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Vatukoula, the Fijian equivalent of gold rock, is the name of the community embracing the gold mines owned and operated by Emperor Gold Mining Company Ltd., Loloma (Fiji) Gold Mines, N.L., and' Dolphin Mines Ltd. It is situated in the Tavua Goldfields approximately five miles from the northern coast of Viti Levu, the largest island of the Colony of Fiji.The climate is sub-tropical, there being a definite wet and dry season. The wet season is somewhat variable in length but usually extends from December to March, during which time most of the rainfall for the year is recorded.Although the average annual rainfall is 71 in., more than twice this amount has been recorded. Precipitation at the rate of 5 in. per hour is not uncommon and 15 in. of rain has been registered in 24 hours. The mining methods adopted, therefore, had to suit these wet conditions.The occurrence of gold in the Tavua area has been known since 1872, but it was not until 1932 that discoveries were made which led to the formation of the present operating companies. In 1934 the Emperor Gold Mining Company Ltd. commenced operations, followed in 1935 by the Loloma (Fiji) Gold Mines, N.L., and later by the Fiji Mines Development Ltd., now known as the Dolphin Mines Ltd. Up to the end of 1951 these three mines had produced 2,501,688 tons of ore from which 1,277,881 oz. of fine gold and 347,429oz. of silver were obtained, realizing in Fijian currency £13,025,153.The three mines are situated close togeth.er on contiguous mining leases, and, although under common management, are operated as separate en,tities. Since 1944 all the...

Jan 1, 1953

By M McDonald

KiwiRail has a goal of significantly improving passenger rail services to west Auckland, as part of its DART (Developing Auckland’s Rail Transport) suite of projects. The New Lynn Rail Trench (NLRT) project was a significant component of this work. The NLRT project facilitates essential doubletracking of the Western Auckland line, and provides a new commuter transportation hub within a busy town centre.The 1.5 km stretch of track through the New Lynn town centre has bisected the township for over 80 years. Double-tracking the line provided the opportunity to grade-separate road and rail, which would help to re-connect both sides of the township and enhance public amenity and safety.KiwiRail employed an Early Contractor Involvement (ECI) procurement model engaging a consortium comprising Fletcher Construction, Beca Infrastructure and Synergine to develop a Design and Construct solution.With weak soil conditions and high groundwater levels, a diaphragm wall construction method to form the trench walls was selected as the best solution. Further challenges to construction included working within a narrow rail corridor constrained by buildings along much of the boundary, and a requirement to keep the existing line open for rail services. Detailed construction planning was required to ensure rail and construction safety in a constrained space whilst building the trench walls, propping these walls during excavation, and constructing the base slab in the most efficient way possible.This paper will detail the geotechnical conditions and the additional constraints that made this rail trench a challenging structure to design. It will also describe the fi nal design and construction methodologies that were employed, that allowed very successful completion of the project.Additionally, this paper will review the design and construction lessons applicable to the current Victoria Park Tunnel project, and indeed for all future cut and cover tunnel projects in the Auckland isthmus.

Mar 8, 2011

THE slag from the blast furnaces having been granulated, a representative sample is taken to the sample mill. It is then dried, crushed through a 100-mesh screen, intimately mixed, and packeted for assay purposes.METHOD OF ANALYSISINSOLUBLEWeigh 1 grm. of the finely-pulverized slag into a 3t-in. casserole, moisten with a little water to prevent sticking, cover with a clock glass, and add 20 cc. of hot acid (1 HNOs, 3 HCI, 4 H2 0). Evaporate slowly to dryness on a hot plate and bake (without overheating) until all the gelatinous silica is dehydrated. Cool, add 20 cc. HCI (1-1), and boil gently for several minutes; filter into a 300-cc. beaker, cleaning out the casserole thoroughly with a rubber-tipped glass rod. Wash residue with hot distilled water and transfer it to a No. 1 porcelain crucible. Dry, ignite, cool in a desiccator and weigh as total insoluble matter. Dilute filtrate to 200 cc. and neutralize some of the excess HCI with NHa.OH. Warm, and pass H2S for 15 min. Filter and wash withhot water. Boil off H2 S, oxidize with 5 cc. HNOll , reduce bulk of the solution by evaporation. to about 100 cc., and transfer to a 250 cc. flask.SILICAFuse insoluble residue over a blast lamp in a platinum crucible with three or four times its weight of anhydrous carbonate of soda, for 10 to 15 minutes, or until decomposition is complete. Cool, and extract fusion in an 8-in. evaporating dish with HCI (1-1); rinse crucible and cover with distilled water, and evaporate to dryness over a water bath. Take up dry mass with 10 cc. strong HCI, and then.

