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By A. J. Oliver, C. E. O’Neil, I. J. Itzkovitch, V. A. Ettel

A new solvent extraction process for the separation of cobalt, copper and zinc from nickel sulphate process streams has been developed. It involves selective extraction of these elements with a quaternary ammonium thiocyanate dissolved in an aromatic diluent. The chemical principles of this process have been investigated and are described, together with background physico-chemical data relating to the use of this solvent. Long-term testing in a continuous "mini-plant" circuit gave high-purity nickel and cobalt products (Ni/Co —200011 and Co/Ni ~1000/1 respectively).

Jan 1, 1976

By A. MacKinnon, P. W. Kingston, W. F. Caley

"Wollastonite (CaSiO3]) is experiencing increased usage in a variety of applications, such as fillers in paints, plastics and resins, as an extender to replace both non-fibrous and fibrous materials (e.g. asbestos), and in the glass and ceramics industries. Significant new deposits of wollastonite have been discovered in Marmora Township, about 175 km northeast of Toronto. The geological setting of these large-tonnage. High grade deposits has recently been investigated to assess the possibility of their development. A preliminary study of the chemistry, as well as the mineralogy of six occurrences is presented. Based upon this information, it is suggested that several of the deposits have an excellent development potential.INTRODUCTIONWollastonite is an anhydrous calcium metasilicate (CaSiO3), with a theoretical composition of 48.3% CaO and 51.7% SiO2; the calcium may be partially replaced by iron, manganese, magnesium, and strontium. Commonly associated minerals include diopside, tremolite, idocrase, grossularite andradite, quartz, and calcite. Wollastonite forms as a contact metamorphic mineral within impure limestone near intrusive bodies of granite, or other acidic rocks, as the result of metasomatism of calcareous sedimentary rocks, or by the crystallization of certain magmas (e.g. carbonautes). Generally, the reaction of calcite with silica to produce wollastonite occurs when siliceous hydrothermal fluids from a granitic intrusion or primary silica in the limestone/marble react with calcite in limestone at temperatures between 450°C and 600°C."

Jan 1, 1989

By G. Hamel

The LCL&L process (Low Caustic Leaching & Liming) is a patented hydrometallurgical route developed by Rio Tinto Alcan (RTA) to economically process spent pot lining (SPL) generated by aluminum cells. The three resulting end-products (carbonaceous, fluorinated and caustic liquor) are inert and have valorization possibilities. An industrial size pilot plant located in Saguenay (Quebec) was inaugurated in mid-2008 to demonstrate and optimize the technology. This paper describes characteristics of the LCL&L process and the experience acquired by RTA since the plant's start-up, including ramp-up capacity and technology challenges that were overcome. Possible end-products valorization methods are also presented. The carbonaceous end-product can be separated into carbon and brick rich fractions and used as either alternative fuel, reducing agents, or as raw material for third party processes. The development of a conversion process for the fluorinated end-product would allow its reuse as a substitute to fluorspar mineral for aluminum fluoride production. Finally concentrated caustic liquor is already valorized at the nearby RTA Vaudreuil alumina refinery.

Jan 1, 2011

By Peter N. Calder

The orientation of planes of inherent weakness (joints) with reference to an excavation in rock is the critical factor determining stability. The purely frictional 'residual' strength remaining following the breakdown of initial cohesion is the only strength which can be counted on to resist sliding for the long term. A simple method of resolving driving and resisting forces in three dimensions along joint intersections 'undercut' by the excavation is presented. Contrary to the case of slope failure in soils, it is shown how significant changes in the slope angle sometimes have no effect on the degree of stability pre-sent in rock slopes. Wall control by reorientation of the slope, the use of cable bolts and water diversion are briefly discussed.

