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By Michael B. Cortie

Mesoporous gold sponge has the unique property of being both metallic and highly resistant to oxidation. It has potential application in catalysis, in bio-sensors, in optical coatings, in analytical chemistry and, as we show here, as the basis for a new kind of ultra-capacitor. Due to the cost of gold, the most probable niche for a gold-based ultra-capacitor would be in the high-power/high-energy regime, a region where gold would compete with devices based on RuO2. A high internal resistance limits the power that can be usefully drawn from existing carbon-based ultra-capacitors, and that this problem can potentially be overcome by gold-based devices. A simple proof-of-concept ultra-capacitor based on mesoporous gold is described and its behaviour during charge and discharge cycles examined. In this work a step change in the input or output voltage of the device was used as the controlling parameter. There was also a residual faradaic current resulting from traces of undissolved aluminium left over from the AuAl2 precursor used to make the sponge, and some charge storage due to polarization of the solution. Deconvolution of these three effects was not entirely accomplished, but an ostensible capacitance of about 7 to 14 mF/g Au was demonstrated. Further improvement from these early results seems likely.

Oct 1, 2003

By Li Keqiang

Among the pile foundations of the 156 tall buildings over 18 storeys in Shenzhen, 86. 5% of them are constructed by slurry drilled piles, bored piles and excavated piles (hand-dug caissons). Based on the experiences of the engineering practices, the paper points out that the main quality problems of pile foundations in Shenzhen are: insufficient bearing capacity of single pile; poor concrete quality of pile; damage of the precast pile; pile tip not reaching the required bearing stratum and the thickness of bored/drilled sediment exceeding the specified. etc. The quality inspection methods that have been used include: check of construction records and excavating; static loading test; core sampling test; non-destructive test, etc. Treatments of quality problems used in Shenzhen are also introduced in this paper.

Jan 1, 1991

The Acid Leaching Process for the Synthesis of Zeolitic Material from Paper Sludge Ash

Sep 13, 2010

By W. Y. Xu

In comparison with shallow foundation, usually higher bearing capacity, smaller average settlement and better stability are the engineering characteristics of pile foundation. Besides, a smaller differential settlement and a lower settlement rate which will converge quickly are more important characteristics. The superstructure of the building with pile foundation may not meet with significant differential settlement. In this paper, settlement records and other data of different kinds of buildings are chosen to illustrate the characteristics of pile foundation. Moreover, some technical problems in connection with foundation engineering solved in consideration of the above mentioned characteristics of pile foundation are also introduced.

Jan 1, 2010

By O. Bernal, G. Velarde

Sociedad Minera Cerro Verde, majority owned by Phelps Dodge produces 200M lbs per year of LME Grade A copper from low cost leaching of secondary sulfides and SXEW processing. Central to the success of Cerro Verde has been the continuous improvement of leaching practices which currently yield over 80% recovery of the contained copper in the ore. This recovery has been achieved by careful attention to operational practices and leaching process fundamentals. This paper details the development of the concept of “Lixiviant Request Rate” where by solution is applied at an optimal rate for the grade, mineralogy, and the point in the leach cycle. Also paramount to the success of Request Rate technology has been the development of irrigation practices such as drip irrigation and irrigation grid design. These developments have ultimately resulted in improved copper production, decreased sulfuric acid and water consumption, decreased pumping cost, and more consistent PLS grades.

Jan 1, 2004

By Carlos Espinoza Zegarra

El presente trabajo describe el método de mecanización del sublevel caving realizado en la mina Yauricocha, donde se aplica a cuerpos que varían de de pequeños a medianos, irregulares o angostos a través del uso de Scoops. Así también el método puede ser usado en roca competente, así como en cuerpos que ya han sido parcialmente explotados como es el caso del cuerpo Cuye. Finalmente no es requisito fundamental que el mineral sea de resistencia muy mala, ya que al descubrir una superficie relativamente grande a través de varios bolsillos, el mineral cae con facilidad debido a la presión del techo aún sin usar explosivos.

Sep 12, 2005

By Fun-Den Wang

This report presents theoretical studies and experimental work dealing with the detection of dangerous roof and pillar conditions in underground mines through measure¬ment of temperature differences on the surface of the mine opening. The theoretical work is directed at modeling the circumstances where a loose slab of rock might be detected. The experimental work provides input data for the theoretical models. At the beginning of the project, little was known by the authors of the conditions that would permit detection of a loose slab of rock or coal by measuring the surface temperature differences. The U.S. Bureau of Mines had found that there were detectable surface temperature differences on the roofs and pillars of mines. The Bureau contracted with Colorado School of Mines to measure temperature profiles around mine openings in an effort to learn if the temperature differences they had detected were directly related to loose pieces of roof and pillar rock. The Bureau was principally interested in learning if loose rock could be found in coal mines by measurement of surface temperature differences with an infrared thermometer.