Jan 1, 1922

Neutralisation, normally using lime, is the most widely used method for treating high flows of acid mine drainage (AMD). Lime costs can be very high however. If carbonate sources could be used to achieve pH values above six, costs could be greatly reduced. For example, use of locally quarried limestone at Mt Lyell could potentially reduce alkali costs from about $A 3.5 to $A 1 million/year. Methods for enhancing the effectiveness of limestone and magnesite for neutralising Mt Lyell and Savage River AMD respectively have been examined through a series of investigations. Small-scale testwork found that the maximum pH economically achievable with ground limestone was about five, due to slow dissolution rates and surface armouring. The problems of surface armouring were greatly reduced by the use of crushed limestone or magnesite at high pulp densities (75 per cent solids w/w), enabling pH values >6 to be achieved in a practical time frame. The use of particle sizes in the range 6 mm and finer also reduces costs by avoiding the need for grinding, and reduces the problems of solid-liquid separation and solid recycling that arise if large additions of ground carbonate are used. Pilot scale tests were carried out using tumbling drum reactors with limestone and Mt Lyell AMD and a pulsed-bed static reactor with magnesite and Savage River AMD. pH values averaging 6.2 and 6.4 were achieved with Mt Lyell and Savage River AMD respectively. Approximately 80 per cent of feed acidity was neutralised. A preliminary engineering design and cost estimate has been completed on the pulsed-bed reactor and shows that the concept is technically feasible and, if results are confirmed, economically attractive. Further pilot testing is planned.

Jan 1, 2002

By F Baars, M Zu, C A. RosiFre, L Lobato

A genetic model for the genesis of high-grade (>65 wt per cent Fe) Proterozoic, banded iron formation (BIF)-related iron deposits such as the Tom Price, Mount Whaleback deposits in the Hamersley Province (Australia), the N4E, N4W, N5 deposits at Carajßs (Brazil), the Aguas Claras, Conceitpo, and Casa de Pedra deposits in the Iron Quadrangle (Brazil), the Donkerpoort West, Kwagas East deposit in the Thabazimbi iron ore district (South Africa), or the Saksagan ore field at Krivoy Rog (Ukraine), needs to take into account the: timing of regional metamorphism with respect to the upgrade of BIF to high-grade iron ore; significance and relationship of the proto-ore to the hydrothermal alteration minerals and zonation and the process of iron enrichment; source and oxidation state of the hydrothermal fluids that caused the iron enrichment; types of geochemical processes that caused the hydrothermal alteration and iron enrichment; and significance of the widespread carbonatisation of the host rocks as a prerequisite for high-grade BIF-related iron mineralisation.We argue that a unifying model for high-grade BIF-related iron deposits cannot, presently, adequately explain the geological and geochemical characteristics observed in these deposits and, therefore, provide two end-member models that take into account the diversity of geological and geochemical ore deposit features. Our discrete model for the genesis of high-grade, BIF-related iron deposits is based on the interpreted tectonic setting, distinct hydrothermal fluid source of, and processes observed in, major BIF-related iron deposits. We divide two end-members: Proterozoic deep fault-magmatic (Carajßs) type, and Proterozoic rift-basin (Hamersley) type.Both end-members experienced varying degrees of deep weathering episodes that effected the hypogene enrichment and, ultimately, yielded the high-grade iron ore mined in many places today.