Jan 1, 1970

By K. Enns, J. J. Byerley

"While thiocyanate (SCN-) is used in a number of industrial processes (production of polyacrylonitrile filaments, synthesis of agricultural chemicals and certain metallurgical solvent extraction and flotation circuits) it is recognized more as an undesirable by-product associated with ' the metallurgical industry. Thiocyanate is present at low concentrations in some waste streams from the iron and steel industry. Of particular significance is the formation of thiocyanate during cyanidation of gold and silver ores, concentrates, tailing s and residues. The thiocyanate levels present in the resulting effluents may range from a few mg/I to several thousand mg/I.At present, thiocyanate does not appear to be as hazardous in the environment as cyanide (CN-) at the same concentration although its interaction with other species and resulting decomposition of products may be unacceptable. Of course the presence of thiocyanate in the leaching circuit and ultimately in the effluent streams may add considerably to the oxidative requirments of any non-selective treatment process for cyanidation wastes.With respect to the thiocyanate as it relates to the cyanidation process, two aspects are evident. Thiocyanate forms and persists in the cyanidation circuit resulting in a ""fouling"" condition with subsequent loss of leaching activity. In order to reduce or control this problem, it is common practice for some mills to discharge daily as much as 20% of the barren leach liquor. Besides contributing to fouling of the leach liquor the formation of thiocyanate represents an irreversible loss of reagent cyanide. It is noteworthy that in some present or proposed mill practice reagent cyanide loss through thiocyanate formation may reach 50%(1). The purpose of this paper is to discus s the application of controlled electrooxidation of thiocyanate with the view of suggesting a process for regenerating cyanide from waste thiocyanate(2). The paper describes the important theoretical aspects and presents experimental data obtained for thiocyanate electrooxidation using both small and large scale electrochemical reactors. Some economic conclusions are presented."

Jan 1, 1984

By T. Ouellet, F. Chiesa, J. Carignan, D. Levasseur

Common practice for the preparation of permanent mold for aluminum casting is to coat the mold with a ceramic suspension to obtain a chemically stable interface with the aluminum melt. This practice serves two purposes: first, it helps the thermal regulation of the mold and second, it prolongs its life. The possibility of increasing the coating durability by applying it by thermal spray is appealing. Plasma spray of zirconium oxide based coatings was performed on H13 tool steel to study the coating’s thermal fatigue resistance. A unique dip test setup was used to characterize the thermal fatigue resistance of the coatings and of bare H13 steel. Observations of the failure mechanism bring an insight on the requirements of the coating to maximize its durability.

Jan 1, 2014

By Simon C. Dominy, Ian M. Platten, Garry F. Johansen, Alwyn E. Annels, Brian W. Cuffley

Abstract - Coarse gold-bearing veins are characterized by high grades that are localized and erratic. Effective sampling of coarse gold-bearing veins is difficult because of the low concentration and erratic nature of the gold particles. Diamond drilling is an effective measure of geological continuity, however, grade distribution can only be reliably obtained from underground development (including close-spaced sampling, bulk sampling, and trial mining). Comparison between surface and underground drilling, underground linear/panel and bulk sampling indicate that drilling and linear/ panel samples generally understate bulk sample grades. Bulk samples are likely to be the closest estimators of true grade. It is unlikely that anything above an Inferred Resource category can be estimated from surface drilling alone, and at best the grade will only be a global estimate. Underground development, in-fill drilling and bulk sampling/trial mining will be required to delineate Indicated and Measured Resources. Closely spaced development and bulk sampling is likely to be the only way to determine Reserves. The resource estimation process must driven by a clear geological model that should attempt to understand both geological and grade continuity. Traditionally, grade interpolation has been undertaken using classical methods, though more recently, computer-based block modelling techniques have been used with some success. Three case histories are presented, documenting the problems of estimating resources in coarse gold-bearing veins and the practical ways in which they were approached.

Jan 1, 2000

By D. C. Martin, P. M. Hawley, C. P. Acott

"In bedded deposits such as coal or sedimentary iron, economic limits of mineable reserves are clearly defined by the footwall of the seams or ore-bearing units. Where open pits are developed in dipping strata, a long, high footwall slope may result. In many cases, unbenched slopes excavated along the base of the lowest mineable seam are operationally simple, economically desirable and geotechnicalty practical, although a variety of failure mechanisms may develop. This paper examines the engineering geology and rock mechanics parameters of importance in the design of footwall slopes. Possible failure mechanisms and stability analysis methods are described. Design considerations for benched and unbenched slopes are discussed with prime consideration given to development of long high stopes without benches or with a minimum number of benches. IntroductionIn bedded deposits, the ultimate depth and economic viability of an open pit in dipping strata may be controlled by the design of the footwall slope. The stability and, hence, design of footwall slopes is strongly influenced by the engineering geology and rock mechanics parameters of the slope forming materials. A clear understanding of the structural geology, engineering geology and tectonic history of the deposit is essential to assess the behaviour of the slope. This is particularly important for long high, unbenched footwall slopes such as shown in Photo I.A rational footwall slope design requires identification and assessment of all possible slope failure mechanisms with respect to the proposed slope geometry. Stability analyses of each potential failure mechanism are used to identify the main controls on slope stability and to develop appropriate slope design criteria. The optimum slope design is based on the most economic and geotechnically practical slope geometry with due consideration of operational constraints and of the possible advantages of specific remedial measures."

