Search Documents

By Michael Boyle, John Zeni

"The Blind shaft boring method is a mechanised process of excavating large diameter vertical shafts downward from the surface. It is a rotary drilling technique eliminating any requirement for personnel to enter the shaft or access underground workings during drilling and lining phases. Excavated material is delivered to surface carried by a flow of circulating fluid through the centre of drill rods. The drill assembly is suspended from a large A-frame rig and powerful winch at ground level providing vertical thrust to a hard rock cutter head. INTRODUCTION The Southern Coalfields Ventilation Shaft was constructed at a mine, 45 km north-west of Wollongong. The 5 m finished diameter (6.2 m drilled) shaft reaches a final drilled depth of 517 m, the deepest, fully lined blind bored vent shaft to date in Australia. Operated by a mining company in the Southern Coalfields, the expanding mine required a new ventilation shaft and associated surface infrastructure to service future operations. An assessment of future ventilation requirements for the coal seam operations identified a need to improve the capacity and reliability of the existing underground ventilation system in order to ensure a safe and efficient underground working environment. Installation of the new upcast ventilation shaft was determined to be the most cost effective and reliable solution to provide adequate ventilation for underground operations. The completed shaft is smooth and fully lined with steel/concrete composite liners that are hydrostatically sealed. The shaft lining is designed to meet the mine ventilation requirements for a service life of 20 years. The shaft intersects the top of the working section of the coal seam at approximately 513 m of depth. This includes the shaft collar depth and shaft bottom profiled intake section.PROJECT METHODOLOGY AND INDUSTRY BEST PRACTICE The shaft was drilled using the blind bore method, an innovative construction technique and an alternative to the traditional methods of sinking deep and large diameter shafts, such as raise boring and conventional drill and blast shaft sinking. The blind bore method allows the shaft to be drilled from the surface down without anyone having to enter the shaft or the mine during the construction process. This is by far the safest method of shaft construction and is especially suitable for difficult ground conditions where there may be unstable or water-charged strata. As this method involves drilling from the surface downward, shafts can be completed ahead of the underground mine development. Thus, allowing underground operations to focus on development and production without the conflicts of managing ventilation priority for underground contractors and mucking out spoil from excavation workings."

Jan 1, 2019

By H. R. Hammond, E. Sadar

Cominco is making substantial savings in secondary breaking by replacing dynamite with a new nitrate-based explosive. Compareo with dynamite. the new explosive, known locally as "Fine NCN," is significantly cheaper, more effective and safer to use. It also works better than prilled NCN, which is unsatisfactory for secondary blasting because of inadequate sensitivity, low strength and awkward handling properties. A simple apparatus has been devised for pulverizing prilled NCN to a fineness practical for effective secondary breaking. Blasting systems using cheap detonating cord for initiation have been developed.

