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By Z. B. Pan

The innovative point of this new technology can be described that under normal pressure and 70°C, using a new combined activating and oxidizing agent, the minerals bearing arsenic and organic carbon are oxidized effectively. This technology can be applied in commercial scale. The high carbon and arsenic bearing gold ore is taken from Gansu, where hundreds of tons gold deposit. The ore has 0.51% of arsenic and 1.75% of carbon (1.07% of organic carbon). The gold occurs mainly in native with particle size 0.02~0.6 mm and a few are enwrapped by pyrite and arsenopyrite. The traditional cyanide leaching process gains a very low gold leaching rate with only 5%. Through systemic experimental study, the technological flowsheet of flotation process for concentrating gold, then pre-treating the gold concentrate followed by cyanide leaching the gold concentrate are used. With 4.92 g/t gold of head sample, the gold concentrate with 46.52g/t gold grade and 96.53% gold recovery is gained by flotation process. Followed by pre-treatment for 6 hours, the gold concentrate is leached with cyanide after filtration and washing. The total gold leaching rate is up to 95.44%.

Jan 1, 2014

By C. Abbruzzese, F. Vegliò, S. Ubaldini, R. Massidda

The aim of this paper was to study the influence of different water/organic solvent mixtures (isopropyl alcohol, ethanol and ethylene glycol) on the gold desorption process. The experimental work was carried out on laboratory scale, using activated coconut carbon with different temperatures and extraction times, without adding cyanide. Best results have been obtained in this order: isopropyl alcohol > ethylene glycol > ethanol. Starting from gold concentration of about 5 g Au per kg of carbon, best kinetics resulted in 97-100% of gold extraction, after 8 hours of desorption, at a temperature of 80ºC.

Jan 1, 2003

By W. X. Yin

Electrowinning of lead from aqueous solution of PbCl2 and electrowinning of manganese dioxide from aqueous solution of MnCl2 are two research focuses in hydrometallurgy. This paper investigated a new process of simultaneous electrowinning of lead and manganese dioxide in chloride medium. The simultaneous electrowinning process in chloride solution not only can prevent chloride from liberating at anodes but also obtain two electrolysis products and decrease electric energy consumption. Diaphragm cell is used in the simultaneous electrowinning process to form separate anode and cathode compartment. The effects of temperature, HCl concentration in anolyte, NaCl concentration in catholyte and electrolysis time on current efficiency and cell voltage are studied. The results indicate that current efficiency of anode and cathode for 5 hours is 99% and 96% respectively, average cell voltage is 1. 701V, the weight ratio of lead and manganese dioxide produced at electrodes is 2. 39:1 under the optimum conditions. As anode products, manganese dioxide is ??MnO2, content of which in the products is more than 92%.

Jan 1, 2014

The present work aimed to verify the possibility of using froth flotation to separate the constitu-ent minerals of an alaskite rock waste having as the main minerals quartz and feldspar. Three stages of tests have been carried through. In the first stage was used an amphoteric collector for flotation, diaminedioleate, at pH 2 and, after analyzing the final products, a very poor selectivity was ob-served. During the second stage of tests, different collectors that are normally used for feldspar flo-tation as amines, sulfonates and soybean oil were employed. Once more, it was not possible to reach reasonably selective results. In the third stage, a salt of etheramine was used for collecting the feldspar and hydrofluoric acid was utilized for controlling the pH. A simulation of three flotation steps (rougher, cleaner and recleaner) permitted to attain a good selectivity in the flotation process. A concentrate with a silica content of 96.6% was obtained. The low concentrate content of alkalis totalizing 0.52% and a feldspar recovery of 96.5% to the tailings, represented by the high content of Na, K, and Al2O3 in the tailings, demonstrated that the concentrate was made up mostly of quartz.

