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By G. R. J. Cooper

In recent years attempts have been made to develop software packages for shallow seismic refraction data analysis. In most cases, mainframe computers were used which were generally non-interactive, did not support graphics and were unfriendly to operate. With these facts in mind, a user-friendly interactive processing package written in PASCAL has been developed for the IBM PC. The package allows the following operations to be performed. (1) data tying, equalisation of reciprocal and common shot times; (2) overburden velocity analysis; (3) refraction leg identification on time-distance plots; (4) elevation correction of refractor data; (5) forward and backward phantoming; refraction leg extrapolation; (6) 'bedrock' velocity analysis; (7) 'time-depth' plot computation; (8) depth calculation. Numbers (6) - (8) above involve Palmer's generalised reciprocal technique of refraction data interpretation. The program is extremely flexible and makes much use of interactive high resolution graphics and 'popup' onscreen menus. The velocity analysis sections have statistical routines built in to provide error estimation. The programs allow data interpretation to take place in the field with a portable microcomputer while the data are still being collected; this is obviously not possible with any cumbersome mainframe-based software. Hence it becomes possible to see the effects of varying the data collection parameters (such as geophone spacing) upon the resulting interpretation and so enable adjustments to be made where necessary. Hard copies of the data may be obtained at all stages of the interpretation process using a small (A3) plotter, or the graphics may be dumped to a dot- matrix printer if a suitable plotter is not available.

Jan 1, 1987

By M. M. Makhofane

Anhydrous zirconium tetrafluoride can be used as a precursor for the manufacturing of nuclear-grade zirconium metal. This can be done by fluorinating plasma-dissociated zircon with ammonium bifluoride in a batch reactor. This paper describes the batch process. It was proved that anhydrous zirconium tetrafluoride can be manufactured by this route as confirmed by X-ray diffraction. The process shows potential for scaling up to the kilogram scale and possibly the tonnage scale.

Jan 1, 2012

By E. E. Almási, G. Mucsi, G. Rákhely, Á. Rácz, B. Csőke, Zs. Pap, K. Bohács, N. Halyag

Wet stirred media milling is a widely applied grinding process in the field of mineral processing to produce <10 μm ground materials. In this paper, the results of wet stirred media milling of different Ti, Fe and Cu-oxide and phosphate minerals are presented. During the experimental work, grinding of ilmenite, vivianite, hematite and cuprite was carried out in a continuous operation wet stirred media mill. During the experiments, the particle size distribution and specific surface area of the ground materials were determined after a certain grinding time, as well as measuring the specific grinding energy, thereby determining the grinding kinetics of the different minerals. The measurement results showed the differences and similarities in the grindability of the individual minerals. Nano particulate vivianite, hematite and ilmenite was successfully manufactured in a stirred media mill; however cuprite was characterised as the coarsest final product for the same grinding circumstances. Keywords: Wet stirred media mill, cuprite, vivianite, ilmenite, hematite

Jan 1, 2020

By J. W. Drelich, H. Zeng, L. Xie, X. Cui, Z. Gao, M. Tian, Y. Hu, W. Hu, W. Sun

Flotation is a mineral separation technology that uses the surface hydrophobic difference of valuable minerals and their associated gangue minerals to separate them. The flotation collector adsorbs on the valuable mineral surface to improve its hydrophobicity, and metal ions are usually used as activators to enhance the collector adsorption. Different mineral surfaces show different charging properties and adsorption behaviours with the collector or metal ions. Moreover, the order of adding metal ions and the collector also show significant and different flotation performance for the same mineral. The adsorption or flotation behaviour or both are governed by mineral surface chemistry, such as surface charging and reactivity. In our recent studies, force measurement using atomic force microscopy (AFM) was employed to study the surface charging and adsorption mechanism of metal ions and collectors. By preparing collector-functionalised AFM tips, AFM can directly measure the adsorption strength of the collector on the mineral surface to determine the anisotropy of mineral surface reactivity. The preparation of collector-functionalised AFM tips provides the foundation for further study of the activation role of metal ion in the collector adsorption. The application of AFM for force measurement in the surface chemistry of mineral flotation can provide important information on developing flotation reagents and lays the foundation for the specific regulation of mineral surface characteristics. Keywords: Scheelite; flotation; surface chemistry; AFM force measurement

Jan 1, 2020

By D. G. Krige

The problem of a realistic investment analysis for a new mining venture that sells its products on the international metal markets IS studied against the background factors, firstly, of different inflation rates between the countries hosting the mines and those. hosting the metal markets; and, secondly, of the changing pattern of currency exchange rates between such countries. The purchasing-power parity theory is used to establish a pattern of relationship between these two factors, and to develop a more logical approach to the long-term forecasting of metal prices in the currency of the country in which the mine is situated.