Jan 1, 1966

By Baochun Wang, Hongli Jia, Zhaolian Wang, Fengliang Liu

"Promote and apply a new beneficiation technology and equipment effectively processing the refractory and medium-fine grained weak-magnetic minerals. HUATE® Forced-oil Cooling Vertical Ring WHIMS adopts the transformer oil cooling technology to cool excitation coils, solving the easily generated scaling problem resulting from water cooling, thereby to eliminate the demineralized water system. With <25 temperature ?raise, its magnetic field is stable. Wrapped by outer magnetic armor, it can generate a background intensity 1360kA/m. It effects very well in 1) wet preseparating the weak-magnetic coarse grains, like hematite, manganese ore, ilmenite, and purifying the concentrate; 2) removing the ferrous impurities and purifying the non-metallic minerals, like quartz, feldspar, kaolin; 3) enriching and recovering tailings from non-ferrous metals, like copper, lead, cobalt, molybdenum, thereby to greatly improve the mine resource utilization. It has applied 14 relative patents in China, and the invention patent in 56 countries, like Russia, USA, Australia, via PCT international organization. HUATE® WHIMS has been applied and accepted in more than 100 mines in and out of China. Compared with water cooling vertical ring WHIMS, it’s energy-saving and water-saving, and avoiding generating the scale. While compared with JONES WHIMS under the same separation indexes, it’s featured of more space-effective, lighter, lower costs, higher gradient, higher efficiency, larger processing capacity and wider grain application scope. Greatly promoting development of mineral processing technologies, HUATE® WHIMS is the equipment to reduce costs and improve efficiency urgently needed by the mine enterprises now.INTRODUCTIONAt present, influenced by the price and production factors, the international market demand for the grade of iron ores is increasing continuously. Restricted by the ore occurrence state, the beneficiation technology level and product economic value, every year the stope strips the stockpiling and discards hundreds of millions of tons of waste rocks containing iron, especially the weak magnetic hematite and limonite with <20% Fe%. The utilization technological bottleneck of these waste rocks makes their concentration ratio as high as 5-6, which leads to the huge wastes of energy, materials and beneficiation reagents and the increase of production costs. The effective solution is to improve the selected Fe% of the waste rocks like hematite. With the successful application of HPGR technologies in Chinese large iron mines, the mill feeding size has been reduced to 6-0 mm or 3-0 mm from the original 15-0 mm in the crushing system with 3 stages of crushing and 1 stage of closed circuit. This creates the conditions for the wet separation and recovery. While for the medium-fine grained weak-magnetic minerals, it lacks of the effective separation and recovery equipment in the world, which’s badly in need of R&D of the medium-fine grained high gradient wet strong magnetic preseparation equipment."

Jan 1, 2016

By F. H. Hueston, R. S. Barclay

"Depending on the application, zirconia, fused magnesia and graphite have been found to be the most suitable crucible materials for melting uranium metal and its alloys. Although graphite has been found to be satisfactory for uranium and uranium alloy castings with cross sections of 4 square inches or greater, ceramic-type molds are superior for small sections and those shaped castings which prohibit the economic use of machined graphite molds. Heating cycles, addition mechanisms and furnace conditions for melting are discussed."

Jan 1, 1967

By R. J. Enkin

Modern mineral exploration depends on multidisciplinary 3-dimensional integration of geological and geophysical data. Identification of the geological sources of geophysical anomalies requires knowledge of the physical properties fingerprint of rock types, formations and their alteration products. Understanding how and why rock physical properties vary within the Earth&apos;s subsurface ensures that appropriate geophysical exploration methods can be chosen, and allows for more efficient and effective surveys to be designed. Physical properties knowledge is integral to geophysical modeling - measured data or values estimated based on geological understanding are used to produce realistic forward calculations and to constrain inversion models. Mira Geoscience and the Geological Survey of Canada, in collaboration with industry and academia, are building a Rock Properties Database System (rpds.mirageoscience.com). It compiles the most valuable physical properties for mineral exploration (density, porosity, magnetic susceptibility and remanence, electrical resistivity and chargeability) linked with location and lithological metadata. A critical knowledge gap, addressed in this study, concerns the dependence of physical properties on alteration and mineralization processes. We report on the results of a collaborative University of British Columbia - Geoscience British Columbia project, ?Integrated Geological & Geophysical Porphyry Models: Adding Value to Geoscience BC Geophysical Data?. As part of the QUEST and QUEST-West geophysical initiatives, Geoscience BC focused detailed geophysical surveys on a suite of six known porphyry deposits: Mount Milligan, Endako, Huckleberry, Bell, Granisle, and Morrison. Physical properties for a set of 269 samples of characteristic host rocks and their altered equivalents were measured. The causes of physical properties variations were investigated through their correlations with ore and alteration mineralogy determined from thin-section observations and X-ray diffraction analyses. Physical properties of variably altered host-rocks and intrusive rocks vary significantly between different BC porphyry deposits. No specific unifying geophysical model exists that can be uniformly applied during exploration. Knowledge of local background geology and local physical properties variations is necessary as host-rocks and intrusive rock compositions vary depending on magmatic affinities, and alteration styles will vary reflecting host-rock compositions, crustal depth and influence of meteoric water. A district-scale exploration strategy requires location of intrusive bodies, which are commonly magnetic, resistive and low in density. Correlations should not be expected between density and magnetic susceptibility, because alteration may lead to magnetite destruction or to secondary magnetite development. Deposit-scale ground geophysics might image potassic alteration zones that can be magnetic in both alkalic and calcalkalic systems. Low magnetic susceptibilities, resistivities and densities might aid in locating the typically more porous phyllic and argillic zones. All geophysical data must be interpreted with background knowledge of local rock types and in light of the expected deposit model and associated magmatic and hydrothermal processes. The most effective means to building physical properties knowledge prior to geophysical investigation remains collecting rock physical properties measurements. The cost of rock properties data collection is low, relative to the overall costs of running a mineral exploration program, and can provide an important framework for design of geophysical surveys, survey method selection, geophysical modelling, and data interpretation.

