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By J. G. A. Stevenson

GENERAL Location of Property THE Stirling zinc-lead-copper deposit is in Richmond county, Cape Breton, about a quarter of a mile southwest from Stirling P.O., and some 45 miles southwest from Sydney. The property is accessible by road for at least nine months of the year, and during the navigation period coastal boats maintain a service touching at the port of Fourchu, eleven miles from the mine. When flying conditions permit, the Cape Breton Flying Club, of Sydney, will carry passengers to or from the property, a service which has been particularly advantageous on two occasions when hospitalization was urgently required. The Company has mining rights on leases Nos. 73-74, 78-80, and 101-104, inclusive, and owns 166 acres at Stirling and one acre at Fourchu. The ore deposit is in lease No. 73. History The Stirling deposit was discovered in the 'nineties', probably about 1895. The original discovery is said to have been made in the bed of Copper creek, which traverses the ore-zone. For a number of years, indifferent development work was carried on with a view to copper production only, and it was not until1915-16 that attention was directed to the possible production of zinc. Previously, the ore had been considered too complex for metallurgical treatment. During the period 1916-24 several operators attempted to develop the property, among them being the Stirling Exploration Company, Stirling Mining & Smelting Company, New Jersey Zinc Company of New York, Hayden & Stone Company of Boston, and The Eastern Mining & Milling Company. Up to 1924, the work was limited mainly to trenching, stripping, ? diamond drilling, and shot drilling.

Jan 1, 1937

By Gyeonghye Moon, Inhyeok Choi, Jyothi Rajesh Kumar, Jin-Young Lee

"This paper deals with the recovery of the tungsten and vanadium from spent SCR catalyst leach liquors by different hydrometallurgical methods. The first part consists of pressure leaching of spent SCR catalyst using caustic soda followed by metal recovery by liquid-liquid extraction. In a leaching process, the following experimental parameters were tested and optimized: NaOH, particle size of feedstock, temperature, and solid to liquid ratio. The optimum condition for leaching of tungsten and vanadium was under the following conditions: NaOH 3 mol/L, temperature 250°C, particle size <300 µm, and solid to liquid ratio 0.4. From these optimum conditions in this experiment, the dissolution efficiency of vanadium and tungsten was 91.5and 87%, respectively. Liquid-liquid extraction following commercial extractants were tested: TBP, Cyanex 272, D2EHPA, Aliquat 336, Primeme JM-T, Alamine 308, Alamine 304-1, and methyl-tri-octyl-ammonium chloride. The conditions for both valuable metal recoveries were optimized.INTRODUCTIONSelective Catalytic Reduction (SCR) catalyst has become the most effective to reduce nitrogen oxide (NOx) emissions from stationary segments such as power plants and waste incinerations around the world due to the reinforcing regulatory trend and emerging environmental issues (Forzatti, 2001; Spivey, 2002; Li et al., 2011).Currently, the most widely used SCR catalyst is V2O5-WO3/TiO2 system due to its great catalytic properties (Li et al., 2011; Marshneva et al., 1995; Marbergeret al., 2015). In general, the composition of the SCR catalyst used in the stationary application is 0.5 to 1 wt% of V2O5and 7 to 10 wt% of WO3(Marberger et al., 2015; Chen &Yang, 1992, Vuurman et al., 1991; Alemany et al., 1991). Currently spent SCR catalysts are treated as waste and disposed of in landfills. This causes a lot of waste of secondary resources of vanadium and tungsten. In terms of industrial value of vanadium and tungsten (Gupta &Mukherjee, 1990; Moskalyk &Alfantazi, 2003) and reduction of pollutant emissions, it should not be disregarded for their recovery for their material recycling from spent SCR catalyst. However, investigations for recovery of metal values from spent SCR catalyst has been rarely carried out."

Jan 1, 2017

By Royston Colbourne

Objectives Of Presentation - Identify specific risks - A fresh look at risk - Provide a moment reflection on risk - Open discussion on risk A route to solution and advanced thinking.

