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A field trial of the prompt neutron-gamma SIROLOG technique was undertaken by the CSIRO - Division of Geomechanics at Callide Coalfields during July 1989. The trial investigated whether the sonde could reliably be used for the determination of Ash and Iron Oxide (Fe2O3) in coal seams, which had a highly variable iron content. Ten boreholes were logged, being water filled of a nominal diameter of 120 mm. The logging probe employed a 1.6 ¦g 252Cf neutron source and a 51 x 51 mm BGO detector. The source to detector distance was 15 cm. The results from one exploration borehole at the Dunn Creek Mine are discussed in the paper. The rms deviations for ash and iron determination between the neutron-capture predictions of the geophysical logs and the laboratory - chemical assays were 1.9 per cent Ash and 0.88 per cent Fe respectively. Using existing empirical equations which relate iron oxide concentration in coal ash to Initial Deformation Temperature (reducing conditions) at Callide, it may be possible to indirectly determine ash fusion properties as least as accurately, on a more detailed ply-by-ply basis, and more cost competitively than current laboratory techniques allow.

Jan 1, 1991

By D Gagnon, P Bouchard, F Vanier, E Soares de Lima Filho, J El-Haddad, M Sabsabi, G J. Wilkie, A Beauchesne, A Hamel, A Blouin, T Vaillancourt, F Boismenu, A Harhira, A Plugatyr, C Padioleau

Quantitative mineralogy is an established discipline in the geosciences and is aimed at providing mineral grade and texture information for geological and mineral processing applications. The two core technologies underpinning Quantitative Mineralogical Analysis (QMA) are Scanning Electron Microscopy (SEM) in combination with Energy-dispersive X-ray Spectroscopy (EDS). Technologies such as QEMSCAN and MLA are now routinely used to optimise the performance of large-scale mineral processing plants in the base and precious metal sectors. One of the major disadvantages of the QMA methods used today is extensive sample preparation requirements which make application of this technique to real-time mineralogical characterization not feasible. A breakthrough has been achieved by the National Research Council Canada in collaboration with CRC ORE by developing a novel Laser Induced Breakdown Spectroscopy (LIBS) based technology capable of real-time mineralogical characterization of process streams without sample preparation. The potential applications of this technology include, but not limited to, in-pit muck piles, underground draw points, cross-belt analysis as well as slurries. This paper describes the development of the LIBS-based technology from a proof-of-concept (TRL2) to the construction of a prototype sensor and its validation in a simulated environment (TRL5). Future work is being planned to test and further validate the LIBS sensor on a mine-site which will progress the technology to its next readiness level (TRL6).

Nov 10, 2020

By M Gwynne

McArthur River Mine is located approximately 50 km south-east of the NT township of Borroloola and approximately 120 km from the Gulf of Carpentaria. The mine hosts a series of layered shallow dipping tabular orebodies, with current reserves of approximately 22 Mt, grading 13.6 per cent zinc, 6.3 per cent lead and 65 g/t silver. Owing to economic considerations, the lower most orebody (No 2 orebody) has been selected for initial mine production. Following the completion of the No 2 orebody, mining will transfer to the lower grade and metallurgically more complex No 4 orebody. The mine employs a total of 235 people throughout the underground and surface areas. The majority of the workforce work a fly-in/fly-out, seven-day- on/seven- day- off roster with 12-hour shifts. Presently, a further 18 contractors are involved in trial mining areas. An apparent dip room and pillar technique has been selected as the primary mining method. Officially opened in September 1995, the current production rate of 1.2 Mt per annum will eventually escalate to 1.5 Mt per annum. Though most production is achieved through the use of conventional loaders, trucks and jumbos, the recent development of methods utilising scrapers, hand held machines and modified jumbos has produced encouraging results in steeper dipping areas of the mine. Initial production has been hindered by several factors including extensive and largely unpredictable faulting, worse than expected ground conditions and difficulties with some mining equipment. Compounded by the relatively thin 3 m ore seam, initial mining resulted in high dilution and poor production. This paper describes the development of unique planning and production systems that were evolved in order to overcome these problems and achieve the targeted production rates and head grade.