Aug 1, 2013

By L. W. Krahenbil

The programmable Logic Controller (PLC), at its present stage of evolution, is now considered as a mature control system. The PLC combines the solid-state reliability of hardwired logic and computer control systems with the simplicity of a relay ladder logic. Relay symbolic programming through a function-oriented keyboard provides a means which plant personnel can easily become accustomed to work with. In a large coal facility, it is shown that the control engineer can provide improved control flexibility with the advanced capabilities of the PLC.

Jan 1, 1979

Operationalizing the Ruggie Framework in a Mining Context Ruggie?s 3 Pillars: The State?s duty to Protect Policies, regulation, adjudication The Corporation?s responsibility to respect Acting with due diligence to avoid infringing Addressing adverse impacts when involved in abuses Access to Remedy ??even the most concerted efforts cannot prevent all abuse.?

May 1, 2013

By P. Simon, G. Falkinger, G. Angerer, B. Gerold

"This contribution presents an investigation of the evolution of shrinkage pores during hot rolling with a special focus on the microscopic mechanism. The reliable closure of pores, which inevitably occur during the casting process, is of crucial technological importance for high-quality hot rolled plate products. Therefore, lab-scale tests were carried out under different typical thermomechanical loadings. Extensive data from optical microscopy was collected before and after deformation. The analysis shows that the average volume of pores evolves similar to the volume of an idealized arrangement of voids in an ideally plastic matrix. The average shape of the shrinkage pores, however, was found to be almost constant during deformation. Even though individual pores exhibit complex morphologies far from any idealized geometries, the overall evolution of a large number of pores is well captured by simple assumptions. In addition to the quantitative analysis, a schematic representation of this counter-intuitive behavior is provided. A simple ‘Gurson’-type void evolution equation was implemented in a three-dimensional Finite-Element model of the industrial hot rolling process. With the help of this mechanism-based process simulation the thermomechanical closure of shrinkage pores during the rolling process has been optimized for a variety of plate products.INTRODUCTION Aluminum alloys of the 7xxx series are widely used in the aircraft industry. They have to meet high quality standards regarding microstructure as well as mechanical properties. For hot-rolled aircraft plates, one of the most important quality requirements is that they are free from pores. Pores, however, are inevitably created during the casting process either due to shrinkage or due to the dissolution of gas from the melt. The pores have to be closed mechanically during the hot-rolling process. Therefore, the mechanism of so-called pore closure or void closure has a high technological relevance for the production of aircraft plates. The behaviour of voids in a ductile matrix subjected to mechanical deformation has been extensively studied, especially in the context of damage mechanics. A recent review (Besson et al., 2010) on modeling methods for ductile damage gives a good impression on how much experimental as well as theoretical effort has been dedicated to the problem of void evolution under mechanical loadings. Although void closure has been studied to a far lesser degree, it obeys to the same general theoretical evolution laws as void growth. The most basic theoretical result is that hydrostatic pressure drives void closure, while hydrostatic tension leads to void growth. The mechanism of void closure depends on the void shape. This is illustrated by the example of a flat penny-shaped void, which under compression obviously closes much faster than a sphere with the same volume. Theoretical models have been developed for the evolution of simplified void geometries, such as spheres or cylinders (e.g. Gurson, 1977), spheroidal (Gologanu et al., 1997) and ellipsoidal voids (Ponte-Castaneda, 1994). In industrial cast ingots, however, the pores exhibit very complex morphologies, which are far from any idealized geometry. X-ray tomography revealed ‘tortuous’ voids in a 5xxx aluminium alloy (Chaijaruwanich et al., 2006)."

