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By Serena Biella

Gold has received a growing interest as a catalyst for the selective oxidation of organic molecules using oxygen under mild conditions1. In the liquid phase application small gold particles (2.5-7 nm) deposited over different solid supports can be used but, like many other noble metals, their catalytic activity depends upon the nature of the support and the preparation metod2-5. In particular, gold on carbon is the preferred catalyst for the oxidation of the alcoholic 2-7 and the aldehydic7-9 groups and one of the best preparation method is the immobilisation of colloidal particles2-5,8,9. Suggested application of gold catalysis in fine chemicals production, tested on laboratory scale preparations, is reported in table 110. In order to produce more efficient catalysts for the liquid phase oxidation and to derive new insights into the reaction mechanism, we have made a comparison among catalytic systems based on different metals. The first effort was to test the activity, if present, of naked metal particles and then to study the influence of various materials commonly used as a support.

Oct 1, 2003

By L. C. Stevens

The particular purpose of this paper is to direct attention to the development of underground conveying as applied to methods of working coal in the mines of Alberta. Historical A retrospective view of coal mining discloses a continuous effort, on the part of those interested, to substitute mechanical contrivances for hand labour. A patent for a coal-cutting machine was granted to Michael Menzies in 1761, at which time much of the transportation of coal underground was accomplished by means of sledges. Early forms of cutting machines attempted to duplicate the action of a miner's pick, and one hundred years lacer than Menzies? patent we still find this class of machine, driven by water power or compressed air, in use to a limited extent. A coal-cutter using the principle of a circular saw and worked by hand was exhibited in London in 1851, and from these crude beginnings the machines of today have been evolved. Transportation of coal underground has similarly been subject to considerable improvement. The above mentioned Michael Menzies took out a patent in 1750 covering the use of a self-acting incline plane, which is probably the earliest record of any system devised to lighten the load of the crammer or car-pusher of those days. In the year 1868 the Gillot & Copley machine was patented, this being a compressed-air-driven disc coal-cutter which proved highly successful. The chain cutters were a natural development from this type, and for a number of reasons they have been even more successful in the majority of cases.

Jan 1, 1930

By C. M. Bartley

Fluorspar, in addition to its familiar uses as a metallurgical flux and as a source of the electrolyte for aluminum production, has become important as an essential raw material in the rapidly growing fluorine chemical industry. The unique ability of fluorine to react and form compounds with al-most all other chemicals has made it one of the important elements in modern chemistry. Research and development over the past thirty years have resulted in a current annual production of fluorine chemicals that is both technically and economically important to industry. Because many of these chemicals and products are relatively new, and most have properties that are not duplicated by other materials, the present uses are expanding rapidly and new applications are being reported continually. Fluorspar, the only immediate and practical source of fluorine, is therefore an important mineral. This fact has been recognized in major industrial areas such as the United States and Western Europe, but has received little attention in Canada.

Jan 1, 1962

By Paul J. Bourassa

Alin de pourvoir aux besoins d'hébergement des quel¬ques 1600 employes qui travailleront dans toutes les spheres opérationnelles de l'exploitation du gisement du Mont-Wright, ainsi que de leurs families, Quebec Cartier a dû, avec l'aide de conseillers reconnus, et /a participation de ses employes résidant a Gagnon, étudier tour les nouveaux établissements résidentiels nordiques des dernières années tout au Canada qui dans lee pays scandinaves afin d'être en position de coneepter une agglomeration moderne répondant a toes les besoins de see future résidants. Les pre¬miers residants ont pu passer Noel 1972, et maintenant les logements prévus et construits sont °coupes a 92%.

