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By G. A. Brady

Laboratory tests were conducted to determine the technical feasibility of separating anthracite particles from a water-anthracite slurry by atomizing the water and removing the resulting mist in an air current. Products containing 21 percent or less moisture were obtained from slurries made with minus 60-mesh anthracite. Typical recoveries ranged between 67 and 79 percent of the feed when the slurries were atomized in air currents with velocities below 70 ft/min.

Jan 1, 1967

By E. G. King

Strontium sulfide and barium sulfide occur as intermediates in commercial treatments of the impure natural sulfates to produce pure strontium and barium chemicals. Thermodynamic considerations involving these sulfides have been hampered by lack of basic data, such as the entropies at 298.15°K. This paper reports the results of heat capacity measurements of strontium sulfide and barium sulfide in the temperature range 50°-298°K. The entropies at 298.15°K. were derived from the heat capacity values. Free energies of formation at 298.15°k. were computed from the entropies and literature values of the heats of formation. Strontium sulfide and barium sulfide are thermo-dynamically less stable than calcium sulfide, but more stable than magnesium sulfide.

Jan 1, 1960

By R. H. Grau, A. Sainato, S. J. Schatzel, T. M. Kohler, A. T. Iannacchione

This Bureau of Mines research study found gas emission rates from an advancing face, and flows and pressure of gas from an exploration drill hole were dependent upon the geology of salt encountered in a domal salt mine. Normal production-grade "pure" salt adjacent to an anomalous' zone was found to have a methane emission rate of less than 5 ft3/ ton (0.1 m3/t) of mined salt from a room advanced by a continuous miner. Extremely low gas flows [less the 4 ft3/h (0.1 m3/h)] and lack of pressure buildup were also observed from this normal salt in a 154-ft (47-m) exploration drill hole. These data indicate that methane emissions should not be a problem when mining in this type of salt. In the adjacent anomalous zone, methane emission rates ranged from 15 to 70 ft3/ton (0.4 to 1.8 m3/t) of mined salt from an advancing face. Gas flows of approximately 42 ft3/h (1.2 m3/h), and pressures in excess of 900 psig (6,200 kPa) were observed in an exploration drill hole when the anomalous zone was encountered. This information suggests a greater methane emission hazard from the anomalous zone than from the associated normal salt. If this trend of increasing emissions problems associated with anomalous zones of salt is common with similar anomalous zones encountered or observed in other domal salt mines, then special control strategies should be employed to minimize this potential mining hazard.

Jan 1, 1984

By G. S. Scott

The investigation of the causes, behavior, and control of anthracite mine fires, which the Bureau of Mines has been carrying on has yielded several publications directly applicable to mine-fire problems. 3/, 4/, 5/, 6/, 7/, 8/ As a further step in elucidating the causes of heating in certain anthracites subjected to oxidation, reliable information vial needed relative to the actual amount of heat that is liberated when a unit volume of oxygen combines with anthracite at varying temperatures.

Jan 1, 1939

By H. J. Coleman

Knowledge of the types of naturally occurring sulfur compounds in petroleum is of both theoretical and practical interest to petroleum chemists and geologists. This knowledge has been extended by the identification of 77 sulfur compounds, including 36 thiols, 23 chain sulfides, and 18 cyclic sulfides in a 111° to 150° C boiling range distillate of Wasson, Texas, crude oil. The characterization procedure used in separating and identifying these compounds included isothermal distillation, vacuum fractionation, liquid-solid chromatography (alumina adsorption), chemical treatment, gas-liquid chromatography, microdesulfurization, and infrared analysis. The procedural steps described represent a systematic method of sulfur compound analysis considered applicable for determining the nature and concentration of the sulfur constituents present in any straight-run petroleum distillate of the above-boiling range.

