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By C. G. Goncalves

The Gautrain rapid rail link project is currently Africa?s largest infrastructure project connecting South Africa?s major airport (OR Tambo), Johannesburg and Pretoria. Phase one is planned for completion in time for the 2010 FIFA Soccer World Cup and involves 80 km of track and 15 km of underground tunnels. The key shaft sinking blasting issues revolve around maximising advance and improving blasting cycles to meet the tight deadlines as well as environmental control which, in some cases takes place only 15m from the city infrastructure. To achieve success, DetNet South Africa supplied a range of electronic detonator systems to cater for the different blasting applications involved (tunnels, portals, shafts and viaduct foundations). One such product, QuickShot, was used for the first time in a major civil engineering project and has been used in most of the shaft sinking blasts to date. The QuickShot system combines pre-programmed electronic detonators with special on-bench components that enable the user to quickly and easily design the firing sequence solely by using the order of connections. This precludes the user from having to deal in absolute delay times. The connecting system enables benches to be hooked-up speedily by multiple users who have differing levels of experience. This paper provides details of how, after 33 months, the system has been embraced by the project by aiding in maximised advances, improved cycle times and meeting the required environmental constraints.

Jan 1, 2009

By I. Zh. Bunin, M. V. Ryazantseva, V. A. Chanturiya

The paper proposes a new method for selective calciferous separation. The effect was achieved through the application of the combination of high-power electromagnetic pulses (HPEMP) and a specific reagent regime of the flotation. The combined application of HPEMP with the special reagent regime allowed for the improvement of the scheelite floatability: the recovery of CaWO4 rises from 41.2 % (untreated sample) to 58.5 (sample treated at 103 pulses). In contrast, the floatability of calcite decreases significantly: the recovery of calcite drops from 74.7% (untreated sample) to 41.1 % (sample treated at 103 pulses). The conditions were found for the selective separation of the minerals with very close flotation properties. Keywords: Calcite, scheelite, flotation, high-power electromagnetic pulses, DRIFT, XPS

Jan 1, 2020

By J. Petersen, K. Shaik1, H. Kolev, Z. Cherkezova-Zheleva

Sperrylite is one of the most abundant platinum minerals globally, valued for its economic importance but also known for its highly refractory nature, making it difficult to process via the conventional route. This study explores the oxidative leaching of sperrylite using a cyanide–ferricyanide system, with a key focus on characterisation of the mineral and surface speciation under varied leaching conditions using x-ray photoelectron spectroscopy. The parameters investigated include the effect of sodium cyanide concentration, the use of potassium ferricyanide as an oxidant, copper sulphate pentahydrate as a catalyst, as well as the effects of temperature and particle size. A limited set of leaching tests was carried out to study the surface chemistry rather than optimising dissolution conditions. This approach identified mineral oxidation states and shifts in binding energies, prior to and post leaching. XPS analysis of sperrylite’s surface chemistry identified key species, comprising the bulk Pt(II)–As (≈73 eV) and As(–I)–Pt (≈41.8 eV) states, together with surface oxidation products Pt(II)–O (≈72 eV), Pt(IV)–O (≈74.5 eV), As(III)–O (≈43 eV) and As(V)–O (44.5 eV). Leaching led to the removal of pre-existing oxides on the ultra-finely ground sample, exposing the underlying bulk species. In contrast, the crystalline sample with an initial low concentration of oxides, generated higher amounts of fully oxidised species after leaching, reflecting greater surface reactivity.

Mar 6, 2026

By D. Gregurek

The complexity of metallurgical processes in the non-ferrous metals industry. especially changes in the process conditions in combination with a diversity of metal processing furnaces, requires a precise knowledge of the system for the selection of refractory products. However, particular importance is still focused on the specific refractory consumption being as low as possible. The addition of recycling material with a high amount of impurities and the increase of low-grade ore concentrates used in the base-metals industry also entails a significant change of slag chemistries, process temperatures, etc., which influence the performance of already approved linings. This acknowledgement of process changes with decreased brick lifetimes provided the motivation for RHI AG to develop high-performance refractory bricks especially for non-ferrous metals applications. The internal laboratory tests with fayalitic slag showed very promising results compared with our approved magnesia-chromite bricks for this application. In order to identify suitable refractory products and to improve the life of the refractory lining, innovative product development has to be undertaken. In addition, the practical corrosion testing methods and facilities available within the RHI Technology Center, such as the induction furnace and the rotary kiln test equipment, allows the best possible understanding of brick wear at a laboratory scale. Based on the results of the test work, the optimal refractory solution can be recommended for a field trial at the customer?s site.

