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By R. C. Corey

Anticipating the need for convenient, economical, and safe means for disposing of combustible wastes contaminated with low-level activity, in connection with private and institutional uses of radioisotopes, the Atomic Energy Commission (AEC) has provided the Bureau of Mines with funds to develop an incinerator for this purpose. A prototype incinerator, designated hereafter as BOMAEC-30, was designed, constructed, and tested, based on fundamental and applied research investigations of the combustion characteristics of rubbish and sawdust, which will comprise the bulk of contaminated wastes. No radioisotopes were used in the tests; the objective was to remove as much particulate matter from the products of combustion as possible. The prototype unit was designed to burn 30 pounds per hour, using 100 percent over fire air admitted tangentially in an all-metal, cylindrical combustion chamber. The gas-cleaning system consisted of special fabric bags and absolute filters.

Jan 1, 1962

By M. Mentser

The exchange of oxygen between carbon dioxide and carbon monoxide that occurs reversibly on carbon surfaces was studied at temperatures of 750° to 850°C and a pressure of 1 atmosphere. Carbon-14 was used to detect and measure the exchange reaction. The extent of oxygen exchange was a linear function of com- position of the gas mixture, and this relationship was used to evaluate the forward and backward rate constants of the reaction. Equilibrium constants, directly determined for oxygen exchange in this study, agreed well with values in the literature that were derived only by indirect procedures. This result establishes the validity of oxygen exchange in the mechanism of carbon gasification by CO2. Rates of carbon gasification were less than an order of magnitude slower than rates of oxygen exchange. Activation energies for these two processes were 58 and 53 kcal/mole, respectively. The closeness in the activation energies argues against any change in the rate-controlling step over a wide temperature span at atmospheric pressure. The role of CO as a retardant on the CO2-C reaction, and the nature of the carbon-oxygen complex are also discussed in view of the data obtained.

Jan 1, 1973

By James Westfield

A brief résumé follows of recent activities of the Division of Coal-Mine Inspection that have had a favorable effect on health, safety, and the reduction of injuries at coal mines: 1. The Federal Mine Safety Code for Bituminous Coal and Lignite Mines of the United States was issued originally by the Director of the Bureau of Mines on July 24, 1946, after consulting with management and labor representatives of the coal-mining industry. The code has been used by Federal coal-mine inspectors while inspecting bituminous-coal and lignite mines as a basis for determining the existence of unhealthful and unsafe conditions and practices in these mines. A revised code was issued by the Secretary of the Interior on October 8, 1953, after further consultations with representatives of management and mine workers and was incorporated by reference in the 1952 and subsequent bituminous-coal wage agreements. The agreement of May 29, 1946, between the Secretary of the Interior, acting as Coal Mines Administrator under authority of Executive Order 9728, and the United Mine Workers of America, covering bituminous-coal and lignite mines in Government possession, charged Federal coal-mine inspectors with the responsibility of making periodic investigations of the mines and reporting to the Coal Mines Administrator any violations of the Federal Mine Safety Code. Federal coal-mine inspectors also had temporary authority to close mines found to be imminently dangerous, but such authority (under Executive Order 9728) was removed on June 30, 1947, when Government control of the mines was terminated.

Jan 1, 1958

By R. L. Bolmer

Rapid depletion of our known mineral resources has stimulated exploration for new mineral deposit. Abandoned mines or prospects may prove to be commercial in today's economy. Often it is necessary to revaluate such properties. Some of these may be inaccessible because of caving of flooding. Many, however, remain in good condition, except that over the years the air in the workings has become depleted of oxygen. Each year the Bureau of Mines receives numerous requests for aid in entering old mines, the air in which is incapable of supporting life. Requests of many individuals who wish to examine or explore-such places with the help, of the Bureau's self-contained oxygen breathing apparatus have been denied because of the hazards involved in the use of this equipment for such purposes. The distance to be traveled in irrespirable gases may be too great for safety; under favorable conditions, a round trip of 2,000 feet from fresh air is the maximum distance that may be traveled.3/ The use of such equipment is hazardous unless a team of at least 5 men thoroughly experienced in its use is provided; and when extensive traveling from. a fresh-air base is required, a reserve team should be provided.3/ Usually, the apparatus is requested for use in exploring workings having only one surface connection, as mines having more than one opening usually are more easily ventilated;,and in some natural ventilation is sufficient or can be made so by cleaning out obstructed openings.