Jan 1, 2014

By Yonghui Hu, Hongxiang Ran, Honggang Wei

"A new PVM vertical ring high-gradient high-intensity permanent magnetic separator authorized by China Invention Patent ZL201110294866.4, which featured with vertical magnetic field structure was developed to dramatically save energy consumption and running costs compared with electromagnetic separators. The specific magnetic circuit design ensures PVM separator generating high magnetic field intensity as well as solving equipment large-scaling. The newly developed industrial PVM separator has been proved suitable for recovery of weak magnetic minerals or purification of non-metallic minerals benefiting from its high background and induction magnetic field intensity up to 0.8/1.5T, stable service performance and low running costs. The first ?1.5mm PVM separator has been applied in removing iron from quartz sand in Fengyang, Anhui, and ?2mm PVM separator will be installed to separate hematite. Industrial applications and tests proved that PVM separators could gain similar separation effects and especially save more than 80% of power consumption compared with the conventional electromagnetic high-gradient high-intensity magnetic separator, which will contribute a lot for energy conservation and environmental protection. The development of high gradient magnetic separator technology has played an important role in utilizing weak magnetic minerals, which has been widely used in many mining enterprises. The main forms of high-gradient magnetic separators include both of electromagnetic high-gradient and permanent magnetic high-gradient. The vertical ring high-gradient high-intensity permanent magnetic separator features with high magnetic field gradient, large processing capacity and never clogging, which has been widely used in recovering fine weak magnetic mineral and purification of non-metallic minerals[1-3]. However, electromagnetic coils excitation needs more energy consumption, and relatively high running costs and maintenance costs as a result of the complicated cooling system. So permanent magnetization of the electromagnetic magnetic separation equipment is a very important research direction at present. With the continuous improvement of resource utilization standard and efficiency requirements, high energy consumption of the electromagnetic vertical ring magnetic separator have been highlighted, which has affected the economic benefits of mining enterprises to a certain extent. In the aspect of high-gradient high-intensity permanent magnetic separation equipment, considerable researches have been carried out at home and abroad and many small-sized prototypes were developed yet never strode into large-scale industry applications[4-6]."

Jan 1, 2018

By D. Moradkhani

The heap leaching of oxide copper ores with copper cathode recovery by solvent extraction and electrowinning is now well established as a low-cost method of copper recovery. The main purpose of this study was to extract copper from the copper low-grade oxide ore of Chodarchaei mine using column leaching. The copper oxide ore contained 1.1% Cu and 1.75% Fe. The mineralogical analysis indicated the malachite (Cu2(OH)2CO3) was mainly composed of oxidized phases. The sulfuric acid leaching experiments were performed under the laboratory conditions. The influence of several parameters on the course of the reaction such as particle size, acid concentration, flow rate, and time was examined. The optimum collective extraction of copper and iron was obtained at a particle size of +10-15 mm for a leaching duration of 3 days with sulfuric acid concentration of 100 gpl and using a flow rate of 2.5 cc/min. Under these conditions, the recovery of copper and iron were 98.54% and 41.99%, respectively. Keywords: column leaching, copper, iron, working diagram.

Sep 1, 2012

By P. K. Fedotov

Centrifugal separation opens its new application fields in the Mining Industry. The up-to-date equipment for ultra-fine ore and concentrates grinding allows an efficient use of centrifugal concentration for micronic gold grains recovery. Moreover, advanced centrifugal concentrators are presented on the market: concentrators with continuous concentrate discharge designed both for ore and non-metallic minerals concentration process. The conducted tests proved the centrifugal concentration to be efficient process for gold recovery from finely ground concentrates and ores (less than 20 µm). Knelson concentrator application for such a fine material in different process circuits makes possible to raise the total gold recovery level of plants. In the circuits of coal plants and in course of coal slimes treatment the centrifugal concentration may be used before flotation in order to improve process performances. A centrifugal concentrator KC-CVD with continuous concentrate discharge working on 0.3 (0.5)mm fraction before flotation is

Jan 1, 2014

By Ashiwani Kr Gupta

The floatability of coal is affected by the presence of dissolved inorganic ions in plant process water. Water quality is characterized in terms of conductivity, hardness, turbidity and composition of oil. These quality indices are correlated with coal flotation performance for three different water named, ?R&D laboratory tap water?, ?process untreated water? from West Bokaro wahsey-2 Tata Steel, India and ?process treated water? after passing laboratory developed treatment process. The study clearly indicated that a significant quantity of clean coal is being lost due to poor process water quality used in the flotation process. The laboratory investigations showed that if these dissolved salts and suspended solids are reduced to even 50%, a clean coal yield improvement by minimum 5%~10% at the same ash level could be expected. Therefore, the conventional practice of water recycling though a thickener or a tailings pond needs a complete re-look. The water treatment process for recycled water has also been discussed for improving the process water quality as well as enhancement in flotation performance efficiency.

