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By W. A. Lang

"IntroductionCARBONIZATION, gasification, and chemical utilization of coal are interrelated topics, which makes it difficult to review one without indicating its connection with the others. Hence, in Progress in Coal Technology, Series No. 5: Carbonization, reference was made to gaseous products recovered in the carbonization of coal, and .to a number of chemicals made from the tars, light oils, and ammoniacal liquors which are by-products of coal carbonization.In this, the sixth paper in the review series, prime consideration will be given to the complete gasification of coal to give a fuel for domestic industrial, or power purposes and a synthesis gas suitable for the manufacture of gasoline, Diesel oil, and chemicals. The hydrogenation of coal, an alternative source of liquid fuels and of chemicals, will be reviewed, as will be a number of processes for •the recovery of chemical products from coal by extraction and chemical treatment."

Jan 1, 1952

By Tadeusz W. Wlodek

THE known phenomenon that a test-piece of ferro-magnetic steel is magnetic after it has been broken in tension indicates that, while it is being loaded, the steel acquires magnetic properties. In the present investigation of the influence of the stress on the magnetic flux, repeated pulsating stresses of increasing amplitude, varying from zero to the maximum tensile value, i.e., pull-pull loading, were employed. The specimens were prepared from two types of carbon steel and two of alloy steel. The magnitude of the magnetic flux was determined indirectly. The voltage and mode of variation of the electromotive force induced in a coil surrounding the stressed steel specimen were measured as an indication of the varying magnetic flux within the specimen. Curves representing the electromotive force induced by the varying magnetic flux show that as the tensile load increased so also the magnetic flux increased, with a corresponding increase in measured e.m.f. At a certain stress there is a sharp bend in the voltage curve (point Win the diagram, Figure 5); this critical stress corresponds very closely with the yield stress (0.2 per cent permanent strain). Beyond this point, slight increases in the stress produce large increases in the voltage. The wave form of the e.m.f. was registered on an oscillograph. Analysis of the curves so obtained demonstrated the necessity of continuing these experiments, in order to determine the type of induced wave form associated with various types and amplitudes of stresses. In these experiments, the shape of the stress wave was sinusoidal, although the shape of the induced e.m.f. was sinusoidal only up to a certain load and became more and more complex above this load.

Jan 1, 1944

By R. K. Collings

The annual production of mineral and mineral-based wastes in Canada is conservatively estimated to be 400 million tons. Over 90 per cent of this amount is waste rock or mill tailings from the mining and mineral processing industry. The remainder are slags and ashes from the metallurgical industry, and sludges from the chemical industry. Because of impurity content, remote location, or both, most wastes have limited usefulness and, indeed, are a liability in that they must be transported to waste disposal sites and contained therein. Certain mineral wastes do, however, have potential value. Some contain small percentages of metals that may be economically recoverable with price increases; others consist of mineral material that may be used for such purposes as road base, construction aggregate, railroad ballast, and in the manufacture of bricks or blocks. Increased interest has been shown in mineral wastes in recent years. This paper reviews the types of mineral wastes available in Canada, briefly describes a number that have potential value, and notes possible uses and related research by CANMET and other organizations.

Jan 1, 1978

By Q. F. Wang, M. H. Lai, T. Q. Liu, G. G. Dong

Compared with the traditional pre-treatment process, biological oxidation process has many advantages including higher gold recovery, less cost, easier operation. The bio-oxidation reactor is the most important equipment for biological oxidation process. In this paper, the characteristics of biological oxidation are investigated, and the design principles are proposed based on laboratory tests. Both increasing the tank height and taking new inflation system can enhance higher dissolved oxygen. The new type of large-scale industrial bio-oxidation reactor is designed, which is 9.5 m in diameter and 10 m in height. The bio-oxidation reactor metallurgical performance has been tested by industrial-scale experiment. The slurry of flotation concentrate is divided into two parts to feed two bio-oxidation reactors. The feeding rates of two reactors are adjusted on the basis of getting the same content of S, Fe, As in overflow. The result shows that the feeding rate of the new type of 700 m3 bio-oxidation reactor is 3.72 m3 per hour, and the feed rate of the conventional 700 m3 bio-oxidation reactor was 3.23 m3 per hour. The processing capacity of the former is 15.2% higher than that of the later, which demonstrates the new type of bio-oxidation reactor has higher oxidation rate.