Jan 1, 1951

By J. R. Soule

"The fluorspar deposits in the Gallinas Mining District, Lincoln County, New Mexico, were examined early in February and again in April 1943 by the Bureau of Mines because of the possible importance of newly discovered deposits and of old mine workings showing fluorite-bearing material. There &re many of these deposits spread over a considerable area, and it appeared that exploration might indicate sufficient reserves to support a local mill that could contribute to the supply of fluorspar needed for war purposes. Accordingly, the Bureau initiated an exploratory program in June 1943, which was completed in August 1944.H. E. Rothrock, Roy Earhart, R. G. Smalley, and V. C. Kelly, geologists of the Federal Geological Survey, began mapping and studying the district in May 1943 and continued this work throughout the Bureau's exploration.David J. Stauffer, district ranger, U. S. Forest Service, and several claim owners assisted in the examinations and subsequent exploration.The fluorspar deposits in the Gallinas Mountains are reached by an unpaved forest road, which, leaves U. S. Highway 54 half a mile south of Gallinas station. The road runs due west for 3 miles, then turns due north just beyond the first cattleguard. This north branch is followed for 2 miles to a second cattleguard. There a left branch extends northwest up Red Cloud Canyon to the Red Cloud, and. All. American deposits; the right branch continues north for 2.miles past the Wade Porter ranch, to another left branch, which goes almost 2 miles west to the Hoosier Group deposits. The remaining deposits are reached by trail from either the Hoosier Group or, more easily, from the Red Cloud claim (fig. 1).The Hoosier Group is in sec. l9,, T.. 1S.,1 R. 12 E.; all of the other known ore occurrences are in secs. 13, 14, and 23 to 27, inclusive, T. IS., R. 11 E. All of the deposits are in the Lincoln National Forest and within the limits of a State game refuge. The nearest railroad loading point is Gallinas, Station on the Southern Pacific Railroad. Corona, the next station north of Gallinas, is a Mile or two farther from the deposits.Minor supplied, telegraph, telephone, freight, and express service, and limited living accommodations, Are, obtainable at Corona, 10 to 15 miles from the deposits of Carrizozo, N. Mex., 50 miles south."

Apr 1, 1946

By L. A. Readdy

Pilot Hole "X" was drilled to test the formations through which the ventilation shaft for the proposed U.S.B.M. demonstration oil shale mine would be drilled. The geologic formations encountered in this hole are discussed. Correlation of the geologic horizons encountered in this hole with those encountered in nearby drill holes was accomplished by the use of geophysical logs. Data on the geophysical interpretations are provided. The anticipated geotechnical characteristics of the geologic units encountered in Pilot Hole "X" are described.

Jan 1, 1977

By Shirley F. Colby

Much interest has been shown recently in the possible utilization of dolomite as a source of magnesium metal, a large production of which is deemed essential for national defense. As a result, many inquiries have been received by the Bureau of Mines as to sources of dolomite. This report has been prepared primarily to augment the Bureau's present published information on the occurrence of high-grade dolomite deposits in the United States. To supplement such data, the report also defines dolomite and related rocks and describes their properties and uses. The uses are covered in some detail in Information Circular 6524 entitled "Utilization of Dolomite and High-Magnesium Limestone," published in 1931 but now out of print. All essential data on uses contained in that report have been incorporated herein, and. have: been supplemented by data developed during subsequent years. DEFINITION Dolomite is a mineral composed of calcium end magnesium carbonates combined in equal molecular proportions, expressed by the formula CaMg(C03)2. Dolomitic limestones contain considerable dolomite but also include either

