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By Dawei Yu, Kinnor Chattopadhyay

In the nickel industry, molten slags produced from a Pierce-Smith converter contain significant amounts of valuable metals in the forms of oxides and physically entrained matte droplets. A slag cleaning step, which takes places in an electrical slag-cleaning furnace, is therefore required to recover the valuable metals as a common practice. Utilization of a waste material from aluminum industry (i.e. spent potlining) as a flux to improve the slag cleaning in terms of both the metal recovery and the operation efficiency was studied by simulation with FactSage program. Results show that the addition of SPL could substantially reduce the slag viscosity due to its fluoride values, thus accelerating the settling of matte droplets. The carbon value in the SPL could also help increase the metal recovery by reducing the valuable metal oxides followed by settling.

Jan 1, 2015

By W. Tse, D. Wong

Dense medium separation (DMS) is one of several preconcentration methods used for early waste rejection from run of mine ores at relatively coarse particle sizes prior to additional milling and beneficiation. DMS has been used extensively in the coal, diamond and iron ore industries but lab scale and pilot test work has demonstrated successful separation and upgrading of other minerals such as lead, zinc, copper and lithium based ores using DMS. This paper reviews historical dense media systems, results from the pilot scale Condor DMS system as well as associated laboratory heavy liquid separation (HLS) test work.

Jan 1, 2014

By Thomas Clark

This report presents a review of the distribution and exploration potential of platinum-group elements (PGE) in Québec; it is based on published and unpublished analytical data. This qualitative evaluation of the PGE potential, whether in PGE-dominant deposits or in Ni-Cu-dominant deposits with co-product PGE, is based on interelement ratios such as Ni/Pd, Cu/Ir, Cu/Pt, and Cu/Pd. Good PGE targets, i.e., deposits associated with magmas fertile in PGE, are identified. Less favorable PGE targets, i.e., deposits associated with PGE-depleted magmas, are also mentioned. The importance of exploring for deposits similar to those at lac des Îles and East Bull Lake (Ontario) is emphasized.

May 1, 2001

By C. G. Anderson

Industrially proven and applied nitrogen species catalyzed (i.e. NSC) acidic pressure leaching has been utilized to treat a number of ores, concentrates and recycled materials. This versatile technology offers many advantages including low temperatures, low pressures, low capital costs, low operating costs, faster throughput and less costly materials of construction than conventional pressure oxidation. This paper will elucidate the application of this technology for production of gold, silver, palladium, rhodium, zinc, germanium, gallium, cobalt, copper and nickel. Recycled material applications will also be elucidated. In addition, details of an application for treatment of a refractory chalcopyrite copper and gold bearing ore will be presented and pertinent economics discussed.

Jan 1, 2004

By P. Kawulka

An integrated pilot plant for the development of the S-C Copper Process was constructed at Fort Saskatchewan in 1975 and operated in 1976. The pilot plant was designed to treat 9 tonnes per day of a pyritic copper concentrate. A demonstration run conducted during the last quarter of 1976 averaged 90% on-stream time, and confirmed that the process is operable as a stable and integrated unit. The paper describes the parameters and equipment developed for thermal activation of chalcopyrite copper concentrates to make them amenable for the dissolution of iron and zinc, and their subsequent separation and recovery. The resulting high-grade copper sulphide was leached with return electrolyte and oxygen to extract 98.5% of the copper into solution. The copper was electrowon at 650 amps per square metre from purified solution, to produce cathodes analyzing 0.1 ppm Se, 0.1 ppm Bi, 4 ppm Pb and 10 ppm S. The electrical conductivity was >101% lACS and the spring elongation value [ ]350 mm. Elemental sulphur and gangue are removed from leach residues to make a concentrate containing over 95% of the silver and gold and most of the unleached copper. Conventional construction materials such as stainless steel, titanium, Hastelloy, acid brick, rubber and plastics performed well. The containment inherent in hydrometallurgy provided high standards of hygiene and safety.