Jan 1, 1977

By Jean-Paul Drolet

"The ultimate aim of the Law of the Sea Conference, held under the auspices of the United Nations, is to ensure that all aspects of the use of the sea are covered by international law. The question facing the nations of the world can be stated as: "" Who will control and benefit from the use and the wealth of the sea?""The United Nations Conference on Law of the Sea - known as UNCLOS - which reconvened in New York during the latter part of August 1978 was the third such Conference in the UN's history. The concepts of sovereignty over the territorial sea and freedom on the high seas have remained fundamental to the international law o f the sea until our time. The legal regime based on these two concepts developed initially from state practice meant that the unilateral actions taken by one or more countries were eventually accepted and followed by others.It was not until 1958, during the first Geneva Conference on the Law of the Sea (pursued in a second Conference in 1960) that the Law of the Sea was codified and modified to a certain extent by the then independent nations of the world in the four multilateral conventions on territorial sea and contiguous zone, continental shelf, high seas, and fishing and conservation of living resources.A third Conference got under way many years later when the members of the UN met in New York at the end of 1973 for preliminary discussions . This meeting stemmed largely from the need to fill gaps in existing international legislation which did not cover the new uses of the sea. The Conference was subsequently reconvened a number of times - in Caracas (1974), in Geneva (1975) and twice in New York (1976) for what was called "" substantive negotiating sessions."" A sixth session was held in New York in 1977; a seventh, held in Geneva at the beginning of 1978, recessed and reconvened in New York at the end of August 1978. This is what is referred to, in international jargon, as the seventh session of the Third United Nations Conference on the Law o f the Sea. The following dates are the principal markers of a saga which began some twenty years ago with the purpose of regulating the use of the oceans."

Jan 1, 1981

By Henri-Louis Jacob et Marc Bélanger

La province de Québec est un important producteur de roches et de minéraux industriels. En 1998, la valeur de cette production se chiffrait à 1,26 milliard de dollars canadiens (données préliminaires). Les minéraux industriels produits comprenaient: l'amiante extraite des gisements de chrysotile associés aux complexes ophiolitiques de Thetford Mines et d'Asbestos; l'ilménite et les scories enrichies en titane produites à partir du gisement d'ilménite massive du lac Tio associé au complexe anorthositique du lac Allard; le talc produit dans la région de Thetford Mines, à partir des roches à talc-carbonates associées à des feuillets de serpentinite; le mica broyé produit à partir de l'intrusion de suzorite du lac Letondal; le graphite en paillettes extrait du gisement du Lac-des-Îles; la wollastonite extraite d'une zone de skarn dans un lambeau de roches métasédimentaires enclavé dans le massif d'anor-thosite du LacSaint- Jean; le sel extrait aux Îles-de-la-Madeleine d'un gîte associé aux évaporites du Croupe de Windsor. Les nombreuses carrières dans le sud du Québec produisent, en plus de la pierre concassée, diverses substances incluant la pierre dimensionnelle (granite surtout); le calcaire pour la chaux, le ciment ainsi que divers usages industriels; la silice extraite à partir de formations de grès ou de quartzite. Le Québec est aussi un important producteur de tourbe de sphaignes qui est extraite de vastes tourbières qui se sont formées un peu partout dans le sud du Québec à la suite de la dernière glaciation. Les autres ressources en minéraux industriels comprennent des gîtes déjà exploités de brucite, de chromite, de magnésite dolomitique et de feldspaths ainsi que des gîtes de magnésite, de barytine et d'apatite faisant présentement l'objet d'évaluation.

Jan 1, 2001

By Scott A. Trebilcock

Nautilus Minerals Inc the world?s leader in exploration and development of deep ocean mineral resources is today focused on the recovery of high grade copper-gold from in seafloor massive sulphide mineralization. These mineralized belts, analogous to land based volcanogenic massive sulphides (VMS) deposits are located near tectonic plate boundaries of the Western Pacific and around the world. Nautilus; first development project is Solwara 1 located in benign waters in Papua New Guinea. Since 2006 the company has completed detailed environmental and geological studies at Solwara 1, culminating in a number of world firsts, including the first Environmental Permit for a deep ocean mineral project and the first NI 43-101 compliant seafloor massive sulphide resource statement. Nautilus has relied heavily on proven deepwater technologies from the oil and gas industry in the design of the first mineral extraction system. Pipeline trenching units, workclass ROVs, deepwater production risers and drill cutting removal systems will all be adapted at Solwara 1. Key contractors to the project have all been selected for their deepwater experience, creativity and determination to launch this new industry. Innovation is at the forefront of Nautilus? success to date. This paper gives an overview of the Solwara 1 development and describes the exploration and production technologies adapted for seafloor mineral extraction.