Jan 1, 2014

By N. R. Mandre

In the present work an attempt has been made to study beneficiation of low-grade iron ore associated with manganese clay by selective flocculation. The representative samples obtained for this purpose were initially subjected to chemical and mineralogical studies. The chemical analyses indicated 42.56 % Fe, 6.25% Mn, 8.72 % SiO2 and 13.60 % Al2O3 in the representative sample. The mineralogical analyses carried out under optical microscope showed that the ore mineral predominantly comprised of iron oxides and hydroxides along with manganese and silicate as gangue minerals. Prior to the beneficiation studies, the samples were subjected to settling tests. These tests were carried out by using poly acrylic acid (paa), poly acryl amide (pam) and guar gum (gg) as the flocculants. From these studies it was observed that settling rate of particles increases with increase in pH and a maximum settling rate of 0.23 cm/secwas obtained at pH 9 in presence of poly acryl amide. Further, the samples were subjected to selective flocculation studies using above-mentioned reagents. From these studies better results were obtained in the experiments carried out with poly acryl amide as the flocculant. Thus, it was possible to upgrade the iron content from 42.5 to 53%, with a recovery of 92%. However, 51% Fe with recovery of 87% and 50% Fe with recovery of 94 % was obtained using poly acrylic acid and guar gum respectively.

Sep 1, 2012

By A. Yörükoglu

In this study, thorium mineral that found in the complex ore deposit bearing bastnasite, fluorite, and barite from Eskisehir - Sivrihisar district has been tried to extract by using HCl and H2SO4 leaching. Ore sample of approximately 3 tons taken from the ore deposit has been homogenized in order to obtain composite samples by means of ore preparation techniques for experiments. Results of chemical analyses of composite samples are as given; 40.8% CaF2, 35.35% BaSO4, 2.01 Ce, 1.5% La, 0.39% and 0.1% Th. HCl and H2SO4 leaching processes have been performed to gain Th in the ore. For determining the optimum particle size, the samples have been ground under controlled conditions and brought to the sizes of 0.065, 0.2, 1 and 3 mm. Leaching experiments have been carried out in both HCl and H2SO4 acids without roasting and roasting at the temperature of 900°C for 1, 3 and 6 h retention times for all particle sizes determined before. In the experiments, the highest Th recoveries reached are as follows; 78.74% Th when H2SO4 and 1 mm particle sized sample used, and 1 h roasting applied and 73.38% Th when HCl and 1 mm particle sized sample used, and 3 h roasting applied. Keywords: thorium, leaching, concentration, sivrihisar, roasting

Sep 1, 2012

By F. Burat

At the present time, methods of mining and coal preparation produce tones of coal fines. The removal of water from these fines is necessary for economical and technological reasons. Supplementary processes that utilize different physical and chemical methods have been developed to in-crease the productivity of mechanical dewatering processes. Researches have shown that chemical reagents used along with conventional systems diminish moisture and increase the capacity and the yields of the dewatering method. In this study, the parameters of the vibrating screen (incline, frequency, feeding rate and screen size), the effects of the application of additional vertical mechanical vibration and surface active reagents (CTAB, SDS, Umectante B-70 and Kerosene) were investigated. At the end of the optimization experiments, 61.0% moisture was decreased to 42.3%. By keeping optimum conditions con-stant, the experiments have been conducted to determine most effective reagent. 41.2% moisture has been obtained with 5 g/t CTAB at the normal pH of the pulp, which were 7.25. By using vibrating screen with combination of the vertical vibrating mechanism, CTAB gave the best result of 40.7% moisture. Finally, the effect of increased surface area of the screen has been investigated and de-creased the moisture level to 38.7%.