Jan 1, 1972

By Robert Stefanko

The growing demand for energy during the post World War I and World War II periods has prompted underground coal production to increase rapidly. This has been met primarily by mine mechanization, resulting in the development and application of new mining machine types. Correspondingly, the total connected horsepower of each machine as well as the number employed has enlarged rapidly since 1950. (2,3,9,14,16,17) Electrical consumption for each mine has also grown. In the early years of mining electrical applications, only d-c power was utilized underground. Yet, d-c machine limitations were soon realized, and many a-c systems were substituted to permit economic and efficient utilization of a-c distribution and motors. Due to the attractive torque characteristics, ease of distribution and speed control, several traction applications have continued to be powered by d-c motors. The result has been the now prevalent use of mixed a-c/d-c mine power. However, augmented electrical power employment seems to have added to underground coal mining electrical accidents.

Jan 1, 1974

Improve the Bureau-developed system for locating and communicating with miners trapped underground following a mine disaster. Approach Include in the wireless system a portable second-generation transceiver that is more reliable, compact, easier to deploy and operate, and ruggedized to withstand a mine environment. How It Works In an emergency, the new transceiver is snapped onto a caplamp battery for power. (Normally the 1 1/2-pound transceiver is either carried by the miner or is strategically located in the mine.) Its antenna wire, coiled inside the transceiver container, is removed and deployed in a roughly square configuration around a coal pillar or on the mine floor. The antenna consists of 300 feet of lightweight wire, which provides a large magnetic moment while remaining intrinsically safe, The photograph shows the

Jan 1, 1981

The need for the hydraulic transportation of coal in the New South Wales coal industry, both from the coal face to the surface and from the coal mine to the consumer or the port for export, is explained. Details of research projects currently in progress and involving the hydraulic transportation of New South Wales coals are given together with information on the hydraulic transportation of coal in the United States of America. The potential of hydraulic transportation as a viable alternative to the proposed expansion and upgrading of the New South Wales railway system to meet the projected New South Wales coal production to the year 2000 is described.

Jan 1, 1980

By John Rudolf

Metropolitan Washington Airport Authority is currently undertaking the first Phase of Metro?s Extension to Northern Virginia. A wide range of tunnel options was considered for the Tysons Corner segment that involves about 20,000 feet of track and four stations. After consideration of many options that involved EPBM single track tunnels, NATM tunnels and large bore tunnel concepts for the entire Tysons alignment, the design now being progressed into construction involves two 520 meter (1,700 feet) long soft ground NATM tunnels with several hundred feet of cut-and-cover construction. The paper discusses the process that led to selection of the short NATM tunnels as the most feasible of the options considered for Tysons.

Jan 1, 2008

By C. M. Badeen, J. Paige, W. Evans, L. McCauley, A. Caddies, I. Alilovic, R. Turcotte, C. O. Lyogun, C. Bonner

Gear pumps are very commonly used for the pumping of AN-water based emulsion products for both handling and blast loading applications. The potential major hazardous problems likely to be encountered with these pumps are: (i) high probability of friction; (ii) possibility of product confinement in the area of the bushings; (iii); high bearing failure rate; (iv) pump running dry; (v) presence of foreign material; (vi) deadheading of pump; (vii) delamination of elastomer from steel gears. Of all these possible scenarios, the no-flow situations where the pump is running dry or deadheaded have always been recognized as the most serious ones.