Jan 1, 2015

By S. L. Gula

"Effective and timely communication during routine operations, and especially during emergency situations, is no easy task in any underground mine. At Cominco Fertilizers, Potash Operations, where 150people are employed underground to produce 3.1 million tonnes of potash per annum at a depth of 1100 m (3600ft), this is no exception. The over-all mine workings underlie an area of approximately 20 km 2 with average travel time to the active mining areas being approximately 30 to 40 minutes by light vehicle, and significantly longer than this for heavy equipment.In a mine of this size, the deployment and management of personnel and materials on a day-to-day basis, and during mine emergencies, is an important exercise. The Personal Emergency Device (PED) system has provided the Potash Division a means to achieve improvements in this area and reduce the communications bottleneck.The MineAt Cominco Fertilizers Potash Operations, approximately 30 km southwest of Saskatoon, the orebody is the same horizon being mined by other potash producers in the Saskatoon area and extends over 300 km in an east-west direction, and approximately 150 km in a north-south direction. Mining operations are carried out with approximately 150 employees operating on a continuous-shift basis, seven days a week.Mining is presently being done from Block 6 which takes the mine to its northernmost boundary and contains reserves of approximately 50 million tonnes. Production is from one level by five twin rotor continuous mining machines, each capable of cutting a face up to 5.5 m wide and 3.3 m high . All ore is transported to the shaft via approximately 20 km of conveyor where it is removed to surface by two 24 tonne skips.After the ore is conveyed to the mill for processing, the finished product is shipped by rail car or trucks to other parts of Canada, the United States or through Vancouver to other parts of the world."

Jan 1, 1993

By James E. Wennen

The through-put and energy efficiency of an autogenous (AG) grinding mill are adversely affected by variability in rock size and rock competency. This applies to both fully autogenous and semi-autogenous (SAG) grinding circuits. In this paper we focus on an approach to overcome the problem of inconsistent mill through-put related to variability in mill feed size and rock competency. The focus is on ores containing hard, competent rock. This approach consists of preparing feed to an autogenous mill that contains 20% coarse media rock and 80% of material crushed to pass 37 mm. Results of pilot-scale testing for two iron-ores will be presented to show that a 10% to 12% reduction in unit energy consumption is possible with prepared feed, compared with feeding the mill with conventional primary crusher discharge.

Jan 1, 2012

By O. S. Perry, G. H. Charlewood, K. Griffin, S Ogryzlo, H. Hopkins, G. MacIntosh

"The gold mines of Kirkland Lake are in Teck township, Timiskaming district, Ontario, latitude 48°9'N. and longitude 80°3'W., at an elevation of 1,038 feet above sea-level.There are seven contiguous producing mines in a length of 3;1/2 miles along the general east-west strike of the deposits. The seven mines are, in order from west to east, Macassa, Kirkland Lake, Teck-Hughes, Lake Shore, Wright-Hargreaves, Sylvanite, and Toburn.The first discovery of gold in the zone was made by W. H. Wright in 1911 on the east claim of the Wright-Hargreaves property, and the following year the Tough brothers and H. Oakes found gold in what is now the No. 1 vein_ at the Toburn. Production began at the Toburn in 1915, followed by Teck-Hughes in 1917, Lake Shore in 1918, Kirkland Lake Gold in 1919, Wright-Hargreaves in 1921, Sylvanite in 1927, and Macassa in 1933.To the end of 1946, 31,938,350 tons of ore had been milled at the Kirkland Lake mines, from which 16,132,700 oz. gold, having a value of $498,517,600, were recovered. The bullion varies from mine to mine between 800 and 900 fine, the average for all the mines being 853. The average fineness of the native gold is 941.The workings of some of the mines are more than 6,000 feet deep and sinking to depths below 7,000 feet is now in progress.GENERAL GEOLOGYThe regional structural geology of the area in which the mines of Kirkland Lake occur is described in a preceding paper in this volume by J. E. Thomson."