May 1, 2010

By Julio E. Claudeville

Approaches and Lessons Learned ??Address business needs?local skills training and employment ?local procurement programs ?health and safety programs ??Ensure consultants/ advisors/ contractors apply Company standards ?especially in the field/ locally ?will not be differentiated from the Company itself

May 1, 2006

The problem of thin and very thin coal seam extraction in a long perspective of Ukraine?s fuel and energy industry development was determined. Technical and economic benefits of coal seams selective mining technique including beneficial environmental impact were substantiated. The scientific and practical aspects of development of borehole underground coal gasification (BUCG) technology are considered. The technological scheme of underground gas generators is offered on the basis of the authors? criteria of fitness and adaptability to the mine and geological conditions. These charts foresee the preparation of gas generators from earth surface and directly from the present mine working by inclined horizontal boreholes. Basic research is directed at abandoned supplies extraction in coal mines. Concepts of technological decisions and technical implementation of the underground part of the gasification system are worked out with analytical models, with subsequent test verification on special options and a mine experimental gas generator. Forming the technological scheme of gasification is founded on the basis of tying up spatial and sentinel factosr of coal seam gasification taking into account sufficient impermeability of the system a «gas generator ? rock massif» and to dirigibility by thermochemical processes that flow in a rock massif. The offered solutions contain the possibility of creation of the power and chemical enterprises of gasification, taking into account the complex use of BUCG products in the ecologically reserved technological cycle. Gas generator efficiency is evaluated from an economic standpoint.

Aug 1, 2013

By P. R. Warner

This paper reviews the development of certain aspects of the electrical specifications of Anglo American?s suite of specifications for gearless mill drives (?GMDs?). These specifications are based on experiences in both Anglo American?s and others? operations, benchmarking against large hydro generators, the advice of industry and university experts, and continuous close co-operation with OEMs. To achieve a step change in availability additional final testing and electrical protection have been implemented, insulation requirements have been specified for machines to be operated at high altitude and clean area and access control systems have been developed.

Jan 1, 2012

By D. G. Almond

Nkomati Nickel Mine in South Africa processes one of the world?s hardest ores in a 375k TPM autogenous grinding circuit. The plant employs an unconventional processing circuit, comprising a primary autogenous mill (AG or FAG) and pebble crushing circuit followed by a secondary hybrid pebble/ball mill and classification cyclone cluster. Advanced Process Control (APC) or Expert Control is now generally accepted as an advantage in most modern high capacity concentrator grinding circuits. This paper reviews the installation of model predictive control at Nkomati and examines the results and benefits of installation in an autogenous mill during plant ramp-up. The paper also demonstrates how predefining process control objectives together with good plant and supplier cooperation can achieve a robust and reliable APC implementation on a very short site program. The results conclusively demonstrate operational and economic benefits during circuit operation with the advanced process control system ON. Production performance and circuit stability were significantly better than during manual control.

Jan 1, 2012

By F. Habashi

"A short account will be presented on the extraction of rare earths from monazite sand, bastnasite ore, and phosphate rock of igneous origin. This includes mineral beneficiation, leaching methods, fractional crystallization [of historical interest], ion exchange, solvent extraction, precipitation from solution, and reduction to metals. INTRODUCTIONOriginally, the term rare earths was only used for the oxides, R2O3, which are similar to one other in their chemical and physical properties and are therefore difficult to separate. Within the rare earth group, the elements scandium, yttrium, and lanthanum differ in their atomic structure from the elements cerium to lutetium (the lanthanides, Ln). Scandium occupies a special position with respect to this classification and its other properties, and therefore does not belong to either of these groups. The rare earth elements always occur in nature in association with each other. The isolation of groups of rare earth elements or of individual elements requires costly separation and fractionation processes owing to the great similarity of the chemical and physical properties of their compounds, which explains why the history of their discovery has extended over such a long period.The word “rare”, when used to describe this group of elements, originates from the fact it was thought that these elements could only be isolated from very rare minerals. Considering their abundance in the Earth’s crust, the term rare is now inappropriate. These elements are lithophilic and are therefore concentrated in oxidic compounds such as carbonates, silicates, titano-tantalo-niobates, and phosphates.The abundance of the rare earth elements taken together is quite considerable. Cerium, the most common rare earth, is more abundant than cobalt. Yttrium is more abundant than lead, whereas Lu and Tm are as abundant as Sb, Hg, Bi, and Ag. For all practical purposes promethium does not occur in nature. It forms only in nuclear reactors."

