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By W. H. Miller

Introduction In this paper we have endeavoured to present a general description of the electrical applications underground at Copper Mountain, including types of equipment used, problems encountered, and methods by which they were overcome. No attempt has been made to outline in detail the wiring of various circuits. Until recent years, the main use of electrical energy underground at Copper Mountain consisted of direct current for locomotives, trolley systems, .and signal and communication circuits. The prohibitive cost of equipment and distribution systems prevented any extensive use of a.c. beyond that commonly used for essential lighting purposes. However, in 1943 the shortage of manpower and the increased cost of labour and supplies necessitated a general mechanization programme.

Jan 1, 1951

By D. J. Scarpato

"Slope construction in shale can present some interesting challenges for geotechnical design engineers and contractors alike. There are challenges that can be expected and designed-for; however, all too frequently, such challenges manifest themselves as “surprises” in the field. Common constructability challenges can include those such as drill hole deviation during drilling for controlled blasting; and, excavation slope instability arising from inconsistent perimeter control drilling. Drill hole deviation results from the cumulative effects from both drilling mechanics and rock mass conditions. Once a hole has initiated the deviation trajectory, it is difficult to rectify drill steel position. Although such challenges are not necessarily unique to shale, they are often exacerbated by weak, weathered and transversely isotropic nature of bedrock conditions. All too often, the working assumption is that shale is “soft” and easily excavatable; however, this blanket assumption can prove to be costly. This paper is intended to provide design professionals and contractors with the practical considerations needed to avoid the “surprises” associated with drill hole deviation, and minimize the potential for costly claims.INTRODUCTIONFor all the slopes that have been excavated worldwide, and for such advancements in excavation technology and field characterization, one might be tempted to believe that the industry almost has slope development down to a science. This is frequently not the case, especially for weak/weathered and anisotropic bedrock. Excavation contractors are still pushed to the limits of what their technology can achieve, and engineers are all too often called to the field during construction, to make potentially risky onthe- fly decisions relative to excavatability, short and long-term slope stability, and project safety. Although there have been a host of other research papers and journal articles that have been written on the subject of deviation over the past 30 years (Brown, Geen, Sinha, 1981), the problems associated with drill hole deviation are still all too frequent. This fact is especially true for civil engineering surface excavations in bedrock."

Jan 1, 2015

By Ray Holmes

This paper describes one approach in our search for greater stope efficiency and lower costs. The uppers technique with wagon drills in cut-and-fill stopes was commenced, on an experimental basis, in our Sudbury mines in 1961. To date, the method has developed into an accept-ed production operation. This technique minimizes the intermittent aspects of the drilling, blasting, mucking and filling operations associated with other cut-and-fill methods. However, studies show that not all cut-and-fill stopes are suitable for uppers, the governing factors being ore width, dip of the orebody, and ground conditions where large areas of unsupported back remain stable for ex-tended periods of time until rockbolting can be accomplished. Introduction F ALCONBRIDGE Nickel Mines Limited operates seven mines within a radius of 30 miles of the city of Sudbury, Ontario. These mines extend in depth from 1,500 to 6,300 ft. The ore consists of brecciated, massive and disseminated sulphides, and the ore minerals consist primarily of pentlandite, pyrrhotite and chalcopyrite. Widths are generally irregular and vary up to 150 ft. The ore dips at between 35 and 90 degrees.

Jan 1, 1965

By J. U. MacEwan

Introduction The equilibrium between copper, zinc, and chlorine may be considered as the simultaneous equilibrium of the two separate chemical reactions of formation of the stable chlorides of copper and zinc at the temperature of the reaction i.e., l440°K. (1,167°C., 2,133°?F.)§ [Zn(g) +Ciz(g) ZnCl2z(g). ... (1) ] [2Cu(l)+Cbi'g) Cu2Cl2(l 1 ....... (21 ] Subtracting, [Zn(g) +Cu2(Clz(l i ZnClz(g) +2Cu!l) ... . (3) ] If this reaction is carried out with a copper-zinc alloy at some constant temperature above the melting point of brass, and at a total pressure of one atmosphere, the equilibrium concentrations obtained will depend on the free energy decrease .of the reaction as written in (3) and on the activities of the various components in. the reaction mixture. If the equilibrium is examined from the point of view of the phase rule, it is a three-component system, and if it exists in two phases (liquid and gas) it will have three degrees of freedom. If the restrictions of constant temperature and pressure are imposed, the degrees of freedom are reduced to one. This means that, in a two-phase system under these conditions, each different alloy phase will be associated with a gas phase of constant composition.

