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By V. Caps

Gold has been often used as an alloying component in order to increase or modify the catalytic properties of an active metal. For example, in the hydroconversion of methylcyclopentane, Riahi et al [1] shown that the addition of gold to palladium or platinum enhances the activity which becomes greater than that of the pure metals whereas the selectivity towards products resulting from ring expansion increases. Molenbroek et al [2] presented a detailed study on Ni-Au catalysts which exhibit activity for steam reforming and have been proved to be more resistant toward carbon formation than the pure Ni catalysts. Blocking of highly reactive Ni edge and kink sites by Au atoms is assumed to be the reason for the increased robustness of the Ni-Au catalyst. Nevertheless, the own catalytic properties of pure gold have been almost ignored up to the pioneering work of Haruta et al [3] which demonstrates the high activity of gold for CO oxidation at low temperatures. Other reactions such as WGS reaction, propylene epoxidation or benzene total oxidation have then been shown to be catalyzed by gold [4]. This discovery induced the publication of papers devoted to analyze the different factors controlling the activity of gold catalysts. Among them the most relevant appears to be the gold particle size, the nature of the support [5] and the preparation methods [6]. Clearly distinguish between support and size effect is not straightforward. Indeed, the calcination step often needed to synthesize supported catalysts on different supports, leads to different particle sizes showing that particle size and support are interdependent. To circumvent this difficulty, Au-based supported catalysts have been synthesized by using laser vaporization and low energy cluster beam deposition. The as prepared catalysts have then been characterized and tested in CO oxidation reaction.

Oct 1, 2003

By Suping Yao, Chuanyu Jiang

In the last decade, the copper industry in China has witnessed a significant change. The capacity and production of refined copper has grown remarkably from 1.5 million tons in 2002 up to 5.88 million tons in 2012. And now, China has become the biggest copper producer in the world, counting about 30% of the global refined copper production. This paper summarized modern copper smelting and converting technologies employed in China copper industry, such as OT flash technology, TSL (ISA/Ausmelt), SKS bottom blowing, Jinfeng side blowing, etc…This paper also presents some key development and improvement of these technologies up to date from their practical application in China, what will contribute as great value to any new / or renovation copper smelting projects down the road. As an engineering company in China, NERIN has been involved in many of these projects in the past decade, played an important role in the engineering works and accumulated intensive experiences. NERIN is one of the best choices for the world clients in the copper industry, providing quick engineering service, delivering cost effective projects.

Jan 1, 2014

By Xuanxue Mo, Kaihui Yang, Steven D. Scott

Abstract -The Changning-Menglian metallogenic belt in western Yunnan, China, is characterized by the occurrences of both Pb-Zn-Cu and Cu massive sulfides in Permo-Carboniferous mafic volcanic sequences. These deposits were formed in a back-arc basin at a rifted continental margin in the Paleozoic Tethys Ocean. Pb-Zn-Cu deposits are associated with alkalic basalt, andesite, and lesser felsic volcanic rocks intercalated with limestone, which probably formed along an immature rifting segment on a continental basement. These volcanic rocks are enriched in K, Ti, LREE, and other incompatible elements, and have the attributes of alkalic within-plate basalt. An extensive unit of sulfide- carbonate-silica shale in proximity to massive sulfides contains high values of Mn, As, Mo, W, Sn, Sb, and Hg, and has REE patterns that are similar to the volcanic rocks. This, together with the graded bedding in the footwall volcanic rocks, suggests that the sulfides precipitated in a shallow, unstable, and carbonate-saturated volcanic basin. A stringer zone is traced downward for 500 m below the massive sulfide orebodies. It is characterized by an upper sericite-quartz zone and an extensive lower skarn alteration with enhanced W, Sn, and Bi. Lead isotope data show both continental basement and magmatic sources may have supplied the ore metals. Cu deposit and occurrences are hosted by tholeiitic units that represent the mature spreading segments in the back-arc basin. The tholeiitic lavas have LREE-depleted or flat REE patterns similar to MORB or back-arc mafic lavas. The cupriferous massive sulfides are overlain by an extensive unit of chlorite-magnetite or ochre, suggesting a relatively oxygenated oceanic basin. Ni and less Co mineralization is found in dolomite veins of the stringer zone. Enhanced concentrations of Ni, Co, Au, and As are found in the massive sulfides and in sulfide-rich tuffites. The geological setting and mineralization of the Changning-Menglian belt has similarities with modern back-arc basins such as the Manus Basin in the western Pacific.