Jan 1, 2012

By M. Alvarez-Silva, A. Uribe-Salas, J. A. Finch, M. Mimezami

The point of zero charge (PZC) of electrokinetically anisotropic minerals (chlorite and serpentine) was determined using the Mular-Roberts (M-R) titration technique, and compared to isoelectric point (IEP) obtained from electrophoretic mobility measurements. To validate the M-R technique, the point of zero charge and isoelectric point of two isotropic minerals (alumina and silica) were shown to be comparable. For serpentine and chlorite, respectively the PZC was found at pH 4.3 and 4.6, while the IEP occurred at pH 3.2 and <3. Settling tests showed that the maximum settling rate, which corresponds to aggregated particles, for chlorite was around pH 3, i.e., close to the IEP; lizardite did not show a conclusive maximum.

Jan 1, 2009

By A. H. Anderson

THE travelling grate coking process was developed by Shawinigan Chemicals, Limited, at their Shawinigan Falls plant. The first production unit went into operation a month prior to the outbreak of the war. Since then a substantial part of the coke used in the manufacture of calcium carbide has been produced by this process. In the following will be given a short account of the development work, a description of the process and the equipment, a discussion of the properties of the coke, the economics of the process and its future possibilities. EXPERIMENTAL WORK The carbide industry is a large consumer of coke, one ton of commercial carbide requiring for its production 1,200 lb. This coke must meet certain specifications in order to be acceptable. It should have a low ash content, preferably below 8 per cent, and the sulphur and phosphorus content must not be above specified limits. The size of the coke is also important. If it is too large it has to be crushed before it can be used in the furnaces, and if it is too fine it may have to be screened and briquetted. In addition, it must be dry. Although it was generally possible to purchase coke, including petroleum coke, and coke fines, in the quantities required, it became increasingly more difficult as time went on to obtain coke of a suitable quality at an attractive price. It was therefore natural for us to look to coal carbonization as a means of basing the supply of the fundamental raw material for carbide manufacture on something more solid than the shifting conditions of the coke market.

Jan 1, 1944

By E. B. Wright

THE property of Falconbridge Nickel Mines, Limited, is in Falconbridge township, approximately thirteen miles northwest of Sudbury. From the mine and townsite, a gravel road leads to Sudbury and a branch line of the Canadian National railway to Sudbury Junction. The ore deposit is at the southeastern corner of the &apos;Sudbury Basin&apos;. It lies in a sheet-like mass, striking in an east-west direction, between norite to the north and greenstone to the south. The general attitude of the ore-body is vertical, but with frequent variations in dip of as much as 10° to the north or south. The deposit is very irregular in outline, the width varying from a few feet to eighty or ninety feet. In the vertical plane, rolls are frequently encountered. Gouge is very often present at one or both ore contacts. The norite to the north shows much jointing. The chief ore minerals are pyrrhotite, pentlandite, and chalcopyrite. The nickel content of the ore is usually double the copper content, average assays ranging from 2 to 2.5 per cent nickel and 1 to 1.5 per cent copper. The ore is of three main types: massive, breccia, and disseminated. The breccia ore, the most common type, consists of sulphides containing rounded inclusions of highly-altered country rock, which, in places, are so large that sorting is necessary in the stopes. In the norite, the breccia ore may grade into disseminated sulphides, which frequently are sufficiently concentrated for profitable mining. In places in the breccia ore, concentrations of solid sulphide masses occur. Until early in 1935, all mining at Falconbridge was by shrinkage scoping, but this method was found to be less and less suitable as greater depth was attained. When mining had reached the 1,000-foot level, ore drawn from large shrinkage stopes was found to have been diluted as much as fifty per cent by sloughing of the wall-rocks, caused by increased rock pressure and insufficient support. It was apparent that this method of stoping was un-suitable and -Mr. E. J. Martin was engaged to superintend the introduction of a method of cut-and-fill stoping.