Jan 1, 1979

The inherent weakness of the Zincor and similar iron removal processes is the relatively high undissolved zinc loss associated with the iron residue. High soluble zinc losses also occur due to poor filterability of the iron residue even though it may be limited to intermittent events. This work focussed on defining the optimum operating window for the Zincor iron removal process where iron is mainly removed in the form of amorphous, intermediate iron phases such as schwertmannite and ferrihydrite. In terms of the main operating conditions, optimum filterability was achieved under the following conditions: pH of 3.0, temperature as high as practically possible (70C), at least 25 kg/m3 seeding, and a retention time of at least 4 hours. When increasing the temperature from 60C to 70C, the required residence time decreased by almost 50%. Undissolved zinc loss was also reduced from 8% to between 2% and 3% by using a basic zinc sulphate/zinc oxide mixture as neutralising agent to effect iron removal.

Jan 1, 2003

By D. Yu Pleev, V. G. Krivolapov

Mines of Southern Kuzbass working out, basically, coal formations of flat seams. Seams, as a rule, are inclined to self-ignition. Detection at early stages of the centers of endogenous underground fires has great value for safe conducting mountain works. One of methods of detection of an early stage of underground fires in the worked out space is the method of superficial radon survey. In the report the method is de-scribed and examples of superficial radon survey on concrete layers are given.

Jan 1, 2003

By I. Wigden

This paper discusses system integration and installation of High-Tec systems in underground mines. ABB has the capability to be a System Integrator and co-operates with partners in different areas of technology. Today it is difficult to find one Company that is responsible for the complete Automation System. The design of the system is also dependent on the caving procedure that is currently being used in mines. Most of the engineering must be done during the feasibility study and the design phase. Any mistakes made during these phases will be costly to rectify in the commissioning phase. The paper will also include a presentation of the benefit of using Automation in an Underground Mine, and the importance of integration with the people component. Most of the experience and discussions in this paper are from different technologies that have been developed in Scandinavia and adopted from LKAB in Kiruna. The author of this paper was responsible for the Automation projects in Kiruna Mine during1994 - 1999. These projects include: • Broadband communication of data, audio and compressed video in one data stream. • Control System for Haulage -1045m • Automation of Load Haulage and Dumping machines (LHD) • Control of Production Drilling Rigs from a Central Control Room.

Sep 1, 2001

By L. Thomas, A. Argyn, B. Mbao, G. Longo Banza

Since the first application of solvent extraction as part of the hydrometallurgical processing of copper, several studies have been carried out to optimize extractant formulations. In 2006, Solvay developed the ACORGA® OPT series of solvent-extraction reagents to optimize copper transfer by use of a blended formulation containing both aldoxime and ketoxime as well as selected modifiers. The incorporation of selected modifiers in these blended reagents resulted in increased copper transfer, due to the interaction between the modifier and oximes within the blend. By changing the ketoxime concentration and ratio of modifier to aldoxime, the strength of the formulation was optimized to enhance copper transfer and improve Cu:Fe selectivity. This formulation is well known in the African region under the ACORGA® OPT5540 name and provides the best performance at the conditions of agitated leach plants with pregnant leach solutions that fluctuate in Cu grade and pH. This paper discusses advantages of using ACORGA® OPT5540 in the Copperbelt