Jan 1, 1951

By R. T. McAndrew

Introduction Drinnan is situated in the Prairie Creek coal area in the Foothills belt of Alberta. It lies on the main line of the Canadian National railway from Edmonton to Jasper. The exact location is shown on the map (Figure I). Interest in the field was aroused by several circumstances: Its proximity to Brule and Pocahontas on the southwest and to Coal-spur on the southeast led to the belief that coal might be economically produced here. There was already at Hinton a 3 ft. 9 in. coal seam being mined by Seabolt. The coal was of very good grade, being black and shiny in appearance with well defined cleavage and a heat value of 12,000 B. t.u. Outcrops of coal had also been noticed on the north side of the Athabaska river and Fish creek. These facts led the Jasper Coal Company to investigate the field. This Company considered taking over the Seabolt property at Hinton, but, owing to the size of the seam, this plan was abandoned and prospecting by diamond drills and test pits was started two years ago in the district east of Hinton. After prospecting had been completed, the most favourable district was found to be in township 51, ranges 24 and 25, west of the 5th meridian. The Company's lease includes all or parts of sections 18, 19, 20, and 28 in range 24, and sections 10, 11, 12, 13, and 14 in range 25. The approximate boundaries of the property are the Canadian National railway on the north, Happy creek on the west, and Cache Percotte creek on the east. The lease comprises 3,100 acres, and the total amount of coal in sight is estimated at 100,000,000 tons.

Jan 1, 1931

By J. Shahabpour

"Many porphyry copper deposits of the Kerman copper province in central Iran are associated with a consistent structurally con-trolled main drainage pattern, which is shown in this paper to be a useful regional prospecting tool in the search for new deposits. The main drainage trends also generally allow the distiction of high-grade (>0.2% Cu) from low-grade (<0.2% Cu) deposits. Topographic maps1:50 000 or geologic maps 1:100 000 have been found suitable for identification of promising drainages.IntroductionTrends of the main drainage systems transecting the high-grade porphyry copper deposits of the Kerman Region in Iran coincide with Quaternary age regional faults and fractures. Observation of such drainage trends can expedite regional evaluation prior to field examination. Thirty deposits located in the Kerman Region (Fig. 1) have been studied to identify common features that can be used for exploration purposes, especially for the first stage of regional exploration. A variety of field criteria are available for subsequent rapid field checking prior to trenching and more costly methods such as drilling, etc.Characteristic geomorphic features have been considered as aids in mineral exploration by many authors (e.g., Faniran, 1971; Piotrovski and Lubkashov, 1976; Verstappen, 1983). Clark et al. (1967) indicated the relationship between geomorphology and the supergene enrichment of copper in Atacama Desert, Chile, and correlated three periods of supergene enrichment with three periods of pediment disection. Seeland (1978) used fluvial drainage patterns for uranium and hydrocarbon exploration in the Wind River basin, Wyoming. Postolenko and Konopleva (1973) used the reconstruction of ancient valley systems for exploration of gold placers"

Jan 1, 1996

By M. A. Power

The diamondiferous Drybones Bay kimberlite pipe is the largest pipe (900 m by 400 m) discovered to date in the Northwest Territories. The pipe intrudes granodiorite of the Archean age Defeat Pluton and contains crater, reworked crater (epiclastic) and diatreme facies kimberlite. In-situ measurements of seismic p-wave velocity were recorded with in-line refraction arrays over representative areas. Refractions from fresh kimberlite were recorded over epiclastic facies kimberlite in the eastern portion of the pipe and returned an average velocity of 4300 m/s. Refractions from weathered kimberlite were recorded on all lines and returned velocities ranging from 1900 m/s to 2200 m/s. Granite surrounding the pipe returned an average velocity of 5400 m/s. The results indicate that there is a definite contrast in seismic velocities between kimberlite and country rocks at Drybones Bay and suggest that seismic refraction surveys may be an effective means of screening kimberlite targets in glaciated areas underlain by igneous or metamorphic rocks.