Jan 1, 1966

By A. J. Leighton

An improved mathematical model with the attendant computer program to calculate multiphase fluid flow in petroleum reservoirs is presented. The model is used to simulate the behavior when a fluid is used to displace hydro-carbon fluids in a reservoir. The method is an expansion of a previously published method, in Bureau of Mines RI 7011, but handles constant injection rate as an alternative to constant pressure. Program documentation is provided along with thorough explanations of the added program features. Using the program, the petroleum engineer can calculate oil recoveries for different flood patterns and operating conditions and select the conditions most likely to optimize recovery. Experience with the previous model demonstrated the need for the improvements in order to simulate reservoir behavior more accurately. The improved method will result in improved oil recovery. In this paper, the significant improvements are described in detail so that anyone interested can put the program to use.

Jan 1, 1975

By H. R. Babitzke

To develop alloys suitable for use at elevated temperatures, columbium and tantalum were combined with tungsten, hafnium, vanadium, zirconium, and titanium, and the resulting alloys were evaluated with respect to fabricability, hardness, Electrical resistivity, strength at elevated temperatures, oxidation resistance, and bend transition. Of the 23 compositions tested, Cb-2OHf-5W-10Ti exhibited superior high-temperature properties. A recrystallized sample of this alloy was fabricable at room temperature, had a strength of 44,000 psi at 1,200° C, and had an oxidation rate of only 7.7 mg/cm2/hr at 1,000° C.

Jan 1, 1966

By Thomas W. Camm

In this U.S. Bureau of Mines report, mine and mill cost models are presented to make quick estimates of the cost to develop mineral deposits in the desert region of the Southwest United States. Regression analysis was used to generate capital and operating cost equations for each model in the form Y = AXB, where Y is the cost estimated and X is the assumed daily capacity in short tons. A and B are constants determined by the regression analysis. Each is broken down into 11 subcategories to facilitate escalation of costs for inflation and to increase their versatility in economic evaluation work. This report contains 2 open pit models, 6 underground mine models, 11 mill models, and cost equations for access roads, powerlines, and tailings ponds. In addition, adjustment factors for variation in haulage distances are provided for open pit models and variation in mining depths for underground models.

Jan 1, 1991

By R. H. Sprute

The Federal Bureau of Mines conducted full-scale field tests in electro-kinetic dewatering and consolidation of slimes in cooperation with the Hecla Mining Co. at two of the firm's underground mines in north Idaho. To test the technique on new deposits, 4,000 ft3 of slimes from a collection sump, pumped into a watertight stope equipped with electrodes, were treated in two steps. Immediately after placement, direct current was applied using a floating electrode to hasten settlement of suspended fine particles. After removal of clarified water, the residue was further dewatered and hardened with electrokinetic treatment. In 25 hours, the material had become firm and dense with a surface capable of supporting workmen. In testing old deposits, 10,000 ft3 of slimes, placed in an unused tail drift 10 to 12 months previously, were treated. This material was sufficiently consolidated by electrokinetics to allow its removal from the mine with standard ore-handling equipment. In both tests, electrokinetic treatment densified slimes in a relatively short time with moderate power consumption.

Jan 1, 1976

By Margaret R. Egan

This Bureau of Mines report presents results from experimental studies on wood crib fires in an intermediate-scale fire tunnel. Gas concentrations, smoke particle characteristics, heat release rates, and ventilation rates were determined. These measurements form a data base for wood, which can be used with previous analyses for coal and future studies of other mine combustibles, to comprehend the potential hazards of these materials in underground mine fires. A knowledge of the combustion products emitted from these materials will benefit fire detection and control. Results show the changes in burning rate and heat release rate produced by different crib configurations and ventilation rates. Also included are the effects that the burning rate has on smoke characteristics and gas production.