Jan 1, 1938

By L. C. So, S. Faucher, S. Mostaghel, D. Sauter, S. -Y. Oh, S. K. Lee

"Molten material from pyrometallurgical furnaces is tapped at high temperature, carrying a large amount of heat. Traditional handling methods of slow air cooling or water granulation do not allow for the recovery of heat from slag and matte. Furthermore, water granulation adds an inherent safety risk of explosions. Recently, there have been numerous studies into processes attempting to recover waste heat. However, most of them have never been commercialized due to numerous challenges including scalability, cost, low heat recovery efficiencies, and difficulties in heat utilization. Ecomaister-Hatch has recently developed and commercialized a reliable and simple dry atomization system that allows for heat recovery while eliminating the use of water. Comparisons of pilot and commercialized dry atomization and heat recovery technologies will be presented and challenges of these technologies will be highlighted.INTRODUCTION Slag has traditionally been regarded as an undesired waste product from smelting operations with slag management focused on removal and disposal of “waste”. Over 500 million tonnes of slag are produced per year, carrying with it ~220 TWh of energy (Barati, Esfahani, & Utigard, 2011). Depending on the process, the energy content of slag ranges from 10-90% of the total energy input (Barati, 2011, Rodd, 2010). There has therefore been great interest in recovering energy from slag. Slag handling methods can broadly be classified into three categories: (1) dumping and slow cooling, (2) wet granulation and (3) dry granulation. As discussed below, only dry granulation routes are amenable to heat recovery. Slag dumping involves the slow cooling of molten material and crushing of the resulting solid. In this process, slag is dumped on the ground directly from furnaces or transferred to slag pots that are moved by rail or haulers and then dumped on the ground. The molten material is left to cool and solidify until it can be broken and handled by heavy machinery."

Jan 1, 2017

By Peter A. Cain, John C. Folinsbee

"A 4-ft.-diameter shaft has been drilled to a depth of 2,790 ft. in strong, hard, basic Precambrian rocks at Lynn Lake Manitoba. This was done on the property of Sherritt Gordon Mines Limited for the purpose of ventilating and developing the ""N"" orebody, which is located approximately 4,000 ft. south of the Farley shaft.The drilling was done under contract by two drilling companies. Peter Bawden Drilling (1964) Limited drilled the initial 12:1,4-in. pilot hole to a depth of 3,000 ft. Shaft Drillers Limited of Canada then reamed the hole to 4 ft. in diameter to a depth of 2,790 ft. At this point, the reaming was stopped because of the difficulty in passing a change in direction in the line of the pilot hole. The hole was completed by driving a raise 200 ft. from the 3000 level to the bottom of the 4-ft. hole using an Alimak raise climber.Cuttings from the reaming operation were directed into the 12:1,4-in. pilot hole, where they fell to the 3000 level and were removed by a mucking machine and standard mine development cars.The elapsed time from the start of the pilot hole to the completion of the reaming operation was ten months, with an average advance of 279ft. per month. There was a two-month delay between the completion of the pilot hole and the start of the reaming operation.The 12:1,4-in. hole was drilled in an elapsed time of 45 days from the time of setting up the rig. The average advance per day was 66.8 ft.The reaming operation was done in an elapsed time of 194 days. A one-month delay required to repair damaged equipment left 163 days for the drilling and setting-up operation, for an advance per day of 17.1 ft."

Jan 1, 1966

By Neil Schofield

"The Pine Creek gold mineralization is associated with saddle reefs and quartz and quartz sulphide veining within the Enterprise Anticline. The anticlinal structure is complex and the mineralization was considered prior to development to be dominantly strata controlled. Gold grades vary up to 160 gin 1.5 m core samples with coefficients of variation in excess of three.The estimation of ore reserves for such a deposit must account for both the geological complexity and the extreme variability of gold grade.This paper describes the structural and variogram analysis of the gold grades and demonstrates the importance of incorporating the geological model in such an analysis. Variogram interpretation is greatly improved and greater insights into the finer geological structure areprovided. Part 2ofthis work presents the application of multigaussian kriging to reserve estimation for deposits with highly variable grade and which consequently demand highly selective mining operations. IntroductionThe Enterprise Gold Mine is situated some 220 km southeast of Darwin in Australia&apos;s tropical north. Gold is believed to have been discovered there in 1869 during the construction of the overland telegraph line.From 1894to 1915, some 75 000 ounces of gold were produced from 121 000 tonnes mined mainly by Chinese leaseholders. From 1906 to 1915, government-sponsored drilling led to the sinking of the Enterprise Shaft to 79 m and several drives were developed. Mining ceased because of war.Since late 1980, Goldfields Exploration Pty. Ltd. had explored on several mining tenements near Pine Creek under joint venture with the title holders, Enterprise Mines NL. This work culminated in the development of the current mine which opened on October 29, 1985.Feasibility studies to determine the economic viability of mining were based on ore reserves generated by project geologists using a sectional polygonal approach tuned to the interpreted geological control of the mineralization.The study motivating this two-part paper covers are-estimation of the recoverable reserve s using the geostatistical approach of multigaussian kriging developed at Stanford University, (Verly, 1984)."