Jan 1, 1998

By M. Myllymäki

"Pre-treatment of mill feed in a minerals processing plant enables for higher production efficiency per ton of product, reduction of consumables and diverting mineral feed types. Sensor based particle sorting allows for pre-concentration of the run-of-mine (ROM) material prior to other concentrating process. Various sensors provide different responses from the minerals in measured particles. The capability of “accepting” or “rejecting” particles based on sensor responses is investigated in specific test work for each project. Modern sorting machines use pneumatic actuators to divert the reject particles from the material stream. This paper discusses the incorporation of ore sorting test work in processing and plant design. When taking the effects of a sorting circuit into account early in the process planning phase, the downstream process can be adequately sized and impacts evaluated. Potential benefits include but are not limited to increased head grade, lower tonnage to the mill, increased mining operations, removal of deleterious elements and changed properties in the process feed. In a case study we present the Keliber lithium project in central Finland. The plant will produce 9000 tons of lithium carbonate per year from a spodumene ore. Ore sorting and flotation tests were carried out in laboratory and pilot scale. Process models were designed and simulations performed using Outotec’s HSC Chemistry Simulation software. Changes in the flotation performance (grade, recovery, impurity levels) were simulated with and without the pre-concentration of the ROM material. The metallurgical performance and mine economics of the different operational scenarios were evaluated using the Ore-Met optimizer module of the simulation software.INTRODUCTION Challenges in the recent years such as declining ore grades, increasing energy prices, scarcity of water and increasing environmental regulations raise the demand for more efficient processing technologies. Sensor based sorting offers a method for pre-concentration or waste rejection at an early process stage. The technology analyzes each rock particle separately for their unique physical and chemical properties, and diverts the particles into separate material streams by high pressure air jets. Successful implementation relies on ore heterogeneity, differential sensor response and suitable feed preparation."

Jan 1, 2018

By Kevin J. Melong

"Redpath Canada Limited and joint venture partner Thyssen Mining and Construction Canada have recently completed the sinking of the Scissors Creek service in Saskatchewan through its joint owned company, Associated Mining Construction (AMC). The Scissors Creek service shaft was sunk at Nutrien’s Rocanville mine. The following paper outlines the shaft sinking plant and the methodology related to sinking and shaft lining. KEYWORDS Hydraulic shaft jumbo, Hydraulic shaft mucker, Potash shaft sinking, Shaft lining, Sinking galloway INTRODUCTION The sinking and lining of shafts at mines to access mineral deposits has always been one of the great mining challenges for owners, engineers and contractors. Over the course of history in Canadian mining, the sinking of potash shafts through the notorious Blairmore formation of Saskatchewan has proved to be some of the most challenging shaft sinking projects on record. There is no doubt that today’s shaft sinking business demands the utmost in safety performance while delivering projects within schedule and budget. Given these requisites, Redpath and TMCC (executed under the joint venture company, Associated Mining Construction or AMC), were taxed with developing the shaft sinking system to deliver this program in the safest and cost effective manner, with due regard to schedule and quality. Traditionally the potash shafts sunk in Saskatchewan involved a significant level of manual labour, owing to the methodology of excavation by means of chipping the frozen shaft sections with hand held pneumatic machines, and manually placing tubbing segments or steel liners of the shaft lining system. Most certainly, the AMC team wanted to make a step change from those earlier sinking programs and develop systems for sinking this potash shaft that removed the high level of manual work, thus making this project inherently safer, while endeavoring to sink more efficiently. With that in mind, the team embarked on a design program to improve its overall shaft sinking systems without the requirement for excessive capital and methodology flexibility to adapt to potential changing conditions expected to be encountered during shaft sinking. This was especially important should the new approach be met with less than expected success, and retrofitting of the system was required. The concepts were developed to provide for a much improved work environment, while easing the manual labour burden on the workers with innovative equipment and approach to the work."