Jan 1, 1986

By W. W. Adams

[The quantity of explosives sold in the United States in January, 1931, for domestic consumption, amounted to 368,100 kegs (9,202,510 pounds) of black blasting powder, 4,810;000 pounds of permissible explosives, and 16,533,000 pounds of high explosives other than permissible. These figures are based on reports received by the United States Bureau of Mines, Department of Commerce, from nearly all manufacturing companies, and include an estimate of sues by several companies that do not furnish monthly reports. Reports actually received from manufacturers shored sales of 365,977 kegs of black blasting powder (consisting of 220,892 kegs of granular powder and 145,085 kegs of pellet powder), 4,687,900 pounds of permissible explosives, and 15,498,152 pounds of high explosives other than permissible. Sales in January, 1931, were smaller than in January last year, the decreases being 14 per cent for black blasting powder, 19 per cent for permissible, and 17 per cent for high explosives other than permissible. Sales in January 1931 when compared with soles in December 1930, show increases for all three classes of explosives as follows: 2 per cent for block blasting powder, 16 per cent for permissible explosives, and 7 per cent for other high explosives. PERMISSIBLE EXPLOSIVES: Of the 4,687,900 hounds of permissible reported sold during January, 97 per cent was used for coal-mining operations, Including 32 per cent for anthracite mines and 65 per cent for bituminous mines. The following Staten were the largest users of permissible explosives daring January: Pennsylvania, West Virginia, Illinois, Alabama, Kentucky, Indiana, and Utah. Their combined sales represented 89 per cent of the entire sales reported for this class of explosives.]

Jan 1, 1931

By W. W. Adams

The quantity of explosives sold in the United States in January, 1931, for domestic consumption, amounted to 368,100 kegs (9,202,500 pounds) of black blasting powder, 4,610;000 pounds of permissible explosives, and 16,533,000 pounds of high explosives 'other than permissible. These figures are based on reports received by the United States Bureau of Mines, Department of Commerce, from nearly all manufacturing companies, and include an estimate of sales by several companies that do not furnish monthly reports. Reports actually received from manufacturers showed soles of 365,977 kegs of black blasting powder (consisting of 220,892 kegs of granular powder and 145,085 kegs of pellet powder), 4,687,900 pounds of permissible explosives, and 15,496,152 pounds of high explosives other than permissible. Sales in January, 1931, were smaller than in January, last year, the decreases being 14 per cent for black blasting powder, 19 per cent for permissibles, and 17 percent for high explosives other than permissible. Sales in January 1931 when compared with soles in December 1930, show increases for all three classes of explosives as follows: 2 per cent for black blasting powder, 16 per cent for permissible explosives, and 7 per cent for other high explosives.

Jan 1, 1931

By Charles Vaught

The U.S. Bureau of Mines evaluated the self-contained self-rescuer (SCSR) donning proficiency of 243 miners. These workers were from eight underground coal mines in the eastern United States. The objectives of the study were (1) to gather information on skill levels, since all miners in the study had prior instruction and opportunity to practice donning the apparatus, and (2) to summarize a quality control procedure useful in conducting periodic evaluations of donning proficiency. The sampling procedure used proved to be both reasonable and efficient in gathering information on training effectiveness_ It also provided a good statistical base for making informed site-specific decisions regarding SCSR training needs. Results from the observed samples at each of the eight mines indicate a wide variability across sites. The rate at which miners failed to isolate their lungs varied from 33 to 40.0 pct. Concomitantly, proficiency rates (miners either performing adequately or demonstrating a perfect 3+3 sequence) ranged from 13.3 to 63.3 pct.

Jan 1, 1991

By R. L. Handy

The goal of this research was to adapt the highly successful rock borehole shear test for use in deep, small-diameter boreholes. Operating somewhat on the principle of a rock bolt, the borehole shear test measures both the expansion pressure and pulling force to give discrete measures of rock shearing strength as a function of the applied normal pressure. A new instrument was designed and built to fit into a 2-3/8 inch diameter hole. Unfortunately the design became so complicated, the operation is nut reliable. This is attributed to constraints of the small hole, and added requirements of an in-hole anchor to push against, and a rotating shear plate cleaner for repeated tests down-hole. A clue to the d: vice complexity is its length, which is over 10 feet. Furthermore it employs concentric cylinders and one hydraulic cylinder bored into the piston of another, or it would be even longer. Meanwhile drilling technology has advanced to greatly reduce costs of drilling 5- or 6-inch diameter holes. The downhole tester therefore should be redesigned and simplified for use in a larger diameter drill hole.

