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By M. B. Shirts

Bench-scale studies were made on a reductive hydrometallurgical procedure to convert chalcopyrite flotation concentrate to copper metal or a readily leachable sulfide. Reductive conversion of chalcopyrite and dissolution of iron and sulfur were accomplished in hydrochloric or sulfuric acid solution by the addition of metallic copper, iron, or lead. Use of metallic copper as the reductant enabled extraction of 95 and 46 percent of the iron and sulfur, respectively. The products were ferrous iron, hydrogen sulfide, and a copper sulfide. Use of metallic iron or lead as the reductant enabled extraction of 95 percent of both the iron and sulfur. The products obtained with metallic iron or lead were ferrous iron, hydrogen sulfide, and metallic copper.

Jan 1, 1974

By R. V. Ramani, K. Bode

"IntroductionIn part 1 of this paper, the results of the experimental work in a wind tunnel under controlled conditions were presented. To understand the spatial and temporal behaviour of airborne dust under mine conditions, experiments were performed in the Lake Lynn Experimental Mine of the US Bureau of Mines. The mine airway experiments were designed to study the variations of ambient concentrations along the length of an airway, and the deposition rates and deposition velocities in an airway cross section. Other objectives of the study were to investigate the spatial and temporal behaviour of airborne dust with regard to air velocity and particle density, the size distribution of the airborne dust cloud as it travels in the airway, and the size distribution of the dust particles deposited along the airway. Other objectives of the study were to compare wind tunnel results with In-Mine results, whenever appropriate.Experimental ProcedureLocationA complete description of the Lake Lynn Laboratory Mine of the US Bureau of Mines (USBM) can be found in the US Bureau of Mines Information Circular 8911 (Mattes et al., 1983). This mine provides excellent facilities for dust experiments. The airway dimensions are similar to those of a coal mine airway. The mine has a drift (D Drift, see Figure 1) that extends almost 500 meters without interconnecting airways, stoppings, or bends. The D drift measures approximately 6m in width and 2,25m in height.The Lake Lynn Laboratory Mine· is ventilated by a variable speed, 75 kW (100 hp), 28,3 m3/s (60 000 cfm) blower fan installed on the top of the ventilation shaft. Air velocities of 1, 1,3 and 1,8 m/s, respectively, could be obtained in the D Drift. However, the temperature changes at the surface can cause small variations in air quantities and velocities underground. The low background dust level in the mine reduces the problem of sample contamination from other sources of dust. Extended periods of uninterrupted data collection can also be scheduled. Mine airway parameters which are important for the analysis include the dimensions of the airway and the ventilation data such as the air velocity, and the pressure loss in the drift. All these data were acquired during altimeter surveys which were conducted prior to each of the experiments."

Dec 1, 1995

By H. W. Wainwright

One phase of the research and development work on synthetic liquid fuels conducted by the Bureau of Mines at Morgantown, W. Va. in cooperation with West Virginia University deals with the purification of synthesis gas.2/ Most of the experimental studies on gas purification have been directed toward the removal of organic sulfur from gas, either catalytically or by adsorption with activated carbon. An important part of the purification program has been the development of suitable analytical methods for determining organic sulfur compounds. As the total sulfur content, organic and inorganic, of purified synthesis gas should not exceed 0.1 grain per 100 cubic feet, the need for accurate analytical methods is apparent. It is also apparent that such methods must be rapid if one wishes to evaluate various processes for removing sulfur from gas. The organic sulfur found in most gas produced from coal is usually present as carbon disulfide, carbon oxysulfide, methyl and ethyl mercaptans, and thiophene, with the exception of thiophene, the remaining organic sulfur compounds respond similarly to catalytic treatment and can be removed effectively. Not only does thiophene resist most catalytic treatment, but it poisons some catalysts, rendering them ineffective in removing the other forms of organic sulfur.