Jan 1, 1978

By G. S. Hume

In the transformation of carbonaceous materials, such as peat, to coals of various grades, the changes are known to be both physical and chemical and the grade of coal finally produced depends on the stage to which alteration proceeded. Those changes, which are frequently spoken of as the results of metamorphism, are due to pressure with accompanying heat and, according to the amount of metamorphism to which the sediments with the included carbonaceous beds have been subjected, there is a gradation from peat to anthracite coal, and even to graphite. The improvement in the quality of the coal as a result of metamorphism is due to an increase of the carbon content of the coal and a corresponding loss of the volatile materials. This rise in the quality of the coal according to the degree of metamorphism is well illustrated by the coals of western Canada. In the Plains area, where the deformation and the attendant metamorphism of the sediments is comparatively small, the coals are lignites, whereas in the mountains, where deformation has been severe, the coals are semi-anthracites. Sub-bituminous and bituminous coals occur in the intervening areas. The same general relationship between the quality of the coal and the degree of metamorphism holds true for the Appalachian basin of the United States, where there is a progressive improvement in the quality of the coals from west to east, that is, from an area of comparatively slight metamorphism to an area of marked deformation in the Appalachian Mountain region. But while it is true that this relationship holds in a general way, it has been found that the improvement in the quality of the coal is not always uniformly progressive, and there may be local variations such that an area containing coal with a carbon content indicating low or medium metamorphism may be surrounded by areas in which the coals are of higher grade. These local variations in many cases can be explained, and they in no way detract from the general rule that, in a region exhibiting a progressive betterment in the quality of the coal from an area of low metamorphism to one of more marked deformation, the quality of the coal, i.e., the amount of fixed carbon in the coal, may be taken as an index of the degree of metamorphism of the coal as well as of the sediments in which it occurs, It has been pointed out (') that certain coals, such as cannels, are unreliable indicators of the varying degree of metamorphism because of the nature of the material from which such coal was derived. Such coals, however, are not known in western Canada and their behaviour need not here be discussed.

Jan 1, 1927

By R. F. Favreau, L. C. Lang

"In modern blasting technology blasts are designed and analysed on an energy-mass-time relationship. The energy of the explosive is derived by computer analysis and the work potential of the available energy is expressed in numerical values. The mass involved in the blast is determined by the geometry of the blast and by the rock density. Time is also a relevant parameter, because time is required to complete the three basic stages of the breakage process.For successful application of the blasting parameters the basic mechanism of the breakage process must be understood.The physical-mechanical properties of the rock, local structural geology and the thermodynamic properties of the explosives can be brought together to create a computer model of a blast with which it is possible to predict separately the results of each parameter and to express the predicted degree of change in any parameter by actual numbers.A long-range project has started to create a ""bank"" of rock properties for as many Canadian and foreign mines as possible. A computer model has been successfully applied to predicting the effect of varying the ratio of spacing to burden at constant rock volume and significantly improved results are achieved, as the S/B ratio is increased up to about 2 to 2.5.High-speed photography has been applied to determine the time that has elapsed between zero time and the beginning of movement of the mass. The results assist in determining minimum and optimum delay time required for multiple-row blasting.The approach as described in the paper is now well proven and is clearly superior to previous methods based on powder factors and human assessment."

Jan 1, 1972

By Dalton. J. L., H. P. Dibbs

An account is given of investigations into the application of two neutron methods to the on-line analysis of slurries. One deals with the application of the neutron moisture gauge principle to the determination of the water content of iron oxide slurries, and the other with the application of gamma radiation from thermal-neutron-capture to the determination of the composition of aqueous slurries of iron oxide, copper oxide, zinc oxide and sulphur. Linear relationships were found between the composition of the slurry and the neutron count-rate in the first study, and between the slurry composition and the prompt-gamma-ray count-rate in the second study. A mathematical relationship has also been developed which relates changes in the prompt-gamma-ray counts from hydrogen to changes in slurry composition.