Jan 1, 2018

By H. P. Whaley

This paper introduces Wabush Mines, including its ownership, physical assets, capacity, goals and achievements. It is to be followed by four papers which will present the detailed story. Wabush Mines, the largest supplier of iron ore to the Canadian steel industry, was brought into production in 1965. The ore is mined and concentrated in Wabush, Labrador, Newfoundland and pelletized at Pte. Noire, Quebec. Annual capacity is over 6,000,000 tons of high-grade iron ore pellets.

Jan 1, 1969

By Kish. L.

"The results of a chemical and mineralogical study of eighteen opaque-oxide occurrences are discussed and the detailed chemical, metallurgical and mining feasibility study of a vanadium-rich magnetite deposit is summarized. A plot of the mol-percentages in the system FeO- Fe2O 3-TiO2 indicates that the deposits fall into two distinct groups: some contain hematite with ilmenite, and some others have magnetite with ilmenite (titaniferous magnetites). The plot also suggests that the two types of deposits were crystallized from liquids of different compositions. Each group has its distinct structural features. Vanadium is present in all of the studied specimens, however concentrations of economic importance have so far been found only in the titaniferous magnetite deposits. The vanadium content of the oxide concentrations of the Dore Lake Complex is the largest among the studied occurrences. Analyses of the concentrates of the drill-core sections show a compositional variation across the orebody; a continuous increase in the tenor of Ti02 and a decrease in the vanadium content upward in the layered sequence is found. Concentration tests on several tons of samples indicate that about 80 per cent of the vanadium is recovered in the magnetite concentrate."

Jan 1, 1972

By S. W. Henley

"Shaft sinking design is typically driven by what has been successful in the past and the availability of sinking plant. This document considers a project where the sinking design and methodology is unconstrained by conventional thinking and removed from the commonly held belief that a sinking methodology should be developed from available winding plant. Schedule was a key driver for the Project and led to an alternative sinking design that aimed to optimise sinking advance rates by specifying new winders that compliment known sinking plant while providing improved safety, redundancy and flexibility within each part of the sinking cycle. KEYWORDS Consistent, Efficient, Flexible, Improved, Innovative, Optimise, Redundancy, Safety, Schedule INTRODUCTION The project is remotely located in the South Gobi region of Mongolia on a brownfield site and the scope of work included the concurrent blind sinking and concrete lining of two (2) ventilation shafts to an approximate depth of 1,150 m at a finished diameter of 10 m and 11 m respectively. All sinking and lining operations to be completed as in-line activities, (no lining whilst other activities are undertaken). The project was schedule driven with a completion date set for the first quarter (calendar) of 2021 and there were no restrictions imposed on the successful Contractor with respect to their equipment selection. Existing sinking plant already onsite from three previous shaft sinking operations would be made available to the Contractor if required on an as is where is basis Sustained advance rates in excess of 2.4 m per day would be required in order to achieve the completion milestone, therefore the design would have to include contingency and demanded flexibility to account for equipment down time. Previous shafts that had been sunk onsite have utilised a single double drum kibble (bucket) winder (hoist) with a single excavator loading on the shaft floor into a large capacity kibble (bucket). DESIGN Mucking The sinking design centred on the mucking cycle given that this is traditionally the most restrictive part of the sinking cycle and typically accounts for one third of the overall sinking cycle. The Vertical Shaft Mucker (VSM) and/or diesel excavator are commonly used plant for shaft sinking that were under consideration. The use of Cactus Grabs was not considered given the higher risk associated with grab ropes and hoist failures."