Jan 1, 1999

By Tyson C. Birkett

Initial indicator mineral sampling covering 425,000 square km of northern Quebec and subsequent follow-up of positive results convinced the Ashton ? SOQUEM joint venture to acquire mineral rights to 380,000 hectares prospective for diamond in late summer, 2000. Drilling in 2001 and 2002 identified eight kimberlitic bodies, all significantly diamondiferous. Commercial size stones (retained on a square mesh sieve with openings 0.85 mm) and encouraging grades have been returned by several bodies tested to date: The Renard bodies are formed by steep-sided breccia pipes with kimberlitic matrix surrounded by irregular outboard breccia zones within country rock. These bodies were emplaced in high-grade metamorphic rocks of the Superior Province of Archean age. Orthogneiss with lesser tonalite hosts the breccias, although regionally paragneiss is also present. Diatreme facies portions and nearby country rock are intruded by minor to major (Renard 1) amounts of hypabyssal-facies kimberlitic rock. Renard bodies are macrocrystic, with large olivine crystals set in a groundmass of olivine, phlogopite, monticellite, spinel, carbonate, apatite and serpentine. Proximity of various Renard bodies, with most in a core area of 0.5 square km will allow planning of an efficient mining operation. Geophysics, especially magnetic surveying, has contributed to identifying bodies of kimberlitic rock.

May 1, 2003

By Garston Blackwell

Abstract - During geostatistical estimation of block grades, the kriging process produces a measure of error, the kriging variance or the kriging standard deviation. Estimation of the block error depends on the semi-variogram model for a deposit, which reflects fundamental characteristics of a deposit such as (1) nugget effect, (2) range of influence of grades, (3) different local spreads of data as a function of average grade (proportional effect), (4) nested structures, and (5) underlying anisotropies in the data; this model may be affected by sampling or assaying limitations, however. Because the kriging error incorporates so many features of both the deposit and data to be used for estimation, it may offer a substantial improvement on block classification over traditional procedures such as data density. Practice indicates that the relative kriging standard deviation (RKSD) is particularly useful for block classification in measured, indicated and inferred categories. Plots of RKSD in plan and section also can be used to demonstrate where extra drilling and sampling would be most advantageous for upgrading the class of some blocks. Moreover, the use of grade and RKSD filters can show where material near cut-off grade is poorly defined, indicating sampling target areas to improve block classification in the vicinity of the ore-waste boundary.

Jan 1, 1998

By X. Cao, X. -G. Chen, K. Liu

Due to the detrimental effect of platelet iron-rich intermetallics on mechanical properties (particularly ductility) in cast alloys, it has been essential to transform these phases into Chinese script morphology. In the present work, the effects of Mn and/or Si addition and cooling rate on the phase transformation of the iron-rich intermetallics in 206 cast alloys with different Fe contents ranging from 0.15 % to 0.5 % were systematically investigated. The results obtained showed that platelet ß-Fe and Al3(FeMn), Chinese script a-Fe, Alm(FeMn) and Al6(FeMn) can be observed in the 206 cast alloys, depending on the Fe, Mn and Si contents as well as the cooling rate. It was found that the addition of either Mn or Si favors the formation of Chinese script iron-rich intermetallics but inhibits the precipitation of the platelet phases. In addition, the combined addition of both Mn and Si has a synergistic effect on the phase transformation. Furthermore, there exists a critical cooling rate to effectively suppress the formation of platelet iron-rich intermetallics for a given alloy. The threshold cooling rate decreases with increasing Fe, Mn and Si contents. Casting process maps are established to correlate the intermetallics precipitated with alloy chemistry and cooling rate for 206 cast alloys containing various Fe levels.