Jan 1, 2023

By N. V. Nemchinova, A. A. Kozlov, A. V. Epiforov

The gold dissolution in sulfuric acid media during industrial oxidative leaching test of sulfide gold-copper flotation concentrates has been achieved. The reason for this was using technological water containing thiocyanates and cyanides, which can dissolve gold under these conditions. The carbon in column (CIC) process for gold recovery from these solutions was proposed. However, significant amounts of copper and iron were adsorbed onto the carbon during CIC technology industrial tests. This resulted in a decrease of the gold content in the loaded carbon up to 0.5 kg/t. Further development of the technology was conducted by optimisation of gold and impurities stripping and implementation of carbon reactivation. It was shown, that the copper extraction from the loaded carbon during cyanide treatment was about 95%. The copper content in the stripped carbon after cyanide treatment was 1.76 kg/t. The gold recovery during high-pressure elution by caustic solution was 98%. The hydrochloric acidic treatment with thermal pre-treatment (reactivation) for removing iron and calcium from gold-free carbon was proposed. In this case, the iron and calcium extractions from carbon were 40-45 and 50-55% respectively. These tests showed that for carbon recycling the sequence operations of ‘cyanide treatment, gold elution, thermal pre-treatment, hydrochloric acidic treatment’ can be used. Keywords: Thiocyanate leaching, recovery of gold, carbon adsorption, gold elution, copper stripping, thermal reactivation of carbon, activated carbon, carbon-in-column

Jan 1, 2020

By Jürgen Antrekowitsch, Harald Osthof, Stefan Steinlechner

"In the case of feasibility assessments or feasibility studies, an important point of discussion is often how to calculate the capital (CAPEX) and operating expenditure (OPEX) of a plant. Generally, there is also the request to know how the CAPEX varies when the size of the plant is increased. Nowadays, many databases give an indication of specific equipment costs in relation to the production rate. These data are based on cost information from equipment suppliers and have to be continuously updated by the owner of the database. The approach presented here is a model which allows sizing of process equipment, for example a leach tank, based on process data in combination with the calculation of mechanical properties. Furthermore, it calculates the CAPEX based on construction material cost and adequate machining surcharges. Thus, a single cost model for a leach tank is adequate for both copper and other hydrometallurgical plants and stays valid with changing construction material prices. To summarize, the advantage of this model is the more versatile approach and thus the flexibility due to the inclusion of design aspects, process and mechanical engineering aspects and an updatable database. The database, which is in regard to material cost and is the basis for the cost estimation, is easily updatable from commonly accessible data. This model thus approaches the procedures of an engineering company when designing a plant and executing a cost calculation. INTRODUCTION Hydrometallurgy nowadays plays an important role in processing of primary and secondary resources. In copper metallurgy, hydrometallurgy accounts for roughly 20 % of worldwide primary production, especially in the case of oxide or low copper-containing ores. Zinc smelters changed their method of production from a pyrometallurgical-dominated concept decades ago to mainly hydrometallurgical routes today. Gold production processes using leaching, especially, have a long history without any development which would not be competitive if not based on hydrometallurgical concepts (Pawlek, 1983; Winnacker-Küchler, 2006)."