Jan 1, 1998

In Australia we usually define "resource" in purely material terms, and rarely relate it to intellect and human capacity. We look at the sheer abundance of our natural resources and are satisfied with the feeling that we don't really need-to rely on using our brains. Certainly our country is fortunate to have the mineral resources it does, but in many ways Australia's worst enemy is its "lucky country" syndrome because we tend to underutilise the great resource we have in the capacities of our people. Raw material exports will undoubtedly continue to contribute a major share of our export revenue, but to harness the riches our country has to offer most effectively we need the vision and planning necessary to bring together our material and human resources. There is a need not only to find, exploit and process our minerals economically, but to turn as much of our mineral wealth as possible into high value products before it leaves the country. In particular we must use our brainpower if we want to maximise economic benefit from and political influence over the strategic minerals which leave our shores. In the past we have been successful in finding and exploiting minerals because our mining industry has been in the forefront of private sector research and development. But if Australia is to have an advantage over other mineral rich countries in insulating itself from the effects of cyclical swings in commodity prices, then the future of the industry must lie even more in technological sophistication rather than depending. on such considerations as size and location of mineral deposits. To survive, our mineral industry must have the foresight and resourcefulness to make its own luck. There are two keys to increased efficiency in exploration and production and in further processing methods: enhancement of the skills of the workforce and continual improvement of R&D.

Jan 1, 1986

By V Seedwell, P H. McGuckin

The Broken Hill Proprietary Company Limited (BHP), started as a silver-lead- zinc mining company in Broken Hill, New South Wales, Australia in the 1880s. Since then it has diversified into the resource industries of steel, iron ore, coal, petroleum and copper. BHP World Minerals, is a Business Group of BHP which is one of the worldÆs largest and most diverse mineral resource enterprises. BHP supplies raw materials for steelmaking, copper concentrate and other mineral commodities to customers in more than 45 countries. BHP World Minerals has operations throughout the world - in Australia, the United States, Brazil, Zimbabwe and Canada. Commodities produced by BHP World Minerals currently include silver, lead, zinc, titanium minerals, platinum group metals and coal. The challenges in the improving performances in safety arena are common to our industry and BHP operations. This paper outlines the vision and values that have been fundamental in assisting BHP Cannington search for and implement a safety system addressing behavioural matters.

Jan 1, 1998

By Theophili CN, Kapenis AP

Seismic tomographic imaging has been applied to determine the blast induced damage zones in bauxite pillars in underground mining. At the retreating stage, when pillar dimensions are reduced from 8 x 8 m to approximately 5 x 5 m, the' seismic tomographies reveal, through measurements of the P-wave velocities which is a measure of the degree of fracturation of the pillar rock mass, the presence of three zones within each pillar. In the external zone, where velocities recorded are below 750 m/s. extensive pillar damage occurs which is attributed to both the growth and coalescence of pre-existing cracks and even the creation of new cracks in the rock mass. This effect is in agreement with literature, when considering the peak particle velocity as a criterion for rock failure in tunnels. In the intermediate zone, where velocities range between 7S0-1000 m/s, damage to a much lesser extent occurs which is due mostly to growth of pre-existing cracks and widening of their apertures. The inner zone, where velocities exceed 1000 m/s, is considered to be unaffected by blasting. Simple remedial measures of low cost, which are based on blasting mechanics are proposed to minimise the blast induced damage zone and consequently the transition zone.

Jan 1, 1995

A new test coke oven of seven cubic foot capacity is described. The oven was designed to simulate conditions in a central section of a battery oven and a special feature is the achievement of unidirectional heating from the flues on either side of the charge. The method of charging permits close control of charge conditions'such as bulk density and moisture content. These conditions, as well as coking conditions (e.g. flue temper- atures., coking time) must be varied to simulate conditions in different batteries, The effects of several variables on coke quality are discussed. Using test oven conditions corresponding to those of Newcastle steelworks batteries, good agreement was obtained between strength indices of test oven and battery cokes; for 17 tests, the average A.S.T.M. stability and hardness indices for the test oven coke were 38,5% and 69.7%, while those for the battery coke were 37.1.% and 67.6%.