Jan 1, 2014

By A. L. Rutledge, R. S. Nichols

"Waste dump development at the Fording River Operation s in British Columbia began in 1971. In 1981, several unique as well as unplanned situations provided an opportunity to study water flows through waste dumps.The key to the drainage is naturally segregated rock sizes .created by end dumping from the crest of a pile. The largest size material accumulates at the toe. Flow rates along the base of the studied dumps varied from 2,800 to 13,500 m3/day or 0.032 to 0. 156 m3/s (1.2-5.5 cfs}. Sediment concentrations in the water ranged from 1 to 1,800 mg/I.This paper describes water flows through dumps of varied lithology and maturity. The results suggest that neither long-term water flow nor contained sediments in small streams are jeopardized when crossed by end-dumped fills.IntroductionThe Fording River Operations are located in southeastern British Columbia approximately 115 km north of the United State s and 10 km west of Alberta, within the medial range of the Rocky Mountains. All production is carried out at elevations ranging between 1,600 and 2,200 m above sea level.The property is within a continental climatic zone, with temperature extremes of - 40°C in January to +35°C in July. The average annual precipitation of 335 mm of rainfall and 390 cm of snowfall feeds the numerous seasonal, small drainage courses along the Fording River valley.Since start-up in 1971, 149 million bank cubic met res of waste from truck-shovel and dragline mining have been placed in numerous dumps or ""spoils"". The dumps were developed to the point that several unique situations could be studied. During the peak run-off period of May-June 1981, water flow studies were performed on dumps of varied lithology and maturity. This paper describes the results of the study."

Jan 1, 1982

By M. Elmadagli

Wear mechanisms of two commercial aluminum alloys, namely a spray formed and extruded Al-25%Si alloy, and a sand cast A390 alloy (18.5 %Si) that are known to be successful in cylinder bore technology were studied to have a better understanding of the requirements for wear resistant aluminum alloy design. From durability point of view these alloys are known to be successful for engine bore applications. It is interesting to compare the wear mechanisms in these alloys because they have significantly different silicon content and microstructures, and were produced using different techniques. The wear tests were done using a block-on-ring configuration, in controlled air atmospheres (5 % relative humidity). In spite of the differences in silicon content and microstructure, the wear mechanisms were similar and consisted of formation and destruction of hard tribolayers that are either formed by either mechanical or chemical interactions on contact surfaces. The differences in the wear rates between the two alloys arose from the differences in the hardness of the worn surfaces, and the alloy's ability to sustain the tribolayers on the worn surfaces.

Jan 1, 2004

By W. Evans, C. E. Ells

Nuclear power reactors using zirconium alloy pressure tubes generate electricity in several countries. Such reactors are particularly important in Ontario, where CANDUs* generate about 30% of the total electricity produced in the Province. Starting with the commitment of NPD-2 in 1956, the pressure tubes of the first five CANDU reactors were made of coldworked Zircaloy-Z, an alloy of Zr and Sn. This alloy was developed by the US Navy, but the decision to use it in a cold-worked condition was based on AECL work. In 1958, the USSR published information on a new alloy, Zr-2.5 wt% Nb. The Nb promotes stabilization of the (3-phase in the material, thus presenting opportunities of exploiting metallurgically strong pressure tubes analogous to the heat-treatable cx-{3 titanium alloys. After construction of two reactors using Zr-2.5 wt% Nb in a quenched and aged condition, an extensive development program on cold-worked Zr-2.5 wt% Nb pressure tubes resulted in them becoming the reference tubes for all CANDU reactors committed since 1966. Anticipating the future needs of the domestic and export markets, AECL have pressure tubes of Zr-3.3 wt% Sn-0.8 wt% Nb-0.8 wt% Mo (Excel) in an advanced state of development. These tubes will be used in an annealed condition; our projections show that they will have improved dimensional stability over the lifetime of the reactors. These improvements result from experimental programs leading to an understanding of the relationship between microstructures and fabrication variables and effects of the environment during service in nuclear reactors.