Jan 1, 1973

By A. Mosqueda Martinez, L. C. Trytten, R. P. Kofluk, J. J. Budac

The Corefco ammonia leach nickel refinery treats Ni-Co mixed sulphides from the high-pressure acid leaching of Moa Bay nickel laterite. Due to the low iron content of the feed, the ammonia leach process generates a leach residue with ~10% Ni+Co. Since commissioning a leach residue pressure filtration circuit in 2002, this residue has been stockpiled, dried, and sold commercially. For several years, the residue was sold to nickel smelters overseas. In 2014, re-processing of the residue in the high-pressure acid leach was tested. Lab test work was completed showing excellent extraction of the contained nickel and cobalt, and additional beneficial effects in the high-pressure acid leach circuit. A plant test in Moa confirmed the results, and preparation for shipment of the valuable leach residue for re-processing has begun. This paper outlines the test work and results, and some commercial considerations.

Jan 1, 2015

By M. B. Kime

"A set of experimental batch leaching tests studied the effect of pH, time, temperature, and stirring speed on the relative Cu, Co, Ni, and Fe leaching yields of an oxidized copper-cobalt ore sample in an aqueous hydrochloric acid solution. The results were statistically analyzed and modelled using the structural equation modelling method. Models showed that Cu, Co, and Ni leaching yields were strong functions of the leaching time and leaching temperature, whereas the Fe leaching yield depended on the leaching temperature, stirring speed, and pH. Under optimum leaching conditions yields were 99.8% Cu, 82.4% Co, 91.3% Ni, and 30.6% Fe.RÉSUMÉ Une série d’essais expérimentaux de lixiviation en bâchée ont été menés pour étudier l’effet du pH, de la durée d’attaque, de la température et de la vitesse de brassage sur les rendements relatifs de lixiviation du cuivre (Cu), du cobalt (Co), du nickel (Ni) et du fer (Fe) d’un échantillon de minerai de cuivre-cobalt oxydé dans une solution aqueuse d’acide chlorhydrique. Les résultats ont été analysés et modélisés statistiquement à l’aide de la méthode de modélisation par équation structurelle (SEM, de l’anglais structural equation modelling). Les modèles ont montré que les rendements de lixiviation du Cu, du Co et du Ni dépendaient énormément de la durée d’attaque et de la température de la lixiviation ; le rendement de lixiviation du Fe, quant à lui, dépendait de la température de la lixiviation, de la vitesse de brassage et du pH. Dans des conditions optimales de lixiviation, les rendements étaient de 99,8 % pour le Cu, de 82,4 % pour le Co, de 91,3 % pour le Ni et de 30,6 % pour le Fe. INTRODUCTIONThe Katanga province in the Democratic Republic of Congo hosts the northwestern part of the Central African Copperbelt. This region abounds with large, rich deposits of sulfide and oxidized copper-cobalt ores. In general, the main valuable minerals present are malachite (CuCO3Cu(OH)2) and heterogenite (CoO(OH)). Common impurities found in heterogenite are Cu, Ni, Si, Al, Mn, and Fe. The substitution of Co by other cations (e.g., Cu, Ni, and Fe) has an influence on the crystallinity of heterogenite (Deliens, 1974). In general, well-crystallized varieties of heterogenite have lower impurity contents, whereas amorphous heterogenite types usually contain more impurities (Thys et al., 2009). Further, in heterogenite, Co can occur in the 2+ and 3+ oxidation states. The gangue generally consists of quartz (SiO2), talc (Mg3Si4O10(OH)2), kaolinite (SiO2·Al2O3·2H2O), limonite (Fe2O3·3H2O), and goethite (FeO(OH)). Oxidized copper-cobalt ores are often treated by hydrometallurgical methods, whereas sulfide ores are often treated by flotation or pyrometallurgy, depending on their grades. Hydrometallurgical methods typically entail selectively dissolving the metals of interest (Cu, Co, and Ni) in aqueous solutions (leaching), transferring the dissolved metals to an organic solution, and retransferring these to a second aqueous solution (solvent extraction). Copper and nickel are readily dissolved in an acidic aqueous media. In contrast, cobalt is difficult to dissolve, especially if it is present in the third oxidation state; however, this species becomes soluble after it is reduced to Co2+ (Mwema, Mpoyo, & Kafumbila, 2002; Kime & Makgoale, 2016)."