Jan 1, 1986

By Lynne Bowen

"On the da y shift in Number One Mine at Nanaimo on Vancouver Island, on May 3, 1887, William Griffiths, a coal miner with many years experience, fired a shot to advance the face of the crosscut. A flame ran out for a distance of fifteen feet along the roof and then extended up the slope for ten to twelve feet, and although many would have called this a blowing out shot, Griffiths said it was just a feeder. ""A blower"", he said, ""would have caused an explosion."" 1There was no explosion. Griffiths reported gas and the area was cleared for three hours and then work resumed. When the shift changed at 3:00 p.m., the fireman reported all places clear of gas and the ventilation good.2The ventilation in Number One Mine was the best anyone had ever seen. The air in the mine was almost too cold. The current was so strong that it sometimes blew out the flame on the miners' fish oil lamps. It delivered five to six hundred cubic feet of air for every man and animal working in the mine. The law required only one hundred cubic feet 3The miners considered Number One to be relatively safe. The manager was proud of the mine and its up-to-date equipment"". Recently, there had been reports from France and America about the explosiveness of coal dust, but the manager did not think his mine was sufficiently dusty to be dangerous.5 The dust lay thick on the floor of the mine. Sometimes when a shot was fired the dust rose in great clouds. When a miner was shovelling it, the dust would billow up and be carried off by the current of air. The dust was also in the roof and in the stopings, put there intentionally to fill up the spaces and prevent the accumulation of methane gas."

Jan 1, 1992

By Albert G. Zima

THE conservation of strategic materials during war rime gives rise to many problems not commonly encountered in times of peace. During normal times, when world trade is unrestricted, we are apt to become lavish to a point of extravagance in our use of those materials which, during rime of war, become scarce owing to inadequate transportation and production facilities or because the enemy may be in position to control sources of supply. It becomes necessary, then, to enforce rationing of available sup-plies, and in some cases, where such supplies are wholly inadequate, we find we must resort to the use of substitute materials. We are now confronted with such a problem to an extent never before experienced, with the result that many of the commodities upon which our civilization depended are now either shut off completely or, because of the heavy demand occasioned by war production, are not available in sufficient quantities to meet requirements predicated on peace-time standards and manufacturing methods. It has become necessary, therefore, to make many changes, some of them very drastic indeed, to enable us to carry on our war effort effectively. This? discussion will deal briefly with one phase of this problem, namely, the conservation of alloys required in the making of steels necessary for war production. In line with a request from the War Production Board, the Technical Committee on Alloy Steels of the American Iron and Steel Institute made a study of experimental steels embodying the !east amount of alloying constituents, with the objective in mind of substituting these steels wherever possible for the standard alloy steels used heretofore. This study embraced the following phases: (1) The availability of silicon and manganese; (2) The average quantity of alloying elements recoverable from scrap; (3) The effect of increases in manganese and silicon contents on the general properties of steel; ( 4) The elements and ranges of elements which might be used to duplicate the hardenability of the steels now in use; (5) The effect of combining several elements in small quantities upon the properties of steel at various hardness and strength levels; (6) A determination as to whether or not the steels selected would suffice for general application. Working on this basis, the Committee arranged for the manufacture of several heats of steels containing various combinations of different amounts of such elements as silicon, manganese, chromium, nickel, and molybdenum. The steels thus produced were compared by hardenability tests.