Jan 1, 1981

By X. Cao, X. -G. Chen, K. Liu

As is well known, the standard Al-Cu 206 cast alloys have extremely low iron contents, usually less than 0.15 wt. %. Recently it is found that the iron contents of the 206 cast alloys can be extended up to 0.5 wt. % through the precise control of the iron-rich intermetallic phases. In the present work, the tensile fracture surfaces of the 206 cast alloys with various iron contents are systematically analyzed to understand the failure mechanisms. Results show that higher iron contents can reduce the tensile properties (especially the ductility) of the alloys mainly due to the increasing volume percent and size of the iron-rich intermetallics. Tensile failure mainly occurs at the iron-rich intermetallics/matrix interfaces for the platelet ß-Fe, but by the self-disassociation for the Chinese script a-Fe and Alm(FeMn). Cracking is easier to initiate and propagate along the longitudinal axis of the platelet intermetallics, but it can be deflected along the branches/arms of the Chinese script iron-rich phases, making the alloy more resistant to the propagation of the cracks, and thus the Chinese script iron-rich intermetallics are less harmful than platelet ß-Fe. In addition, it was also found that the Chinese script a-Fe has even a less damaging effect compared to the Chinese script Alm(FeMn) due to the relatively small size and compact morphology.

Jan 1, 2014

By Mehmet F. Taner

"Abstract - The East Sullivan Stock (ESS) is a small, composite felsic alkaline pluton of presumed late Archean age in the Val d’Or mining district. Three main facies have been distinguished: monzonite sensu stricto, porphyritic monzonite, and green trachytic porphyry. This monzonitic group of rocks is of relatively homogeneous composition with high abundances of Na2O, K2O, Ba, Sr, Rb, Zr, Mo and LREE. The alkaline ESS is distinguished from other igneous units in the Val d’Or mining district, such as the Bourlamaque Batholith, by relatively high concentrations of Ba, Sr, Rb, Mo, Cu and Au. The ESS hosts many base (Cu, Mo) and precious (Au) metal occurrences, including: (1) porphyry style Cu-Au-Mo disseminated sulfide deposits, (2) Cu-Au deposits in volcanic rocks near the ESS contact, and (3) pyritic gold mineralization in east-west trending shear zones. The ESS is well defined by concentrical zoning on the aeromagnetic vertical gradient color map, and displays four linear trends, which are assumed to be structural lineaments, at 035°-055°, 320°-300°, eastwest, and north-south. The main mineral occurrences related to the stock display a preferred spatial association with the east-west linear magnetic trends.The ESS is preferentially located along a major structure and was emplaced late in the evolution of the Abitibi subprovince like other felsic alkaline plutons. This stock is similar to late-tectonic mineralized felsic alkaline intrusions of the Kirkland Lake and Larder Lake mining districts in Ontario, and to the Allard stock in the U.S.A. which is associated with gold and base metal mineralization. Similarities also exist with younger alkaline plutons associated with Cu-Mo-Au porphyry deposits in the Canadian Cordillera, which formed in tensional tectonic environments. The felsic alkaline magma may have formed by partial melting of deeply buried supracrustal rocks, concomitant with the development of deep fractures such as the Cadillac Fault. In such an environment, hydrothermal solutions carrying remobilized metals from deep supracrustal rocks may have deposited gold and base metals in structural traps. Plutons similar to the ESS should be good targets for mineral exploration. Résumé - Le Stock de East Sullivan (SES) est une intrusion composite alcaline d’âge tardiarchéen, situé dans le camp minier de Val d’Or. Trois principaux faciès ont été identifiés: une monzonite sensu stricto, une monzonite porphyrique et un porphyre trachytique vert. Les données chimiques montrent que ce groupe des roches monzonitiques est relativement homogène en composition avec des concentrations élevées de Na2O, K2O, Ba, Sr, Rb, Zr, Mo et ETRL, définissant une suite alcaline typique. Cet alkalin stock peut être facilement distingué des autres unités géologiques de la région de Val d’Or, tel le batholite de Bourlamaque, par une concentration élevée de Ba, Sr, Rb, Mo, Cu et d’Au. Le SES contient plusieurs importants prospects de métal précieux (Au) et de métaux de base (Cu, Mo), incluant: (1) une minéralisation disséminée de type porphyre Cu-Mo-Au, (2) une minéralisation de Cu-Au dans les roches volcaniques encaissantes hôtesses près du contact et (3) une minéralisation d’or pyritique dans une zone de cisaillement de direction est-nordest. Le SES est bien défini sur la carte aéromagnétique en couleurs du gradient vertical par des zonages concentriques, où quatre linéaments structuraux ont été reconnus: 035°-55°, 320°-300°, est-ouest, et nord-sud. Les principales zones minéralisées spatialement associées au stock sont généralement situées soit près des linéaments magnétiques est-ouest, soit le long de ceux-ci.Le SES semble s’être mis en place le long d’une structure majeure, développée tardivement dans l’évolution de la Sous-province abitibienne, comme les autres plutons alcalins felsiques. Ce stock est similaire à la suite tardi-tectonique d’intrusions alcalines minéralisées des camps miniers de Kirkland Lake et de Larder Lake en Ontario, ou"