Jan 1, 2019

By L. Iacopetti, A. Calderara, M. Perego, P. Perrone, T. Furusawa

De Nora, a global leader in the development, manufacture and sale of all DSA® anodes based on titanium coated with mixed metal oxide (MMO) for electrochemical processes will present key advancements made to Self-Protected Anodes (SPA) for metal electrowinning. (DSA® is a registered trademark of Industrie De Nora S.p.A., Italy). In 2017 pre-commercial demonstration cells were operated in industrial environment. The program’s focus was to fully demonstrate the SPA anode’s superior mechanical and electrochemical robustness during normal and induced dendrite shorting occurrences while providing quality of plating in commercial operation. De Nora specialists focus on key components, in particular the engineering of the self-protection system, DSA® anodes and catalyst formulation capable to cope with high levels of pollutants while providing long service life in the meantime. Results of field trials confirmed the expected anode performance and enabled the selection of the most suitable “SPA” structure, based on resistive protective elements. Summarizing the economic benefits to copper electrowinning tankhouse operation with De Nora’s self- protected all DSA® anodes are; Double-digits power savings Cobalt-free electrolyte operations Minimal dendrite shorting damage incurred at the SPA anode Smoother, uniform cathode deposits with tangible improvement on current efficiency Tankhouse operations producing lead-free copper quality cathodes, in addition to elimination of lead waste for improved operator health and environment. INTRODUCTION De Nora’s engineered “Value Technology Package” (“VTP”) for electrowinning, consisting of our DSA® anodes coated with mixed metal oxide specifically formulated for copper electrowinning in conjunction with an advanced self-protected full titanium anode (“SPA”), underwent an intense field qualification program, inclusive of the behavior under massive short-circuits as part of the field investigation, with the goal to select and appoint the ultimate design configuration of “SPA”. Optimized wireless-based monitoring system was included in the field program, demonstrating good functionality for cell parameters monitoring and remote shorts detection.

Jan 1, 2019

By K. D. Bulin

"An interesting brief history review of shovels as the primary excavating tool will permit the reader to see that immeasurable development and resources have preceded the shovel excavators which today are used extensively throughout the mining industry. With this as a background, the shovel manufacturer has the ability to utilize his resources best in those areas of shovel development in which the maximum benefits of increased reliability, performance and ease of maintenance will improve the operating rewards to the user of the equipment. The author explains the function of the shovel as a part of the material handling system. A detailed description of those areas of the shovel in which the most recent developments and major improvements have been implemented in the manufacture of the shovel excavator arc included."

Jan 1, 1973

By E. Barnard, J. Tero, J. Rajala, N. Avenido, M. Fullam, A. Nashitati, S. Mbalamba

"The Otjikoto mining and milling complex is 90% owned by B2Gold Corporation, and began commercial operation on February 28, 2015. The milling circuit operates at a throughput 3.3 million tonnes per annum, with an average reserve gold grade of 1.28 g/t. The ore is high in Gravity Recoverable Gold (GRG), which varies between 73-91%, depending on ore type. Overall gold recovery since start-up is 98.2%, with about 63.5 % coming from the gravity circuit as doré. 2016 cash operating costs, and all in sustaining cost (“AISC”) were $361 and $604 per ounce, respectively.During design, three ore types were tested for GRG content, and based on the high GRG value of all three ore types, the decision was made to treat the full ball mill circulating load by gravity. Once operating, the gravity circuit performance was characterized by performing a detailed gravity audit, which included the ore, cyclone classification, Knelson concentrators, and the Consep Acacia intensive leach system. The deeper ores contain significant pyrrhotite, and this created some unusual challenges that had to be overcome. This paper presents the gravity circuit design process, the circuit commissioning, and the audit results and ongoing improvements.IntroductionHeadquartered in Vancouver, Canada, B2Gold Corp. was founded in 2007. Currently, B2Gold has five operating mines, and numerous exploration projects in various countries, including Nicaragua, the Philippines, Namibia, Mali and Burkina Faso. The Otjikoto Mine is located in the north-central part of the Republic of Namibia. It is situated approximately 300 kilometers north of Windhoek, the country’s capital, within the Province of Otjozondjupa. The Otjikoto mining and milling complex is 90% owned by B2Gold Corporation, and began commercial operation on February 28, 2015. The milling circuit operates at a throughput 3.3 million tonnes per annum. During design, a large emphasis was placed on gravity recovery, as the Otjikoto ores are unusually high in Gravity Recoverable Gold (GRG)."