Jan 1, 2019

By J. Bouchard, A. Clapperton, L. Ebacher, N. Singh

"Canadian Royalties Inc. owns and exploits the Nunavik Nickel project: a copper and nickel deposit in Nunavik, Quebec. Froth flotation is used to produce nickel and copper concentrates. As is the case at other operations, the presence of magnesium is detrimental to the flotation products. In the past year, the exploitation of a new deposit has increased magnesium in the feed. Thus, it has been challenging to meet the required ratio in the final nickel concentrate. In search for a consistent solution for this problematic, an empirical flotation simulator making use of selectivity curves was developed. The circuit was expressed as a system of linear equations, which considered the distribution of copper, nickel and gangue minerals in the different streams. The relative quantities of each mineral are given by the separation efficiency curves of the various banks in the circuit. Three sources of data were used to calibrate the simulator: historical plant data (metallurgical balance), infinite dilution bench-scale flotation tests, and direct sampling of flotation cells. The calibrated separation curves were used to predict the recovery of the different species based on a single mineral recovery. Validation of the simulator showed good fit for the valuable minerals. The simulator was then used to infer the optimal operating conditions of the flotation circuit to optimise magnesium oxide content of the nickel concentrate. Simulation of two re-arrangements of the circuit gave a promising solution with a Fe:MgO ratio 2.42 times higher than the minimum value.INTRODUCTION Canadian Royalties Inc. owns and exploits the Nunavik Nickel project: a copper and nickel deposit in Nunavik, Quebec. Figure 1 shows the location of the mine site. After crushing and grinding, froth flotation is used to produce nickel and copper concentrates. The flotation circuit is designed with multiple stages consisting of bulk copper/nickel flotation, copper/nickel separation, and a separate nickel circuit (bulk float and cleaning)."

Jan 1, 2018

By N. Shi, T. G. Joseph

ABSTRACT: An interactive cable shovel simulation has been developed to mimic any shovel dipper geometry for a given cable shovel operating in any homogeneous face material. This interactive cable allows the user to predict shovel performance in any face material encountered and track both its ground stability and the dipper-ground interaction. An embedded Microsoft® Visual Basic spreadsheet was used as the platform for developing an interactive simulation that allows for maximum user-defined parameter input and interactive visual output. The result is an analytical dipper-ground interaction solution that yields crowd, hoist, and digging effort as a function of face activity position.

Jan 1, 2011

By M. Hardy

"The structural design of mine headframes is challenging due to the significant differences in the geometry, rigidity, and behaviour of these structures compared to conventional buildings. The differences are related to the main purpose of these structures, which is not human occupancy, but rather the support of hoisting equipment. The main objective of this paper is to present the seismic elastic behaviour of headframe structures in comparison with conventional buildings, which is the base case for the definition of seismic loads. This paper highlights the impact of backlegs on the dynamic behaviour of mine headframes, more specifically the resulting torsional sensitivity. INTRODUCTION The design of industrial structures is often governed by industrial processes rather than by architectural constraints. In ground-mounted hoisting plants, the structural configuration of headframes must allow clearances around conveyances and ropes while resisting the lateral loads associated with the hoisting equipment. Typically, these structures use backlegs to withstand the lateral loads, which leads to highly irregular structures with unconventional dynamic behaviour. The codes and standards applicable to the structural design of mine headframes in Canada are often incomplete or not adapted to the reality of practising engineers. This situation creates confusion, and engineers must look at various guidelines and international standards to support the engineering calculations required for the design of these structures. The loads resulting from the support of hoisting equipment, such as ropes and conveyances, are usually simple to calculate and are determined based on the information from manufacturer and industry related guidelines. Moreover, the loads associated with snow accumulation and wind are calculated applying the same methodology used for conventional buildings, without any major issues. On the other hand, the seismic loads are often difficult to calculate based on the methodology from the National Building Code of Canada due to the significant differences in the dynamic behaviour of the structures. The resulting structures may be either over-designed or worse, under-designed. Hence, there is a lack of uniformity in engineers’ designs. The latest edition of CSA S16-14 “Design of steel structures” includes Annex M (Informative) “Seismic design of industrial steel structures” to help designers close the gap between the requirements of traditional regulations and actual engineering practice."