Jan 1, 2005

By P Joyce, A S. Ray, P S. Thomas, J Haggman

Climate change and global warming present a significant challenge as unsustainable levels of greenhouse gas emissions arising from human activities continue to be emitted. The cement industry is responsible for between five and ten per cent of annual world carbon dioxide emissions; most arising from the manufacture of Portland cement (PC). An effective way of reducing emissions is by incorporating supplementary cementitious materials (SCMs) as partial PC replacements. SCMs are silicate or aluminosilicate based pozzolanic materials which, in finely divided form, combine with water and calcium hydroxide (lime), liberated by cement hydration, to form compounds exhibiting cementitious properties. Pitchstone is such an aluminosilicate and has the potential to act as an effective pozzolan for partial replacement of PC. In North Queensland, Australia, a vast deposit of pitchstone is mined and processed for expandable perlite aggregate. During the classification stage of the excavated natural material, waste pitchstone fines (PF) less than 0.5 mm in size are generated. This study evaluates the waste PF as a viable, eco-friendly pozzolan for the partial replacement of PC. The reactivity of the PF is compared to fly ash (FA), using the pozzolanic compressive strength activity index (SAI) after seven, 28, and 91 days ageing at 20 per cent and 40 per cent PC substitutions. PF was found to be comparable to FA as a pozzolan at 20 per cent PC substitution at all ages tested. However, for the 40 per cent substitution blends significant strength was only achieved at 91 days ageing for the FA blend. The pozzolanic reactivity was also investigated using thermogravimetric analysis to determine the degree of free lime present after 91 days. In all cases where an SCM was added, the free lime was observed to be consumed with increasing age.

Jan 1, 2008

By J Davidson

Ion exchange using strong base resins is a well established technology for the recovery and purification of uranium from sulfuric acid leach liquors. Production of uranium at the Beverley Mine in South Australia includes acidic in situ leaching, ion exchange and uranium precipitation. The salinity present in the groundwater results in a relatively high concentration of chloride in the leach liquor reporting to the ion exchange plant. The impact of chloride on the ion exchange process is discussed in this paper. The results presented show that an increased chloride concentration in the lixiviant solution feeding the ion exchange plant leads to increased uptake of chloride by the resin during the loading cycle. At the highest chloride concentration studied (7.5 g/L Cl) chloride took up to 60 per cent of the resin loading sites. The impact of the chloride can be summarised as follows: for a given uranium concentration in the lixiviant feed solution, the uranium loading decreased with increasing chloride concentration; a consequence of decreased uranium loading is an increase in the frequency of elution, with an associated increase in elution reagent costs; and for a given elution efficiency, the uranium concentration in the barrens is expected to increase with increasing chloride concentration.A few options were examined to counteract the impact of chloride: an increase in elution efficiency was targeted to reduce the amount of uranium returning to the loading circuit; increasing the pH improved uranium loading, but this was found to also increase iron extraction; and preliminary screening of alternative resins showed that the higher the theoretical ion exchange capacity of the strong base resin, the higher the uranium loading.Work is continuing on uranium recovery from saline leach liquors, specifically investigating the performance of alternative resins.