Jan 1, 2017

By A. E. Hilder

Introductory The following pages present the results of field investigations, laboratory and commercial tests, drilling, surveying, and preliminary development of the refractory clays which have been discovered recently in the township of Kipling, at the foot of Long rapids on the west side of the Mattagami river about 57 miles north of Kapuskasing and approximately 7 miles north of Smoky Falls, the terminus of the privately owned railway operated by the Spruce Falls Power and Paper Company, Kapuskasing (see Figure 1). Investigations on the clays of northern Ontario have been carried on over a period of seven years by officers of the Ontario Department of Mines, and I am indebted to the information published by that Department in reports by W. S. Dyer and A. R. Crozier, as well as?by Professor R. J. Montgomery, of the Ceramic Department, University of Toronto. It was, in large measure, the data given in the 37th, 38th, and 42nd Annual Reports of the Ontario Department of Mines that led me to make a personal investigation of the Mattagami River clays, with the result that we now have a commercial undertaking that will develop eventually into an industry of considerable importance in supplying the central manufacturing districts of Canada with refractories that heretofore have been largely imported from the United States. An extract from the 42nd Annual Report of the Department, Part III, 1933, page 75, reads as follows: "As for the refractory clay, the deposits are undoubtedly very large, but what is urgently needed is a deposit near the railway under sufficiently shallow overburden for recovery by stripping'. Having previously made an investigation of the clays adjacent to the Temiskaming and Northern Ontario railway, and these clays proving unsuitable, I turned my attention to the outcrops of refractory clays on the Mattagami river, first reported by Keele in 1919. This area offered possibilities within the economically permissible distance from rail transportation.

Jan 1, 1935

By G. Chahal, L. C. So, S. Faucher, S. Mostaghel, S. -Y. Oh, S. K. Lee

Slag dumping and water granulation are the most commonly used slag treatment methods in the metallurgical industries. In both processes, water is present (by desire for cooling and dispersion or as a result of rain accumulation) and thus equipment and operations are designed to minimize and mitigate the risk of steam explosions resulting from the inappropriate contact of slag with water. Slag handling practices have, therefore, never been inherently safe; even good design, operation, and maintenance are not sufficient to prevent explosions or other related injuries from occurring. For slag handling to become inherently safe, our industry must eliminate the potential contact of water with molten slag. This is today feasible with the advent of dry granulation technologies, a review of which is presented, and it thus falls to us, in the metallurgical sector, to lead the way in their final stages of development and adoption. Furthermore, while slag dumping and water granulation offer some metallurgists the means of valorizing their slag as a by-product, for most, this is not the case. The energy in slag is lost through dumping and water granulation processes, and where slag is sold as a by-product, it is for its chemical content only. Here, dry granulation processes also offer advantages including the production of by-products which hold value in both their chemical content and physical properties and heat recovery. Dry granulation, therefore, augments the methods by which slag may be valorized over traditional processing methods.

Jan 1, 2015

By T. Adamcewicz

The province's lignite resources lie mainly in the south, extensions of the much larger deposits in Montana and North Dakota. Because of planned additional capacity, conventional steam power generation will probably remain as the dominant resource usage for many decades. Conversion of coal to other energy forms is receiving emphasis and in the future will compete with steam power generation in terms of quantities used.Economic deposits, minable by present-day technology, have been generally defined. Because a large percentage of the total lignite resource is in seams containing multiple partings, future extraction will become much more difficult and capital intensive.Increased public involvement will ensure that the impacts of future coal mining and usage operations are compatible with environmental and social objectives.