Jan 1, 1954

By A. H. Lang

"The great interest taken in uranium in Canada during the past few years has resulted in the discovery of a very large number of occurrences, and in much research that has added to the knowledge of the mineralogy and geology of uranium deposits. The object of this paper is to present that information in condensed form. Some of it has been published before, but the writer has been asked to bring it together and to add more recent, unpublished data. The paper therefore contains short accounts of the mineralogy of uranium and of the types and distribution of occurrences; brief regional descriptions, including information on some of the characteristic deposits; and conclusions regarding prospecting and development possibilities.The writer has access to much confidential information supplied in compliance with regulations of the Atomic Energy Control Board. He has used this only for making broad generalizations that could not affect individual interests, and only where the owners of properties have agreed to its use.Much of the information on mineralogy and geology is derived from the work of others. The writer is particularly indebted to M. H. Haycock and S. Kaiman of the Mines Branch; H. V. Ellsworth, S. C. Robinson, E. J. Brooker, H. R. Steacy, W. E. Hale, and A. M. Christie of the Geological Survey; and E.W. Nuffield, J. S. Stevenson, and other officers of provincial Departments of Mines. For information and many courtesies he is greatly indebted to so many officers of Eldorado. Mining and Refining (1944), Limited, and owners and staffs of private properties, that it is impossible to mention them individually."

Jan 1, 1950

By Jaeheon Lee, Junmo Ahn, Doyun Shin

"Many alternative leaching systems including bacterial leaching have been introduced to avoid passivation on the surface of chalcopyrite and to increase the leaching efficiency of copper from chalcopyrite. Recently, glycine, one of the simplest amino acids, has been emerging as an efficient and environmental-friendly lixiviant to recover copper. In the present study, an alkaline glycine–peroxide lixiviant system was used to leach copper from chalcopyrite concentrate and the leaching mechanisms were also investigated by a suite of kinetic studies under different conditions. The chalcopyrite concentrate contains 28.8% copper with 30.8% sulfide sulfur. The effect of concentration of glycine and hydrogen peroxide of the leaching solution was investigated. Glycine concentration was varied from 0.5 to 1.0 M and the hydrogen peroxide concentration was changed between 3 to 5%. Leaching time and pulp density were also varied. Hydrogen peroxide is an oxidant of the system and the leaching efficiency with periodic additions of the peroxide was also studied. A mineralogical study was performed using XRD and SEM. To investigate the surface of the residue materials, XPS was used to see if any passivating layer was formed during the leaching. Detailed results from mineralogical, chemical, and metallurgical studies will be presented and discussed.INTRODUCTION The greatest global resource of copper is low-grade chalcopyrite and heap bioleaching may be the only economic option for its processing. However, formation of a passivating layer on the surface of chalcopyrite slows down the oxidation reaction and reduces the efficiency of the process."

Jan 1, 2017

By David R. Winfield

I would like to thank you for spending the time with me today to review the FLIR PathFindIR thermal imaging camera system: It is truly an innovative safety system that has the added benefit of offering increased efficiency Our company the Winsted Group, specializes in mobile video systems that are fully customizable to address standard and unique operational requirements in a variety of industries from heavy equipment cameras to police and military digital recording systems, high end video camera systems are a hallmark of Winsted?s product line. The use of thermal imaging camera systems to enhance mobile safety is a relatively new concept as it relates to their use in both transportation and heavy equipment operation. This technology, like so many before it, has been adopted for civilian use from its military roots. The identification of enemy combatants through their heat signature has given our troops a decisive edge in military operations in total darkness Likewise, the ability to discern people and objects that give off heat is a significant step forward in collision and accident avoidance. The PathFindIR camera system that I am demonstrating today is so advanced that it cannot be exported outside of continental North America without a US government approved export license I would like to commence my presentation with a short video clip that discusses the technology associated with the FLIR PathFindIR Thermal Imaging camera systems. The video demonstrates the operational effectiveness of thermal imaging camera systems installed on a vehicle operating on the roadway at night, of course there are definite parallels to use in a mining environment, primarily the fact that lighting is limited and the chance for vision limiting dust is ever present. We are, of course more concerned with personnel safety in our mines than encountering wildlife on the roadside. From the same perspective, the transport driver is just as concerned with encountering a stalled vehicle as our mine truck operators are with other mine traffic.