Jan 1, 1996

By Bian Xue, Wu Wenyuan

In order to recycle the iron and rare earth from the Baotou tailings, a roasting method was developed involving the addition of C, Ca(OH)2, and NaOH, designed to both decompose the rare earth minerals and convert haematite into magnetite and allow its recovery. The effect of various parameters such as roasting temperature, roasting time, C addition, Ca(OH)2 addition, and NaOH addition on the reduction ratio of haematite (iron sesquioxide) and decomposition ratio of rare earth were investigated. The results showed that the reduction ratio of haematite and the decomposition ratio of rare earth could be as high as 85% and 95% respectively when the roasting temperature was 650°C, roasting time was 60 min, Ca(OH)2 addition was 4%, NaOH addition was 3%, and C addition was 1.5%.

Jan 1, 2014

By L. Nutter, J. Clancy

"Barite is used extensively by the oil and gas well-drilling industry as a weighting agent. It is particularly well suited for drilling mud because of its qualities; it is non-abrasive, heavy, virtually inert chemically, easy to handle and inexpensive compared to other available heavy materials. Increased deep well drilling in Western Canada, and especially in the Arctic regions, could dramatically affect the demand for barite through this decade. Known deposits in northeast British Columbia are possible sources of incremental barite supplies, should the situation develop.IntroductionThe purpose of this report is to examine the opportunities for expanding barite production in British Columbia. Of primary interest will be the relationship between the projected future levels of production and consumption of barite in Western Canada and the extent to which increased domestic production could replace the need for imports in filling any expected supply shortages.After a brief overview of the nature and uses of barite and some of the relevant features of the barite supply industry, the discussion will turn to the supply gap in the Canadian market and the possibilities for import substitution.OverviewBarite is an industrial mineral which is used in large quantities by the oil and gas well-drilling industry. It is often an important component of drilling mud, a fluid circulated continuously in the well during the drilling process to lubricate and cool the drilling apparatus and to contain the high oil and gas pressures found at depth. Barite (BaSO4) is particularly well suited as a weighting agent for drilling mud because it is a heavy (specific gravity to 4.5) inert mineral which is inexpensive in relation to other materials having a high specific gravity. In the on-site use of drilling mud, ground barite is combined with numerous other solid ingredients and chemicals in the form of a slurry. Other advantages of barite include cleanliness, ease in handling and its non-abrasive character (hardness of 3-3.5)."