Jan 1, 1941

By D. A. Reynolds, A. C. Fieldner, S. H. Katz

"03-01-192403-31-2019RI 2591 - Reports of Investigations - Department of the Interior - Bureau of MinesBureau of MinesPittsburgh Experiment Station American Society of Heating and Ventilating EngineersU.S. Public Health ServicesTucson Experiment Station Introduction.""Carbon monoxide self-rescuers,"" or simply ""self-rescuers,"" are pocketsize gas respirators which protect the wearer from air contaminated with poisonous carbon monoxide gas. On March 6, 1924, the Bureau of Mines approved the ""M.S.A. self-rescuer’ manufactured by the Mine Safety Appliances Co., Pittsburgh, Pa., after the M.S.A- self-rescuer bad passed all the tests and requirements of the Bureau's Schedule 14A4.The purpose of the self-rescuer is to help miners to escape from mines in which fires are burning or explosions have occurred, by providing protection from carbon monoxide for at least one half-hour. The self-rescuer can be used similarly by workers above ground who may through accident become surrounded or entrapped by atmospheres containing carbon monoxide.no hazards threaten the miner, who escapes serious injury by fire or violence in a large mine fire namely, ( 1) asphyxiation by poisonous carbon monoxide gas; and (2) suffocation by insufficient oxygen to support life. In order to save himself, the miner must either erect a barrica4e5 against afterdamp and wait restoration of ventilation and rescue or take a long chance at getting out of the mine through entries not permeated by afterdamp.. The self-rescuer removes the hazard of carbon monoxide poisoning for one half-hour or more, and accordingly greatly increases the miner's chance of saving his life.This paper describes the construction and details of the M.S.A. self-rescuer as approved by the Bureau of Mines, and discusses its performance under test condition"

Mar 1, 1924

By D. W. Frommer

Composite samples of nonmagnetic taconite from the western Mesabi range were evaluated by reductive roasting, fine grinding, and magnetic separation to determine potential sources of concentratable material. Although large tonnages of nonmagnetic taconite are known to occur in the western Mesabi district, these materials are not as yet a commercial source of iron ore. The technique employed permits the evaluation of individual composites and blocks of composites in terms of responsiveness to a process of potential commercial significance. The 159 composites, from open-pit mines located between Grand Rapids and Chisholm, Minn., were evaluated in the following sequence: 1. Minus 8-mesh material was roasted at 500° C. in hydrogen. 2. The roasted are was ground to one or more sizes in the minus 100-to minus 400-mesh range. 3. The roasted ground ore was magnetically separated in a Davis tube. 4. Composites were classified according to degree of grinding required to produce minimal concentrates. (Minimal concentrates are herein defined as those containing less than 10 percent silica, and responsive composites as those yielding minimal concentrates.)

Jan 1, 1962

1. A total of 14,413 mining operations reported employment to the Mine Safety and Health Administration (MSHA). Nearly half (48.9%) were sand and gravel operations, followed by stone (28.5%), coal (14.7%), nonmetal (5.7%), and metal mines (2.1%). 2. Mine operators reported 240,000 full-time equivalent workers1 (down 3.9% from 1999). Independent contractors reported 42,000 full-time equivalent workers working on mine property (up 8.6% from 1999). Coal operators accounted for 26.8% of reported employee hours, followed by stone operators (25.9%) and sand and gravel operators (12.1%). 3. Eighty-four (84) work-related mine fatalities occurred in 2000 compared to 90 the year before. •The mine fatality rate was 29.8 per 100,000 full-time equivalent workers compared to a fatality rate of4.6 per 100,000 employees for all private industry. •Thirty-one percent (31%) of the fatalities occurred in underground work areas, which account for only17% of total employment. •Although the largest number of fatalities (28) occurred among miners who work for coal operators, coal contractor employees had the highest fatality rate (61.1 per 100,000 full-time equivalent workers). 4.There were 10,839 nonfatal lost-time injuries reported to MSHA, occurring at a rate of 3.8 injuries per 100full-time equivalent workers, and resulting in a total of 417,918 lost workdays.2 •Among all employees,3 the highest injury rate occurred among coal operator employees (5.6 nonfatal injuries per 100 full-time equivalent workers). •The highest percentage (34.7%) of nonfatal lost-time injuries were due to handling materials (e.g., over-exertion in lifting, pulling, or pushing objects), which also accounted for the greatest percentage of lost workdays (29.3%). •Among the most frequently occurring injuries, the most severe (as measured by the median number of days lost) were associated with accidents involving falls of ground, the use of powered haulage, and slips or falls. •The most frequently reported part of the body injured was the back (22.9% of all injuries). Back injuries accounted for the highest percentage of lost workdays (21.6%). 5.Seven hundred sixty-seven (767) cases of occupational illness were reported to MSHA. •The most frequently reported illness was repetitive trauma, resulting in joint, tendon, or muscle inflammation or irritation (37.3%). •There were 155 (20.2%) illnesses reported as hearing loss. The majority (68.4%) of hearing loss cases occurred among surface workers. •Coal workers' pneumoconiosis accounted for 14.5% of reported illnesses.