Jan 1, 2019

By K. O. J. Sidwell

STRATMAT LIMITED, through its subsidiary, the Strategic Manganese Corporation, controls two adjoining iron-manganese properties five miles west of Woodstock, New Brunswick. One is a staked property of 77 claims traversed by one trunk highway, several secondary roads, and a branch line of the Canadian National railway. The other property, a 20-square-mile Concession immediately to the north-east, is also traversed by an excellent network of roads. Both proper-ties are situated in gently rolling farmland. The deposits were discovered in 1836 by Dr. C. T. Jackson. The first attempt to exploit them was made in 1848 when a blast furnace was erected with a capacity of 7 tons per day. The ore was mined by a series of deep trenches that followed the folds of the enclosing slates. In the late years of operation, bog iron ore from Burton and Maugerville, in Sunbury county, was used in conjunction with the Wood-stock ore. An additional 5-ton furnace was erected in 1863 and mining was carried on intermittently until 1884. No further extensive work was done until 1953. During the period of activity, approximately 70,-000 tons of ore are said to have been smelted ( 1). During these earl y operations the Iron Ore Hill and Moody Hill deposits were partially opened, with the ?bulk of the furnace feed being mined from the Iron Ore Hill workings. The low tenor and apparently limited extent of the deposits, the high. ?content of phosphorus, and the increasing scarcity of fuel, were the chief factors that brought the enterprise to an end.

Jan 1, 1957

By M. J. Latva-Kokko, T. J. Riihimäki

"Oxidation autoclaves are normally operated at elevated temperature and pressure. The improvement in kinetics is due to combined effect of temperature and partial pressure of oxygen. In this paper exclusive effect of pressure has been studied with a low grade sulphide ore at below 100 °C temperature. These studies are related to development of a novel tower-like reactor that utilizes hydrostatic pressure. Technology is designed to generate high amount of effective fluid volume for high solid content slurries with lower energy consumption and improved kinetics compared to normal atmospheric operation.INTRODUCTIONEconomical utilization of low-grade ores requires handling of enormous amount of material. This sets new requirements for process equipment in terms of size and energy efficiency. For example on the field of mineral processing this has lead to a six fold increase in the operating volume of mechanical flotation cells over the past two decades. Ore beneficiation methods like flotation greatly reduce amount of material that needs to be further processed in smelters or hydrometallurgical refineries. However with some ore types, such as nickel laterites and refractory gold ores, traditional concentration technologies cannot be utilized. Thus direct leaching of ground ore could be an attractive option. In many cases normal atmospheric tank leaching has traditionally been a non-feasible option mainly due to high capital and operational expenses induced by large amount of stirred reactors required. Main restriction for increasing reactor size to beyond 500 m3 has been mechanical load and power requirements set by mixing in cases when high dispersion efficiency of gas is required. THEORETICAL BACKGROUNDIn hydrometallurgical industry autoclaves are typically operated at elevated temperature and pressure. In many cases increase in operating temperature is the desired phenomena and improvements in kinetics are strongly related to that. Thus increase in pressure might be induced solely by water vapor pressure. However when gaseous feed is present, pressure itself has a strong effect on leaching kinetics for various reasons and its role should not be neglected."

Jan 1, 2012

By Henry Hengeveld

Are the IPCC results credible? The most recent IPCC assessment is??an admirable summary of research activities in climate science? US National Academy of Science 2001 report to President Bush Joint statement by Academies of Science from 17 other countries ? May 2001 ?The work of the?IPCC represents the consensus of the international science community on climate change science. We recognize IPCC as the world?s most reliable source of information?and endorse its method of achieving this consensus.?

Nov 1, 2002

By A. Alfantazi

Recently, titanium and its alloys have been the materials of choice for the liner and internal components of autoclaves used to extract Ni and Co from laterite ores. There have been many corrosion incidents ranging from localized attacks due to scale formation or welding, to damage caused by pockets of concentrated acid. Most of the literature focuses on methods to avoid the corrosion altogether. Little has been published to increase awareness of the chemistry at these conditions. For this paper, a literature review of the thermodynamics of titanium was undertaken to decipher the slew of information available. E-pH diagrams were constructed from select data and compared with the results of electrochemical experiments. Since nickel laterite leaching takes place in sulphuric acid, and in many cases chloride concentrations are very high, the Ti-H2O, Ti-Cl--H2O and Ti-SO4---H2O systems were considered.