Jan 1, 1988

By Hongpu Kang

The fully mechanized top coal caving mining method has been the main mining approach for thick coal seams with high output and efficiency in Chinese coal mines. The gateroads for the top coal caving mining faces should be driven along the floor of the thick coal seam with a part of the seam as roof. The support of the gateroads is commonly difficult because of the low strength and broken structures of the coal seams, and the increasingly large section of gateroads meeting the need of greater and greater face coal output. Based on the analyses on the geomechanics properties and production conditions of the top coal caving mining, the influences of the top coal caving mining parameters on the stability of gateroads, including mining thickness and face length, are studied. The deformation and damage features of the rock mass surrounding the gateroads with the top coal seam as roof are investigated, the interaction of the support with the surrounding rock mass, the support theory are studied. The bolting design method and criteria, bolting forms and parameters for the gateroads with the top coal as roof are put forward. The rock bolting components, including bolt bars, face plates, cable tendons, meshes, and steel straps, are introduced. Finally, the gateroad bolting effects are evaluated through a typical case study on the basis of field monitoring data, such as the displacement of surrounding rock mass and the forces along bolts and cables.

Aug 1, 2013

By G. F. MacDonnell

THE Privateer mine consists of a group of mineral claims situated in the Zeballos area, on the west coast of Vancouver island, approximately 180 miles north of Victoria. Although Zeballos is a comparatively new mining camp, its transportation facilities can be considered exceptionally good. General freight and supplies are brought in by either C.P.R. or Frank Waterhouse steamers from either Victoria or Vancouver. Service by these boats varies from five to ten days and the trip from Victoria takes approximately two days. Passengers may use the C.P.R. boats, or, if speed is essential, they may fly, in which case they have the choice of two flying companies, namely, Canadian Air-ways, Limited, and Ginger Coote Airways. The average flight from Vancouver takes approximately two hours. Excellent unloading facilities are provided at the beach by a government dock for the steamers and a floating dock for aeroplanes. The mine, which is approximately five miles from the beach, is serviced by a fairly good gravel road, which has proved satisfactory for all haulage purposes. Zeballos has the reputation of having one of the heaviest rainfalls on the west coast, but as no accurate records have been kept, no comparisons can be made. H. C. Gunning, in his report, comments on the weather from 1929 to 1932, and one would judge that the practically continuous rainfall did not add to the pleasures of the field work. During the summer of 1938, the opposite condition prevailed and the area had exceptionally dry and pleasant weather. The snowfall is generally light at the lower elevations, but very heavy higher up. No extreme cold weather is encountered during the winter, which is generally short.

Jan 1, 1939

By V. C. Wansbrough

First, permit me to say with what very great pleasure we find ourselves assembled in this most ancient and honourable city of Quebec. It is a city which we deeply respect as the fountain-head of the culture of French-speaking fellow citizens, and the seat of government of a province which is steadily recording new achievements in Canadian mining. Such achievements prove what can be accomplished when enlightened and progressive government policy, technical and scientific competence, and private initiative pull forward together in harmonious rhythm. It is a most happy and auspicious event also that the guiding control of the affairs of the Institute and of the fine traditions of provincial administration have for the past year been united in the person of our honoured President, Dr. A. O. Dufresne. This year, again, we have bad prepared for us by our hosts a splendid programme of technical sessions and social entertainment. Each year we pay an unspoken compliment to the Institute, expecting as a matter of course nothing but the highest standards in both these spheres. In its annua1, semi-annual, and regional meetings, in the constant activity of its local Branches, the Institute continues with marked success to perform its great dual service, social and educational. We are all its beneficiaries to the extent to which we choose to profit by participation in its affairs. But, one imagines, to none are the advantages of Institute membership more valuable than to young men embarking on their professional careers.

