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By Alla D. Mah

Energies of combustion of vanadium nitride (VN) and vanadium carbide (VC) were measured. Correcting to vanadium tetroxide (V204) as the final state, the heats of combustion were ?H298.15=-118,700±100 cal/mole of vanadium nitride and ?H298.15=-240,270±360 cal/mole of vanadium carbide. With vanadium pentoxide (V205) as the final state, the heats of combustion were ?H298.15= -133.440±100 cal/mole of vanadium nitride and ?H298.15=-255,020±360 cal/mole of vanadium carbide. Combining these results with vanadium oxide data, the heats of formation obtained were ?298.15=-51,880±200 cal/mole of vanadium nitride and ?H298.15=-24,350±400 cal/mole of vanadium carbide. Heats and free energies of formation of vanadium nitride and carbide were calculated to 2,000° K.

Jan 1, 1963

By James H. Scott

A technique of seismic refraction data analysis has been developed in which a digital computer is used to generate a two-dimensional model representing a layered-earth depth interpretation. Travel times are picked on seismic records by the human interpreter. These times, together with shot point and geophone locations and refraction layer control information, are submitted to the computer on punched cards. A first approximation delineation of each refraction horizon is obtained by a computer adaptation of the delay-time method. The approximation is then tested and improved by the computer through the use of a ray-tracing procedure in which ray travel times computed for the model are compared against field-measured travel times. The model is subsequently adjusted in an iterative manner so as to minimize the discrepancy between computed and measured travel times. The Fortran program is listed in the appendix of the report together with instructions for preparing data cards and examples of results.

Jan 1, 1972

By J. G. Croeni

The titanium-iridium alloy system was investigated to determine whether alloys of this system would merit further development as control-rod material for nuclear reactors. A study was made to determine the titanium-iridium phase diagram by using melting-point, thermal analyses, X-ray diffraction, dilatometric, electrical resistivity, and metallographic techniques. The titanium-iridium alloy system was investigated between 500° and 2,400° C. Results indicate the formation of two intermetallic compounds, Ti3Ir rind TiIr3, and one intermediate solid solution centered about the 50 atomic percent iridium composition. A eutectic reaction occurs at 1,475° C, and 19 atomic percent iridium. The Ti3Ir decomposes peritectically at 1,520° C. The intermediate solid solution exhibits a maxima of 2,140° C. at 50 atomic percent iridium. This phase is also believed to undergo an order-disorder transformation at 1,750° C. Another eutectic reaction takes place at 2,000" C. and 60 atomic percent iridium. The compound TiIr3 formed at 75 atomic percent iridium decomposes peritectically at 2,115° C. Further increases in iridium content result in the formation of an iridium-rich terminal solid solution. Information obtained below 900° C. in titanium-rich alloys indicates that iridium acts as a beta stabilizer in titanium, and the authors believe that a eutectoid decomposition of beta-titanium occurs near 500° C. and 10 atomic percent iridium.

Jan 1, 1962

By L. Cheng

This report describes a laboratory investigation of the effectiveness of low-pressure steam and a steam-water spray sequence for the collection of airborne respirable (<10 µm) coal dust. Comparison of present results to previous results obtained with water spray alone indicates that the use of steam in a steam-spray sequence increases the collection efficiency by about 14 percent over that obtained by water spray alone. However, the use of steam to collect airborne dust requires cooling the steam-dust mixture in order to achieve condensation of the steam, and steam does not appear to be an attractive approach for collecting airborne dust in underground coal mining operations.

Jan 1, 1974

By I. L. Nichols

Volatilization of cesium from pollucite ore was investigated as an initial step in the production of purified cesium metal or cesium salts. High recovery of cesium and rubidium as chloride sublimates was accomplished by 2-hour roasts in a tube furnace using charges containing 1 part ore, 2 parts limestone, and 0.23 part calcium chloride. Recoveries of cesium in the sublimate product were 89.1, 92.9, and 95.2 pct, respectively, using 1,100° C and vacuum, 1,250° C with an air sweep, and 1,250° C without an air sweep. Most of the lithium, sodium, and potassium sublimed with the cesium and rubidium, but virtually none of the calcium, aluminum, and silicon in the charges was volatilized.