Jan 1, 2005

By T J. Sheer

Water vapour refrigeration (systems using water as the refrigerant) could potentially be used to provide chilled water at underground locations in mines, as an alternative to conventional refrigerators using refrigerants such as R-134a. The use of water as both the primary and secondary refrigerants is attractive in concept since direct-contact heat exchangers could be used, yielding higher coefficients of performance. The disadvantage of water is the very high specific volume of the vapour at low pressures, which leads to great challenges in compressor design, as has been reported previously in the context of slurry-ice plants for mine applications (Ophir and Koren, 1999). Steam ejectors have long been known as alternative compression devices for refrigerators, but no work has been done previously on the possibility of using ejectors powered by high-pressure water, which is readily available in mines from long pipe columns in vertical shafts. This paper presents the results of a laboratory investigation into the use of high-pressure water as the motive fluid in an ejector refrigerator. No previously reported liquid ejector system has achieved subcooling of the process fluid, ie a reduction in fluid temperature within the evaporator to a level below that of the motive fluid. In contrast, the present work demonstrated that subcooling could occur at motive water pressures above 5 MPa. Mine cooling applications were considered and it was concluded that while this concept would not be feasible as a mine-wide cooling source, there could be specialised applications where it would be beneficial. One application would be to cool backfill and thereby reduce the heat load at the working face. In this case the best performance would be achieved by using the ejector in combination with an energy recovery system such as a Pelton turbine or a three-chamber pipe feeder.

Jan 1, 2005

By L Huang

"Successful rehabilitation of tailings landforms of tens to thousands of hectares in size at base metal mines is critical to mining companies’ ‘social licence to operate’. Rehabilitation technology used is closely related to both the economic sustainability of the mining company and the ecological sustainability of the mined environment. Conventional technology to rehabilitate mine waste landforms is costly and constrained by the availability of soil (to reconstruct root zones) and clay materials (to reconstruct compressed layer). Depending on mine waste properties and site-specific resource availability, it is not uncommon to cost A$0.1–0.5 M/ha for the establishment of conventional cover systems over mine waste domains, which often accounts for large proportion of the total closure costs. This can lead to costs approaching several hundred millions dollars for rehabilitating larger tailings and acidic waste rock using conventional cover systems.The present extended abstract proposes a suite of new technologies to tackle the problems outlined above and discusses critical factors in successful rehabilitation from substrate levels to the whole landform performance, in two key aspects:in situ engineering of tailings soil to offset/reduce materials requiredin situ chemical engineering of massive hardpan layer through alkali-activation and mineral gel cross-linking network mechanisms to encapsulate reactive tailings and achieving sustainable hydro-geochemical stability in root zones.This aims at functionally replacing the roles of the compressed clay layer and capillary breaks in conventional covers. These technologies would improve both the economic and ecological sustainability of mine waste rehabilitation, thus addressing the triple-bottom line of mining and mineral processing industries not only in Australia but other countries.CITATION:Huang, L, 2016. Emerging technology for economic and ecological sustainability in the rehabilitation of metal mine tailings, in Proceedings Life-of-Mine 2016 Conference, pp 128–131 (The Australasian Institute of Mining and Metallurgy: Melbourne)."

Jun 28, 2016

By C Zhang, I Canbulat, S Saydam, H Yu, H Chen

Natural rocks are frequently exposed to groundwater and complex geological conditions. Environments with water presence are more susceptible to chemical corrosion, which notably affects rock’s micro properties. Generally, the pH of acid mine drainage in hard rock mines can be low to 5, and the pH of quarrying waste deposits can be below 3. With the expanding scope of mining engineering in aquifers and salty areas, chemical corrosion can also caused by different types and concentrations of anions. The anions can significantly affect rock’s mechanical properties. Therefore, it is critical to emphasise the impact of anion and acid on the mechanical and micro characteristics of rock. This paper commences with an introduction to representative corrosive environments. Then the UCS tests are conducted on granite samples corroded by chloride ions and sulfate ions. Anion has negative effects on the strength of granite. The reason is that certain minerals can react and be dissolved by anions and hydrogen ions, such as Al2O3. Furthermore, the scanning electron microscope (SEM) shows that the roughness of the fracture surface increases with the anion concentration. The effect of acid is notably more pronounced than anion on the micro properties of granite. The initiated fissures and pores also increase with the concentration of SO42- and Cl- ions, which is the micro explanation for the impact of anion on rock strength and stability. Subsequently, the permeability of the granite specimens is tested. The reason that granite performs insensitivity to acid and anion is attributed to its low permeability and high content of inactive oxides, such as quartz. To summarise, anionic and acidic conditions can slightly deteriorate the mechanical and micro properties of granite. While SO42- demonstrates a higher level of corrosiveness on granite than Cl-.