Feb 1, 2008

By Lar Liljeblad

"As demands upon the earth's natural resources continue to grow, exploration companies, mining organizations and others face the problem of the need to tackle increasingly more difficult strata to open up new reserves. Innovations in materials technology and tool design have steadily improved this capability, but none perhaps so drastically as a recently introduced cemented carbide in which tool wear resistance and/or toughness can be tailored precisely to the user's drilling needs.Introduction Until about forty years ago, the bulk of rock-drilling operations had to be carried out with hardened steels. Short life between re-grinds was common especially in abrasive rock formations. Shortly after World War II, Sandvik, Sweden, pioneered the development of sintered (cemented) carbide-tipped steel tools as a means of improving drill tool life. The new material was a composite of tungsten carbide and cobalt, the latter acting as a 'cement' to bind the wear-resistant carbide grains together, and the composite, in turn, was brazed to the steel. The immediate effect was a 100-fold increase in the service life of the tool.Intractable ProblemsWhile the carbide-tipped tools served the mining and quarrying industries admirably there were, nonetheless, some seemingly intractable limitations. The greater the wear resistance of the material - the quality for which it is selected - the more brittle it is. Also, rocks vary widely in hardness and abrasiveness and no single tool, either in terms of material or shape, meets every need. Specifically, for fast penetration of non-abrasive rock, toughness must be combined with a relatively sharp tool prome. Highly abrasive rock, on the other hand, demands a substantially broad area of extremely wear-resistant material on the tool if long bit life is to be assured. Between these extremes there are innumerable variations in rock"

Jan 1, 1991

By Yang Shuxin, Guo Qiliang, He Ping, Lu Lizhi, Yao Rui

"We combined stepwise regression and constrained regression statistical method to obtain the best boundary conditions for the calculation of in-situ stress field in Wushaoling tunnel using finite element method. Our numerical results reveal that: the main geologic factors contributing to the initial background stress are gravity and tectonics; the principal stress values would drop in fault zones; the angle between the maximal horizontal stress and the axis of Wushaoling tunnel is acute; Wushaoling tunnel tends to become stable when this tunnel has 2:1 ratio of the height to its width; the possibility of rock-burst exists under high stress.INTRODUCTIONStress state of engineering region is an important factor affecting the stability of project. Geological disasters in the project area are closely related to their stress environment. Wushaoling tunnel which is 20,050 meters long, lying along Lanzhou-Wuwei segment of Lan-Xin Railway in China, is the key project of Lan-Wu double-track railway. The region surrounding this tunnel is under a high stress environment. Accurate identification of the stress environment of the engineering area and the interaction between geomaterials and geotechnical engineering construction holds significant scientific and practical value for engineering design, construction, and operation.Many scholars explored and discussed the present-day tectonic stress through investigations of tectonic evolution history (Ding, & Lu, 1986), crustal deformation (Zoback, 1992), focal mechanisms (Yang et al., 2003, Xie, Cui, & Zhao, 2004), and so forth. However, the above methods would only provide the approximate direction of the principal stress in a broad region, and could not give the absolute stress values. In-situ stress measurement is one of the primary means to directly gauge the current crustal stress. However, in-situ stress measurement can only be applied in small number limited by measurement conditions."

Jan 1, 2015

By G. Eaton

Safety management is an important mortal and business function in construction. Contractors have traditionally tracked and reported lagging indicators, e.g. fatalities and lost-time accident rates, to measure their safety performance and stay in compliance with relevant regulations. Over the last several decades, contractors became more proactive in their approach to safety and developed programs that track leading indicators, e.g. safety audits and safety climate. In particular, safety climate measures workers? perception of safety management and its effectiveness in the workplace. Past literatures indicated that, while some industrial construction contractors ignore safety climate measures, others are limited by a lack of a formal means to measure safety climate. In this study, a survey approach is used to measure an industrial construction contractor?s safety climate through three key areas: management commitment, job control, and general safety climate. As a pilot study, a total of 214 individuals at a fabrication facility participated in the survey to verify the validity and effectiveness of the proposed survey approach. This survey study also confirms that job control and management commitment have a positive correlation and that worker demographics have an effect on respondents? perceptions of management commitment.

Aug 1, 2013

By Z. S. Shao, X. Z. Li

"Sub-critical crack growth plays an important role in long-term creep failure in brittle rock. Based on micromechanics established by using relationship between micromechanical wing crack growth model and macroscopic strain, and comparing theoretical model with testing results, a method, which applies the theory to real rock, is suggested in this paper. Using this method, properties of creep, damage and progressive failure in brittle rock are investigated. Effects of stress state on creep failure time and steady-state creep rate are analyzed and graphically presented. The results are helpful to support structure design and service life evaluation of underground structures with high geostatic stresses. INTRODUCTIONDuring the long-term operation in underground space with brittle surrounding rock, due to chemical action between pore water and rock, the failure of rock often occurs at stresses below its short-term failure strength, which brings serious effect on the long-term stability of underground structure. Thus, the long-term strength of brittle rock attracted wide interests of scholars around the world. The static fatigue limit was predicted by exponential function that is derived from abundant experiment data of stress level and failure time(Schmidtke & Lajtai, 1985), and similar result by relationship between stress state and failure time was also suggested (Lau & Chandler, 2004; Aubertin et al., 2000; Sangha & Dhir, 1972). According to relationship between steady creep rate and stress state during creep, a critical stress that transforms steady-state creep to accelerated creep was studied and the long-term strength was suggested (Tsai et al., 2008; Ma & Daemen, 2006; Lajtai et al., 1991). Based on the results of experiment in compression, the long-term strength of rock was defined by stress at volume strain reversal. When applied stresses are larger than the long-term strength, the microcracks in the rock will grow constantly, damage of rock will increase and failure of rock will occur finally (Chandler, 2013; Bieniawski, 1967; Brace et al., 1966)."