Jan 1, 2015

By M. D. Raganya

The Kriel Colliery is an Anglo Coal mine which is contracted with Eskom to produce No. 4 seam for Kriel power station. The mine previously found it uneconomical to mine No. 5 seam due to the low qualities and tonnages of the seam, both at the opencast and underground sections. An area has been encountered for the first time at Kriel Colliery opencast pit 5, where the tonnage and qualities of No. 5 seam warrant further investigation. The primary reason for the investi¬gation of No. 5 seam by Kriel Colliery is because of the advantage of the high selling price (R450/t) that the market is currently prepared to pay for the No. 5 seam. The aim of this project is to mine No. 5 seam economically without interrupting No. 4 seam mining operations. The problem is that the equipments that are currently being used at the mine belong to Eskom and are dedicated to mining No. 4 seam only, not No. 5 seam. Through geology investigation, it is found that the whole No. 5 seam (No. 5 seam upper and lower) has an average thickness of 1.8 m. It also contains a parting of carbonaceous shale which divides the seam into two parts. No. 5 seam upper contains less tonnage compared to No. 5 seam lower. The calorific value and ash content of No. 5 seam lower is far better than No. 5 seam upper, but would still require washing the coal. This makes No. 5 seam lower the preferred seam to mine because it meets the requirements of the customer which is Highveld Steel. It is a coincidence that the area containing No. 5 seam under investigation encounters high overburden problems. The problem of drilling to No. 4 seam was going to be encountered because the thickness of the overburden ranges from 35 to 39 m. The Gardner Denver at the mine can drill blastholes only to a depth of 34.5 m, meaning the full overburden will not be drilled at once. This means the mining of No. 5 seam will do favours for Eskom because the overburden thickness will be minimized. This then led to an agreement between Anglo Coal and Eskom to mine No. 5 seam because both companies benefit from the project. In order to identify a suitable mining method for No. 5 seam lower, literature studies took place. It is found that San Juan mine from the USA has similar geological features to Kriel Colliery&apos;s No. 5 seam. Through comparisons, it is found that truck and shovel mining would suit the geology of Kriel Colliery&apos;s No. 5 seam since San Juan mine is using it. The sequence of mining No. 5 seam lower allows for a clearance of two cuts between the truck and shovel operation and the dragline. The mining sequence of No. 5 and 4 seam will be in the order of top soil removal; soft overburden pre-stripping; pre-strip drilling; pre-strip hard overburden; No. 5 seam lower coaling; interburden drilling and blasting; interburden stripping and No. 4 seam coaling. Financial evaluation of the project shows that a contractor will charge Kriel Colliery (Anglo Coal) approximately R 102.2 million to mine No. 5 seam successfully. The sales of No. 5 seam lower will provide a profit of R99.4 million at a yield of 70% from the washing plant. The project is beneficial to both Eskom and Anglo Coal because Eskom will have eliminated the problem of pre-stripping and Anglo Coal will generate additional profit. Through investigation and analyses of the project, it is proven to be viable and should take place. This is after looking at the advantages that the project has for Anglo Coal and Eskom. Keywords No. 5 seam, truck and shovel mining, Kriel Colliery, No. 5 seam mining at Kriel Colliery opencast, Anglo Coal and Eskom, No. 5 seam upper and lower, top soil removal, soft overburden pre-stripping, pre-strip drilling, pre-strip hard overburden, No. 5 seam lower coaling, interburden drilling and blasting, interburden stripping, No. 4 seam coaling.

Jan 1, 2011

By M. G. Maruma, L. A. Mampuru

"Mill liner wear is a major cost item in the mining industry and there is continuous research to prolong the life of the liners. Over the years it has become apparent that even though high-chromium white cast irons are highly efficient as abrasion-resistant materials, a combination of wear resistance and fracture strength remains difficult to achieve. Increasing the hardness of the high-chrome white cast iron (HCWCI), which improves the resistance to abrasion wear, is often accompanied by a deterioration in fracture strength. Operational conditions inside the mill require that the liner should be made of highly wear-resistant material with some fracture strength. Vanadium additions ranging from 0.2 to 3 wt% were made to HCWCI in an attempt to refine the microstructure. It was found that an increase in vanadium content promotes grain refinement. A content of 1.5-3 wt% gave the best results as measured by the maximum breaking strength.IntroductionOver the years it has become apparent that even though high-chromium white cast irons are highly efficient abrasion-resistant material, a combination of excellent wear resistance and fracture strength remains difficult to achieve. The exceptional wear resistance of highchromium white cast iron (HCWCI) is attributed to hard chromium carbides embedded in an austenitic/martensitic/pearlitic matrix. When the chromium contents exceed 12 wt%, interconnected MC3-type carbides of conventional cast irons are replaced by rodshaped and isolated M7C3 carbides (Powell, 1980), leading to an improvement in the impact toughness, ductility and fatigue resistance. However, the main M7C3 carbides in HCWCI are hard and brittle and can provide an easy path for crack propagation. This limits the applications of HCWCI, particularly in severe impact conditions. Most operations involving HCWCI are in crushing and grinding and the life of a part/liner is limited by its wear resistance. However, improving the wear resistance of HWCI comes at the cost of a significant reduction in fracture strength. Concerns about premature failure of HCWCI mill liners in the mining industries prompted a study to improve the wear resistance and mechanical properties of HCWCI."