Jan 1, 1982

By Teresa Sikora

For over 40 years the Institute of Innovative Technology EMAG has specialized in the development of systems and equipment for laboratory and on-line monitoring of coal quality parameters, as well as the implementation of these systems and devices in mines and power stations. Some of these systems, based on advanced radiation detection techniques such as ?-ray backscattering (ALFA-06 and ALFA -06/T systems) or dual energy ?-ray transmission measurement (ALFA-06/2E ash meter), and also the ALFA-06/3E system applying microwave technology for the measurement of moisture, have had numerous applications in Poland. At present, over 100 systems and devices are used in Polish hard and brown coal mines. For over 10 years, EMAG has been specializing in the development of systems and devices, based on natural gamma measurement technology. An on-line ash meter, RODOS and RODOS Ex, based on measurement of natural gamma radioactivity of coal, has been developed and put into operation. This technique has been also used in developing the portable ash meter WALKER and laboratory analyzer GAMMA NATURA. The paper briefly presents features of the above-mentioned devices, their limits and their obtained accuracy, but in particular refers to the laboratory analyzer, GAMMA NATURA, as the first such device in the world, and presents the results of ash and moisture content measurement in hard, brown coals and potassium salts. The possible applications and advantages of the device in coal mines are discussed. The paper also presents the implementation results of the portable ash meter, WALKER, and the on-line ash meter, RODOS, that is used underground in coal mines.

Aug 1, 2013

By P. R. A. Andrews

"Areas of bubble contact were delineated for cassiterite in the presence of chloride, fluoride, sulphate, phosphate, oxalate and citrate ions using dodecylamine hydrochloride collector. The limits of pH, and the minimum collector concentration were established using the bubble pick-up technique.Bubble contact did not occur below the p.z.c. (point of zero charge), estimated to be 4.7, in the presence of chloride ion, and fluoride ion showed only a weak response in the same pH range. These anions are considered to act as indifferent electrolytes. Activation at pH values below the p.z.c. was obtained with sulphate, phosphate, oxalate and citrate ions; the greatest response was by oxalate and phosphate ions extending pick-up to between pH 2.0 and 2.5.Activation appeared to be strongest when anionic protonated species were in maximum concentration. Strong activation also corresponded to the formation of very stable metal ion species, thought to be formed on the surface of cassiterite, between exposed stannic ions and modifying anions; dodecylammonium ions being absorbed on the surface so modified."

Jan 1, 1991

By M. Isac, R. I. L. Guthrie, S. Ge

The Al-Mg-Sc-Zr alloys have shown exceptional potential as structural materials for transportation applications. These alloys have proved to be good candidates to be processed as thin strips via the Horizontal Single Belt Casting (HSBC) process. The HSBC process is a near-net-shape casting technology, which involves casting molten metal directly into thin strips, close to the final product thickness, at high cooling rates. It offers an efficient, economical and environmentally-friendly approach to the production of metal strips. Fluid mechanics and associated heat transfer are important aspects of any casting process, and the novel HSBC process is no exception. Three dimensional Computational Fluid Dynamics (CFD) simulations using ANSYS FLUENT 14.5 were performed, in order to assess the importance and effects of the various operational conditions of the HSBC process. This enabled process parameter optimization. Numerical predictions were validated against experimental casting results.