Jan 1, 2015

By A. H. Anderson

THE travelling grate coking process was developed by Shawinigan Chemicals, Limited, at their Shawinigan Falls plant. The first production unit went into operation a month prior to the outbreak of the war. Since then a substantial part of the coke used in the manufacture of calcium carbide has been produced by this process. In the following will be given a short account of the development work, a description of the process and the equipment, a discussion of the properties of the coke, the economics of the process and its future possibilities. EXPERIMENTAL WORK The carbide industry is a large consumer of coke, one ton of commercial carbide requiring for its production 1,200 lb. This coke must meet certain specifications in order to be acceptable. It should have a low ash content, preferably below 8 per cent, and the sulphur and phosphorus content must not be above specified limits. The size of the coke is also important. If it is too large it has to be crushed before it can be used in the furnaces, and if it is too fine it may have to be screened and briquetted. In addition, it must be dry. Although it was generally possible to purchase coke, including petroleum coke, and coke fines, in the quantities required, it became increasingly more difficult as time went on to obtain coke of a suitable quality at an attractive price. It was therefore natural for us to look to coal carbonization as a means of basing the supply of the fundamental raw material for carbide manufacture on something more solid than the shifting conditions of the coke market.

Jan 1, 1944

By A. A. Wessels, D. P. Allison

"Mine hoists are built to handle a certain nameplate capacity; they are specified and designed according to the required duty. However, as production capacity increases in other parts of an operation, the hoist capacity can become the critical constraint. Such a situation occurred at Lundin Mining’s Neves-Corvo operation. This paper examines how each component of the existing hoisting system was examined and optimized. Through a combination of engineering study and hoist simulations, the annual hoisting capacity was improved by 24% through increases in payload capacity and available hoisting time combined with a reduction in cycle time, while no changes were made to the hoist motor, drum or headframe. The additional payload capacity was achieved by reducing the mass of the hoist ropes and skips, and improving load monitoring systems. The cycle time was reduced through the shortening of the creep distances and increased availability through the installation of a shaft collar safety platform, alternative guide rope bushes, and superior liners for both the skips and underground measuring flasks. Enhanced cooling of the hoist electrical system was also incorporated to increase hoist availability by reducing downtime during hot summer months. The changes will increase the capacity from the current 4.5 mega tonnes per annum (Mtpa) to a planned 5.6 Mtpa and are being implemented over a 2-year period whilst maintaining the mine production during the upgrade work. INTRODUCTION Neves-Corvo Mine Neves-Corvo is primarily a copper and zinc mine producing copper, zinc and lead concentrates. The operation is owned and operated by Somincor, the Portuguese subsidiary of Lundin Mining. Located in the Alentejo district of southern Portugal, the operation is situated approximately 15 km southeast of the town of Castro Verde, where summer temperatures can reach as high as 45ºC, and approximately 220 km southeast of Lisbon. The principal means of mine access is via a ramp from surface, with the vertical shaft used to hoist ore and waste from the 700 m level, while conveyors descend from the 700 m level to transport ore and waste up from the deeper levels of the mine. The mine is highly mechanized and several different stoping methods are employed, with the most significant being bench-and-fill and drift-and-fill. The Neves-Corvo mine currently exploits five orebodies: Neves, Corvo, Graça, Zambujal and Lombador for copper and zinc-lead ores which are processed in one of two plants. All the orebodies are currently exploited over their full elevation with the exception of Lombador which is only mined down to the 220 m level, approximately the top 50% of the orebody, known as Lombador Phase 1."