Jan 1, 1982

By M. E. Charles

The use of water flowing as a lower layer to reduce pressure gradients in petroleum pipelines was investigated using 17.5 deg. A.P.I. Lloydminster crude oil in a 1-inch laboratory pipe-line and a 21h-inch field pipeline. The method was found to be very effective in reducing the pressure gradient below that for the oil flowing alone. The factor by which the pres-sure gradient was reduced varied with the percentage of water added, and in general exceeded 10 for water contents ranging from 40 to 60 per cent. Within this range of water content the pressure gradient reduction factor was independent of the oil flow rate.

Jan 1, 1960

By Mansoor Barati, Xue Yin, Yanhui Sun, Alex McLean, Yindong Yang

The formation and evolution of inclusions in Ti-Stabilized, 17Cr Austenitic Stainless Steel produced by the ingot casting process were investigated through systematic sampling of liquid steel and rolled products. Analysis methods included total oxygen and nitrogen contents, optical microscopy, scanning electron microscopy (SEM), and energy dispersive X-ray spectroscopy (EDS). The results indicate that the composition of inclusions was strongly dependent on the types of added alloying agents. During the AOD refining process, after the addition of ferrosilicon alloy and electrolytic manganese, followed by aluminum, the composition of inclusions changed from manganese silicate-rich inclusions to Al2O3-rich inclusions. After tapping and titanium wire feeding, pure TiN particles and complex inclusions with Al2O3-MgO-TiOx cores coated with TiN were found to be the dominant inclusions when [%Ti] was 0.307 in the molten steel. These findings were confirmed by thermodynamic calculations which indicated that TiN inclusions could be formed in the liquid phase due to the high contents of [Ti] and [N] in the molten steel. From the start of casting to the rolled bar, there was no obvious change in the composition of inclusions compared to the titanium addition stage. Stringer-shaped TiN inclusions elongated along the rolling direction with lengths varying from 17 to 84µm were observed in the rolled bar, which could detrimentally impact the mechanical properties of the stainless steels.

Jan 1, 2015

By W. R. Richmond, T. S. Li, D. Ilievski

The reactive precipitation of ferrihydrite was studied in a laboratory semi-batch precipitator, where a highly concentrated sodium hydroxide solution was fed into an iron nitrate solution. Instantaneous hydrolysis of iron[III] takes place when the two reagents are mixed generating supersaturation, and leading to immediate precipitation of ferrihydrite via a primary nucleation mechanism then followed by limited crystallite growth to 3 to 7nm. A mathematical model of the semi-batch laboratory precipitator was used to simulate the pH responses during the precipitation of ferrihydrite at different reagent feed rates. The model comprised of interconnected compartments of averaged hydrodynamic conditions, incorporating physically meaningful turbulent mixing time constants. The precipitation process is described by the solute concentration conservation equation incorporating a postulated ferrihydrite primary nucleation model. It was found that the semi-batch precipitator model predicted the experimental pH response reasonably well. The experimental results demonstrated that the reagent feed rate has a critical effect on the course of the precipitation of ferrihydrite, i.e. it is a rate determining step given the fast hydrolysis and precipitation kinetics.