Jan 1, 2012

By E. S. van Druten, M. C. Bekker

"The complete and successful closure of a mine in the South African environment remains problematic. Closure remains an elusive mining phase due to unclear roles and responsibilities, inaccurate closure management data, and the inability of stakeholders to conceptualize and integrate closure information into business processes. Currently there are no proven methods available to address the complexities encountered during a closure application, and to date no mine has been granted full closure. Many mines are left abandoned and unrehabilitated, resulting in risk to investors, surrounding communities, and regulators. This investigation aimed to determine, categorize, and rank reasons for unsuccessful mine closures. Focus groups consisting of public and private stakeholders were identified and surveyed through a structured, rank-order questionnaire to determine the relative importance of reasons why achieving formal and final mine closure remains elusive. Various requirements and aspects were identified and listed according to four categories: namely, primary, secondary, process drivers, and information sources. These aspects should be considered in the development of an integrated mine closure model.Background and rationalePrior to 1956, mine closures were not subject to legislative requirements, being merely governed by insufficient environmental regulations under the Mines and Works Act 27 (MWA) (Swart, 2003). In 1981 the Chamber of Mines (COM) published a document titled ‘The rehabilitation of land disturbed by surface coal mining’, which constituted the first notable contribution to environmental protection. This guideline was later referenced in the Minerals Act of 1991, which for the first time laid definite environmental burdens on the Mining Right Holder (MRH). The Minerals Act of 1991 was superseded by the current Mineral and Petroleum Resources Development Act (MPRDA) and the Mineral and Petroleum Resources Development Act Regulations (MPRDAR), which specify a regulatory process for mine closure applications and financial provisions."

Jan 1, 2017

By Z. Zitron, G. J. de Korte, D. W. Horsfall

This paper summarizes work carried out on the treatment of fine coal, nominally classified as minus 0,5 mm (wedge-wire screen), which is removed from the raw coal prior to the treatment of the plus 0,5 mm sizes. The minus 0,5 mm coal divides, for treatment purposes, into fines, nominally between 500 and 150 !tm, and ultrafines, nominally minus 150 !tm. Studies on processes for the treatment of minus 0,5 mm coal are discussed, and the lower size limit beneficiated is indicated for each process. The installation and operational results from a pilot froth-flotation plant treating minus 150!tm coal are described.

Jan 1, 1986

By R. Weideman, K. du Preez

Biological sulfate reduction has become a successful treatment alternative for acid mine drainage and Mintek is developing biological processes for treatment of highsulfate mine waters. Treatment of these high-sulfate waters is achieved by sulfatereducing bacteria that reduce sulfate to produce sulfide as a product, in the form of H2S and HS− at neutral pH. This introduces the opportunity to apply treated effluents from biological treatment processes for the recovery of metals, such as copper, from metallurgical waste streams. This study models the kinetics of copper sulfide precipitation from a complex bioleach liquor. The results indicated a rapid rate of reaction and the formation of covellite, suggesting the potential to use biogenic sulfide to recover copper as a metal sulfide product.

Jan 1, 2023

The treatment of gold-plant tailings with ferrous sulphate to remove the cyanide is currently in use, on several gold plants. In some cases there is scope for optimization the process. The present work provides a detailed study of the reaction between cyanide and ferrous sulphate. Optimal conditions for the removal of total cyande required a ph of 5,.5 to 6,5 and an Fe:CN molar ratio of 0,5. Ferrocyanide ion is shown to be unstable In aqueous acidic solution, with rapid oxidation to ferricyanide, (Fe(CN) 6 ), and formation .of Fe(CN)5H2O3- at pH values below 4, The precipitate from the reaction between cyanide and ferrous sulphate consists mainly 01 Insoluble Prussian blue, Fe4[Fe(CNI&!.3,and IS shown to be unstable in the presence of alkaline solution, since it decomposes rapidly at pH values above 7 to form ferrocyanide, (Fe(CN)6 ), in solution and various insoluble iron oxides,