May 1, 2010

By B. S. Ignasiak, Dennis Carson

"Laboratory study of the behaviour• of binary coal blends shows that coke strength is more closely dependent on the distribution of ""reactive"" oxygen in the parent coals than on their proximate, elemental or petrographic compositions, and it also appears possible to qualitatively predict coke strength from information about reactive oxygen. Proceeding from this recognition, experiments were carried out to test the possibility of preparing metallurgical cokes from binary blends in which non-caking hvb coal was substantially freed of reactive oxygen by prior heat t1•eatment under controlled conditions. The results indicate that such blends can yield surprisingly strong cokes and that coke strength may be amenable to further improvements by modifying the size distribution of the pre-heated component and the rate at which it is charred."

Jan 1, 1976

By O. G. Olvera

"Refractory sulfidic ores consist of materials in which gold occurs finely disseminated within metallic sulfides or forming solid solutions, with pyrite and arsenopyrite being the two sulfides most commonly associated with gold. Typical cyanide operations show poor performance and require oxidative pretreatments to increase gold recovery. Pretreatment alternatives include roasting, pre-aeration, acidic and alkaline high pressure oxidation, and bacterial oxidation. The presence of arsenic, however, introduces a serious disadvantage to the use of roasting and bacterial leaching, while high pressure oxidation involves high capital costs. This work focuses on evaluating the effect of the addition of a carbon resin as a sulfur collector on the oxidation of different arsenopyrite concentrates under atmospheric tank leaching (ATL) conditions. The addition of the resin improved the oxidation of sulfides and favored the formation of elemental sulfur over the generation of sulfate. The use of AF5 in ATL resulted in higher gold recoveries under standard cyanide carbon-in-leach and thiosulfate leaching.INTRODUCTION Refractory sulfidic ores consist of materials in which gold occurs finely disseminated within metallic sulfides or forming solid solutions, with pyrite and arsenopyrite being the two sulfides most commonly associated with gold. Gold is not readily accessible to solutions in these types of ores and typical cyanide operations show poor performance, thus making the use of oxidative pretreatments a requirement to increase gold recovery. Pretreatment alternatives include roasting, pre-aeration, acidic and alkaline high pressure oxidation, and bacterial oxidation. The presence of arsenic, however, introduces a serious disadvantage to the use of roasting and bacterial leaching, while high pressure oxidation involves high capital costs. The use of carbonaceous materials to enhance the dissolution of sulfides is not novel, and leaching additives such as coal, activated carbon and carbon powder have been considered for the improvement of bioleaching, atmospheric leaching, and pressure oxidation leaching processes. However, this type of technology has been focused mainly on the recovery of copper from copper concentrates containing chalcopyrite with less attention paid to other sulfides."

Jan 1, 2017

By F. R. Archibald

Introduction It is the purpose of this paper to review the subject of roasting as preparation of refractory gold ores and concentrates for cyanidation, with particular reference to operations at the mill of Beattie Gold Mines (Que.), Ltd., Duparquet, Quebec. Two earlier papers relating to the Beattie roasting operations are cited as background to the ? present discussion, and more general reference is made to other publications relating? to geology and metallurgy at Beattie. The Beattie roasting plant was built in 1937 as an addition to the existing flotation and cyanidation plant to permit complete processing of the ore at the mine property. Previously, the flotation concentrate had been cyanided, yielding 70 per cent of the gold values, followed by re-flotation of a concentrate from the cyanide residue. This re-floated residue was shipped to a smelter for recovery of gold values unavailable from direct cyanidation. The roasting plant itself is of interest through application in its design of multiple-hearth roasters and a Cottrell plant for separate recovery of dust and arsenic. In the laboratory and plant studies that accompanied development of the plant into a dependable and efficient working unit have been found principles and ideas applicable to other roasting 'problems. Before enlarging on these aspects relating particularly to the Beattie problems and plant, brief consideration is given to roasting in general.