Sep 1, 2024

By R Huntley, D Sims

Pajingo gold mine produces over 240 000 oz Au per year from underground mining using longitudinal bench stoping methods with a 15 m sublevel interval. Average mine head grade is around 12 g/t Au, contained within quartz veins between 0.5 to 16 m wide. The veins dip steeply (>60¦) and exhibit strike variations which lead to many curved and meandering drive/stope geometries. Unplanned dilution at Pajingo is predominantly controlled by fault planes that subparallel the vein and commonly lead to slabbing failure from the stope walls. Initial efforts at determining maximum spans were based on using the Stability Graph method of stope stability. However the method had a number of shortcomings that did not address mine site observations, including previous mining, interaction of different joint sets and the presence of discrete shears which resulted in poor prediction of stability. A method was developed to rate the risk of dilution for a stope based on observations made in the ore drives. The method utilises profile mapping of the ore drive, structural features observed and the orebody itself, on 10 m spaced sections along the ore drive. A matrix of factors determines the dilution risk for stoping at the time of mapping and the rating is transferred to longsection plots in the office. The dilution risk rating is used to determine the position and density of cable bolt support aimed at lessening the risk, and can be used to review blasthole designs prior to finalisation. The method has been used for more than two years and has proven to be a good indicator of potential unplanned dilution (ie waste outside of ring design). A recent review of the dilution risk mapping process has indicated it is assisting in reducing the impact of dilution at the operation and has the scope to be utilised further in the design process.

Jan 1, 2002

By K Hskansson

In earlier studies along a mining region recipient (the river VormbScken, northern Sweden), the fraction of certain trace metals recovered in the particulate phase has been found to increase with increasing concentrations of particulate iron. This study was conducted to see if the pattern could be reproduced by adding minor amounts of ferrous iron, simulating groundwater inputs. When the iron is oxidised in the near neutral river water, it will form iron oxyhydroxides and precipitate. Trace metals may be either co-precipitated along with the iron, or adsorbed onto the freshly formed precipitates. If this is the case, such a mechanism may be incorporated as a part of a final polishing step in a mine drainage treatment system based on natural attenuation processes. The experiments were performed at 0¦C and 22¦C, on authentic river waters collected during the winter and summer of 2002, respectively. In order to investigate the influence of particles and bacteria initially present, filtered river waters (4 solution were added to the experimental beakers, increasing the iron content of the waters by 0 - 1.5 mg/L. The oxidation and precipitation processes were followed by means of filtration (0.2 ¦m) for up to seven days. In order to be able to compare the experimental results with the actual field situation, on both experimental occasions, surface water samples were collected also from three stations situated along the river. The samples collected were analysed for iron, calcium, and trace metals by AAS and ICP-MS. The iron oxyhydroxides formed in the experiment did not influence the partitioning of As, Cu, and Pb to the same extent as the particulate iron encountered along the river appeared to do. Cd and Zn were recovered mainly in the dissolved (