Jan 1, 1943

By M. M. C. Lima, L. C. S. Solimani, M. A. Quintela

Galvanized steel scrap is recycled to B OF converters where zinc escapes from the bath and is captured by the gas control system, appearing in BOF sludge. As BOF sludge contain high iron content, it could be recycled, but due to its zinc content, it is disposed in landfills. In this study techniques were evaluated for zinc layer removal from scrap by sulfuric acid leaching. The effects of coating weight, temperature, time and sulfuric acid concentration were evaluated for three different galvanized scrap. The results showed that the behavior of each galvanized scrap was different. Nevertheless zinc removal efficiency was more than 80% with low dissolved iron in the leached solution.

Jan 1, 2011

By Unknown

With the present-day trend of rising labour costs and a lowering of production efficiency of workmen, it has become imperative that every effort be made to use manpower to the greatest advantage and to mechanize mining as much as possible. During the past few years this trend has gained much prominence in the Porcupine camp. In view of this, the executive of the Porcupine Branch considered that the Mechanical Movement of Muck would be a very timely subject for a Symposium. Accordingly a Committee was formed, with A. K. Douglass, Mine Superintendent for Delnite Mines, Ltd., as Chairman, and the Symposium was held in the Auditorium of the McIntyre Community Building, Schumacher, on March 25th last. Papers dealing with shovel loader and mechanical scraper operation at six of the larger mines of the camp were presented and discussed, and a tabulation was prepared giving data on the machines in operation at a total of eleven mines. The papers and tabulation, reproduced below, will doubtless be of considerable interest to operators of mines in all parts of Canada.

Jan 1, 1948

By W. J. Taylor, T. D. Parris

"Over 90,000 feet of raise have been bored at International Nickel underground mining operations throughout the Sudbury District since the advent of raise boring in the early part of July, 1964. With a total of 10 raise borers on hand at this time, techniques have improved steadily since introduction at INCO mines. The first unit, designed for use in rock of low compressive strength, had to be modified and redesigned to cope with Sudbury Area Precambrian rock. As equipment and boring techniques improved, a specially designed machine for larger holes was developed and is now in use. More powerful units, with a thrust capacity of up to 750,000 pounds, are under investigation. Raises have been bored up to 84-inch diameter, and the changeover to 5- and 6-foot flat reaming heads with improved cutter design has increased performance substantially. As a result, 5-foot-diameter raises have been completed to a length of 750 feet and 6- and 7-foot raises to over 500 feet. Reference is also made to the drilling of over 23,000 feet of drainage and sand-fill holes, ranging up to 7% inches in diameter, with smaller underground rotary drill equipment.Finally, a look into the future indicates the need for further improvements in equipment design to permit economic boring of 7- to 8-foot-diameter raises in Sudbury Area ground types."

Jan 1, 1972

By G. R. Cope, J. S. Getsinger, K. D. Lund, T. Neale

"Mineral exploration in the Sicker Group, a belt of Paleozoic volcano-sedimentary rocks on Vancouver Island, has traditionally centred on auriferous polymetallic volcanogenic massive sulphide deposits such as those currently mined by Westmin Resources Ltd. near Buttle Lake. Recently, however, the focus of exploration in the Sicker Group has shifted toward targets of structurally controlled gold concentrations, with notable success. Major north and northwesterly-trending structural features such as the Cowichan-Horne Lake break (one of several regional high-angle thrust fault s active throughout a long period of geological time) and related fault systems have contributed to localization of gold mineralization.Using the extensive information database compiled by MPH Consulting Limited during numerous exploration projects in the Sicker Group, two cross sections through areas with significant gold occurrences southeast of Port Alberni are presented. The cross sections combine geological, geochemical and geophysical data in an attempt to emphasize the relationship between structural trends and gold mineralization. Examples from specific properties, including gold discoveries along the Mineral Creek fault zone, are used to illustrate this relationship."