Jan 1, 1949

By A. Ignatieff

This is the second review of developments in coal mining engineering (see C.I.M .M. Transactions, Vol. LI, 1948, pp. 262- 264) and covers the period from October, 1948, to January, 1950. Mechanization The period under review was characterized by the intensive development of appliances providing for complete mechanization of coal-face operations. A variety of machines are being evolved or have already been placed on the market which embody the principle of 'continuous mining'. This trend can be observed in all coal producing countries. In the United States, two continuous mining machines have been developed for entry and room application and by the end of 1 949 were being used in a number of mines. These are the Joy Continuous Miner in which the coal is ripped from the face by means of multiple cutter chains, and the Jeffrey Colmol employing cutters on rotating arms for chipping the coal from the face. The Joy machine is made in tw6l models, 34-in. and 48-in. high and designed for a range of seam thicknesses from 3-ft. -t-in. to 4-ft. 6-in. and from 4-ft. 6-in. to 8ft., respectively. Some experience has been gained with this machine and accounts of its performance are already appearing in the technical literature. The Jeffrey-Colmol has a more limited range of working height. The first model, 38-in. high, was designed for seams about 4 feet in thick11ess but more recently the 28-in. low model has been placed on the market for seams 2-ft. 6-in, to 3-ft. 4-in. in thickness. Conventional mobile loading machines of the gathering-arm type are continuing to yield high production under suitable conditions, and improvements or modifications of the basic principle are embodied in new machines as, for example, the Jeffrey mobile (conveyor) loader with extensible (gathering-arm) head developed for conveyor mining.

Jan 1, 1950

By J. G. Mieczaniec

"A key element for a successful mining operation is the grinding circuit. It must be reliable, maintainable and must perform to or above design capacities for 95% of the time. Once chosen and installed major modifications are either prohibitive or very expensive. The selection of mills and drive system is probably the single most important decision made within the concentrator complex.Economic studies revealed that the optimum expansion for Lornex was a 68070 increase in plant throughput. This indicated that the new mill would have to be larger than the existing 32-foot mills.The Lornex ore has a wide range of hardness which has a great influence on mill throughput (Table 1). To smooth out the fluctuations, a blending program ha s always been in effect at the mine, coupled with ball charge control for the primary mills. As can be appreciated, an optimum balance is difficult to achieve. A sudden change to so ft ore with a high ball charge puts the mill into jeopardy with a constant speed drive.The blending philosophy would continue after the expansion, but with the addition o f a second primary crusher, it was envisaged to have the new mill process harder ore to maintain production targets. In theory, the new mill would have a proportionally larger ball charge than the existing mills.This scheme makes the new mill vulnerable for processing so ft ore for a fixed speed mill. Thus, variable speed seemed an attractive option.In early 1979 prominent mill manufacturers were invited to submit proposals for the new mill. Fixed and variable speed mills were to be considered with mill size ranging from 32-foot to 36-foot diameter. The proposals were to include the drive, ball charge, % critical speed, couplings, gears, etc. - the complete package. The recommendations were variable with most manufacturers submitting several alternatives. Recommended mill speed varied from 68% to 78% critical. The concept of variable speed was becoming more attractive, Lornex ultimately decided on a twin DC motor drive system for a 34-foot diameter mill.After start-up it was discovered that best throughput occurred at 78% mill critical speed or top speed of the drive motors. The motor speed range was adjusted upward from 186 to 200 rpm. Today the mills operate at 79% critical or a motor speed o f 193.5 rpm.Clearly the selection of the variable speed mill allowed the flexibility to optimize throughput."

Jan 1, 1985

By James A. Robertson

"The Pronto Mine located at the east end of Lake Lauzon, Long Township, some 12 miles east of Blind River is of historic note being the discovery locality and the first producing mine of the Elliot Lake uranium camp. Radioactive bedrock was discovered in 1949, a commercial deposit was verified in 1953 and production commenced in 1955. Production continued to April 1960: total tons milled 2,264,404 from which 4,643,835 pounds U,O, were recovered at a recovered grade of 2.05 pounds U3O8 per short ton.The orebody is in a bed of pyritic quartz pebble conglomerate at the base of the Matinenda Formation of the Elliot Lake Group of the Huronian Supergroup. The rocks strike east and dip 15 degrees to 20 degrees south and unconformably overlie Early Precambrian granite, the upper surface of which is marked by a regolith. Several diabase dykes cut the orebody which is also affected by albite, chlorite, and carbonate-rich alterations. To the south the orebody is cut by a fault. The orebody is 6to 10 feet but locally 10 to 15 feet thick, has a strike length of 3,500 feet and extends down dip for 3,600 feet to a depth of 1,000feet. Some 300,000 tons of ore grade mineralization remain in the deeper portion of the mine.IntroductionThe Pronto Mine, (Photo I) at the east end of Lake Lauzon in Long Township some 12 miles east of Blind River, is of particular interest as being the discovery site and the first producing mine of the Elliot Lake camp.Production at the Pronto Mine commenced in 1955 and continued until 1960 when the mill was converted to treat copper ore from the nearby Pater Mine at Spragge. A description of both mines, based on material provided by the mine staff, was given in the report on ""Geology of the Spragge Area"" (Robertson, 1970).As little study has been done on Pronto geology or petrology since mine closure, the earlier description of exploration and geology is essentially repeated, but shortened, here- the main change being that the stratigraphic terminology has been amended as recommended by the Federal-Provincial Committee on Huronian Stratigraphy (Robertson et al., 1969)."