Jan 1, 2003

By D E. Ralph, D-J Kim, G-J Ahn, Y-H Rhee

The amount of discarded dry batteries are presently found to be increasing globally and waste cathode active materials of the lithium ion battery industry are among them. Hydrometallurgical operations are being applied to recover the valuable metals from these waste batteries. To find an economic and environmentally friendly process, the bioleaching process was applied in the present investigation for recovery of valuable metals. Its principle is the microbial production of sulfuric acid and simultaneous leaching of metals. Bioleaching of spent lithium ion secondary batteries, containing LiCoO2, has been studied in this investigation. A new method for recovery of cobalt, potentially the basis of an economic and environmentally friendly process was examined. The present study has been carried out using chemolithotrophic and acidophilic bacteria Acidithiobacillus ferrooxidans, which utilises elemental sulfur and ferrous ion as the energy source to dissolve metals from spent batteries. Bio-dissolution of cobalt was found to be faster than lithium. The effect of initial Fe(II) concentration, initial pH and solid/liquid (w/v) ratio were studied in detail. Higher Fe(II) concentration showed a decrease in dissolution due to co-precipitation of Fe(III) with the metals in the residues. Similarly, at higher initial pH values and higher solid/liquid ratio (w/v) metal dissolution was found to be inhibited. The optimised conditions for bio-dissolution were solid/liquid (w/v) ratio û 10 g/L, initial Fe(II) concentration û 3 g/L, elemental sulfur û one per cent (w/v) and initial pH û 2.5. In the optimised conditions, cobalt dissolution was observed to be about 60 per cent, whereas that of lithium was ten per cent after 20 days. A first order kinetic model was derived to study the rate of dissolution of both the metals.

Jan 1, 2006

By McIlveen GR

The water pollution hazard posed by the derelict Conrad mine site, to the water and associated stream sediment of Borah and Maids Creeks and the nearby Copeton Dam storage, has been assessed. Mine water, tailings and tailings dump leachate have polluted water and stream sediments in Borah Creek downstream of the mine site. Acidity, arsenic, copper, lead, iron, silver and zinc are the principal pollutants. Under dry and low flow conditions, mine water was found to be the dominant polluting source, however, leachate and run-off from tailings dumps were also significant under and following wet conditions. Soluble arsenic, lead, iron and silver species in mine water and leachate were found to be rapidly incorporated into sediments, but acidity, copper, and zinc persisted in the creek water. Under low flow conditions, the water of Maids Creek is polluted with copper and zinc (up to 4.4 and 34 mg/l for copper and zinc respectively) and the pH is decreased (from pH 5 - 7 to pH 3 - 6) by entry of Borah Creek water. Values found in Maids Creek were variable and related to flow regime and distance downstream from Borah Creek confluence. Water in Copeton Dam storage, having a much larger volume of water with a higher bicarbonate buffering capacity (50mg/l versus 15mg/1), is not affected by entry of Maids Creek water. Polluted sediment from Borah Creek has contaminated Maids Creek for 2km downstream to Copeton Dam storage. Stream sediment downstream of the Borah Creek confluence, contains up to 1.0% As and 1.4% Pb in the less than 200 micron size fraction. Under high flow conditions, arsenic was found to be moved out from the mine site as insoluble species, associated with suspended sediment in Run-off.

Jan 1, 1988

IT is most remarkable and valuable property of mediurn and high carbon steels that they should be so susceptible to heat treatment, the wide range of variability in tenacity, ductility, etc, due to the normal influence of the carbon in the untreated material being enormously inereased thereby.The physical properties of steel and other metals are much more closely related to their structure than to their ultimate analysis.For instance, we may by chemical analysis determine the carbon content of a steel to be 0.5% ; but this information alone is insufficient to enable us to say what are the physical properties of the metal.Such a steel may possess 11 tensile strength of anything from 35 tons per sq. in., with much ductility, up to 80 tons per sq. in., with practically no ductility, according to its heat treatment. A microscopie examination, on the other hand, would show the structural composition of the steel, from which its physical properties could be approximately deduced. From this it will readily be understood that the microscope has played an important part in the development of modern rnetallurgy, and to-day it is in daily use for the examination of metals and alloys in the laboratories of most works dealing with the rnanufaeture and working of metals.THE IRON-IRON CARBIDE EQUILIBRIUMTo understand fully the mode of occurrcnce of the different constituents of a knowledge of the Iron-Iron Carbide equilibrium diagram (Fig. I) is essential to heat-treat steel successfully and to interpret microstructures correctly such a knowledge isabsolutely indispensable.A portion of the Iron-Iron Carbide Diagram, dealing with steels below 1000 and containing up to 1 carbon is given below.It should be noted that the diagram deals entirely with pure carbon steels, and does not indicate the influence of the usual so-ealled "impurities" present in all commereial carbon steels...