Jan 1, 2016

By F. Nakhaei, A. Noury, S. Ghodrati

To achieve maximum efficiency in any purification stage, the flotation should be continued until the concentrate grade reaches the feed grade. During sampling from rougher cells of the Iranian Sarcheshmeh copper concentrator plant 1, it was revealed that the concentrate grade of the last five cells of rougher circuit was close to feed grade. Therefore, it was suggested that the concentrate of the aforementioned cells be mixed with rougher feed. In this study, one of eight rougher circuit rows was selected and evaluated. The floatability tests were performed to compare the flotation behaviour of rougher feed and mixture of concentrate of the last five cells with rougher feed in the laboratory scale by a tree analysis process. The results showed that mixing of rougher last five cell concentrate with feed has a detrimental effect on flotation efficiency that leads to a 3% decrease in recovery. It was also observed that with grinding of this concentrate, recovery can be improved. Keywords: Efficiency, flotation, rougher, tree analysis, floatability, concentrate, mixing

Jan 1, 2020

By I. Nolet

Matte tapping is one of the most critical operations of a matte smelter. Every smelter has developed particular matte tapping practices and tap-hole repair strategies that are often based on the experience of the smelter personnel. As a result, very little information has been published on these critical topics. This paper aims at providing the information gathered from a survey conducted in the PGM and Ni industries on matte tapping practices and tap-hole maintenance strategies for different PGM-Ni matte smelting operations.

Jan 1, 2014

By J. D. Zhou, F. Yang, X. G. Bi

"In this investigation, the phosphorus distribution ratios in the CaF2 system and B2O3 system dephosphorization slags for high-phosphorus hot metal pretreatment were measured by an indirect method under laboratory conditions. Firstly, the phosphorus distribution ratio between liquid slag and solid iron was measured, and then the phosphorus distribution ratio between liquid slag and hot metal was calculated. Phosphorus capacity was calculated in terms of the composition and optical basicity of the slag. Dephosphorization slag was also studied by scanning electron microscopy, energy dispersive analysis, and X-ray diffraction analysis. The experimental results show that the phosphorus capacity of the B2O3 slag system is much greater than that of the CaF2 system. It is demonstrated thatB2O3 can completely replace CaF2 as fluxing agent for high-phosphorus hot metal pretreatment. With CaF2 as fluxing agent, the phosphorus capacity increases with increasing CaO content in the slag, but the phosphorus distribution ratio decreases. B2O3, when used as fluxing agent, can react with high melting point phases such as 2CaO·SiO2 and 3CaO·P2O5 in the slag to form new phases with low melting points such as 11CaO·B2O3.4SiO2, 2CaO·B2O3.SiO2, and Ca9.93(P5.84B0.16O24) (B0.67O1.79), thereby acting as a fluxing agent. When the ratio of w(B2O3)/w(CaO) is 0.16, the phosphorus distribution ratio reaches its maximum value, that is, the dephosphorization ability of the slag is at its maximum. IntroductionAs international iron ore prices continue to rise, the development of China's steel industry is facing a lot of pressure. Against this background, development and utilization of domestic high-phosphorus iron ore resources is particularly important. When highphosphorus iron ore is used in ironmaking, the phosphorus content in the hot metal can reach 0.35% or more, and the hot metal must be pretreated. For hot metal with 0.08–0.10% dissolved phosphorus, the traditional hot metal dephosphorization pretreatment technologies are relatively mature. However, when using these methods to dephosphorize hot metal containing 0.35% P or more, the amount of dephosphorization slag can reach 100–150 kg per ton of hot metal. Furthermore, the traditional dephosphorization methods require the addition of large amounts of CaF2 as fluxing agent, and this results in high fluoride levels in the dephosphorization slag. The fluorine in the slag can partially dissolve in water and thereby causes high fluoride concentration in the water and soil. Once the fluoride is absorbed by humans or animals, it can result in toxic effects on the central nervous system and myocardium. In addition, fluoride can accumulate in the environment, and thereby pose a health risk to animals and humans through the food chain (Li, 2007; Liu, Wang, and Dong, 2011, Diao, 2013). The objective of this research is to replace CaF2 with B2O3 as fluxing agent while achieving the expected goals of hot metal pretreatment."

Jan 1, 2016

By M. N. Mathabathe, A. S. Bolokang, C. W. Siyasiya, R. J. Mostert, G. Govender

The b-solidifying g-TiAl intermetallic alloys of nominal composition Ti-48Al (binary alloy), Ti-48Al-2Nb (ternary alloy), Ti-48Al-2Nb-0.7Cr (quaternary alloy), and Ti-48Al-2Nb-0.7Cr-0.3Si (quinary alloy) (in at.%) were developed. The materials produced were tensile tested at room temperature. The as-cast microstructures and fracture surfaces of the tensile tested specimens were examined using conventional metallographic methods. Microstructural examination indicated that the alloys were comprised of lamellar structures (a2+g) embedded in columnar dendritic cores in the as-cast condition. However, the quinary alloy contained a Ti5Si3 second phase. The alloys exhibited no detectable ductility during tensile deformation, indicating the brittleness of all the materials. The fracture surfaces revealed that the alloys failed by translamellar fracture with correspondingly few cleavage facets.