Jan 1, 2004

By T. Xue, A. Singhal, D. Wrana, I. Mihaylov

"At Vale's Thompson Nickel Refinery, the copper and arsenic in the nickel electrolyte are removed by precipitation using H2S, generating a sulphide precipitate containing about 40% Cu, 8% Ni, 2 to 4% As and 30% S. This residue has been typically stored in impoundment ponds within the plant site. Various options for reprocessing it have been investigated over the years. One of the options involved oxidative pressure acid leach, whereby over 95% Cu, Ni and As were extracted. More recently, an atmospheric alkaline sulphide leaching process for selective removal of 70 to 90% As was developed and mini-plant tested. After alkaline sulphide leaching, the dissolved arsenic is precipitated as stable basic ferric arsenate (BFA) with the addition of ferric sulfate, while the low-arsenic Cu/Ni sulfide is suitable for processing in Vale's operations elsewhere in Canada.INTRODUCTIONVale’s Thompson Nickel Refinery was commissioned in 1961 and currently it has the capacity to produce about 56,700 tonnes per year of electrolytic nickel as cathode slab and rounds products. A sulphate and chloride mixed electrolyte is used in the Thompson refining process and it typically contains 75 to 85 g/L Ni, 50 to 60 g/L Cl, 90 to 120 g/L SO4 2-, 25 to 30 g/L Na and 8 to 9 g/L boric acid. The main impurities in the Thompson anolyte are copper, cobalt, arsenic, iron and lead.The simplified Thompson electrolyte purification flowsheet is shown in Figure 1 (Oliver & Wrana, 2009, Goble & Chapman, 1986); it consists of precipitation of copper, arsenic and lead with H2S, followed by nickel replenishment with ground matte and acid and removal of cobalt and iron with Cl2 and NiCO3."

Jan 1, 2012

By B. Haneman, J. A. Gorst, W. Slabbert

"The Bayer process involves the digestion of bauxite in caustic liquors at high temperature and pressure. Typically the digestion section of the plant involves the heating of liquors up to the digestion temperature followed by flashing of the digestion product to atmospheric pressure with the flashed steam used to pre-heat the incoming cold slurry. Despite the heat recovery, the digestion process is a high consumer of energy. The application of tube digestion technology in such plants has resulted in significant improvements in refinery energy efficiency with associated benefits of process simplification and refinery flow sheet capital cost reduction. This paper reviews the potential application of this technology to other metals within the non-ferrous industry.THE BAYER PROCESSA typical Bayer flow sheet is shown in Figure 1. The raw feed material bauxite (containing aluminium hydroxide as gibbsite Al(OH)3 and boehmite AlO(OH)) is digested in caustic liquors (caustic soda is the solvent) at high temperature and pressure. This process extracts the alumina and silica and any carbon present on the ore. The slurry is then flashed down to atmospheric condition allowing for heat recovery from the flashed vapour and producing slurry supersaturated in alumina.Following the digestion process the mud is removed via thickening and then pressure filtration to remove fine particulate and produce a clarified liquor with dissolved alumina in solution. The resulting pregnant liquor is then cooled allowing the alumina in solution to precipitate as aluminium trihydrate Al(OH)3. The precipitated hydrate is then filtered and washed and classified into fine and coarse fractions. The fine material is returned to the precipitation process as seed while the coarse fraction is calcined at high temperature to produce alumina. The filtrate from the filtration process (spent liquor) is then heated by the incoming pregnant liquor before being fed to an evaporation process which produced the strong caustic liquor required in the digestion process. Finally, the mud from the thickening process is washed to recover caustic and then fed to tailings ponds. The washer overflow is then mixed with the digester product to increase super-saturation."