Jan 1, 1990

By G. Kolosay, J. Rajala, G. Deschênes, A. Romanov

ABSTRACT: The Kupol project, located in Far East Russia, treats a high-grade, free-milling ore containing 25.5 g/t Au, 298.3 g/t Ag, and 0.5% pyrite,with a P70of 53 microns. Most of the gold occurs as elec-trum and the silver is predominantly present in the forms of acanthite, stephanite, pyrargyrite, andproustite. The mill reached the design throughput of 3,000 tpd six months after start-up. AKnelson con-centratorrecovers10.4% gold and 0.5% silver. Leaching (14.5 hours pre-treatment and 116 hours cyanidation)of gravity tailings is performed with the CANMET Enhanced Leach Process (CELP),using only 490 ppm NaCN (cyanide consumption of 1.1 kg/t). The precious metals are recovered by counter-current decantation and the Merrill-Crowe process. Calcium hypochlorite destroyscyanide and thiocyanate. Overall, gold and silver recoveries for 2008 were 95.4% and 85.6%,respectively (2.8% and7.5% higher than targets). In the first eight months of 2009, gold and silver recoveries were 95.0% and82.6%, respectively. By August 2009, the mill processed 1.42 million tons of ore with production of 1.1 million ounces of gold and 11.3 million ounces of silver. CELP performance was not affected by changes in feed grade and ore mineralogy. Additional modifications to the leaching strategy allowed further reduction in cyanide consumption and effluent treatment costs.

Jan 1, 2011

By J. E. Hawley

"The zinc-lead deposit of the Lake Geneva Mining Company is on lot 7, con. VI, Hess township, Sudbury district, Ontario, about 10 miles northwest of the northern rim of the Sudbury Basin. Though a relatively small deposit, it shows some rather interesting relations to cross-cutting, pre-ore, quartz diabase dykes, which merit description.The deposit was discovered in October 1924 by J. H. Collins beneath iron-stained drift and oxidized sulphides. This proved to be the northwestern extremity of the orebody, the remainder of which extends southeast below swampy ground. Exploration began in 1927. In 1928 a vertical shaft was sunk to 250 feet and a level established at 235 feet. Later the shaft was deepened to 400 feet and new levels opened at 315 and 375 feet. In 1943 an inclined winze was sunk below the vein from the 315-foot level to a vertical depth of 640 feet, and two additional levels were opened at 525 and 615 feet respectively.The geology of the area has been described by T. T. Quirke (1), F. F. Osborne (2), F. J. Alcock (3), and Ralph Tuck (4). Private reports have also been made by Carl Tolman, J. E. Gill, and K. W. Fritzsche. Tuck's paper, covering the work completed to 1930, gives a detailed account of the character of the ore and enclosing rocks.Up to May 1944, when the property was closed, all ore above the 375-foot level and a small tonnage from below this elevation had been removed. Ore mined from 1941 to 1944 yielded the following:"

Jan 1, 1954

By V. G. Papangelakis, A. Dani

"Alkaline pressure oxidation, particularly in the presence of trona as additive, can be used to oxidize high carbonate refractory gold ores as it prevents the formation of CO2 in the autoclave. However, the presence of silica in the ore can lead to the encapsulation of pyrite due to the solubility of silica in alkaline solutions and its subsequent reprecipitation on the reacting pyrite surface, leading to the formation of a passive layer. This fundamental study investigates the chemical composition and thickness of the passive layer on a rotating pyrite disk using XPS and SEM, as a function of process conditions at 230°C, in an aqueous slurry containing silica sand, sodium carbonate and calcium carbonate under 100 psi of oxygen overpressure.INTRODUCTIONAlkaline pressure oxidation (POX) has been used successfully to treat high carbonate refractory gold ores, which contain carbonates in addition to sulphides, most notably at Mercur and Goldstrike mines operated by Barrick Gold. There are several advantages to using alkaline POX over its acid counterpart, especially due to high carbonate content. First, it eliminates the production of CO2 in the autoclave without resorting to pre-acidification, which allows for high oxygen utilization. Second, alkaline POX suppresses the formation of elemental sulphur and intermediate sulphur oxyanions (such as thiosulphates and dithionates), which reduce gold recovery. Third, the use of sodium hydroxide or salts prevents the formation of anhydrite scale by forming soluble sodium sulphate. Other advantages are the use of cheaper materials of construction and the formation of non-acidic residue that do not require further treatment prior to cyanidation (Thomas, 2005).Sodium carbonate in particular is a promising reagent for alkaline POX because it was shown to significantly accelerate the kinetics of pyrite oxidation by molecular oxygen, when compared to other reagents such as sodium hydroxide, sodium borate and calcium hydroxide. This has been attributed to the following factors: a) the faster oxidation kinetics of Fe2+-CO3 complexes compared to Fe2+ oxidation, b) the buffering effect of carbonate ions on the acidic pyrite surface, and c) the increased solubility of oxidizing Fe(III) species due to carbonate complexation (Caldeira, 2010)."