Jan 1, 1986

By John E. Callahan

"A stream sediment geochemical survey covering an area of 13.000 sq. km near Churchill Falls. Labrador. was conducted for Brinex (British Newfoundland Explorations Ltd.) prior to partial flooding by the Churchill Falls power project. Stream sediments (minus 80-mesh) were analyzed for Cu, Pb, Zn, Ni, Ag, Mo. U and Mn, and the heavy mineral, nonmagnetic fraction (minus 60-mesh) for Cu, Pb, Zn, Ni, Ag, Mo, Ba and Mn. A binocular examination of the concentrates for sulphides and pyrope garnet was done on the heavy mineral concentrates. The concentrates were also examined for fluorescent minerals.Two distinct areas with high trace-element values indicate the need for follow-up studies. The first is in an area of gabbro erratics containing massive and disseminated sulphides (pyrrhotite, pyrite and minor chalcopyrite) on the western edge of the survey area along the Esker Road. The second, largest area (several hundred square kilometres) is anomalous in U and Mo and associated with felsic intrusives (Red Wine Complex?), syenites. granite gneiss and sedimentary rocks (Seal Lake Group?).The binocular study showed that almost 15% of the heavy mineral concentrates contained pyrite and no other sulphides. This indicates that this technique may be worthwhile in determining the presence of sulphide minerals in stream sediments from glaciated environments. The only fluorescent mineral observed in the study was zircon."

Jan 1, 1981

By J. Suarez Condezo, E. Herrera Alarcon

The Ilo Smelter Modernization Project will require treating the slag from the Peirce Smith converters in Slag Cleaning Furnaces using pig iron technology. Currently the slags from the converters show variable magnetite contents. The copper contained in this slag is recovered in Reverberatory Furnaces, where the smelting rate was improved due to the high silica content of the converter slag. Preliminary industrial tests where developed to clean the slag from converters using pig iron. The results showed that the magnetite content has a significant influence in this process. This work describes the actions that are being implemented in the converter operation to control the magnetite content in the slag in order to maintain the high copper recovery of the smelter when the new facilities are commissioned. This task will demand a strong control of both the slag chemistry and converter practices in order to get the copper recovery considered as the design criteria (~97.4%).

Jan 1, 2007

By J. Talja

"Non-ferrous metal concentrates contain typically 7 – 12% water when received at the smelter. Removal of this water prior to smelting is always economically feasible because unnecessary heating of vapour (from 100 °C to 1200 °C) in the smelting furnace can thus be eliminated. This results in major reduction in CO2 emission and direct annual savings of several millions of dollars due to improved energy efficiency. Next step to further improve the energy efficiency, to gain substantial savings and simultaneously cut emissions is to select modern technology for the drying process. Consequently, all CO2 emission will be completely eliminated (from 40,000 tpy down to 0 tpy), NOx emission will be negligible, and the SO2 emission will be reduced by over 99 %. Switching of conventional direct heated drying technology to modern indirect steam drying brings, in addition to dramatic emission reduction, additional savings due to further improved energy efficiency. Direct energy savings count for 900 – 1300 MJ/t H2O, which depending on the concentrate feed rate and its moisture load can be worth several millions of dollars every year. Additional savings in operational expenses related to drying and gas cleaning may be worth a few million dollars more. Sustainability is a key issue today, and major savings together with significant emission reduction are readily available by proper technology selection for concentrate drying. INTRODUCTIONSustainability is a decisive principle in any process industry accompanied with emissions and high amount of energy. This is of significant importance in metal processing, including concentrate drying, where minimum impact on the environment, people and community are targeted, and all this with minimum cost, effort and resources. Therefore, special attention is paid to high energy efficiency, low energy consumption with preferable utilization of waste energy, safety issues, availability, level of maintenance, cost of maintenance, and emissions among other things.Non-ferrous metal concentrates can be dried using various techniques. Conventional drying based on direct heating, and use of fossil fuels for drying energy has almost entirely been replaced by steam drying. It is based on indirect heating and it has become the most dominant drying technology for copper concentrates during the last decade with over 90% of the market share of all new dryer installations. Among the steam dryers the Kumera Steam Dryer is the most pre-dominant technology with some 70% of all new dryer installations world-wide."