May 15, 2002

By D. R. Wilburn

The Bureau of Mines investigated the potential availability of magnesium from 45 properties in market economy countries (MEC's). The 38 significant deposits evaluated have demonstrated resources of approximately 29 billion short tons (st) magnesium-bearing material containing 416 million short tons (MMst) magnesium oxide (MgO). Using data it gathered, the Bureau determined the magnesium production potential for each property including a 15-pct rate of return on invested capital. Total and annual availability assessments for the next 30 yr were completed for magnesium (Mg) metal, deadburned MgO, and caustic calcined MgO. At a January 1984 market price of $1.34/Ib Mg metal, the properties evaluated could economically produce an estimated 13 MMst Mg metal. At a market price of $400/st nonmetal magnesium product, these properties could economically produce 109 MMst deadburned MgO and 43 MMst caustic MgO. These properties could produce approximately 301,000 st Mg metal, 3.0 MMst deadburned MgO, and 430,000 st caustic MgO annually at current full production levels and 1984 market prices until at least the year 2000. Total 1984 MEC production assessed in this study was 153,000 st Mg metal and 4.3 MMst nonmetallic MgO products.

Jan 1, 1986

By Alex C. Smith

This report describes laboratory studies conducted by the Bureau of Mines on the spontaneous combustion of U.S. coals. Approximately 11 pet of U.S. underground coal mine fires are attributed to spontaneous combustion. The relative self-heating tendencies of 24 coal samples were evaluated in an adiabatic heating oven. Minimum self-heating temperatures (SHT's) in the oven ranged from 350 C for a lignite and high-volatile C bituminous (hvCb) coal, to 1350 C for two low-volatile bituminous (lvb) coals. An empirical expression was determined predicting a bituminous coal's minimum SHT in the adiabatic oven based on the coal's dry ash-free oxygen content. Several factors that can affect the self-heating process were also evaluated. The self-~eating tendency of a coal increased when the coal was dried and exposed to humidified air, and was dependent on the particle size and oxygen concentration of the air. A new moderate-scale apparatus is described, in which the self-heating tendencies of larger coal samples, 3 kg, can be evaluated. The minimum SHT's of two coals were determined and the results were in good agreement with those found in the adiabatic oven. Finally, results of a test in the moderate-scale apparatus indicated a strong dependence of the self-heating rate of a low rank coal on the moisture content of the air.

Jan 1, 1987

By G. A. Smyres

A GaC12--B2 l-eachtng procedure and meEal-recovery method for treating an arsenical Cu-Co sulfide concentrate was developed by the Bureau of Mines as an alternative to smelting, which is no longer considered an environmentally acceptable method for treating arsenic-containing ores. The procedure involved leaching in a CaC12 solution with CaC03 for 96 h at 26 pct solids (concentrate and CaC03), 1150 C, and a pressure of 50 psig (345 kPa) with oxygen. More than 98 pct of the cobalt and 97 pct of the copper were extracted, and 99.98 pct of the arsenic and 99.9 pct of the iron remained in the leached residue. A filtration rate of 2.9 gal/(ft2.h) [118 L/(m2.h)] and a cake formation rate of 36 Ib/(ft2.h) [172 kg/(m2.h)] were obtained by filtering reacted pulp at 1000 C. More than 99 pct of the copper in the pregnant solution was extracted as CuCl2 by golvent extraction with a new copper extractant. Copper was stripped from the loaded organic with a sulfate-chloride solution, which was used as the anolyte for electrowinning of copper in a membrane cell. Copper plate produced was more than 99.99 pct pure and requi.red 0.81 (kW'h)/lb Cu [1.78 (kW·h)/kg Cu]. Cobalt sulfide was precipitated at pH 3 with Ca(HS)2.