Apr 1, 2021

By F. S. Hoseinian, B. Rezai, E. Kowsari, M. Safari

In order to remove heavy metal ions from a large volume of wastewater with a low ion concentration, ion flotation appears to be promisingly effective. In the ion flotation process, because of the high ion removal percentage, the amount of water recovery percentage is a very important factor which determines the process efficiency. However, ion flotation suffers from relatively high collector concentration to achieve the high removal percentage to the desired limit, which subsequently increases the water recovery. In this study, functionalised graphene oxide (FGO) was synthesised, using a chemical method in the ion flotation process, applied as a collector for increasing process efficiency by reducing the collector consumption and water recovery. The high ion removal was achieved with both collectors of sodium dodecyl sulfate (SDS) and FGO, while the water recovery with a collector of SDS was 3.4% higher than that with a collector of FGO. The results indicated that the FGO could be effectively used for high ion removal and low water recovery in the ion flotation process. Keywords: Ion flotation, synthesised collector, ion removal, wastewater, water recovery

Jan 1, 2020

By C. Chapman, M. G. Reading, M. P. Amsden

Ecstall Mining Limited, a subsidiary of Texas Gulf Sulphur Company, operates the Kidd Creek Mine, a 10000 tons per day base metal producer, near Timmins, Ontario. Two different types of ore are mined and milled: copper-zinc and silver-lead-zinc. At the highly automated Ecstall concentrator the ores are processed by selective flotation in three individual circuits. One of the most important metallurgical tools for process control is a sample system incorporating continuous on-stream X-ray analysis. Recently this system was automated further by the addition of computer control of reagents for two copper-zinc flotation circuits. The computer programs, utilizing optimum seeking methods and smelter contract terms, have increased copper recovery by 1.1 per cent, zinc recovery by 1.4 per cent, and have reduced reagent costs by 16 per cent. Although not expected, copper and zinc concentrate grades were improved slightly as well.

Jan 1, 2014

By V. V. Getman, V. A. Chanturiya, T. N. Matveeva

Most of the Au and PGM ores in Russia are characterised by a thin mineral impregnation of noble metals in sulfide minerals, and a large variety of mineral forms that lead to high loss of precious metals with fine fractions during flotation. In modern flotation technology, the rational choice of reagents is one of the main trends for selective separation of minerals and effective metals recovery. New data on the selectivity of the thermo-sensitive polymer with specific functional groups (TMPPh) as a flocculant and collector of Au and Pt fine fractions are available. The selective modified collector (DEDTCm) for the recovery of Au and Pt from complex ores is discussed in this paper. Scanning electronic microscopy (SEAM), laser SIM and AFM microscopy, UV and IR spectroscopy were applied to study the adsorbed layer of new reagents on the mineral surface. Flotation tests of TMPPh on the gold-bearing ore of the Olimpiada deposit showed an increase in Au extraction and Au content in the concentrate of the rougher flotation. Using a combination of reagents TMPPh and ButX, the quality of the Au and Pt concentrates increased in 1.7 time with an increase in recovery up to 15 % compared with the traditional reagent mode. Testing of TMPPh polymers in flotation of Pt-Cu-Ni ore at Norilsk Nickel has shown the ability to obtain a concentrate with a higher Pt content. Recovery of platinum is 17% higher than recovery in an experiment without polymer. Application of DEDTCm helped to achieve higher technological parameters in flotation of lowgrade Rt-Cu-Ni ore. Compared to the basic mode Pt recovery was plus 13%, Pd recovery was plus 9% and the content of precious metals in the rougher flotation concentrate increased in 2,5 - 4 times. The studies have been supported by Grants of the President of RF “Scientific School of Academician V.A. Chanturiya” NSh-220.2012.5, NSh-748.2014.5. Keywords: Au and Pt complex ores, flotation, flocculation, thermo-sensitive polymer TMPPh, modified collector

Jan 1, 2020