Jan 1, 1969

By Bishop I, Toon S

To determine whether 130 felt earth tremors around Edwinstowe, Nottinghamshire U.M, which also experienced severe surface fissuring, were caused by coal extraction, a surface seismometer array was established around Thoresby Colliery. Over the next year, 785 microseismic events were detected. The spatio- temporal seismicity patterns are clearly associated with the commencement, continuing extraction and closure of faces. Of particular note are events which locate at the surface and appear to be related to the active fissuring. Events occur within days of commencement of production and cease when production finishes, with good correlation between face advance and hypocentral position. Naturally occurring microseismic events have also been detected up to 1 km ahead of active longwall faces in the Midlands using triaxial geophone packages grouted into the seam together with a surface seismometer in the top of the borehole. The quality of these data were very high and guided waves can clearly be seen with the dispersive characteristics associated with seam waves. In one experiment more than 2000 events were detected in only two days of monitoring even in a relatively noisy surface environment. This paper demonstrates how very accurate locations (5 10 metres) can be generated using three-component digital data from only one borehole. The surface seismometer and the borehole P-wave onset can give extra precision for the height of the event relative to the seam. The event distributions give a dynamic, three-dimensional image of the developing patterns of fracturing above, below and ahead of the longwall face with important implications for roof control, subsidence prediction and gas Migration.

Jan 1, 1992

By E M. Wightman, C L. Evans

A recent survey of mineral processors undertaken as part of the International Mineral Processing Council (IMPC) Education Commission identified mineralogy as one of the key skills required for mineral processors (the other key areas being comminution, flotation, physical separation, sampling and extractive metallurgy). Past experience in a number of operations has shown what can be achieved when the data outputs from mineralogical tools are coupled with people with the right skills who can transform the data into actionable information. This paper reviews what has been done successfully in plant operations over a period of more than four decades and gives examples of a range of applications with both long and short-term objectives. The examples demonstrate the usefulness of mineralogical data – both basic and complex – in optimising mineral processing operations, whether the data are applied in a simple analysis or in more complex modelling. Similarly, the examples show the range of options available for operations to access the mineralogy information they need – through in-house experts and equipment based in centralised technology centres, through on-site equipment and experts or through external laboratories and consultants.The examples from industry highlight the huge potential benefit of including mineralogy as an integral part of operational best practice and raise the question of why more operations do not utilise what should be readily available data. Successful application of mineralogical data requires skilled people to generate relevant data of the required quality, together with skilled people to interpret the data (this may be the same person). And, as in any project, corporate recognition of the value of this approach to best practice is required to ensure continuing support. With fewer university courses providing courses in process mineralogy to undergraduate mineral processing engineers and chemical engineers, there is an increasing lack of knowledge about what mineralogical information is needed, how to get the required data and, equally importantly, how to turn the data into useful information.CITATION:Evans, C L and Wightman, E M, 2018. Understanding minerals in mineral processing – the basics and beyond, in Proceedings 14th AusIMM Mill Operators' Conference 2018, pp 363–376 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 29, 2018

By Abbott T. M

Alcoa of Australia operates three Alumina refineries in the South West of Western Australia at Kwinana adjacent to the South suburbs of Perth and at Pinjarra and Wagerup in rural settings 100 and 150 kilometres south of Perth respectively (see Figure 1). Alcoa's total alumina production is currently around five million tonnes per annum and this will increase to 5.5 million tonnes by early 1990. Further expansion of production is likely if current world aluminium demand trends continue. Alcoa's refineries utilise bauxite mined in the nearby Darling Range which is low grade by world standards having around 32 % by weight extractable alumina (by comparison Weipa bauxite yields around 55% alumina). This means that for every tonne of alumina produced two tonnes of solid wastes remain and therefore while we in Western Australia can boast of hosting the largest alumina industry in the world with around 18% of total world production we suffer from having the lion's share or 40% of the world's bauxite residues to dispose of. In its Western Australian setting the management of these residues in a manner which is acceptable to the community creates many challenges. These are primarily due to the mass and volume of waste produced, its chemical and physical characteristics and the environmental features of the local area including close proximity of neighbours, competing land uses and the presence of natural resources such as surface water and groundwater. In addition the trend towards more stringent statutory environmental controls and greater political and community awareness of environmental issues means that we must be able to demonstrate improvements that will reduce the considerable adverse impacts of past practices. Of course we must also try to keep the overall cost of residue disposal as low as possible to maintain our competitiveness with refineries which may have much smaller volumes of waste to dispose of and less environmental constraints.