Jan 1, 1986

By Jacqueline A. McClaskey

The U.S. Bureau of Mines (USBM) Information and Analysis Directorate collects worldwide data on virtually every commercially important non fuel mineral commodity. These data form the base for tracking and assessing the health of the minerals sector of the U.S. economy. The USBM's data collection activity was instituted by the 47th Congress in an appropriations act of August 7, 1882 (22 Stat. 329), which placed the collection of mineral statistics on an annual basis. The most recent authority for the USBM survey activity is the National Materials and Minerals Policy, Research and Development Act of 1980 (Public Law 96-479, 96th Congress). This act strengthens protection for proprietary data provided to the U.S. Department of the Interior by persons or firms engaged in any phase of mineral or mineral-material production or consumption.

Jan 1, 1993

By R. J. Fantel

The Bureau of Mines investigated the resources, costs, capacities, market relationships, and short- and long-run supply of phosphate rock and phosphoric acid. The 206 mines and deposits evaluated in 30 market economy countries contain an estimated 35.1 billion mt of recoverable phosphate rock (demonstrated resource level). U.S. resources are sufficient to satisfy the domestic and export markets for phosphate products well beyond the year 2000. Because of resource depletion at current producers, however, new properties (with higher cost levels) need to be developed if U.S. production levels are to be maintained. Existing worldwide capacity can satisfy expected demand through the early 1990's. Expansion at existing mines or low demand growth could mean that no new property development will be needed before the late 1990's. Worldwide, almost $8 billion could be required for development of new phosphate rock properties between now and the year 2000, given 3-pct annual growth in demand. Most properties that could develop in the 1990's would require price increases of 20 to 50 pct to break even. To earn a 15-pct rate of return on investment, prices must rise to nearly double the present level of $24 to $29 per metric ton.

Jan 1, 1988

The first metal-mine accident-prevention course was prepared and published in 1942-45 as a series of seven miners' circulars (Nos. 51-57). The scope of the course has been broadened, revised, and brought up to date and is being published as a similar series of seven miners' circulars (Nos. 51-57, revised) on accident prevention in metal and nonmetallic mines. These circulars are: Accident Statistics (Miners' Circular 51), dealing with general statistics on accidents and injuries at metal and nonmetallic mines, including causes, costs, and the use of investigations and reports of all accidents.

Jan 1, 1957

By J. R. Ross

The extraction and recovery of nitrate from waste solutions generated in the production of titanium were investigated using solvent extraction techniques. Laboratory studies and continuous tests in a small solvent-extraction system showed that up to 98 percent of the nitrate can be selectively extracted by a solution of tributyl phosphate in kerosine. The extracted nitrate can be recovered as nitric acid, at concentrations suitable for reuse, by stripping the loaded organic with water.

Jan 1, 1973

By L. B. Pankratz

Thermodynamic data on the halides were reviewed, evaluated, and compiled at the Bureau of Mines Albany Research Center. Values for Cp°, S°, H-H°298, -(G°-H°298)/T, ?Hf°, ?Gf°, and log Kf are given in tabular form. CP°, H-H°298, ?Hf°, and AGf° are also expressed algebraically.

Jan 1, 1984

By Lewis M. McNay

The Bureau of Hines and industry (mining and private) have studied the placement of hydraulic sandfill in deep-vein mines to identify existing problems and to develop techniques to strengthen the support characteristics of the sandfill. The hydraulic sandfill system, physical properties of typical classified mill tailings, and properties of sandfill modified by various techniques are discussed. Computer analysis has defined the support capability of various sandfills using actual mine field data as a reference base. High-modulus sandfill can provide adequate support in deep-vein mines to alleviate rock and pillar stresses and to reduce rock-burst incidence.

Jan 1, 1975

By B. H. Eccleston, R. F. Kendall, D. E. Hirsch, Norman G. Foster

The mass spectra of 23 alkylthiophenes are presented , including 21 that have not been previously reported . Correlations between mass spectra and the structure of the thiophene homologs are discussed . Comparisons with , and corroboration of , earlier workers ' correlations and predictions are made . Several additional correlations are reported to enable the spectroscopist to identify the substituents on alkyl - substituted thiophenes , and the relationship of the mono - substituted and 2,5 - disubstituted alkylthiophenes is discussed in detail .

Jan 1, 1964