Jan 1, 2015

By Marius Jacobs

"Safety performance in many companies and even industries has stalled in the few years. Accidents rates are at a "plateau" and yet, serious accidents and fatality rates are not. In more dramatic cases, such as in the BP Texas disaster, organizations that have "exemplary" safety statistics, suddenly have a catastrophic or multi-fatality event occurring. Other classic examples are the Piper Alpha disaster and NASA’s Challenger and Columbia disasters and even the Chernobyl nuclear reactor. Looking into the root causes of these accidents provides an insight into the events and deficiencies that led up to the accident, but what are the common features in the organization’s mindset? What characterizes these organizations’ decision-making, their approach to safety and to risk and are there specific cultural features that can be delineated? The research and review presented in this paper covers a period since 1994, which started in the Australian resource industry and since then covered international events. The features of these organizations are summarized as the seven deadly delusions, based on extensiveresearch since 1997 of organizations that suffered unexpected disasters.The Piper Alpha Oil Rig disaster in the North Sea, on the 6 July 1988, was one of the most pivotal events in safety around the world. It changed the thinking and focus of governments, whole industries and led to numerous books and papers. It resulted in new legislation, textbooks and a critical self-examination by the oil and gas industry.In short, an explosion and fire occurred when a pipe started leaking gas and ignited. A temporary flange, with no safety valve, was used to block off this pipe during a maintenance operation the previous shift. The permit to advise operators not to start the pumps on this line was misplaced and lost. Several deficiencies, problems and system failures coincided. A key factor was that the water deluge system was inoperable at the time and failed to extinguish the large fire that erupted, followed by an even larger gas explosion. The accommodation unit, situated on top of the oil rig, was the main "killing field" - most men gathered here to await instructions (which never came) and where they died from smoke inhalation. Later, a large explosion of the gas pipeline from an adjoined rig exploded and killed more people.The line of events and the associated system failures are all very relevant in the analysis of the accident, and provide the only insight into what caused the accident. But much "further back", inside the organization’s culture, lurks more dark matter. The first inclination is to ask what was "deficient" in the culture. Did they not care enough about safety, or about their people? Did they have a culture where production decisions were more important than safety considerations? Did they ‘coerce’ supervisors and employees to ignore safety precautions or did they just "fly by the seat of their pants"?Not surprisingly, it is very difficult to identify the true nature of the culture in that business because in such an aftermath of death and destruction, no one dare say that the safety culture was a ‘positive one, focused and caring’ or that the company was doing well in safety and that this is only a freak accident. Indeed, there were many deficiencies in the organization’s systems and procedures, such as the permit to work system.But there are some niggling questions: How is then that the Piper Alpha Oil Rig was actually considered the company’s most productive and safest oil rig in the North Sea? Why would this rig win a safety competition, 6 months before the disaster, with the deficient permit as its most outstanding successful system?"

Jan 1, 2014

By J. -F. Lagueux

Goldex Mine is an underground mine located near the town of Val-d?Or. Multiple innovations were required to work the mine. Due to its low grade, it was important to develop a bulk mining method to economically extract the ore. The method used is a combination between shrinkage stope and long hole stope methods. This modified method is more than adequate; however, all of the ore body must be liberated in a very short period of time. Therefore, to bring down 23 Mt of ore, large blasts up to 1.8 Mt are required. The situation is also complicated by the fact that the mine is located in a residential area. No less that 40 homes are built within a 1 km radius of the mine site. In addition to managing mass blasts, means must also be found to mitigate the vibrations produced by the blast to diminish the disturbance to the neighbourhood. Therefore, the mine used numerous tools to properly plan the blasts and reduce the impacts. A program to control vibrations was one of the first tools put in place. The program?s aim was to draw up an action plan to ensure a follow-up of the homes by inspecting them. The second tool was to develop a methodology to plot a reliable attenuation curve and to adequately determine the maximum charge weight for each blast. Finally, effective communication tools were developed to inform the neighbourhood. There was a huge amount of work to be done in relation to the bench. Reliable and fast loading techniques had to be found to load large blasts in a very short period of time. Adequate logistics had to be developed to send underground more than 20,000 kg of emulsion per day while performing the daily underground operations. Technology had to be developed to adapt the i-kon electronic blasting system to large blasts. Since the control of the charges was the major factor to reduce surface vibrations, it was important to employ loading techniques that would permit decking of the long holes to reduce the charge weight per delays without adversely affecting the loading. All of this work requires an enormous amount of energy but also close collaboration between the different stakeholders (various departments, suppliers and consultants).

Jan 1, 2011

Tailings embankments can develop a high phreatic surface if the original design for the embankment does not include drainage facilities or if existing drainage facilities become ineffective. Subsequent raises can develop a seepage surface due to a high phreatic surface that can lead to stability problems. The U. S. Bureau of Mines amended contract J0100013 to initiate this study of horizontal drains in tailings embankments. This study developed a technique for determining the length of and spacing between parallel drains through the use of the finite element model UNSAT2. The analysis is based on the combined output of a vertical planar mesh and a horizontal planar mesh. The slot opening in the drain pipe and the length of the perforated section are determined from an analogy to water well design. The pipe diameter and gradient can be determined from Manning's equation. To the authors' knowledge, this is the first attempt at horizontal drain design using a finite element model. Additional research is recommended in this area.

Jan 1, 1982

By C. E. Brechtel

A testing program was conducted to design a cemented backfill fur hydraulic placement in underhand cut and fill mining of a steeply dipping coal seam. The testing evaluated the use of three different backfill aggregates, locally available at the coal mine, with Portland cement and five different pozzolans, including a Class F fly ash, a Class C fly ash, a cement kiln dust and ground smelter slag. Both viscosity and uniaxial compressive strength of backfill mixtures with different pozzolan and Portland cement contents were used to evaluate their suitability. Based upon the results of preliminary testing, an optimum mixture of alluvial sand with six percent Portland cement and ten percent Class F pozzolan was chosen for further compression testing.