Jan 1, 1951

By M. B. B. Research Council of Alberta Crockford

Introduction Kootenay strata of Lower Cretaceous age contain much of the highest rank coal produced in Alberta. These strata outcrop in the foothills and mountains of southwestern Alberta and southeastern British Columbia, and the economic value of the coal seams contained in them was evident to the earliest explorers, who refer co them in their journals. Lacer, investigation of the .coal measures was undertaken by prospectors and by a succession of geologists, most of whom were in the employ of the Federal government, but some acted for private interests. Surveys by these men proved chat foothills and mountain regions hold immense quantities of high-grade coal within easy reach of transportation facilities, and their conclusions have accelerated the development of the coal-mining industry m Alberta. Among geologists who have contributed much to our knowledge of the region are J. M. Dawson, G. M. Dawson, R. C. McConnell, D. B. Dowling, J. D. Mackenzie, B. Rose, J. R. Marshall, B. Rose, J. R. Marshall, B. R. McKay, J. A. Allan, and J. L. Carr. The present paper is to a great extent a compilation of the work of the above men and of several others who have investigated the area lying between Bow river and Crowsnest pass. Space does not permit a list of all the sources of information so chat only chose of prime importance are given in the text. Data for the map and ?cross-sections of Figure 1 were taken from the following published maps of the Geological Survey of Canada: Cascade Coal Basin, Pub. 933; Canmore, Maps 322 and 323; Upper Elk River and Upper Highwood Rivers, Pub. l980; Blairmore, Pub. 1584; Southfork Coal Area Map l03A; and of the Research Council of Alberta: Highwood-Elbow Area, Map 20; and Ribbon Creek Area, Map 21. In some cases, the cross-sections have been simplified or otherwise altered, and for these revisions the writer cakes full responsibility. The stratigraphic sections of Figure 2 have been taken from published reports of the above mentioned organizations. The area covered in this paper is shown in Figure l. It is wholly within Alberta, and reaches from township 5 to township 27 and from range 1 co range 11, west of the fifth meridian. Its location is about fifty miles west of both Calgary and Lethbridge. Topography of the area ranges from foothill on the east to mountainous on the west. In this paper&apos; the foothill region is considered to be chat which lies immediately east of the most easterly mountain ranges, such as Livingstone and Highwood. There are two principal coal mining districts in the area, one served by the main line of the Canadian ?Pacific railway and centring about Canmore, the other by a branch line of che same railway and centring about Bellevue, Blairmore, and Coleman.

Jan 1, 1949

By G. Clarkson, M. Hitch, R. Clarkson

"A novel reagent-free method of extracting gold from gravity middling concentrates in the Yukon placer fields is presented in this paper. This method exploits the malleability of gold by submitting concentrates to grinding in a rod mill. Brittle waste minerals are effectively reduced, whereas malleable gold particles are flattened and are then extracted by classification through sieves. Recoveries in the field using a laboratory-sized rod mill regularly exceeded 90%, whereas correlation laboratory tests indicated recovery to be most sensitive to the mill charge size. This method has broad potential, including application to the gravity circuits of large hard-rock processing circuits.RÉSUMÉ Cet article présente une nouvelle méthode sans agents réactifs d’extraction de l’or dans les concentrés gravimétriques mixtes que l’on trouve dans les districts placériens du Yukon. Cette méthode exploite la malléabilité de l’or en broyant des concentrés dans un broyeur à barres. Les déchets miniers cassants sont bien réduits, alors que les particules d’or malléables sont écrasées puis extraites par classification au travers de cribles. Si les récupérations sur le site à l’aide d’un broyeur à barres de laboratoire excèdent 90 %, les essais de concordance en laboratoire indiquent que la récupération est très sensible à la taille de la charge du broyeur. Cette méthode présente un grand potentiel, notamment une application possible aux circuits gravimétriques des grands circuits de traitement des roches dures.INTRODUCTIONExploiting the high density of gold to separate it from waste materials is the oldest known mineral processing technique. This basic technique is still widely used in gravity concentration circuits today; however, gravity processing invariably results in high-value middlings, especially in the Yukon placer gold fields. In addition to having a uniquely high density, gold is also the most malleable metal. This unique malleability can be exploited to extract gold from otherwise inaccessible gravity middlings.The Yukon placer gold industry has been continuously ongoing since the 1860s, and today produces approximately 60,000 oz t (1.87 million grams) of crude gold annually, most of which is from the Klondike region near Dawson City (Van Loon & Bond, 2014). It is important to note that Yukon placer miners do not use any chemical extraction methods; rather, gravity upgrading methods are the sole processing techniques used. Placer deposits are typically coarse, well liberated, and naturally gravity concentrated and recoverable, thus making more expensive chemical extraction unnecessary (Mitchell, Evans, & Styles, 1997). Furthermore, a strict permitting regime, environmental concerns, lack of expertise, and fear of repercussions from regulators prevent miners from attempting more advanced processing methods, such as flotation or cyanidation. Even simple chemical extractions like mercury amalgamation have not been implemented for decades, with one observer noting that, as many as 30 years ago, “the art of mercury for amalgamating appear[ed] to be dying [in the Yukon]” (Osler, 1983)."