Jan 1, 1982

By R. D. Currie

A study of the accident statistics in the coal mining industry convinces one that an organized effort must be put forth to prevent the vast destruction of human life in this industry . The fatality rate in Pennsylvania has not improved in the past several years and during 1928 it was higher than the average for the period 1916 to 1927 , inclusive . Although the accident rate for this State is less than that of the coal mines of the United States as a whole , nevertheless the rate is unduly high ; however , there are many companies which have exceptionally good records as regards both fatal and nonfatal accidents . A study of the methods used by some of these relatively good- record companies to reduce accidents in their mines shows that they exert an organized effort to prevent accidents , and that their safety organizations usually affect every employee in and about the mine from the highest official to the check boy . The chief executive must be actively and personally interested in accident prevention if real safety results are to be obtained ; when he shows this interest it is almost invariably reflected in the officials under him and throughout the organization . Safety organizations vary in form and are readily changed or adapted to the varying conditions found in the bituminous field . The companies whose organizations were studied in preparing this report are all getting good results , and it is their opinion that the safety organizations have been a big factor in obtaining these results . At their request the identity of some of the companies whose organizations were studied has not been divulged in this paper , but this does not affect the value of the information concerning their safety organizations .

Mar 1, 1931

By R. E. Peterson

Scrap iron is partially oxidized at elevated temperatures in the selective oxidation process to produce iron oxide and a dense residual metal of high purity. Investigation of the process was confined to converting automobile hulks into useful products. In one test series, compressed, sheared automobile scrap was processed at 1,000° C in a 36-foot-long rotary kiln at feed rates ranging from 300 to 1,200 lb/hr. Less fuel was required to maintain the temperature at the higher feed rates because of the heat generated from the burning of the combustibles and the oxidation of the iron. The bulk density of the residual metal exceeded 75 pounds per cubic foot. In an attempt to lower the quantity of contaminants in the residual metal, another test was designed using automobile hulks which had been prepared by ripping, a low-cost method of scrap fragmentation. Before oxidizing the ripped scrap approximately 62 percent of the total copper was removed in a tumbling, screening, magnetic separation and hand-sorting system. Cast iron made from the residual metal obtained by selective oxidation contained 0.15 percent copper; iron oxide scale obtained from the kiln averaged 0.13 percent copper. Pellets made from the scale demonstrated compressive strengths necessary for blast furnace reduction; lead and zinc were removed by volatilization when the induration was performed in a reducing atmosphere.

Jan 1, 1972

By R. S. Dean

The development of metallurgical processes may be divided into periods : First , the discovery of a basic reaction which brings about the production of the desired product from the available raw material ; second , a long stage of mechanical development during which little or no attention is paid to the reaction itself ; and third , a careful study of the reaction . Most metallurgical processes are to -day approaching the end of the second period . This we may illustrate by the steel process . The reaction of carbon with iron ore to produce pig iron and the subsequent refinement of the pig iron by an oxidation reaction is very old . Development in modern times has been almost entirely mechanical , the development of the blast furnace , furnace , the Bessemer process , the Siemens process , and even the Aston process for wrought iron being mechanical improvements almost entirely . Metallurgy is now entering a phase where the reactions are being considered . The question of how far can they be made to proceed is being repeatedly asked . As mechanical processes are improved , we approach a limit to which our basic reactions can be pushed which is determined by the nature of the reactions themselves . We want to know : How far can iron be decarbonized by iron oxide ? How low can the oxygen of copper be reduced by any given reaction? How efficiently can the fuel in a zinc reduction process be used ? The demand for purer metals and lower production costs has forced these and similar questions upon us . How are we to answer them ? The determination of these equilibria or end points of metallurgical reactions by direct means is fraught with difficulty because here we must overcome mechanical difficulties which too often become the limiting factors even in the laboratory and we do nottherefore get the actual limit to which the reaction itself may be carried . Further , there are so many reactions of metallurgical materials that to survey each separately is a job to give pause to any experimenter or group of experimenters .