Jan 1, 1966

By D. B. Gawthrop

"One of the properties of an explosive, of interest to the user, is its ability to transfer detonation across an air gap to another explosive charge. This Property is of particular importance with permissible explosives used in coal mines, since they are relatively insensitive to detonation when compared to many of the commercial dynamites used in metal mining.An essential characteristic of an explosive is that it shall always be sufficiently sensitive to propagate detonation completely. An insensitive explosive constitutes a hazard because of (1) the danger of drilling into unexploded portions of charges of explosives which have partially misfired, and (2) the likelihood of a low order of detonation, or the burning, of all or part of the charge in a hole prepared for blasting. The latter condition not only usually produces large volumes of poisonous gases, but it is particularly hazardous in gassy or dusty coal mines where explosions may result.The Bureau of Mines and manufacturers of explosives determine the sensitivity of explosives to detonation over an air gap by means of a [(halved-cartridge gap test,"" for which the ends of the cartridges of explosive exposed to one another, are cut off. Since in blasting, the crimped ends remain on the cartridges used, this investigation has been made to ascertain the effect of the crimped paper ends on the distance detonation is propagated over an air gap as compared with the propagation distances obtained when the crimped-paper ends are removed."

Nov 1, 1932

By H. L. Riley, B. W. Gandrud

"INTRODUCTION AND SUMMARYIn connection with a program of research work on coal at its Southern Experiment Station, the Bureau of Mines, in cooperation with the University of Alabama, conducts washability studies of samples of coal from coal fields in Alabama and other Southern States in which commercially important deposits of coal occur. The first such study on coal from a bed in the Arkansas field has been completed, and the results are presented in this report.One of the main objectives of a washability study is to obtain technically and commercially important data in connection with the best methods for preparing and utilizing the Nation's limited reserves of good coking coal. Such information is important from the standpoint of conservation in that it facilitates selection of preparation methods that will yield a good grade of coking coal with a minimum of losses of coal in the rejects.The coal on which this report is based was obtained by underground and tipple sampling at the quality mine of the Quality Excelsior Coal Co. about 3 miles east of Hackett, Ark. This mine operates in the Upper Hartshorne bed, which, as the main source of coal in what is known as the Hackett-Excelsior district, yields an excellent grade of low-volatile coking coal, which is marketed at steel plants in Colorado and California. Production from this bed by the major producers in the Hackett Excelsior district was at the rate of about 125,760 tons annually in 1949, according to the Keystone Coal Buyers Manual. 2/In the laboratory, the tipple sample was crushed to 6-inch top size and screened on a 2-inch round-hole screen. The 2-inch to 0 undersize, amounting to 71.4 percent of the total sample, was fractionated into a series of screen sizes and float-and-sink products to get data for determining the washability characteristics of the coal. Before the screening and float-and-sink tests were made, however, machine cuttings, which are now gobbed underground, were added to the 2-inch to 0 sample. Enough of these cuttings were added so that the resulting mixture was considered representative of what the 2-inch to 0 run-of-mine coal would be if all machine cuttings, including the part now being gobbed, were brought to the tipple as a part of the run-of-mine coal.The mixture obtained referred to in this report as the run-of-mine or raw coal."

Mar 1, 1953

By Richard A. Thomas, Michael J. Sapko, Gary L. Mowrey, William D. Monaghan, Michael A. Trevits

Over the years, more than 20,000 mine seals have been erected in underground coal mines in the United States. Seals are used extensively in underground mines to isolate worked-out areas, active mine fire zones, and to control water inundations. Seals are most often built directly in the mine and can be fabricated from blocks made of wood or cementitious material. Recently, several explosions occurred within sealed areas of underground U.S. coal mines. These explosions, believed to be initiated by lightning strikes on the surface, destroyed numerous seals and caused considerable damage external to the sealed area. The National Institute for Occupational Safety and Health is conducting research to develop design guidelines, to investigate noninvasive techniques to characterize seal strength properties, and to evaluate seal test methods. As part of this work, a 30-ft wide, 16.1-ft tall and 4-ft thick seal was built in an underground experimental mine using cement and foamed water. Two types of noninvasive techniques are currently being investigated, namely the Schmidt Hammer for measuring compressive strength and ground penetrating radar (GPR) for detecting the presence of anomalies (e.g., voids, discontinuities) within the seal. Once these noninvasive tests were completed, the seal was subjected to destructive explosion testing. This study presents the results of the Schmidt Hammer tests, GPR scans, and the characteristics of seal failure during explosion testing.