Jan 1, 2014

By X. L. Song

A large amount of tailings in concentrators bring a series of problems to the environment and society. It is significant to reclaim the huge tailings and reuse them in industries in order to utilize mineral resources adequately. Primarily Lead-Zinc tailings with a certain quality of clay and feldspar were used to produce ceramic tiles by sintering method under specific technical conditions. By testing the properties of the ceramic tiles, it was shown that the amount of Lead-Zinc tailing used in the tiles was 60%~70%, and the mechanics properties were good. The optimum proportion parameters were Lead-Zinc tailing 60%, clay 35%, feldspar 5%, and the maximum flexural strength of tiles was up to 38.2MPa when it was sintered at 1090? for 30min. Its flexural strength, water absorption and thermal shock resistance reached the State Standard of GB/T4100.4. The product is suitable to be used in pavements and paths of parks.

Jan 1, 2014

By M. Paymardi, A. Foroutan, T. P. Oladele, M. Abbaszadeh

"Reducing the amount of zinc and iron in lead concentrate is one of the important aspects of processing in lead and zinc flotation plants which results in improvement of lead concentrate quality and prevents zinc loss. In mineral flotation industries, lignin sulfonates are known for their depressant properties for both non-metallic and sulfide minerals such as pyrite and pyrrhotite.This paper investigates the effect of lignin sulfonate on flotation of galena, sphalerite and pyrite in sulfidic lead and zinc bearing ores. Batch flotation tests were carried out on a high pre-activated zinc samples. The feed contains 0.9% lead, 2.3% zinc and 7.5% iron. The dosage of all reagents such as sodium cyanide, zinc sulfate, ethyl xanthate and methyl isobutyl carbinol (MIBC) were kept constant for lead flotation step except calcium lignin sulfonate (CLS) that was varied between 0 and 80 gr/ton.Results for lead rougher concentrate showed that the grade of lead increased by 2.7% while the recovery decreased around 4 % at the highest dosage of CLS. Furthermore, zinc recovery decreased by 6.3% with no significant change in grade. Iron recovery in lead rougher concentrate decreased by 2.3 % while the grade changed around 1%. In sphalerite flotation step, CLS dosage was changed in the range of 0 to 80 gr/ton while the dosage of other reagents such as copper sulfate, lime, amil xanthate and MIBC were kept constant. In this step, no decreasing in grade and recovery of zinc was observed, while iron recovery decreased. It was suggested that CLS has a depression effect on sphalerite in conjunction with other zinc depressants such as zinc sulfate and sodium cyanide. CLS was further used in plant with non-pre-activated zinc minerals. Similar trends were observed in plant.INTRODUCTIONlead-zinc sulfide minerals play an important role in the production of lead and zinc metals in the mineral processing industry (Luo, Feng et al. 2016). Due to complexity of the lead-zinc ores mineralogy, in some situations, their flotation properties vary significantly from one deposit to another one even in itself (Bulatovic 2007)."

Jan 1, 2018

By G. J. Feng

Based on detailed theoretical analysis of coarse floatation and three-phase froth, a laboratory system which contains a new type of froth floatation equipment is established. Through water experiment, the relationship among floatation dynamics parameters of the equipment is studied and the best work parameters are educed too. Based on all of above, Slurry test is carried out in a copper concentration plant. Granule between 0.28~0.45mm can be reclaimed successfully. The slurry test proves that to separate coarse minerals in froth floatation equipment is a kind of effective method, it is well worth to make a further study.

Jan 1, 2014

By A. P. Das

Biomining technology focuses on achieving effective recovery of precious metals from their ores and concentrates using microbial techniques. Biomineral extraction of manganese from low-grade manganese ores using bioleaching was investigated in this paper. Five fungal strains were selected for screening of bioleaching of low-grade Mn ore collected from Sanindpur iron and manganese mines, Koira Sector, Keonjhar, Odisha, India. A fungal strain, Aspergillus niger was selected as it showed high efficiency of manganese leaching. Growth of the fungus was determined in terms of sbiomass dry weight and the final pH was monitored. The selected fungal strain was used for bioleaching of low-grade manganese ore of -150µm size particle size at 2 % pulp density with 2g/100ml sucrose concentration for duration of 20 days. About 60 % of Mn bioleaching was obtained with A. niger. The fungal species proved to be useful for manganese biomining.