Jan 1, 2005

By Wayne D. Goodfellow, William M. Luff, Steven J. Juras

Abstract-Brunswick No. 12 is a vent-proximal massive sulfide deposit that formed above a feeder pipe with associated hydrothermal alteration. Because of the replacement of bedded sulfides deposited above the hydrothermal vent, individual sulfide lenses show the following vertical and lateral zoning outward from the vent complex: massive pyrite-pyrrhotite-chalcopyrite core - interlayered pyrite-sphalerite-galena (Pb-Zn ore zone) - bedded pyrite. The feeder zone which underlies the Cu-rich core consists of an anastomosing network of pyrite-pyrrhotite-chalcopyrite­ quartz veins with variable and generally minor contents of ferroan carbonate, Fe-rich chlorite, sphalerite, galena and arsenopyrite. Hydrothermal alteration of felsic igneous rocks hosting and adjacent to the feeder pipe is represented by an inner zone (zone 1) characterized by sulfide stringers, Fe-rich chlorite, muscovite, quartz, and ferroan carbonate that formed at the expense of feldspars and what was probably glass; outer zones (Il and III) are represented by Mg-rich chlorite and muscovite formation, and the albitization and silicification of K-feldspar. Accompanying these alteration trends is a marked decrease of Na + Ca, and an increase in Fe + Mg + C03 in zone 1, and increases in Mg + Na in the outer zones. The classic zoning of metals within the sulfide lenses, the formation of a feeder pipe below the vent-proximal sulfide core, and the hydrothermal alteration of felsic volcanic rocks cut by the feeder pipe all support a vent-proximal origin for the Brunswick No. 12 deposit. Furthermore, restriction of sulfide stringer mineralization to the footwall sequence, the folding of the stringer zone by an F1 fold, and the difficulty of long distance mass transfer of metals from the sulfides into the host rocks all argue against a tectonic origin for the stringer zone. All of the evidence indicates that the feeder pipe formed during the ore forming hydrothermal event, but has been distorted and in some areas detached from the overlying massive sulfides during subsequent deformation.

Jan 1, 1992

By Hans Lundberg

Introduction Today, geophysical exploration is recognized as a special science wedged between geology and mining. Universities and technical institutes have special professors teaching geophysics applied to oil and ore prospecting. The list of literature on geophysical exploration has grown from practically nothing at all some twenty-five years ago to ~ several thousands of books, some of them very imposing volumes. Most of the methods now used have been developed since the first World War, and very large systematic exploration campaigns have been carried out in many places, in many countries. It has been rather difficult to obtain enough information as to what is going on in Canada. However, since the Associate Committee on Geodesy and Geophysics of the National Research Council became more actively engaged in promoting geophysical research, it may be easier to obtain information and, in the future, the quarterly issued Canadian Geophysical Bulletin may throw considerable light on the current geophysical activities in Canada. Some twenty crews have been engaged the last few years in geophysical prospecting for ore. In the United States, between 500 and 600 crews are employed exclusively in geophysical prospecting. Most of these, however, are engaged in oil exploration. During the winter 1942-1943, the German Government employed some fifty crews on geophysical exploration, and some ten crews were working for private enterprises.

Jan 1, 1948

By W. G. Mine

In September, 1953, seismographs were installed in the Crowsnest Pass area of Alberta and British Columbia to study the 'bumps' which were occurring in the coal mines at Fernie and Coleman, and to investigate the possibility that they might be related to minor earthquakes in the area. During the initial phase of the work, three seismographs were operated at widely separated stations, two in the region of coal mines at Coal Creek and Coleman and one at Turner Valley, distant from any mining operations. Some earthquakes were recorded at all three stations and, in addition, many small disturbances were recorded by the seismographs located near the mines, especially -by the instrument at Goal Greek. A closer network of radio-linked seismographs was then in-stalled near Fernie, the records of which definitely established that the small disturbances were occurring in the mine workings, both active and inactive. No relationship was established between bumps and local earth-quakes in the area. This work was initiated as a -co-operative effort with the Fuels Di-vision of the Mines Branch, Department of Mines and Technical Surveys, which has undertaken a study into the phenomena of ground stress relief in underground mine workings.

Jan 1, 1958

By Jr. Jones

This paper is derived from a document that compiles autogenous and semi-autogenous mill installations worldwide, through the end of 2010. Updates have been solicited from all major mill manufacturers and most have responded. A review of AG/SAG mills sold to date and in the last five years indicates that the AG/SAG mill market is very healthy and the trend is larger diameter mills with high diameter-to-length ratios. Ring motors (gearless) are the preferred drives for large mills even though the power transmitted through a gear drive is expected to near 11,000 kW per pinion in the near future.

Jan 1, 2012