Jan 1, 2014

By L. Bichler, A. Siebert-Timmer

In this research, novel YSZ ceramics doped with 5 mol% Nd2O3 were manufactured via Spark Plasma Sintering (SPS) process. The sintered Nd2O3-YSZ ceramics were subjected to a static supercritical water environment at a temperature and pressure of 400 °C and 31 MPa, respectively. The weight loss and microstructure development of the sintered ceramic before and after exposure to supercritical water was studied. The results suggested that Nd2O3 addition significantly improved the degradation resistance of the YSZ ceramics. This was attributed to the improved phase stability of the 5 mol% Nd2O3-YSZ ceramics, since X-ray Diffraction (XRD) studies showed that the cubic stabilized matrix in these ceramics was retained after exposure to supercritical water. In comparison, pure YSZ ceramics exhibited a rapid degradation behavior as well as a phase change.

Jan 1, 2014

By M. Hozayen, E. S. Radwan, P. A. Nawrocki, A. Jebbouri

"A major geomechanical study was conducted for one of the UAE onshore oil fields with the purpose of studying reservoir rock properties and stress distribution, based on which a 3D coupled reservoir geomechanical model was built. This model was later used for wellbore stability analysis and for analyzing the effect of fractures on future reservoir production performance, including fracture deformation and permeability evolution occurring due to reservoir depletion and resulting changes in local stress field. The subject of this study was a complex fractured Upper Cretaceous carbonate reservoir characterized by high degree of heterogeneity, both vertically and laterally. Wellbore instability related drilling problems were encountered while drilling the wells in this field. The problems were mainly in drilling the horizontal wells, including breakouts and mud losses. Experimental results of laboratory tests are summarized in this paper whereas wellbore stability analysis and formulation of a 3D geomechanical model that was built for that purpose is summarized in a sister paper (Part II).A suite of tests reported includes tensile strength, uniaxial and triaxial compression and permeability under stress at simulated reservoir conditions. All tested rocks have been grouped into twelve test units and reservoir geology, rock types and challenges related to designing a viable sampling and testing program for a big reservoir are discussed first followed by sample selection criteria and details of the testing program. All test units showed brittle behavior at zero confinement and some samples showed similar behavior at low confining stresses. With confining stress increase, the behavior gradually turned to plastic but some samples showed features of ductile behavior even at low confinement.Obtained experimental data have been summarized in the form of strength criteria and correlations. The Mohr-Coulomb strength equations were obtained for each test unit and also for the averaged values. It was noticed that triaxial compressive strength (TCS) increases with decreasing porosity or increasing density but their influence on TCS is getting smaller with confining pressure increase. Good correlation of porosity and density with Young’s modulus, Poisson’s ratio, unconfined compressive strength (UCS), friction angle, cohesion and tensile strength has been noticed and there was an increasing trend between the confining pressure and TCS. Rock type (mud or grain supported) was not influencing the TCS as much as porosity and density and the two lithologies encountered affected TCS approximately in the same way. These results and correlations are summarized and explained in this paper. They were further used in the numerical modelling part (Part II) of this paper, Hozayen et al. (2015). It is also concluded that rock lithology is not a decisive factor and mechanical properties of tested rocks should be rather considered dependent on porosity and permeability. This helped greatly in reducing the number of tests that had to be performed."