Jan 1, 1985

By Dan Brown

Two drilled shaft foundations were subjected to axial load tests in order to measure the influence of drilling fluid on performance. Other than the differing drilling fluids, the shafts were constructed with great care to ensure identical conditions. The results indicate superior performance in both side shear and base resistance of the shaft constructed using a polymer over that of the shaft constructed using bentonite drilling slurry.

Jan 1, 2002

By R. H. Walton

"In recent years the recovery of copper from low grade oxide ores has received widespread attention. The cost of treating such ores using conventional technology, such as milling and flotation, is frequently prohibitively high and copper recovery is generally low. The introduction of heap leaching, solvent extraction (SX) and electrowinning (EW) has resulted in high recoveries, good copper cathode quality and low production costs. This technology has now been successfully applied on a worldwide basis.This paper reviews the various process and design options and gives approximate capital and operating costs for a 1.0% copper ore.INTRODUCTIONAs a result of the low copper prices that prevailed for much of the last two decades, aggressive attempts were made by the industry to cut operating costs. Under such circumstances heap leaching, solvent extraction and electrowinning, to recover low cost copper from oxide ores, has received particular attention and ultimately widespread acceptance.Low grade copper ore (typically containing less than 1.0% Cu), which could not be economically treated by other methods, is placed on heaps and leached with dilute solutions of sulphuric acid. The copper rich, pregnant solution, drains from the heap into a collecting pond and is pumped to a solvent extraction plant where it is purified and upgraded. The resulting solution, termed the pregnant electrolyte, passes to the electrowinning section where the copper is recovered as high grade cathodes and sulphuric acid is regenerated, (Figure 1).This paper specifically describes the processing of copper oxides. Other copper minerals such as chalcocite and chrysocolla are also leached by dilute solutions of sulphuric acid. In practice the oxide minerals are frequently associated to varying degrees with less easily leached sulphides, such as chalcopyrite. In some cases, once the oxidized capping of the ore body is removed, the oxides are totally replaced by more refractory sulphides. Under these circumstances the leaching recovery is significantly reduced. However the principles described here for solvent extraction and electrowinning are also applicable to solutions received from heaps containing sulphide minerals, which are leached more slowly and involve bacterially induced reactions."

Jan 1, 1990

By H. W. Fleming, R. R. Brooks

The Clearwater Deposit, a small occurrence of massive-sulphide mineralization enclosed in an envelope of disseminated-sulphide mineralization, was discovered as a result of an aeroelectromagnetic survey in New Brunswick in 1955. Subsequently, additional flights were made over the deposit and various ground follow-up methods were employed to ascertain the nature of their response. All methods proved to be capable of indicating the occurrence with varying degrees of precision. This paper is a presentation and a discussion of the magnetic and electromagnetic data, both airborne and ground, and the self-potential data obtained over this deposit. The attention of Canadian mining exploration companies was initially focussed on New Brunswick by the discovery, in 1953, of the Brunswick ore body. Ground electromagnetic surveys were of considerable assistance in locating and developing this deposit. In the following year, 1954, the Heath Steele base-metal deposits were discovered by employing an airborne electromagnetic device and ground electromagnetic surveys to follow-up the airborne indications. These discoveries demonstrated clearly that both airborne and ground electromagnetic techniques were applicable for locating the near-surface deposits of massive sulphides present in this region. Airborne electromagnetic equipment became available on a contract basis through Aeromagnetic Surveys Limited early in 1955 and was used extensively thereafter throughout a large portion of northern New Brunswick. It was as a result of one of these surveys with Aeromagnetic Surveys Limited equipment in the summer of 1955 that the Clearwater Deposit was detected. The airborne anomaly was located on the ground by means of an electromagnetic survey using a Swedish Slingram unit. During 1956, the region was investigated more thoroughly- in the hope that other sulphide bodies might be located. Airborne electromagnetic coverage was extended and the Clearwater Deposit itself was used as a testing ground for the various methods and types of equipment currently in use in New Brunswick. In this paper com prative data are presented for the airborne magnetic, airborne electromagnetic, ground magnetic and ground electromagnetic surveys over this deposit. The ground electromagnetic instruments used were the McPhar vertical-loop unit and the Slingram and Boliden horizontal-loop units. Self-potential surveys were carried out with a McPhar unit. From the geophysical point of view, all ground electrical methods employed indicated the presence and the extent of the massive-sulphide mineralization with a good degree of accuracy. The horizontal-loop methods however, defined the contacts more precisely as is to be expected when dealing with a flatly-dipping

Jan 1, 1961

By Milne J. Schmid

A program has been conducted to determine the feasibility of providing a borehole liner for Kelly Bar drilled boreholes in Southern Florida. The concept was to drill the borehole with the Kelly Bar and with it still in the borehole insert a tube which would remain in the unstable ground after withdrawl of the bar. The tube then will provide an unobstructed borehole for the charging of explosives upon completion of the drilling the shot pattern.

Jan 1, 1977