Jan 1, 2018

By M. Harrison, C. H. Stockwell

"Metals vah1ed at more than $200,000,000 have been obtained, mainly since 1930, from the mines of northern Manitoba. The greater part of this production has been copper, zinc, and gold from the Flin Flon, Sherritt Gordon, and Mandy mines. The chief mines from which gold alone has been produced are God's Lake, Laguna, and Gurney. At present (May 1947) Flin Flon and Sherritt Gordon are the only producing mines, but the Nor-Acme property is being developed for large-scale production of gold. Large deposits of nickel and copper are being diamond drilled at Lynn Lake, and the Thompson, Ferro, and other properties are being developed. The mineral deposits lie within irregular or elongated areas of Precambrian sedimentary and volcanic rocks, surrounded by granite ( Fig. 1).The common rock types include basic and acidic flows, agglomerate, ruff, greywacke, arkose, argilli te, conglomerate, and their gneissoid and schistose derivatives. They are invaded by sills, dykes, and irregular bodies of gabbro and diorite, and all are cut by granite. Some of the sediments are interstratified with volcanics, and others are deposited unconformably on them.STRUCTURAL GEOLOGYLittle is known of the structures of the rocks in the area as a whole, because by far the greater part is unexplored or has been covered only by reconnaissance surveys. Available information indicates a general east structural trend in the southeast part, whereas in the west part the folding is mote complex with no definite overall trend. However, in a few small areas in the western part where detailed work has been done, as around the Flin Flon, Sherritt-Gordon, Nor-Acme, and other properties, the structure is fairly well known. The following descriptions apply chiefly to these areas ."

Jan 1, 1954

By T. Xu

"The CTL-500 centrifugal extraction machine, which was independently developed by Baotou Shibo Rare Earth Extraction & Equipment Co., Ltd., is presented in this article. The machine is based on centrifugal extraction principle and has been used in P507-HCl-RECl3 extraction system. Automatic control has been utilized in the system. In this paper, a comparison is made between centrifugal extraction and conventional mixer-settler extraction and satisfactory results are shown. INTRODUCTIONCentrifugal extraction is a fast and efficient liquid-liquid extraction method. The process includes solute transfer and separation of the two liquid phases. In the CTL-500 machine, the organic and aqueous phases individually enter a lower mixing chamber in certain proportions and are mixed and dispersed and solute thereby transferred from one phase to the other. The mixed phases pass into a rotating drum and the two liquid phases are separated under centrifugal force. As it flows upward, the aqueous phase, which has a higher specific gravity, flows away from the rotating drum centre towards the drum wall and the organic phase flows towards the drum center. The two liquid phases enter into collection chambers through independent weir plates and are discharged from the machine.The centrifugal extraction machine has been widely used in liquid-liquid separation, either without solid or with small quantities of solids (Chen, Zhang, Zhuo, Chen & Li, 2008; Duan, Jing, Zhu & Chen, 2007; Duan, Zhou & Zhou, 2006). Examples of the use of the centrifugal contactor include the separation of water from crude oil, treatment of heavy oil and diesel to eliminate water and salt; the extraction of penicillin, garlic oil, malathion, and interferon; the hydrometallurgy recovery of nickel, copper and uranium; extraction of edible oil, spice, refined oil and food color; treatment and recycle of print and dyeing wastes; treatment of hydroxybenzene-contaminated sewage by multistage extraction and separation of water from oil in ship sewage."

Jan 1, 2012

By B. K. Gorain

Barrick&apos; s Buzwagi copper-gold deposit in Tanzania comprises oxide, saprock and sulphide mineralized zones averaging approximately 0.058oz/t gold, 0.13% total copper and 0.03% cyanide-soluble copper. A comparative evaluation of the project based on two potential flowsheet alternatives is presented. The first flowsheet included a gravityconcentration and carbon-in-leach (CIL) plant. The second flowsheet was based on a Gravity-Flotation-CIL plant, which proved to be more economically robust. Selective flotation of copper minerals to produce a saleable copper concentrate proved to be challenging. Detailed characterization of the Buzwagi deposit was carried out through understanding of ore mineralogy, mineral liberation, floatability and selectivity, reagent chemistry and regrinding issues. With this insight, a flotation concentrate of greater than 25% Cu was achieved, recovering a significant amount of copper minerals and tellurides. The overall economics of the project improved significantly with the addition of flotation. Leach tests on gravity and flotation tailings showed an overall increase in gold recovery of approximately 6% for a Gravity-Flotation-CIL plant compared to that for a Gravity-CIL plant.