By J. Schlocker

The present emergency has greatly stimulated interest in the light metals - aluminum and magnesium - owing to their extensive use in airplane construction. The $63,000,000 plant being erected in the Las Vegas Valley by Basic Magnesium, Inc., under the auspices of the Defense Plant Corporation,

Jan 1, 1942

By S. R. B. Cooke, J. Bruce Clemmer, F. P. Diener

"The limestone deposit utilized by one of the plants of the Universal Atlas Cement Co. is covered in part by a stratum of cherty limestone. If this overlying deposit could be utilized by removing the excess of chert economically, quarry costs could be reduced and the amount of rock economically available would be increased greatly. On account of the distribution of flint and limestone, a product fairly free of flint can be obtained until the quarry face is about 50 or 55 feet high. As the face is worked farther back into the hill, the comparatively clean stone is overlain with a constantly increasing amount of high-flint limestone. If this flint remained with the limestone, there would be a prohititively high silica ratio in the finished cement; if the flinty layer were removed as overburden a very large tonnage would be handled and much good stone lost. Consequently it was felt that means should be devised for separating the flint from the limestone after it reaches the plant.The investigation was undertaken by the Mississippi Valley Experiment Station of the United States Bureau of Mines in cooperation with the Universal Atlas Cement Co. and the Missouri School of Mines and Metallurgy, Rolla, Mo.CONSIDERATION OF PROCESSESMany schemes for the separation of Minerals are based on differences in the specific gravities of the minerals to be separated. In this case the flint has a specific gravity of approximately 2.62 while the limestone averages about 2.70. This differential is not large enough to permit separation by any method based on specific gravity. Furthermore, all the limestone particles in any given sample are not alike; usually about 10 percent of them have a specific gravity the same as, or lower than, the flint."

Mar 1, 1935

By Paul B. Harder

Round Mountain Gold (RMG) in central Nevada, reports that over a nine-year period and a million operating hours, its fleet of 150-ton and 190-ton haul trucks has averaged better than 93% availability, with some of the trucks approaching 70,000 operating hours. Repair costs have been far below industry averages. Mine operations manager Pete Kesl credits the high availability and low repair costs to a succession of Product Support Agreements between RMG and Caterpillar dealer Cashman Equipment. He adds that good equipment and a high level of trust and co­operation between all parties to these agreements have been essential to their success at Round Mountain.

Jan 1, 1998

By Uldis Jansons

This report evaluates the economic Mining feasibility of four selected mineral deposit types that can be anticipated to be found in (d)(2) lands in the western Brooks Range, Alaska. The major assumption made for this study is the availability of a rail system for transporting equipment and concentrates for the base metal mines. Commodity prices used are those in existence in July 1976. Mine models were established based on known deposits and then evaluated. A lead-zinc-silver-barite deposit for which grades were available but ore reserves were assumed would require approximately 25% higher ore grades or higher metal prices to yield a 15% discounted cash-flow rate of return an the investment if mined at a rate of 10,000 tons per day open pit methods. Large copper-zinc mineral deposits could be mined economically at rates either of 5,000 tons per day underground or 10,000 tons per day by open pit methods. A high-grade copper deposit require a copper price of over one dollar ryes pound to yield an economic profit to be mined at 2,000 tons per day by underground methods. A small high-grade gold underground mine would require a gold price of about $295 per ounce to yield a 20% discounted cash-flow rate of return on investment if all new mine equipment were used and if existing labor rates were paid: Enterprising mining groups operating as partnerships might be able to operate this mine profitably at a gold price of about $152 per ounce, perhaps slightly less.