Jan 1, 1992

By L. A. Cornish, I. A. Mwamba, R. A. Couperthwaite

"In previous work by the authors, it was established that additions of 0.2 at.% Ru to an Fe-40 at.% Al alloy improved the corrosion and oxidation resistance of the alloy. The alloy was produced by mechanical alloying and spark plasma sintering and the work showed that nonequilibrium processing was able to significantly refine the grain size of the material. The sintered material had a higher hardness than the as-cast material and the change in grain size did not significantly affect the oxidation and corrosion. In the present research, the mechanically alloyed powder was coated onto a mild steel substrate using cold-spray coating at a gas pressure of 10 bar and a temperature of 500°C. The coatings were found to be 5–10 um thick, although thicknesses of up to 30 um were observed. The coated materials were subjected to oxidation and corrosion tests to determine the effectiveness of the coating in increasing the oxidation and corrosion resistance of mild steel. This was done to determine the effectiveness of cold-spray coating as a technique to coat these mechanically alloyed powders. IntroductionPrevious work conducted by Mintek (Couperthwaite et al., 2013, 2015) investigated the effect of precious metal additions on the structure, oxidation and corrosion properties of an Fe-40 at.% Al (Fe- Al) alloy. Initial work determined that additions of more than 0.5 at.% precious metal did not improve the oxidation and corrosion properties of the materials and in some cases even decreased the resistance to corrosion. Further work identified Pt and Ru as beneficial additions to the FeAl alloy. Four alloys were then produced by mechanical alloying and sintering (FeAl–0.2 at.% Pd, FeAl–0.2 at.% Ru, FeAl–0.5 at.% Ag, FeAl–0.5 at.% Pt). These alloys were all successfully produced by melting and casting and mechanical alloying sintering and it was found that the nonequilibrium processing greatly decreased the grain size of the materials compared to the ascast materials. It was found that the additions of Ru and Pt were still the most beneficial to the oxidation and corrosion properties, with Ru being considered the most beneficial."

Jan 1, 2016

By B. Rezai, Z. Pourkarimi, M. Noaparast, S. Chehreh Chelgani

Nanobubbles (NBs) flotation separation can be an indicator for improving the efficiency of fine particles through the conventional process. Since flotation reagents such as frothers can reduce bubble size, they can potentially be used for the generation of NBs and develop a selective NB flotation separation. This study explored the flotation separation of fine phosphate particles from their associated minerals in the presence of NBs, which were generated by using a phosphate flotation reagent (Flo-YS: collector-frother). The results of flotation tests showed that in the presence of NBs, the flotation efficiency was significantly improved. However, in the presence of NBs, surface chemistry analyses (Fourier Transform Infrared Spectroscopy and High-Performance Liquid Chromatography) illustrated that the collector adsorption on the surface of phosphate particles decreased. A comparison between outcomes of various phosphate flotation conditions indicated that increasing the flotation efficiency in the presence of NBs may be due to the aggregation of fine particles by the generated NBs, and also selective adsorption of NBs (hydrophobisation) on the surface of particles. In other words, generating NBs by selective collectors may increase efficiency and decrease the collector consumption of a flotation process. Keywords: Phosphate, selective separation, fine particles, collector-frother, efficiency, mechanical flotation cell

Jan 1, 2020

By W. Soetaert, P. Dhar, H. R. Kota, M. Thornhill, S. Roelants, I. V. Chernyshova

Yeast-derived bola-amphiphiles have attracted considerable attention for their applications in various industrial sectors in recent years. However, only a few studies on this class of surfactant were reported to be relevant to mineral processing applications. In this paper, one of the novel surfactants, acidic glucolipid obtained from Candida bombicola sophorolipids and modified by using Penicillium decumbens naringinase substrate has been evaluated for its interaction with chalcocite and calcite minerals because of a new Cu-ore Nussir deposit in Norway containing calcite impurity. The interaction of glucolipid biosurfactant with copper sulphide and carbonate minerals was investigated with zeta potential, adsorption and FTIR studies, and also by Hallimond tube and bench scale flotation tests using pure minerals and Nussir copper ore, respectively. The results illustrate collector adsorption and flotation of copper sulfides at neutral pH. The bench-scale flotation results demonstrate that copper sulphides can be selectively floated from carbonate and silicate gangue minerals. This study underlines the glycolipid’s high potential for its use as collector for flotation of valuable copper sulphide minerals. Keywords: Flotation, biosurfactants, adsorption