Jan 1, 2019

By K. Esmaieli

This paper addresses issues associated with ore pass degradation caused by material impact. A series of numerical experiments, using the particle flow code, were undertaken to investigate the influence of various finger raise configuration. This has allowed the identification of favorable configurations. The results of this analysis, when coupled with field observations, can contribute to the design of ore pass systems that can prolong the useful operating life of ore pass systems.

May 1, 2009

By Frédéric Flament

The aim of this paper is to present the development of a data validation software as component of a commercial mass balance package. Data reconciliation through mass balance is basically an optimization problem constrained by the law of mass conservation. As any optimization problem solved with a modern and robust software application, erroneous information or starting point will always lead to a solution, whether it is realistic or not. Moreover, good information wrongly weighted by an incorrect error model will lead to the same bad ending. In an industrial context where competition requires accurate information, data reconciliation without validation can be disastrous and calls for data validation before and after reconciliation. The challenge in automated data validation resides in the development of general theoretical solutions. Until now, none has been presented and only partial solutions are available. The development presented in this paper incorporates some of these partial solutions. The integration of human knowledge into the application paved the way to a more general solution. The combination ?theoretical validation ? human expertise? proved to be flexible and reliable enough to be integrated in a commercial data validation package. Numerous examples though industrial applications are presented. These applications demonstrate the validation of raw measurements, user support in the development of error models and validation of reconciled measurements.

May 1, 2001

By Douglas C. Fraser

"Geophysical data are often presented on maps, sections or profiles with minimal data processing. A common example is magnetic data, in which the diurnal-free raw readings are merely contoured on a map. Other examples include profile presentation of VLF-EM data, IP pseudo-sections and airborne EM anomalies which may be shown on a map with only the measured amplitudes indicated.In recent years, efforts have been directed to the portraying of data in more useful forms. A number of algorithms (i.e., manipulative procedures and equations) have proven to contribute significantly to the usefulness of geophysical data. Some can be applied manually; others are sufficiently complicated to require a computer. Some merely alter the data to a more useful geometric form without altering the units. Others yield quantitative estimates of source body parameters such as conductivity and shape. Several examples follow:1. A simple algorithm is in common use which transforms noisy non-contourable VLF-EM data into less noisy contourable data. The input is the dip angle in degrees or per cent and the output is also in these same units.2. A simple algorithm has recently been developed which allows multi-level dipole-dipole IP data to be contoured on a map. Again, the units are not altered.3. A relatively complicated algorithm is in common use which transforms non-contourable height-sensitive helicopter EM data into contourable resistivity data,4. An algorithm has been recently developed which transforms non-contourable height-sensitive EM data into contourable weight per cent magnetite.The purpose of all the above techniques is to present the data in a simplified form. This, in turn, allows an easier assimilation by the user of much of the information content of the data."

Jan 1, 1981

By J. E. Dutrizac, Alba Sunyer

The factors affecting the precipitation of arsenic-free alunite (KAl3(SO4)2(OH)6) were investigated in a series of laboratory experiments. Although the amount of alunite precipitated increased with increasing retention time, temperature, solution pH and the concentrations of Al(SO4)1.5 or K2SO4, the composition of the products remained nearly constant. The preferred conditions identified for the precipitation of arsenic-free alunite were then used to assess the behaviour As(III) and As(V) during alunite precipitation at 98°C. Increasing additions of As(III), as NaAsO2 or As2O3, resulted in a slight increase in the amount of precipitate formed at pH 2.80. However, X-ray diffraction analysis showed all the precipitates to be alunite, and <0.2% As(III) was detected in the products. In contrast, increasing additions of As(V), as KH2AsO4 or As2O5, resulted in significant increases in the amount of precipitate formed at pH 2.80 or 3.00. Furthermore, the arsenate (AsO43-) contents of the precipitates increased up to 15%, and the sulphate contents decreased, as the As(V) concentration of the synthesis solution increased from 0 to 9 g/L. X-ray diffraction analysis of the products detected only alunite, but there was a progressive expansion of the alunite cell with increasing arsenate content. The implication is that arsenate substitutes for sulphate in the alunite structure. Preliminary observations on the environmental stability of the arsenate-bearing alunite using the TCLP protocol gave solubilities <0.4 mg/L from a precipitate containing 8.5% AsO4 and 7.8 mg/L from a product containing 19.5% AsO4. Thus, it appears that alunites containing less than -10% AsO4 would be an acceptable vehicle for the disposal of arsenic from hydrometallurgical processing solutions.

Jan 1, 2011