Jan 1, 2012

By D. S. Kimmel

The Bureau of Mines sponsored development of a system to remotely energize and de-energize the trolley wire in a section in response to demands from vehicles as they enter and leave the controlled section. The system developed utilizes a detector/actuator that controls a dc contactor at the outby end, and a 3 kHz oscillator at the inby end. A prototype system has been built and installed at the Bureau&apos;s trolley test site at Bruceton, Pennsylvania which has demonstrated the ability to also provide load discrimination for faults of 300 amperes or more. The system could readily be modified by locating the oscillator on the vehicle to provide automatic de-energizing of the trolley wire when the vehicle&apos;s pole is removed or the vehicle leaves the section.

Jan 1, 1978

By E. J. HOFFMAN, J. c. W. FRAZER

The apparatus and methods described in the following pages were devised and used by the writers in connection with certain investiga- tions of the technologic branch of the United States Geological Sur- vey, especially those bearing on the improvement of furnace condi- tions and on efficiency in the use of fuel. The Bureau of Mines, which has charge of such analyses and tests of fuels as were formerly made by the technologic branch of the Sur- vey, is using the same apparatus and methods in connection with similar investigations that are being carried on at the testing plant of the bureau at Pittsburg, Pa. The furnace conditions prevailing both in small plants and in large industrial establishments in this country are frequently far from satisfactory. If such conditions are to be improved, they must be more thoroughly understood, and means must be found to insure complete combustion of the fuel, and yet to permit operation with such an excess of air as will result in the greatest efficiency. In this work the services of the chemist are indispensable. A very important problem is the determination of the small percentage of unburned combustible matter that escapes from the furnace in the flue gases. Under ordinary circumstances so little as 0.1 per cent of unburned combustible matter in a furnace gas is equivalent to about 1 per cent of the fuel used; and for the determination of such small percentages of gas more accurate and refined methods are required than have ordinarily been available heretofore. It is the purpose of this paper to describe some apparatus and methods which have proved satisfactory to those engaged in the chemical work of the investigations mentioned. While these methods and apparatus have been designed more particularly with regard to analysis of furnace gases, their use is by no means limited to that purpose. The reader will readily see their applicability to other uses in which the sampling and analysis of gases are involved.

Jan 1, 1911

By Ralph L. Brown

"IntroductionThe accumulation of gummy and resinous deposits in consumers' gas meters began to assume serious proportions about 1917. As the trouble developed and spread in the years following, it manifested itself in several ways, which ultimately began to the expressible in distinctly economic terms, more specifically in terms of costs; in 1922 an organized and fundamentally based investigation of this trouble was begun. In an earlier paper*** a short statement of the occurrence and costs of the deposition was given and at the same time an analysis of the problem, as well as well as a general plan of attack, was presented. That plan included two general phases, first, a chemical study of typical was 1 quarry or 2 cosinous content , mauformly consituents, rmln and selected subjects; and secondly, a comparative survey of plants affected and sufficient therewith, attention being paid to construction, operation, meter conditions and related data. In reporting progress in the axtual investigation, it was definitely set down that the basis of the gummy deposits was the unsaturated hydro consulting from the carburxtion of the water-gas with oil. That the presence of oily-gas condensate was closely associated with and largely"

Jul 1, 1923

By Floyd G. Anderson

The increasing trend toward use of continuous-type mining machines created a significant dust problem in coal mining, which resolved itself into three categories: Visibility at face, deposition on return airways, and the potential health hazard. The control measures applicable to these conditions and studied or developed from 1955 through 1957 are summarized and reviewed in this report. Other important problems brought into focus during the same period were radiation exposure in uranium mining and high temperature and humidity. Although temperature and atmospheric pressure alone may not be contributing factors in the incidence of silicosis, the few mining companies who operate under the extremes of these conditions are dust conscious and keep dust-control engineers on their operating staffs.