Jan 1, 2020

By D. van Rensburg

Jointed rock slopes are generally stable, as there is no freedom of movement for blocks of rock. In an open- pit mining environment, blasting opens up space into which blocks of rock can fail, resulting in the common occurrence of slope failure. Prior to the blasting of a trim pattern, the immediate highwall is scaled, where loose rock material is removed by means of a mechanical scaler. As mining of the pit progresses, the height of the scaled highwall from the pit floor progressively increases. These highwalls are never scaled again for the remainder of the pit life, and time-dependant deterioration contributes to these highwalls becoming subject to rockfall and, sometimes, slope failure. This paper documents the development of a South African innovation, a remote-controlled mechanical highwall scaler, a world first for the mining industry. The scaler will enable open-pit highwalls to be scaled from crest to toe whenever the need arises. It will reduce the risk associated with highwalls and deliver on the Anglo American promise of producing safe, profitable platinum.

Jan 1, 2012

By S. Krishnannair

Singular Spectrum Analysis (SSA) is an effective data-adaptive multimodal tool for monitoring chemical processes. However, monitoring multiscale signals using principal component analysis obtained from the multilevel decomposition of process signals using basic SSA assume the upper control limits of monitoring charts (" ) to have a Gaussian distribution. This assumption deteriorates the performance of basic SSA when applied to the monitoring of nonlinear processes. To address the issue in this paper, the kernel density estimation (KDE) was used to estimate upper control limits of monitoring charts for basic SSA based nonlinear process monitoring techniques. The monitoring performance of the resulting basic SSA-KDE approach was then compared with a basic SSA approach of which upper control limits of the monitoring charts were determined based on a Gaussian distribution. Application on nonlinear dynamic simulated process and base metal flotation plant chemical processes showed that the SSA-KDE approach provided better overall performance than the SSA approach with Gaussian assumption-based upper control limits for its monitoring charts. Keywords: Fault detection, singular value decomposition, singular spectrum analysis, kernel density estimation

Jan 1, 2020

By M. L. Mahlatji

Mechanical alloying of an equiatomic mixture of crystalline Ti and Pt elemental powders in a high-energy ball mill formed an amorphous alloy by solid-state reactions. Mechanical alloying was carried out in an argon atmosphere at a rotation speed of 1200 r/min and a 20:1 ball-to-powder weight ratio, for time intervals of 4 to 40 hours. At an intermediate stage of mechanical alloying, scanning electron microscopy showed the formation of characteristic layered structures of inhomogeneous composition within the powder particles. X-ray diffraction analysis showed the gradual disappearance of crystalline Bragg peaks and the emergence of broad amorphous maxima as milling progressed. The amorphization process was completed after 8?12 hours. The amorphous state of the product indicated that temperatures during processing did not exceed the crystallization temperature of the alloy.

Jan 1, 2014

By M. Pierce, E. Karampinos

"One of the main challenges in the numerical modelling of ground support in underground excavations is to reproduce the performance of the sequential installation of the reinforcement while capturing the rock mass behaviour of an advancing face in 3D. The 3D modelling approaches used to simulate the progressive advance of excavations are mostly continuum and often cannot reproduce the rock mass failure mechanisms. The 3D discrete element method (DEM) can better reproduce structurally controlled rock mass failure mechanisms and can explicitly represent the reinforcement elements. This paper builds on previous work that reproduced the structurally controlled squeezing conditions in an underground hard-rock mine using 3D DEM and the in situ behaviour of reinforcement under pull conditions. It addresses important issues on the way reinforcement is explicitly introduced in discrete element models. A pseudo-3D model is employed to overcome the computational restrictions and time limitations of a 3D modelling approach. The work focuses on the scaling of the material properties of the ground support elements when the thickness of the model is not equal to the out-of-plane spacing of reinforcement. It demonstrates the scaling methodology based on the type of the modelled reinforcement elements used and investigates the significance of this approach. The advantages and disadvantages of this approach with respect to 2D and 3D methods are discussed. The results are compared with field data and previous modelling work done at the mine. IntroductionNumerical models can provide significant insight into the anticipated behaviour of underground excavations. The modelling of ground support, however, is not a trivial exercise. An effective representation of ground support in underground excavations should capture the behaviour of both the rock mass and the support elements. When numerical models are used for design purposes, the complexity of the problem requires significant time and expertise (Sweby, Dight, and Potvin, 2016).At a laboratory scale, numerical models have successfully reproduced the results of laboratory tests on rockbolts by explicit modelling of the bolt, the borehole, and the grout. Chen and Li (2015) used a continuum FLAC3D (Itasca Consulting Group Inc., 2012) model to simulate the mechanical behaviour of D-bolts as observed experimentally. Grasselli (2005) used a 3D finite element code to model the behaviour of fully grouted rods and expandable bolts under shear."