Jan 1, 1989

By Smith I. T

Mine operators have long recognised that the results achieved in primary blasting are critical to subsequent mining activities. With the introduction of "in the hole" drills under- ground and the advantages offered by the use of water gels in conjunction with ammonium nitrate-fuel oil (ANFO) explosives, new mining methods have been developed and enabled improvements in older methods. Pumpable water gels have been used with varying success underground. These gels allow a high loading density even in ragged bore- holes. The problems encountered with slumping in upholes is recognised so the current trend is to use these gels in downholes where wet holes are prevalent. Cartridged water gel technology has advanced to the point where it has allowed the replacement of nitroglycerin (NG) based explosives and pumpable water gels. Today, gels can be made as a tampable product for use in development headings or as a slump- ing product for downholes to give an effective coupling. With the introduction of the Tovex« pneumatic loaders, the problems associated with a pumpable gel were eliminated and gave the user the ability to alter his loading density.

Jan 1, 1977

By A Jyoti, J R. Black, R R. Haese, E O. Ansah

Copper (Cu) is a critical metal in the transition to a low-carbon power supply. Presently, low-grade copper sulfide ores account for almost 80 per cent of the global reserves. Large amounts of water are required to process these low-grade copper ores. The mining industry utilises lixiviants from recycled water from different sources to conserve water, whilst enhancing Cu recovery. Some utilise intermediate to pregnant leach solutions, sea water, and processed water from electrowinning circuits with highly variable concentrations of ions. Previous studies have highlighted the formation of precipitates that passivate the surfaces of minerals in these low-grade copper ores and/or block flow paths for lixiviant during heap leaching. In this study, we utilised concepts of phase replacement to devise an innovative means of controlling precipitation and increasing copper recovery using industrial brine as opposed to freshwater. We propose the formation of Al-rich phases (such as AlSO4 + or alunite) to replace iron sulfate and iron hydroxysulfates (such as jarosite) during the chalcopyrite dissolution-precipitation mechanism. The rationale is to have available Fe3+ throughout the chalcopyrite leaching process. We tested this method by carrying out various batch experiments using CaCl2, AlCl3, and NaCl industrial brine types compared to freshwater and explored the capacity to leach Cu from chalcopyrite. There is higher Cu recovery during oxidative leaching of chalcopyrite in industrial brine with 91 per cent recovery using AlCl3-rich brine, 84 per cent with NaCl-rich brine, and 56 per cent with CaCl2-rich brine as compared to 35 per cent recovery using freshwater. In the absence of Al3+, various forms of iron sulfates, and jarosite are formed, reducing the availability of Fe3+ for chalcopyrite dissolution. The introduction of Al3+ leads to the formation of AlSO4 + species, thus lowering sulfate activity and the tendency for K-jarosite formation.

Aug 24, 2022

THE area of the State of New South Wales is not great, nevertheless it has very large and important Mineral Resources. This is the more noticeable when the values of the annual mineral production from the individual States of the Commonwealth arecompared with the value of the New South Wales production. The principal minerals mined now are not gold, copper, and tin, as they were in the early years following the gold rush of 1851, the centre of gravity of commercial mineral activity having moved to coal and "oil-shale," water, limestone (with cement), silver-lead-zinc cadmium, sulphur, slate and other building and ornamental stone, road materials, and clays.From small areas totalling only 650 sq. miles, coal to the extent of 311,000,000 tons, valued at £151,000,000, has been won.The estimate of actual and probable reserves by the Mines Department within an area of less than 1000 sq. miles is about 14,000,000,000 tons, while the potential reserves within the remaining 15,500 sq. miles of concealed coal fields must be enormous. Even taking into account only the actual and pI:obable reserves in the 1000 sq. miles known, and assuming a depletion at the rate of 350,000,000 tons a year, or somewhat greater than that of the British Isles at present, and assuming an average value of £1 a ton, with money at 5% compound interest, then the present value of this coal (40 years of depletion) would be £5,575,000,000 approximately: truly an enormous present value for a business of 40 years, dealing only with 1000 sq. miles of country. The location of the main coal basin in New South Wales is one of great strategic importance. It lies almig and near a seaboard, with excellent facilities for anchorage; the coal is of very high quality, and is readily accessible; the climate is admirable. Were this same coal at Port Darwin, its commercial importance would not be be pronounced.