Dec 1, 1930

By Adrian J. Mathias

This report presents the results of an investigation of a mine production-scheduling model and a critical path analysis for long-range mine planning. An example is given to illustrate how these techniques might be used to plan long-range development and production scheduling for a large underground mine. The model, based on estimated ore block grades and tonnages, and on designed mine development layout, simulates mining of ore blocks in a sequence necessary to fulfill mill requirements for ore tonnage and grade evaluation within pre-established system restrictions. Simulated production schedules are obtained as output from the model. These production schedules are then incorporated into a critical path analysis to determine the sequence for the long-range development work so as to fulfill the production schedules and thereby meet the ore grade and tonnage requirements of the mill.

Jan 1, 1967

By Cleo Griffith Rall, D. B. Taliaferro

The method for determining oil and water saturations described herein has been used successfully for several years in the core laboratories of the Bureau of Mines. The apparatus constructed according to the original specifications has proved very satisfactory; in fact, it has been widely adopted by core laboratories throughout the petroleum industry. The writers have found that the method gives reproducible results, the degree of accuracy depending largely on the attention to details given by the operator. The relative importance of these details of procedure and the design of the apparatus are discussed in this report. In September 1940, the Bureau of Mines published a report describing a method used in its laboratories for the determination of the water content of oil-field cores. The procedure was essentially the same as that adopted by the American Society for Testing Materials for the determination of the water content of petroleum products, although the apparatus and technique were altered slightly to increase the precision of the method and to adapt it to the characteristics of the material to be tested. The report also contained a description of the method used at that time in the Bureau’s core laboratories for measuring the oil content of a core, utilizing the sample on which the water-saturation determination had been made. The procedure involved the transfer of the weighed sample, from which the water had been distilled and measured, to a Soxhlet extractor and the removal of the remaining oil by means of a suitable solvent. Soon after the report was published, the water-determination apparatus described therein was modified so that both the oil and water contents of a core sample could be determined simultaneously. This method, which has been described by Yuster, is now widely used throughout the industry.

Dec 1, 1946

By A. F. Baker

Laboratory flotation of synthetic coal-pyrite mixtures and high-pyritic-sulfur coal indicated that ferric chloride (FeCl3), aluminum chloride (AIC13), chromium chloride (CrCl3), and cupric sulfate (CuSO4) are potential pyrite depressants. For each metal salt there appeared to be a range of pH values and optimum concentration for selectively depressing pyrite in coal flotation. Pyrite was depressed in the pH range from 4.5 to 7.0 with ferric chloride, from 5.8 to 7.0 with aluminum chloride, from 6.4 to 7.1 with chromium chloride, and from 6.4 to 7.4 with cupric sulfate. Best separation of pyrite from coal was achieved in flotation solutions containing from 2 X 10-5 to 5 x 10-5 mole/ liter of each salt. In solutions containing excess salt concentrations, coal was also depressed. These Bureau of Mines tests demonstrated on a laboratory scale that, in solutions containing 4 X 10-5 mole/liter ferric chloride and from 1 x 10-4 to 2 x 10-4 mole/liter sodium hydroxide, the pyritic sulfur content of a Lower Freeport bed coal sample could be reduced from about 2.51 percent to less than 0.60 percent with recoveries of over 83 percent. The depression of pyrite appears to be due to the adsorption of positively charged colloidal metal hydroxide at the pyrite-solution interface. This hypothesis is supported by zeta potential determinations which showed that suspended coal and pyrite particles in solutions containing metal salts are positively charged in the pH range where depression occurs.

Jan 1, 1971