Jan 1, 1961

A working understanding of present coal mine communications equipment and its usage is an essential prerequisite to the determination of future communications systems needs. As a means of gaining this understanding, a field survey program was planned and implemented. The plan formulated called for obtaining both qualitative and quantitative data from three main areas of interest: the types, physical condition, and performance characteristics of equipment presently used in the sample of mines to be visited; the relationship present communications has to safety and productivity; and the practical, future communications needs as de- rived through interviews with present mine management. In compliance with the original plan, the type and physical condition of equipment in use was found through at-mine interviews of personnel responsible for installation and maintenance. Further evaluation was made through the review of equipment instruction books and maintenance manuals and through in-mine inspection of communications equipment and signal distribution networks. The performance characteristics were determined through listening to conversations and noise levels and by talk-testing from randomly selected stations throughout each mine. System operation was evaluated by asking communication system users their opinions and by noting any difficulties personnel had using the systems. Plans in the second area of interest--that of relating communications to mining operations-- were to observe mining operations and usage of communications; to gain insight through interviews with mine management, from mine superintendents to section foreman; and to look for correlation between communications, production, and safety. Lastly the communication systems needs and requirements were determined from first hand interviews of mine personnel, from the analysis that lead to the individual reports on the eight mines, and from an overview of all of the mines studied. The latter was done to find commonality between the needs of the individual mines such that system requirements having the greatest universal value could be derived, thus lowering per-mine cost of equipment through economics of scale. Armed with tape recorders, backgrounds in communications technology, and with an interview questionnaire that was improved as experience was gained, engineers visited the eight mines to obtain the raw data from which the needs and requirements could be developed through analysis. During the first part of the program two days were spent at each mine so that interviews and tours could be completed, and so that full eight hour shift phone usage recordings could be obtained for statistical analysis. One day visits were sufficient for those trips where tape recordings were not made. During the later trips less attention was given to the statistical nature of communications, and more to how communications relates to the total mining operation.

Nov 15, 1974

By R. S. Sanford

The Muir Inlet or Nunatak molybdenum deposits arc in the Glacier Bay district, Muir Inlet, miles northwest of Juneau. The deposits were examined by Bureau of Mines engineers, and the area was mapped by a field party of the Federal Geological Survey during the summer of 1942. 5/ The following year the Bureau of Mines began developing the deposits. A total of 217 channel samples were taken, and 2 diamond drill holes totaling 256 feet wore drilled. The samples were sent to the&apos; Bureau&apos;s laboratories at Rolla, Mo. for beneficiation.

Jan 1, 1949

By R. C. Annear

This report describes open, sublevel, and shrinkage stoping at the Greenwood mine, operated by Inland Steel-Co. The iron ore mine is in Marquette County, Mich., about 6 miles southwest of Ishpeming (fig. 1). The Greenwood is one of three active underground hard-ore mines on the Marquette range, the others being the Cliffs-Shaft and the Champion mines. The operation reflects an achievement in exploiting small, difficult-to-mine hard-ore bodies lying beneath a 200-foot overburden of glacial drift, which is partly water bearing. This report can indicate only briefly the efforts of personnel in overcoming adverse conditions in mining more than 2 million tons of ore, 80 percent of which was in lump form, for open-hearth production of steel. Significant data presented include descriptions of the principal mining methods employed, sublevel and shrinkage stoping; percent aged mining costs for the entire year 1957, covering both direct mining costs and general expenses; and performance records in units of labor, power, and supplies.

Jan 1, 1960

By Russell R. Trengove

In order to extend or delimit the known ore reserves adjacent to the Comet Coalition property on the western slope of the Highland Peak Range about 8 airline miles west of Pioche, Nev., the Bureau of Mines undertook an exploration project of diamond drilling. Production figures from this property, formerly known as the Schodde, are not available, but it has been reported that small amounts of rich silver and gold ore were Shipped by wagon to a smelter in the Salt Lake valley during 1900-1910. Small shipments were reported for the period 1915-1927, also. A study of the Pioche District by the Federal Geological Survey in 1942 and 1943 was the basis for the exploration program of the Bureau of Mines in 1947 This program consisted of diamond-drilling three holes. The total footage was 2,967 feet. No. 1 hole was drilled 1,260 feet, a record depth for diamond drilling in the Pioche District. Silver-bearing lead-zinc sulfide ores are found in the Combined Metals limestone, known locally as the C.M. bed, These deposits have been formed by replacement of the limestone that is inclosed in the Pioche shale.

Jan 1, 1949