Jan 1, 1950

By D. K. Dysinger

In this U.S. Bureau of Mines study, neodymium metal of 99.8 pct purity was prepared by electrolysis of Nd203 salts dissolved in a molten fluoride electrolyte. The metal was electrowon in a molten state at current efficiencies of 50 to 60 pct. Oxygen and carbon were the major impurities detected in the product. During operation of the small-scale laboratory cell, a number of technical problems including anode effect, low oxide solubility in the electrolyte, high neodymium metal solubility, reactivity of the metal with the cell materials, and back reaction of the metal with the anode gases were encountered. Approaches to improve cell operation and prospects for commercial adoption of the electrolytic production of neodymium metal are discussed.

Jan 1, 2010

By Ralph L. Brown

The chemical properties of the unsaturated members of the aliphatic series of hydrocarbons are such as to render them " made to order" starting points or basic . materials for the synthesis of hundreds of important organic chemicals . The tremendous quantities of these unsaturated compounds that are being produced daily in the various coal carbonization and oil refining processes , and which at present have little value other than that of fuel , render a survey of the identity and ex- tent of occurrence of these compounds important from the viewpoint of economic utilization and resource conservation The increased need of liquid fuel and the relatively early exhaustion of petroleum resources will eventually require every utilization of liquid fuel products obtainable directly or indirectly from coal . Accordingly , the Bureau of Mines took advantage of an opportunity for examining the gaseous unsaturated hydrocarbons found in the gas obtained when a mixture of water- Collection of the material gas tar and coal is distilled in a gas-making retort . for examination was made possible through the courtesy of the Trent Process Corporation , Washington , D.C. , which was at that time carrying on at the Georgetown Gas Works , distillation of " amal gams " prepared from various coals and oils by the Trent process for cleaning coals . Kanawha gas coal ( 70%) and water gas tar ( 30 % ) from the Washington Gas Light plant were used in the " amal gam" being distilled at that time . The results obtained in this examination are presented here .

Feb 2, 1922

By E. J. Kloos

The Bureau of Mines devised a new machine-test method for measuring carbon dioxide inspired by a wearer of self-contained breathing apparatus. The new method compares favorably in speed and precision with standard man-tests in which the apparatus is tested while actually worn, and is scheduled for use in future approval tests for facepiece carbon dioxide 'measurements. However, man-tests will still be used to measure the efficiency of the carbon dioxide sorbent materials in closed-circuit breathing apparatus.

Jan 1, 1966

By Larmon J. Heath

The Bureau of Mines explored the use of air or natural gas for recovering additional oil from natural water-drive reservoirs with little or no original gas saturation. Engineering and production data for a field in the Mid-Continent area, results of limited laboratory experiments, and data shown in the literature were considered. Injecting air into a water-coned well could seriously damage the well. Injecting natural gas into the watered-out zone could improve the producing water-oil ratio. In the reservoir studied, oil recovery can be increased by injecting natural gas to decrease water-oil ratios. Laboratory tests on a core from the field show an increase in oil recovery of 7.6 percent of the original oil in place as a result of increasing the free gas saturation. This recovery could amount to as much as an additional 6 million barrels of oil from this field.

Jan 1, 1966

By Robert P. Vinson

This report describes three coal mine ventilation studies by the Bureau of Mines in which sulfur hexafluoride (SF6) was used as a tracer gas. One of these studies was conducted to determine air movement and leakage in a sealed area. Another was run to determine the ventilation efficiency of a bleeder system. Finally, a study was made of air leakage across permanent stoppings of parallel intake airways. These studies proved sulfur hexafluoride to be a useful addition to the equipment commonly used in coal mine ventilation analysis.

Jan 1, 1976

By Walter K. Utt

The U.S. Bureau of Mines conducted research to develop an accurate, real-time, position monitoring and warning system for the vehicles used in surface mining. The product of this research will be technology to reduce accidents and injuries associated with the operation of surface mining haulage equipment. The position monitoring system should reduce accidents related to vehicle position and also increase the efficiency of haulage operations. This research was conducted in preparation for development of an accurate, real-time position monitoring and warning system, which notifies equipment operators when they deviate from a known safe course and are approaching a fixed hazard. A radar positioning system designed for marine applications was evaluated and a series of tests was run to determine the accuracy of the radar positioning system when used in a land vehicle. The radar position determination was compared to surveyed values. Both static and dynamic (moving vehicle) tests were conducted. The static test results were marginal and the dynamic test results were not accurate enough for the position monitoring and warning system. Although a promising technology, the system tested needs to be modified to meet the accuracy requirements of mobile mine equipment.