Jan 1, 1926

A significant resource of uranium has been discovered within a buried palaeochannel located in the south western corner of the Officer Basin of Western Australia by PNC Exploration (Australia) Pty. Ltd. The mineral- isation is redox controlled and is hosted by Eocene organic rich paludal sediments. Prob- able insitu reserves are 13,000 t of contained uranium with an average ore grade of 0.12% at a cutoff grade of 0.03% U. The Mulga Rock palaeochannel has been traced for at least 100 km beneath the Quaternary surficial cover. The main channel is horseshoe shaped with the channel arms vary- ing from 5 to 15 km in width. The western arm connects to the Lake Raeside-Ponton Creek drainage system, whilst the eastern arm'is open to the south. The headwaters of the palaeo- channel are thought to have been the Lake Minigwal drainage system, prior to its capture by the Lake Rason system. Differential.erosion of the basement rocks during the Late Cretac- eous to Early Tertiary strongly influenced channel shape and resulted in the main channel being confined to a Permian,mudstone filled valley. Upwards of 100 m of fluviatile sediments accumulated within the palaeovalley during a period of subsidence in the Early Tertiary. Three broad stratigraphic units have been re- cognised within the channel: 1. An upper unit of fluviatile sands with interbedded lacustrine sediments, which have subsequently been wholly oxidised and variably silicified and ferruginised. 2. A middle unit of lacustrine to paludal sediments, which host the main mineral- isation. 3. A basal unit of fluviatile gravels and sand. The presence of excellently preserved Nothofagidites in organic rich paludal sediments from the middle unit, suggest that unit was laid down in a non-marine, fluviatile, humid environ- ment during the Middle Eocene.

Jan 1, 1988

By J Webb

Anoxic limestone drains (ALDs) have been widely used in the passive treatment of acid mine drainage (AMD), but their effectiveness has often been less than anticipated. Iron hydroxide often precipitates around limestone particles and inhibits neutralisation. To determine the conditions under which iron hydroxide precipitates, a small-scale laboratory ALD system was built to enable a detailed examination of the chemistry of iron within the drain. For one experiment, a mixture of limestone and quartz was introduced to the drain to assist in the determination of the key mechanism governing iron precipitation. Synthetic anaerobic acid mine drainage containing Fe2+ (~130 ppm), SO4 2- and H+ was pumped at a rate of 30 mL/min up a 90 cm tall, 15 cm diameter vertical column filled with limestone gravel of 98 per cent purity. Three sampling ports were fitted at equal intervals along the column; water was periodically extracted for analysis at the sampling ports over an 11-hour period. Experiments were run at influent pH levels of 2 and 4. Results show that acid neutralisation to pH greater than 6 occurred at the inflow end of the drain. The greatest amount of iron precipitation (19.5 per cent) also occurred in this area. The lack of iron precipitation on the quartz surfaces in the quartz/limestone mixture indicates that neutralisation is the key mechanism for the precipitation of iron hydroxide on limestone particles. A pe-pH stability diagram derived for the laboratory ALD system indicates that ALDs will not be effective for AMD with pH 2. Influent waters with pH 2 require a pe of -2 (Eh: -118.4 mV) to avoid Fe precipitation upon neutralisation. Influent waters of pH 4 require a pe between -2 and -4.