Jan 1, 2015

By Eiichi Sato, Koichi Kitazono, Hiroshi Masuda, Kenta Higane

"The present study investigated the low-temperature creep mechanisms in ultrafine-grained (UFG) aluminum manufactured by accumulative roll bonding. UFG aluminum with grain size 0.39 µm showed steady state creep even at room temperature under low stresses as confirmed by the creep curves in the strain rate–strain plot. The low-temperature behavior was divided into four regions by three distinctive stresses, sI, sII and sIII: sI (=45 MPa) is denoted as the micro-yielding stress with which dislocations start movement, sII (=85 MPa) the dislocation-multiplication stress above which dislocations multiply with creep deformation, and sIII (=171 MPa) the conventional yield stress above which macroscopic plastic strain is generated. During low-temperature creep, below sI, negligible plastic strain is generated. Between sI and sII, creep deformation with stress exponent 2.5 occurred, which is accommodated by dislocation absorption into grain boundary and grain boundary sliding, similarly to the low-temperature creep of HCP metals. Between sII and sIII, creep deformation with stress exponent 7.0 occurred, whose mechanism is similar to the low-temperature creep of coarse-grained aluminum. Above sIII, power-law breakdown occurred.INTRODUCTIONIt is well understood that the creep deformation brings about at high homologous temperatures (T/Tm) of >0.4, where Tmis the melting point, with diffusion processes. Recently, the importance of aluminum is increasing for cryogenic temperature parts such as a metallic liner or a cap in high pressure-hydrogen vessels, and the presence of creep behavior in aluminum at room temperature has become recognized (Matsunaga, 2013;Kassner, 2015).In HCP metals and alloys, especially intitanium, steady-state creep behavior appears at room temperature with apparent activation energy of1/10 of that for self-diffusion(Neeraj, 2000; Matsunaga, 2009).On the other hand, Kassner (2015) claims that aluminum shows creep behavior at room temperature with apparent activation energy of 4/5of that forself-diffusion, but never reaches the steady state. We should note that it is derived from the data obtained from short-term creep tests of few hour, and Matsunaga (2013) already claimed the presence of steady state in room temperature creep in aluminum with activation energy of 1/5of that for self-diffusion.The mechanisms for low temperature creep are considered different between HCP and FCC metals: in HCP metals, grain boundary sliding is observed and is thought to accommodate piled-up dislocations at grain boundaries through absorbing them. The so-called slip-induced grain boundary sliding occurs with low number of activated slip systems(Matsunaga,2009).On the other hand, in FCC metals, many activated slip systems bring about work hardening with dislocation cell structure formation. In the initial stage of creep, it results in primary creep (Kassner, 2015), but Matsunaga (2013) claimed that once the annihilating of a cross-slipped dislocation to another reaches balance, steady state is established. It has been, however, strongly required to show more convincing experimental verification for the presence of steady state in FCC metals at low temperature."

Jan 1, 2018

By David R. Ray, Arthur J. Pyron, William F. Thomann

"Proterozoic plutonic and volcanic rocks in the Franklin Mountains, west Texas, exhibit similar values in average concentrations of equivalent uranium (eU), equivalent thorium (eTh) and equivalent potassium (eK) when compared to Proterozoic igneous rocks of the southwestern United States. Variations of radioelement concentrations for all Proterozoic igneous rocks of the Franklin Mountains range from 1.1 to 357.1 ppm U, 2.1to 259.1 ppm Th and 2.5 to 10.2% K.Recent geologic mapping of the Proterozoic rocks in the Franklin Mountains revealed several types of granites previously unrecognized, and these warrant further exploration for U and Th resources. Fluorite-bearing granites and riebeckite pegmatites are likely targets for further investigation, as these have the highest U and Th concentrations compared to all other granites.IntroductionThis is a summary of the paper presented at the CIM Geology Division Uranium Symposium held in Saskatoon, Saskatchewan, September 8-13, 1981. The purpose of this study was to evaluate the distribution of uranium (U), thorium (Th) and potassium (K) in Proterozoic igneous rocks in the Franklin Mountains, and compare radioelement concentrations to Proterozoic igneous rocks elsewhere in the southwestern United States.General GeologyThe Franklin Mountains are located in west Texas and southcentral New Mexico, within the southeastern part of the Basin and Range Province o f the southwestern United States. The Franklins are a complex fault-block range trending northsouth with strata dipping toward the west. Ages of the rocks range from Proterozoic to Cretaceous. Harbour (1972, 1960) provides the most recent account of the general geology of the Franklin Mountains. Most recent accounts of the detailed Pro Proterozoic geology o f the Franklins are provided by Hoffer (1976), Thomann (1980, 1981), Pyron (1980), Ray (1982) and McCutcheon (1982)."

Jan 1, 1983