Dec 1, 2018

By J. N. Baloyi

"In atomic emission and atomic absorption spectrophotometry, the sample is heated to a high temperature and thereby decomposed into atoms and ions that absorb or emit visible or ultraviolet electromagnetic radiation at energies characteristic of the elements involved. The flame test is a very simple form of this technique. The yellowing of a flame by the addition of salt, for example, occurs because the sodium in salt emits strongly in the yellow portion of the visible spectrum. These methods are especially useful for low concentrations of metallic elements in both qualitative and quantitative analysis.Interference on Iep-OES has not always been considered a serious problem, especially in the beginning, when compared with Atomic Absorption Spectroscopy. This was due to the euphoria created by the new technique. It meant that criticism was subdued. The Iep was vastly superior to the Atomic Absorption technique, that the interferences suffered by the Atomic Absorption technique dwarfed the little interferences suffered by the rep-OES technique. This is how rep-OES has had a reputation as an interference free technique."

Jan 1, 2014

By Z. Halifa, P. G. Geyer

Tapping a blast furnace is necessary not only to deliver the product, but is also essential for the safety of the furnace and workers in the cast-house. This paper will highlight the practices at ArcelorMittal’s blast furnaces in the Vanderbijlpark Works, with specific focus on tap-hole design and monitoring as well as casting practice. Extension of the tap-hole life and hearth campaign will be illustrated with reference to the methods of maintenance of the tap-holes, troughs, runners, and cast-house equipment. The importance of proper cooling, good thermocouple installation, and temperature monitoring will be explained.

Jan 1, 2014

By K. M. Primrose

Electrical tomography has developed rapidly over the last few years in its sophistication and practical use to enable three-dimensional information on the distribution of phases within flowing mixtures to be observed1. This paper reviews the current state of application from the industrial perspective, drawing on applications case studies based on scaling studies in the laboratory right through to installations on plant. In the laboratory, applications have looked at scale-up of mixing2 processes involving gas-liquid and solid-liquid suspensions3 with a particular interest in verifying computational fluid dynamics simulations or in checking scale-up design4,5. In the processing plant, the circumstances are usually bespoke and may range from simple detection of the degree of homogeneity of a flowing mixture through to the need to measurement a sophisticated batch process such as crystallization, sedimentation, filtering and drying. Examples drawn from the chemical and pharmaceutical industries will be presented and related to the benefits that can be gained through application of the method.

Jan 1, 2008

By A. Dabbagh

The aim of this research was to investigate the effect of coke particle size on the thermal profile of the charge bed in the sintering process of iron ore. Six different ranges of coke particle size that could be used in practice in the sintering line of Esfahan Steel Company (ESCO) were used while parameters such as ratios and particle sizes of other ingredients, ignition temperature, and suction power were kept constant. Thermal profiles were obtained by measuring the temperature changes at three points in the sintering bed. The influence of coke particle size on rate of temperature rise, maximum temperature of the sintering bed, and the flame front velocity of the sintering bed was determined by analysing the thermal profiles. Moreover, the cold strengths of the sinters were measured using the Tumbler method. The results indicated that the coke particle size has a significant impact on the thermal properties of the sintering bed. Based on the results, a coke particle size between 0.212 mm and 3.350 mm was determined as the optimal range for the specific conditions in the sintering line of ESCO. Keywords iron ore sintering, coke particle size, thermal profile, flame front velocity, Tumbler index.

Dec 1, 2013

By Mike Stanley

This is a case study of an opencast coal mining operation where the physical and financial performance was improved via applying a process of transformational leadership development. [ ]

Jan 1, 2008