Sep 1, 2012

By Yagmur Sirinyurt, Ayhan Ali Sirkeci, Gülay Bulut, Mustafa Özer, Tuncer Acar

"The basic requirement of glass industry for the silica sand is at least 99% SiO2 content. On the other hand, coloring impurities such as Fe and Ti, must be removed. Flotation is the most widely used method for the purification of silica sands from impurities. In this study experimental studies were carried out to reduce Fe content of Mersin (Turkey) district silica sands by flotation. Silica sand sample with a d80 particle size of 1.85 mm was reduced below 0.5 mm in size. Then the size fraction -0.5 +0.106 mm was subjected to flotation tests. In flotation tests, sulfonate-type R801-R825, fatty acid based DER NA 7 (Produced by a Turkish company) and HA110-HA150 a blend of various chemicals produced by Mersin Cam-Is Mining Company (producer of glass raw materials) were used as collectors. Flotation tests showed that sulfonate type R801-R825 collectors provided much better results in acidic medium (pH: 3). The optimum pH value for DER NA, HA150 and HA110 collectors was found to be 7. It was observed that the addition of collector at once caused an increase in the amount of floated product that resulted in a loss of silica to the tailings. In the case of multistage addition of the collector much better selectivity was achieved. As a result of flotation tests conducted under best conditions, a concentrate assaying 0.046% Fe was obtained with a weight percentage of 93.4 when DER NA 7 was used as a collector. In the case of R801-R825 a concentrate was produced with 0.058% Fe content with a yield of 98.4%. On the use of HA150-HA110 the concentrate was produced with 96% weight recovery and 0.052% Fe content."

Jan 1, 2014

By Kaiwen Liu

Activated carbon is widely used in the removal of organic and/or inorganic contaminants from waste water due to its high surface area, porous structure, and specific surface reactivity. However, in practical applications, it is difficult to recover the activated carbon completely by screening or classification. In this project,we prepared a magnetic form of activated carbon (magnetic activated carbon or M-AC) by precipitation of iron oxides on the surface of activated carbon. The M-AC can be easily separated from effluents by applying an external magnetic field, thus it can be recycled and regenerated for reuse. M-AC was characterized by X-ray diffraction (XRD), specific surface area measurement, and scanning electron microscope (SEM).XRD results show that the major phase of coated iron oxides on activated carbon is magnetite (Fe3O4). The specific surface area of activated carbon was found to be reduced after the impregnation of magnetite particles on the surface. The SEM micrograph shows the aggregation of the iron oxides on the surface of activated carbon. M-ACwas found effective in removing DETA (diethylenetriamine) species and metal ions from solutions. Cu (II) with initial concentrations from 5 ppm to25 ppm in solution is removed by more than 99% with the addition of 0.1 wt.%ofM-AC. For the removal of 25 ppm DETA species from solution, an addition of 0.5 wt.% of M-AC is required due to the larger size of the DETA molecule. Moreover, M-AC showed a good loadingproperty for nickel and gold ions from solutions. M-ACshows a better adsorption capacityover activated carbon and its potential applications in carbon-in-pulp for gold leaching and waste water treatment. Keywords: magnetic activated carbon (M-AC),diethylenetriamine (DETA),metal ion,adsorption