Jan 1, 2017

By Davood Moradkhani, Maryam Rasouli

"The present study reports solvent extraction and separation of zinc from concentrated nickel sulfate solution. In our previous study, Zn and Cd in cold filter cake (CFC, 45-55% Zn, 11-16% Cd, and 2.5-4% Ni) were extracted by alkaline leaching followed by electrowinning processes respectively. The strip solution from electrowinning process, was a pregnant liquor solution (PLS) containing 16.8 g/l Ni and 4.2 g/l Zn. In this work, PLS is subjected to the solvent extraction process for separation of traces of Zn from high grade nickel. The zinc free raffinate containing 16.6 g/l Ni sulfate solution will flow to nickel electrowinning plant for cathode production. Di-(2-ethylhexyl) phosphoric acid (D2EHPA) is the organic phase used in this study. The effects of various parameters such as organic phase concentration (10- 40 % v/v), pH (1.5-3), and temperature (25 and 45°) are investigated. Zinc over nickel separation factor increases by increasing pH from1.5 to 3. The results show that 98.7% of Zn was loaded at25°C O/A ratio of 1, pH 3, and 10% vol. D2EHPA. A 10 M NaOH is used for pH control. However, replacement of pH controlling agent with ammonia solution (25%. v/v) results in interesting observations. Ammonia addition, reduces the solubility of Ni2+ cations in solution. Nickel starts to precipitate from raffinate in a crystalline bluish-green form. The obtained crystals are characterized by XRF and identified to be nickel-bearing analog of boussingaultite, a rare sulfate mineral of nickel with chemical formula of Ni (NH4)2(SO4)2.6H2O. The crystallization rate of crystals is studied. It is a slow precipitation process with 75% in 4 days.INTRODUCTION Annually, many hydrometallurgical processes such as electrowinning, solvent extraction and leaching are applied to waste filter cakes in Zanjan, Iran. These additional processes on filter cakes are critical from both environmental and economic points of view. CFC (cold filter cake) is a toxic but valuable filter cake (45-55% Zn, 11-16% Cd, 2.5-4% Ni, and 0.2-1.5% Cu) produced in many zinc production plants. Our research group at Research and Engineering Company for Non-ferrous Metals (ReCo.), developed a series of hydrometallurgical methods for extraction of zinc, cadmium and nickel from CFC (Moradkhani, & Rasouli 2012). The recovery of zinc and cadmium with alkaline leaching and electrowinning was successfully studied. The strip sulfate solution from cadmium electrowinning unit, contains high concentration of nickel with some traces of zinc impurity. This pregnant liquor solution (PLS) was analyzed and reported to contain 16.8 g/l Ni and 4.2 g/l Zn. In this work, PLS is subjected to the solvent extraction process to separate Zn from nickel (Fig. 1). The organic phase stripping solution containing 4.2 g/l zinc and 200 ppm nickel can be circulated and used in the acidic leaching step. This generates nickel solution with high purity suitable for nickel cathode production."

Jan 1, 2017