Jan 1, 2007

By B. Ignasiak

Laboratory studies suggest that improvements of coke strength brought about by pre-heating caking coals before carbonization accrue from inadvertent oxidation rather than from other low-temperature changes in the coal mass. Controlled oxidation of highly caking coal, followed by laboratory carbonization, produces cokes which, in terms of a laboratory scale tumble test index, are equivalent to those obtained from prime metallurgical blends. Appropriately formulated blends of exhaustively oxidized and fresh caking coal similarly yield cokes with strength indices comparable to those of cokes made from the same coal after oxidation under optimum conditions.

Jan 1, 1979

By R. Rumpold, J. Antrekowitsch

"The continued increase of the automobile production leads to a higher platinum, palladium and rhodium (PGM) demand. Due to the high value of the PGMs the recycle of these metals from automotive catalysts is of special interest. Pyrometallurgical processes, which are only focused on the PGMs, represent the state of the art of automotive catalysts recovery. However, hydrometallurgical recycling processes offer additional recovery of other valuable metals and compounds. The method presented in this paper is based on a combination of hydrochloric acid and hydrogen peroxide to dissolve the valuable metal fraction which can be precipitated afterwards.INTRODUCTIONPlatinum and the corresponding metals from the PGM group, especially palladium and rhodium are well known as catalytic active materials. They support chemical reactions which are inhibited. This effect is used to decrease the amount of harmful compounds like hydrocarbons, carbon monoxide or nitrogen oxides in automotive exhaust gases. The generation of these toxic substances is based on incomplete combustion, which in turn is caused by non-ideal conditions in the combustion chamber. Catalytic converters minimize the harmful compounds by supporting the following Reactions 1 – 3 (Votsmeier et al., 2009).CO + ½ O2 ? CO2 (1)CnHm + (n + ¼ m) O2 ? n CO2 + ½ m H2O (2)2 NO + 2 CO ? N2 + 2 CO2 (3)Platinum and palladium are very effective for the oxidation (Reactions 1 and 2), while rhodium supports the decomposition of nitrogen oxides by carbon monoxide (Votsmeier et al., 2009). The classical three way catalyst was a platinum – rhodium combination with a Pt:Rh ratio of 5:1 (Hagelüken et al., 2005). Today the platinum, palladium and rhodium ratio is highly variable and strongly depends on the engine type as well as on the car producer. Diesel engines are operated with a super stoichiometric air addition in comparison to spark ignition systems. Therefore the exhaust gas composition and off gas temperature is different. Based on the high oxygen amount, diesel engines produce less carbon monoxide and hydrocarbons but more nitrogen oxide in contrast to gasoline engines. This leads to various requirements for the catalytic converters."

Jan 1, 2012

By Matthew R. Ward

This paper aims to describe the reasons and methods to extend enterprise networks into underground mines. Currently mines use a number of communication networks for telephones, PLCs, two-way VHF radio and computer networking. Each system can have different wiring, protocols, converters and interfaces all which require expansion and maintenance. The convergence of voice, video and data using Ethernet and TCP/IP has the very real benefit of one ?wire? for underground networks. Now that the majority of underground equipment can communicate using TCP/IP, network convergence can offer reduced network expansion and maintenance costs. Cost savings are good, but the truly exciting aspect of network convergence using Ethernet is the low-cost, high speed wireless networking now available . These wireless networks offer an opportunity to facilitate mining automation even on a small budget. How would mine operators change they way they operate if they could gather vehicle location and data in real time? What about controlling equipment remotely? The list of applications is long and includes traffic control, dispatching, real-time ore blending, tele-operation, automated production reporting, vehicle health monitoring, elimination of paper forms and immediate network access for surveyors and geologists. An ideal converged network for underground mining would be robust, inexpensive, easy to expand, enable fast and secure connections while keeping voice communication performance equivalent or better than what is now provided by VHF radio

Apr 1, 2005