Sep 1, 2012

By Nirmal Weerasekara, Malcolm Powell, Mohsen Yahyaei

"The conditions under which rocks become superficially damaged during the grinding process are not well understood. The main purpose of the work presented here is to understand how superficial breakage occurs under incremental low-energy impacts. To enable this study a series of abrasion tests with multi-size pilot mills have been performed. Outcomes of numerical simulation corresponding to each test were examined to investigate the experimental results. Abrasion tests have been conducted using three grinding mill sizes (i.e. 1.8, 1.2, and 0.8 m). Two types of ore were used to investigate different hardness strengths. To ensure abrasion was the dominant mechanism, in all tests the mill speed was reduced to 40% of critical speed. The relationship between the Fractional mass loss rate and particle size was investigated by randomly collecting seven tracer particles from sizes -73+63, -53+45, and -37.5+31.5 mm. It was evident from the results that the Fractional mass loss rate of angular particles declines as the particle size increases whereas the Fractional mass loss rate decreases from fine to coarse in rounded particles. Results of Discrete Element Method (DEM) simulations indicate that fine particles experience higher levels of collision energy per particle and this value reduces as the particle size increases and mill size reduces. This explains the higher Fractional mass loss rate of smaller particles as well as the increase in the Fractional mass loss rate as the mill size increases. Linked DEM and experimental data indicates that under these test conditions surface damage attrition is the dominant mechanism. This work suggests that DEM simulation can be implemented to predict the abrasion wear of particles in mills."

Jan 1, 2014

By Kazutoshi Haga, Batnasan Altansukh, Atsushi Shibayama

Results of flotation process combined with atmospheric leaching and high pressure leaching for recovery of copper from low-grade silicate-copper ore have been presented in this study. The low-grade copper ore contains a small amount of copper (0.42 mass %), iron (4.6 mass %), and silicon (38.3 mass%) and among many other metals (Al, Ca, K, Mg, Na, Ti and S). The main mineralogical constituents of the copper ore are calcium aluminosilicate (Ca(Al2Si2O8), amesite (Mg2Al2SiO5(OH)4) and gypsum (CaSO4×H2O), and quartz (SiO2) as resulted from the alteration of an igneous rock. This study has shown that about 92 % of copper can be recovered with a maximum copper grade of 4.2 mass% in a froth after 15 minutes of flotation at pH 8.5 when used potassium amyl xanthate as a collector, MIBC and Dow-froth 250 as frothers and calcium hydroxide as a pH adjuster. The images of bubbles in the cell during flotation process were recorded using a high-speed camera. The froth concentrate with average copper grade of 2.0 mass% was further processed by atmospheric leaching with a solution of sulphuric acid and hydrochloric acid, respectively and high pressure leaching with sulphuric acid solution. As a result, leaching rate of copper reached about 60 % in an atmospheric leaching with sulphuric and hydrochloric acid respectively, whereas the rate can reach more than 70 % by autoclave leaching at high pressure under the controlled condition. A process to recover of copper from its low-grade ore can be developed by optimization of flotation combined with acid leaching.

Jan 1, 2014

By Leopoldo Gutierrez, Esau Arinaitwe, Marek Pawlik

"The effect of various polymers, including: anionic carboxymethyl cellulose (CMC), polystyrene sulfonate (PSS), humic acids (HA) and non-ionic hydroxypropyl cellulose, on the wettability of Athabasca bitumen was evaluated through dynamic contact angle measurements using the captive bubble technique. The tests were carried out as a function of pH at a constant ionic strength (0.01 mol/L sodium chloride). The evolution of the three-phase contact angle between the solution, bitumen and an air bubble was followed as a function of time over a period of ~6 minutes. The contact angle data were modelled using a first-order kinetic equation. The results were analyzed in terms of the initial contact angle, the evolution rate constant, and the steady-state contact angle value. In the case of anionic polymers, a pronounced decrease in the initial contact angle value was observed at pH 3. Under acidic conditions, there was no significant effect of CMC observed on the steady-state contact angle value but PSS and HA significantly decreased the steady-state contact angle value. At pH 8.5. the anionic polymers did not affect the wettability of the bitumen surface but they significantly decreased the contact angle evolution rate. These results suggested that CMC is not capable of permanently lowering the hydrophobicity of bitumen, and the polymer only slowed down the evolution of the contact angle to the steady-state value. The results also showed that polystyrene sulfonate and humic acids were capable of making bitumen hydrophilic but only under acidic conditions. Only hydroxypropyl cellulose (HPC) produced a large decrease in the steady-state contact angle under alkaline conditions (pH 8.5). The kinetics of contact angle evolution in the presence of HPC was also drastically lowered. The results were discussed in terms of the chemical composition of the polymers and their different affinities towards the bitumen surface."

Jan 1, 2014