Jan 1, 1926

By Blockley J. G, Laeter J. R

The history of the Ph-Cu-Zn mineralisation in the orthampton Block of Western Australia has been further investigated. It was hoped that (1) Rh-Sr studies on partially-remelled granulites, wall-rocks to the dolerite dykes, should date the dolerite intrusion, (2) Rh-Sr data on hydrothermally-altered dolerite should date the sulphide mineralisation, (3) Pb model ages on the galenas might provide an independent dating of the mineralisation, in addition to any geochemical information that might be derived. Only the second dating aim was fulfilled, but the Pb isotope data, when combined with the Rh-Sr data, have permitted deductions about U, Th and Pb abundance changes during the regional metamorphism, and about a possible source of the ore Pb. In detail the following has been found. (1) The partially-remelted granulitic wall rocks yield a scattered whole-rock Rh-Sr isochron which seems not to have been reset by the dyke intrusion (age 1037 ± 146 Ma, with initial Sr ratio 0.7171 ± 0·0054, MSWD = 111). This date agrees well with that reported previously for granulites from another locality; together theyestablish the time the metamorphic period closed. (2) The hydrothermally-altered dolerites yield a Rh-Sr whole-rock date 434 ± 16 Ma, with initial Sr ratio 0.7072 ± 0·0029 and MSWD = 31, taken as referring to the time of Ph-Zn mineralisation. This contrasts with a report of much older palaeomagnetic and K-Ar datings of the dolerite (not less than 550 Ma, possibly older) and suggests that neither the dolerites nor their heat have had any connection with the mobilisation of the Pbscavenging solutions. (3) The Pb isotope ratios of galenas from the ores yield a well-correlated regression which is not amenable to any of the model-age calculations. (4) The Pb-isotopic trends negate any genetic connection between dolerite and mineralisation, but the country-rock granulites could be the Pb source. (5) Combination of the Rh-Sr dates and the Pb data in a "simultaneous isochrons" construct permits the inference of major losses from the system during the regional metamorphism, in the order U>Pb>Th, with substantial homogenisation of the remaining Pb. This left a wide range in local UlPb and Th/U among the source rocks which eventually were scavenged by the mineralising solutions. (6) These geochemical deductions are shown to be compatible with previously-published information on the abundance ofU and Th in the Northampton Block granulites, which are thus seen to be credible as source rocks for the ore lead.

Jan 1, 1985

By J L. Mauk

The Favona adularia-sericite epithermal Au-Ag deposit is located at the southern end of the Hauraki Goldfield, about one kilometre southeast of the world-class Martha deposit. The deposit occurs in Late Miocene andesitic lava flows and local dacitic tuffs of the Waipupu Formation. In some places, post-mineralisation ash fall and ignimbrite, up to 50 m thick, cover mineralised rocks and andesite. We collected soils samples from 110 sites along eight traverses over Favona, and from three regional lines: two south of Favona, and one north of Favona.   Analyses of soils identify prominent enhanced concentrations of Au, Ag, and Hg, and lower enrichments of Sb and As. At Favona, Au and Ag appear to be highly anomalous in areas over mineralisation with Au concentrations greater than 100 ppb and Ag concentrations greater than 1000 ppb, whereas background concentrations are approximately 5 ppb and 50 ppb respectively. The background concentrations of Hg in soils are approximately 100 - 200 ppb, but in mineralised areas, Hg generally exceeds 200 ppb, and some soils contain greater than 600 ppb. Antimony shows enrichments, although weak, above known veins and As locally shows some enrichment above areas of known mineralisation. Therefore, soil sampling at Favona defines geochemical anomalies that correlate with the position of known mineralisation at depth. Thus, there is strong empirical support for the use of Au, Ag and Hg, and possibly Sb and As geochemistry to identify mineralised trends associated with buried deposits at other epithermal prospects.

Jan 1, 2007

By C Niemann-Delius

The problem of long-term open pit mine planning is a large combinatorial problem, which canÆt be solved easily by mathematical programming models because of the large problem size. In this paper a new metaheuristic algorithm, which has been developed based on the ant colony optimisation (ACO) and its efficiency, have been discussed. To apply the ACO process to a mine planning problem, a series of variables is considered for each block as the pheromone trails that represent the desirability of the block for being the deepest point of the mine in that column for the given mining period. During implementation several mine schedules are constructed in each iteration. Then the pheromone values of all blocks are reduced to a certain percentage and additionally the pheromone value of those blocks that are used in defining the constructed schedules are increased according to the quality of the generated solutions. By repeated iterations, the pheromone values of those blocks that define the shape of the optimum solution are increased, whereas those of the others have been significantly evaporated. By using this algorithm a high degree of complexities could be considered in objective function and constraints of optimisation model. In addition it can improve the value of the initial mining schedule up to 34 per cent for some cases in a reasonable computational time.