Jan 1, 2003

Basicity(aO2−) has been known to affect the physicochemical properties of molten slags in the metallurgical processes. However, because of the impossibility of direct measurement of single-ion activity, various indirect measures such as capacity, redox equilibrium of transition metal ions, activity of basic oxides, and (theoretical) optical basicity have been proposed; but these basicity measures have been restricted within slag systems and the interaction between measuring elements and slag components has affected the quantitative estimation of slag basicity. Recently, since it was reported that solubility of noble metals in molten slags could be an indirect measure of basicity, the influence of slag basicity on the solubility of platinum and silver has been reported. The reaction mechanism of platinum dissolution into basic slags has been reported, whilst that in acidic slags has not (Nakamura and Sano, 1997; Sano and Nakamura, 1997; Nakamura et al, 1998). Richardson reported that the solubility of metals such as cupper, gold, silver, and lead in the CaO-SiO2-Al2O3 slag was presumably dependent on the atomic radius and the accommodation ability of the silicate network (Richardson, 1974). Swinbourne and You measured silver solubility in the Na2O-SiO2 slag over a wide range of oxygen partial pressure and suggested that silver would be present as both Ago and Ag0.5 in the slags (Swinbourne and You, 1999). For brevity, these previous works discussed the dissolution mechanism of silver into the slags based on the existence of silver as a neutral or molecular species. However, because the almost chemical reactions occurring in the slag are affected by the basicity, the reaction formula with O2- ion is required based on the ionic characteristics of the slag such as desulphurisation and dephosphorisation reactions as given in Equations 1 and 2, respectively.

Jan 1, 2000

The Osborne copper-gold deposit (within the Trough Tank project area) is located in the Cloncurry Shire about 195 kilometres south-east of Mount Isa. It is hosted by Proterozoic metasediments of the Eastern succession of the Mount Isa Inlier. The deposit is overlain by 25-40 metres of Mesozoic cover, so it represents a true "blind target". Placer Exploration has 100% outright ownership of the property, having purchased the remaining 10% interest in the property from Shell in early 1993.Intensive exploration, both surface and via drilling at Osborne, has taken place since 1985, when CSR Limited Mineral Exploration and Development Group (acquired by Placer in 1988) entered into a joint venture with Billiton Minerals. Exploration effort from 1985 to June 1988 outlined a 20 kilometre strike length of magnetic horizons, in what was termed the North-East, Central and Southern anomalies, which were drilled with weak indications of copper-gold mineralization in the North-East anomaly. During the later half of 1989, four core holes were drilled into the shallower northern partofthe North-East anomalywhere previous drilling had outlined economic intersections of mineralization. These holes encountered high-grade copper-gold mineralization confirming the potential for an economic deposit to be hosted within the ironstone sequence. Further drilling involving over 400 holes (100 kilometres of drilling) has brought the deposit up to its present resource status.The current resource inventory is 36 million tonnes grading 2.0% copper and 1.0 grams pertonne gold and includes a high-grade zone of 13 million tonnes grading 3.6% copper and 1.5 grams per tonne gold. The discovery of this potential economic mineralization resulted from a persistent exploration effort based on indications that a large mineralizing system existed within a sequence of ironstones.

Jan 1, 1993

By A Buckingham, R M. Hancock

The underground Sunrise Dam gold mine commenced in October 2003 to extract ore from a series of orebodies with various dips, widths, and ore grades over a strike length of 1.5 km. To successfully operate flat stopes it was identified that a means to extract ore left behind after blasting in stopes with dips ranging from 15 to 40 degrees was needed. Various options were available, which included a bulk water cannon, hand held high-pressure water jet, remote controlled small dozer, several mini excavators and finally a specialised remote controlled excavator from the demolition industry. Trials were commenced for the bulk water cannon option in 2006 that proved that the concept worked, however, the system was too cumbersome to set up for use in cycle with production. Hand washing down using mine (low pressure) water with a two-inch bullhose proved of limited value. The small, one metre high remote controlled dozer as used in South Africa was reviewed, but the steepness of most of the stopes precluded this machine. The hand held high-pressure water jet option is still being investigated; with safety factors still being addressed. Several mini excavators were trialled to clean out the flat stopes with generally poor results, the machines being either too large to fit in the drives and pull ore down or too small with too short reach to effectively and efficiently pull ore out of the stope. In early 2007 a Brokk 330 remote controlled excavator was trialled on site with the low profile of the machine and unique arm configuration proving an effective tool for pulling ore from the footwall of short, flat stopes. A Brokk 330 remote controlled excavator was purchased in late 2007 and is currently in operation.

Jan 1, 2008