Jan 1, 2012

By E. Henderson

"This paper outlines the upgrading of a double-drum 2000 hp cage hoist to provide fully-automatic operation from shaft station control panels. The application utilizes programmable controller technology to provide all necessary functions for movement of personnel and material to 22 locations in a 4000 ft shaft.Various functions involving special design considerations such as ""chairing"", ""jogging"", and three modes of ""multi-level calling service"", are outlined. The use of higher level PLC functions to optimize memory utilization and simulate ""elevator service"" required the addition of a comprehensive fault finding software section to aid in troubleshooting.This paper will deal primarily with the automation portion of the project with references made to other pertinent aspects which were prerequisite to automatic operation. It is not intended to deal with every design detail, but rather to provide an overview of what can be done in the area of automation for those considering such an application. INTRODUCTIONEarly hoisting control systems provided only the essential elements of control, leaving many responsibilities with the operator. With advancements in various areas of technology, electromechanical devices were incorporated to enforce slow-down in end zones, control acceleration rates, monitor safety devices, etc. Brake control systems were supplied to allow for ""single-stick"" operator control, regulated deceleration during emergency brake applications, etc.These additions enhanced the over-all performance but were generally confined to speed and current regulation. Some mechanical devices, such as travelling nut limits, etc.; were used to provide ""position"" control to multiple locations within the shaft. These devices, in conjunction with rather extensive relay control panels, did allow for the establislunent of some automatic cage hoists . The hoists were often limited to service from point ""A"" to point ""B""', involving a limited number of levels due to the complexities of the mechanical interfaces employed. Only limited systematic work sequences were possible . .Programmable Logic Controllers (PLCs) were introduced into industry in the mid-70s and have since gained acceptance in mining applications such as pumping, ventilation, ore handling, etc. This technology, being ""software"" based, allows complexities to reside in the program rather than increasing the number of physical control elements. This has opened the door into hoisting systems for automatic loading and hoisting of ore as well as a means to achieve a comprehensive package of automated cage hoisting functions."

Jan 1, 1989

By G. F. Doggett

In describing accounting methods at Lake Shore Mines, it is the intention of the writer to limit the discussion to the principal features of the system used in securing cost figures and other statistics. The subject can be conveniently treated under the following divisions: (1) Time-keeping and Labour Distribution (2) Supplies: Handling and Distribution (3) Method of Assembling Data for Cost Purposes (4) Details of Operating Costs Time-Keeping and Labour Distribution After a new employee has gone through the routine of being 'hired on', he is assigned an employment number corresponding with the group applying to his occupation. This is for identification purposes in the plant and time office. He is also given an individual serial number, the use of which will be refer-red to later. On entering and leaving the plant, each employee passes through the clock room adjoining the time office, where he registers the time in and out on time recorders, on the clock card (Figure 1) bearing his name and number. It is the duty each morning of the time clerk to extend the hours worked by each employee, as indicated by the clock for the previous day, and at the end of the half-month period the total hours are multiplied by the rate and entered in the space provided for total wages at the bottom of the card.

Jan 1, 1935

By C. A. Sosa-Blanco

Minera Sabinas in central Mexico treats a complex sulfide ore containing galena, chalcopyrite, sphalerite and argentite as valuable minerals, and in some cases important amounts of non-magnetic pyrrhotite. For high pyrrhotite ores, results obtained by selective flotation showed good grades and recoveries in the lead-copper circuit, but a commercial zinc concentrate could not be produced due to the high floatability of pyrrhotite. When this is the case, an alternative method was proposed to produce a bulk concentrate by flotation which is then leached to recover copper and zinc from liquor in a SX-EW circuit. Leaching was conducted in an autoclave in order to study the effect of temperature and pressure, but bioleaching tests were also conducted. Leaching lead-silver residues were treated by cyanidation in order to recover silver values. The results obtained by selective flotation and by bulk flotation with leaching of the bulk concentrate showed that the latter alternative increased zinc recovery by 30 % with similar recoveries of the other metals.

Jan 1, 2007