Sep 26, 2011

Thank you chairman, good afternoon ladies and gentlemen. In my talk this afternoon I intend to cover a brief history, some of the recent experiences and an overview of the McArthur River project.If we consider the themes of this forum, Obstacles and Opportunities, I can confidently say that in attempting to develop the McArthur River deposit Mount Isa Mines Limited (MIM) must have encountered almost every obstacle that can be imagined. However the large size and the high grade of the deposit has ensured an opportunity, from which it is very difficult to walk away from.The McArthur River Here's Your Chance (HYC) Deposit is located in the Northern Territory of Australia. It was discovered by Mount Isa Mines Limited geologists in 1955 and is one of the largest known sedimentary stratiform zinc-lead-silver deposits. The deposit has been the subject of numerous investigations and considerable expenditure culminating in a major feasibility study in 1979. There were a number of factors which prevented development, these being the size of the project, the fine grained mineralization, geographical location, market, social and capital cost. The latter had been estimated in the 1979 study to be $800 million at that time.

Jan 1, 1993

By S Matos Camacho, K G. van den Boogaart, R Tolosana Delgado, U Mueller

"The precise formulation of a geometallurgical optimisation problem is by necessity a simplification of reality. It includes implicit choices such as data availability or mining block geometry. Additional data can be orebody data, production data or market data. Often these choices are predetermined by the software, the workflow or the corporate culture, and as such are not even queried. There are several aspects that might play a role in the optimisation. They include not only the spatial model on which the selection of mining blocks and the potential mining sequence are based, but also the complexity of the processing model, the way in which uncertainty is treated, the scope of responsibility and the complexity of the model. In addition the timing of the optimisation and the availability (or lack thereof) of information will influence the outcome of any optimisation.We show that different modelling choices and different model formulations for the same mine can lead to very different processing choices, substantially different net present values (NPV), opposite investment decisions and so to overall different values for the entire operation. The selection of adequate simplifications and corresponding formulations for the optimisation problem is thus an important task in itself.For this purpose we introduce a method for quantifying the impact of certain simplifications prior to the optimisation. For example, the effect of mining block choices depends mainly on the spatial structure and the structure of the processing gain function. Both can be quantified beforehand. Based on the outcome, appropriate simplifications can be selected for the geometallurgical optimisation.CITATION:van den Boogaart, K G, Tolosana Delgado, R, Mueller, U and Matos Camacho, S, 2016. How Details of the Geometallurgical Optimisation Influence Overall Value, in Proceedings The Third AusIMM International Geometallurgy Conference (GeoMet) 2016, pp 303–312 (The Australasian Institute of Mining and Metallurgy: Melbourne)."

Jun 15, 2016

By J Boland

Polycrystalline diamond compacts (PDC) have been widely used as cutting elements in the drilling tools for the oil, gas, civil and mining industries because of their faster penetration rates and longer bit life. US Department of Energy reports that PDC bits account for more than one-third of the total footage drilled worldwide (US Department of Energy, 2004). However, non-thermally-stable diamond composites (NTSDC) have seldom been applied to geothermal drilling, since premature failures of such PDC cutters have been observed in hard rock formations. Several factors need to be considered to prevent premature failure of cutters and improve cutting performance when using PDC-based bits and other rock cutting tools. The first set of factors consists of the strength, density, stiffness, toughness and thermal resistance of the PDC and the rock. A second set relates to the complex behaviour of the bonding between the PDC cutter and the bit matrix, or the pick and the pick holder, which is vital in maintaining stable, reliable and durable adhesion of the cutters to their hubs. Finally, based on a better understanding of the cutting processes, the formulation of a predictive model would assist in further development of cutter design.

Jan 1, 2004

By Hayes P. C

The reduction of small, dense zinc oxide (ZnO) samples in CO/CO2, and CO/N2 gas mixtures has been investigated at temperatures between 900 and 1100¦C. The microstructural characterisation of the reacted and partially reduced samples was complemented with measurements of the rates of the reactions. The mechanisms and kinetics of reduction of zinc oxide were found to be dependent upon the CO partial pressure, the oxygen potential of the gas mixtures, temperature and degree of reduction.

Jan 1, 1991