Jan 1, 2010

By Noel N. Moebs

Coal mine roof failure is categorized according to character, trend, or pattern of occurrence. Two principal categories of failure are proposed--geology related and stress related. Geology-related failure includes both lithology and structure. Each of several subcategories reflects the probable cause of failure and thereby provides a basis for the selection of appropriate techniques for reducing the incidence of failure. These control techniques, depending on local conditions, may include supplementary support, destressing, reduction of mine air humidity, or a change in the customary support methods.

Jan 1, 1986

By Van E. Shaw

Fusion of an 86-percent euxenite concentrate with ammonium sulfate was investigated by the Bureau of Mines. Reaction for 4 hours at 400° C results in conversion of both the rare-earth elements and the titanium-columbium components to water-soluble compounds. Similar results are obtained with ammonium bisulfate. Stirring the fusion mass decreases the reaction time substantially. Alternatively, treating the fusion product with a 3-hour, 650° C calcining step renders the non-rare-earth constituents insoluble, thereby allowing selective leaching of a pure rare-earth fraction with an overall yield of 97 percent.

Jan 1, 1967

By Harry E. Tufft

Data were obtained by the writer from a number of the large coul-mine operators in Illinois, on the consumption and cost of timber used in their mines and the quality of the timber now being used as compared with former years. This information supplemented by comparative date for previous years published in bulletins of the filinois Coal Mining Investigation series, and other sources, is presented below. This survey is part of a cooperative study with the . S. Forest Service, of the mine timber situation, with particular regard to the economies to be derived by better selection, preparation, and storage of timber, and especially treatment with preservatives to prolong the life. Geo. S. Rice, chief mining engineer of the J. S. Bureau of Mines, under whose general direction the work was done, gave valuable advice and criticism. R. B. Miller, State Forester, contributed helpful data which he had recent- ly obtained in an independent study of the mine-timber situation in Illinois.

Apr 1, 1923

By W. R. Wrzensinski

This report presents the findings from a l-yr Bureau of Mines program in which sulfur concrete reinforcing materials were tested and evaluated to determine their resistance to corrosion. It also summarizes the permeation characteristics of sulfur concrete and the exemplary performance of precast, reinforced sulfur concrete structures in various industrial environments. The Bureau is furthering the development of sulfur concrete technology as part of a larger effort to find uses for the Nation's plentiful sulfur resources in construction materials. Sulfur concrete is a corrosion-resistant material that can be used in acid and salt environ-ments where conventional materials fail. Penetration of corrosion-inducing agents is minimized because of the low permeation characteristics of sulfur concrete.

Jan 1, 1988

By Robert D. Schmidt

This Bureau of Mines report describes the development and application of a computer model for simulating the hydrological activity associated with in situ leaching. The model is intended to provide uranium resource developers with a description of the flow behavior of leachants and ground water during the development, production, and restoration phases of a leaching operation involving an arbitrary pattern of injection and recovery wells. Different aquifer environments are modeled, using a closed-form solution to the partial differential equation that describes three-dimensional changes in piezometric head as a result of pumping from leachant injection and recovery wells. The computer program can model a maximum of, 50 arbitarily located wells. Numerical techniques involving difference quotients and Taylor expansions about time points are used to derive time, velocity, areal sweep, and fluid volume parameters associated with leaching hydraulics. These parameters are output by the program in graphic and tabular formats. Other numeric methods insure that the program running time is minimized without significantly affect-ing the accuracy of results.

Jan 1, 1980

By Edward D. Thimons

Several types of inflatable stoppings, developed under Bureau of Mines contract for use as mine air barriers during underground production, have been tested by the Bureau. All of the stoppings tested showed significant internal leakage initially but, in all but one stopping, the leaks were sealed with limited effort The stoppings were tested underground in two western noncoal mines under production conditions. The results from the Colorado molybdenum mine showed the stoppings to be generally unsatisfactory for daily mine usage if they are deployed near blasting areas or in locations where near-perfect air seals are required. They were very susceptible to blast damage and seldom were better than 90 percent efficient as air barriers. However, stoppings tested in the New Mexico uranium mine were located substantially distant from any blasting. Because slight leakage past the stoppings was acceptable, they proved very satisfactory in that application.