Jan 1, 2012

By R. V. Fox, L. K. Sinclair, D. L. Baek

"In this study, rare earth elements were recovered from bastnasite concentrate and waste fluorescent lamp phosphors using supercritical carbon dioxide extraction with a nitric acid/tributyl phosphate adduct. Several pretreatment methods were used to alter the crystal structure of the source materials, and thus improve rare earth element recovery. Pretreatment methods included 1) dry roasting of the source material at 730oC, 2) decomposition with 50% sodium hydroxide solution at 150oC for 4 hours, and 3) decomposition with 12 M sulfuric acid at 300oC for 4 hours. Treated and untreated samples underwent supercritical extraction at 24 MPa and 65oC for 1 hour. Untreated bastnasite and phosphor samples showed <10% rare earth element recovery, but sodium hydroxide digestion resulted in >60% recovery for most rare earth elements. Dry roasting of the bastnasite concentrate was also effective, resulting in >60% recovery for cerium.INTRODUCTIONRare earth elements (REEs) consist of the 15 lanthanides, scandium, and yttrium. Scandium and yttrium are included because they are in the same group as lanthanum, appear in many of the same ore deposits as the rest of the lanthanides, and exhibit many similar chemical properties. REEs are used in a wide array of applications including electronics, magnets, catalysts, glass, and solid-state lighting (Xie, Zhang, Dreisinger, & Doyle, 2014). Because of China’s continued dominance of worldwide REE production, the United States Department of Energy has sought to diversify domestic supplies of REEs (United States Department of Energy, 2011). A key part of this strategy is the development of improved extraction methods for both ores and recycled sources.Supercritical fluid extraction (SFE) is a promising technology for extraction and separation of rare earth elements. Contact with an acid adduct dissolved in supercritical carbon dioxide allows for the rapid extraction of REEs from solid matrices. Supercritical CO2 has several potentially useful properties as a solvent, including high diffusivity and the ability to tune solvation properties by adjusting pressure. Such tunability may have applications in separating the REEs once they have been extracted from the solid phase. Tributyl phosphate/nitric acid adducts (TBP:HNO3) are a particularly promising class of adducts for SFE extraction of rare earth elements. Using TBP:HNO3 adducts in supercritical CO2, several researchers have successfully extracted REEs from their oxides (Wuhua, Pijia, & Yongjun, 2010; Zhu, Duan, Xu, & Zhu, 2009). However, there is a complication in applying this technique to many types of ores and recycled sources: REEs are often locked in refractory minerals which are resistant to acid attack, resulting in limited recovery in supercritical extraction."

Jan 1, 2016

By Julian Boldy

"A review of lI5 significant volcanogenic massive sulphide discoveries in the Canadian Precambrian during the past 65 years reveals that only 7% resulted from surface exploration methods aimed at depths below the effective reach of current geotechnical systems. This has been due to the relative ease of shallow discovery, resulting in the harvesting of ore deposits within 100 m of surface. This surficial layer has been more or less effectively supersaturated by routine exploration. In view of the fact that a mining district&apos;s metal content is not likely to be confined to a surficial layer, the time has come to explore the vertical dimension, prospecting for ore at depths in excess of 150 m in productive districts.Essential to this task is an understanding of the Precambrian volcanogenic ore deposit model. The deposits generally have .a tendency to be associated with the terminal phases of felsic volcanism, and to be located along certain time-stratigraphic horizons, marked by the products of volcanic exhalation. The significant massive sulphide deposits are discrete entities, ranging from the top 5% of deposits greater than 45 million tonnes in size, with a surface area of 0.30 km2, to median-sized deposits greater than 1.2 million tonnes in size with a surface area of 0.02 km2. These significant economic ore deposits range in value from $5.5 billion for the top 5% of deposits to $125 million for median-sized deposits. In terms of their frequency of occurrence, the former group has a 4% distribution and the median-sized deposits have a 15% distribution.An historical review of many of the principal Precambrian mining districts, such as Noranda and Flin Flon, shows that major tonnages are usually discovered during the initial phase of application of each new geotechnical search system, until carried to its ultimate limit of effective depth penetration. With the exception of the Noranda district, the mean depth of ore discovery in the other districts is still generally confined to within 50 m of surface.Targeting deep ore is difficult. One effective prospecting method is the detection of fracture-controlled mercury leakage haloes in outcrop (or core) above and peripheral to blind deposits. This technique has proved to be a useful pathfinder, and focuses attention on deposits buried at depths in excess of 700 m in some instances. Down-hole EM systems also promise to be effective in locating deposits previously bypassed by drilling. In addition, trend surface analysis programs of trace element geochemistry should be used as an aid to targeting ore by directing exploratory drilling along the plane of ore-hosting stratigraphy.By definition, mining districts have a proven ""favourability"" for the occurrence of ore. Discovery probabilities in these districts will be considerably enhanced if future search efforts are concentrated below a depth of 150 m, and more use is made of ""deep"" ore search systems coupled with sound geological reasoning. Deep drilling programs to a depth of800 m should initially be designed to search for the top 25% of deposits greater than 3.3 million tonnes in size, with a surface area of0.05 kmt. :a value of$310 million and a 12% frequency of occurrence; This can be accomplished for an over-all cost approximating $40,000 per drill hole. If the search depth is limited to 400 m, the over-all cost of each drill hole is $20,000, equivalent to expenditures routinely allocated to grassroots exploration drilling in the remote greenstone belts of the Precambrian. Depending on a company&apos;s objective, prospecting for deep ore offers a stimulating challange - though risky, it has its rewards."

Jan 1, 1981