basis, seasonal basis, and day-today basis, but also on a minute-by-minute basis, due to the inhomogeneity of MSW. This makes it extremely difficult to define cause and effect relationships, because both cause and effect are transient in nature."

Jan 1, 1991