Jan 1, 1976

By Philip W. Holland

The U.S. Bureau of Mines has designed and built an inexpensive, weatherproof, temperature-controlled cabinet to provide temporary housing for analytical instrumentation. The cabinet consists of an inverted Styrofoam ice chest, an electric fan for air circulation, and a proportional temperature controller equipped with a thermistor sensor and a light bulb as the heater. The cabinet provides a constant-temperature environment for a moisture analyzer and a strip chart recorder when outside temperatures range from -SO to 21° c.

Jan 1, 1993

By Robert P. Vinson

The Bureau of Mines investigated the presence and extent of methane accumulations in mine roof cavities using a full-scale mine model. Methane was released at a constant rate into the roof of a cavity built onto a 700-ft wind tunnel. Two box-shaped roof cavities were used in the study: one had a volume of 114.7 cu ft; and the other had a volume of 57.3 cu ft. Methane concentration was measured at 28 sampling points in the cavities using 21 different combinations of gas emission rates and air velocities. Brattice hung in the cavity helped reduce methane concentrations without auxiliary ventilation. It was also found that the effective ventilation rate increased by a factor of 40 in the large cavity and by a factor of 20 in the small cavity when air velocity was increased from 100 to 600 fpm.

Jan 1, 1978

By Thomas M. Barczak

This report describes a study that examined load transfer mechanics in longwall shield supports as part of the Bureau of Mines research program to optimize support design and utilization. The objectives of this study were to determine the contribution of the leg cylinders and the caving shield-lemniscate assembly towards full shield vertical and hor-izontal load resistance capability and to determine how the interaction of these members affect overall shield response. Load-displacement characteristics of the leg cylinders and the caving shield-lemniscate assembly, independent of the full shield, were evaluated from controlled displacement tests in the Bureau's mine roof simulator and responses were compared with full shield responses to identify load transfer mechanics. It is concluded from this research that the participation of the caving shield-lemniscate assembly significantly affects the response of the shield support. It is likely that the caving shield-lemniscate assembly is not participating fully in current shield designs because of translational freedom in the numerous pin joints. It is also concluded that the shield will respond differently to different boundary condi-tions resulting from interaction with the strata. This report describes load transfer mechanics of shield supports and the implication of these research findings on shield design and utilization.

Jan 1, 1988

By John Durkin

Owing to the daily exposures of uranium mining personnel to 222Rn daughters, a device is needed that will continually monitor individual exposure. Such a device has been built and tested by the Bureau of Mines and is known as a radon daughter dosimeter. This is an electronic instrument using a solid-state detector and circuitry. The concept of the instrument, which is a personal device worn throughout the working shift, is to evaluate an individual's cumulative exposure to airborne radon progeny, expressed in units of working level hours. Since the instrument is in close proximity to the miner and measures continual exposure, it avoids the errors caused by the present technique of spot checking of the environment and provides a more accurate account of total cumulative exposure.

Jan 1, 1977

By L. B. Berger, W. P. Yant, George W. Jones

Improper combustion of natural gas is the cause of low efficiency in heating appliances , also the liberation of carbon monoxide , an insidious and deadly gas . Carbon monoxide is produced during the incomplete combustion of any carbonaceous material , and quantities as low as 0.2 per cent may product death in a very short time . For healthy atmospheric conditions in the home , in which the occupants are continuously exposed , carbon monoxide should not be present in amount greater than 0.01 per cent , which value is taken as the safety limit in this report . The tests herein reported give the conditions which produce carbon monoxide when radiant -fire heaters burning natural gas are used . The conclusions drawn are based on tests made on one type of radiant heater only , but the general conclusions should apply to other types of radiant heaters of similar construction . The gas consumption , gas pressure , orifice pressure , size of orifice , and heater adjustments were changed so as to obtain as many different operating conditions as possible . In a general way the tests were carried out under the same conditions that the heater might be operated in the home .

Feb 1, 1923