Jan 1, 2012

By S. Averill, B. Schreiner, V. Sopuck

The La Ronge. Kisseynew, Glennie Lake and Flin Flon domains. the main focu for gold exploration in the southeast part of the Saskatchewan Shield, were subject to continental glacial ice advances from the northeast during the Quaternary. Based on forty-four auger hole along with surficial mapping, the general Quaternary stratigraphy in this area is observed to be composed of a lower till unit , an overlying stratified unit of glaciofluvial sand and gravel and/or a glaciolacustrine silt-clay unit. an upper till. and an upper tratified unit. The lower till is commonly found throughout the geological domains except where it has been eroded in glaciofluvial or fluvial channels. Glacial Lake Agassiz fo rmerly covered most of these prospective domains. The lacustrine deposits associated with the lake impede surficial geochemical surveys including soil. lake sediment. and biogeochemical surveys. The approximate extent of clay cover can be predicted from beach elevations. For instance. in the Waddy Lake area. clay i not known to occur above about 1,400 feet (425 m) elevation. Exploration techniques are hampered by clay in at least one third of the volcanic belt. Thi s influence is indicated by the fact that nearly all gold prospect found to date are located above 1,400 feet (425 m) while the area of clay cover is vi rtually unexplored. The upper till i related to a minor ice readvance. This till is the medium often sampled during soil surveys in the area . lts value as a geochemical ampling medium is dependent on the extent of erosional contact with bedrock highs on the lower till. Those areas which are relatively free of lacustrine and fluvial deposits are those where surface geochemical methods work best. In the Waddy Lake volcanic belt approximately 25-50% of the area may be suitable for surficial surveys. The area of the Star Lake prospect occurs above the 1,500 foot (460 m) elevation and was not covered by Lake Agas iz. The effectivene of till sampling as a surface sampling medium was tested in those areas above the clay level. Till orientat ion surveys were carried out at the Star Lake property and the Tower Lake prospect (Waddy Lake area) within the La Ronge Domain . Gold grain counts and analy es of heavy mineral concent rate from 7 kg surface ti ll samples were used to delineate dispersion trains down-ice from mineralization. In addition, the clay fraction and a 30 g (-80 mesh) subsample from the same till sample, were analyzed for gold . In the Star Lake area, ice direction is subparallel to the strike of several narrow northeast trending auriferous structures. arrow dispersion trains down-ice from known

Jan 1, 1986

By J. J. Laffin

In the pursuit of comfort and safety, the wonders of science have given us controlled heating and cooling, thus enabling us to enjoy all the aspects of present-day living to an extreme never previously •envisaged. Man's attempt to conquer the elements largely involves con-trolling the temperature around him. Without having conquered this aspect, his body energy would be consumed in trying to maintain physical comfort, rather than being invested in the explorations which have resulted in man's control over the forces of nature. The indirect methods used to obtain the most agreeable temperature environment were developed because of the natural tendency to strive for increased safety, convenience and comfort. Until the twentieth century, when heat generated by atomic fission became a reality, man's only source of heat, except for that of the sun, came from his discovery of fire.

Jan 1, 1962

By W. R. A. Graeser

"The Nordenham finishing mill is situated in the town of Nordenham, Fede1•al Republic of Germany, on the banks of the Weser River opposite the town of Bremerhaven, with access by water to the North Sea.The unfinished fibre, shipped j?•om Deception Bay during the sub-Arctic summer shipping season, is unloaded from bulk ocean carriers, stored and then processed throughout the year until the following shipping season. This paper describes the unloading and storage facilities,the finishing mill and the finished-fibre storage arrangement. Details of environmental and dust control practices and West German environmental standards are discussed. A resumé of fibre markets is included."

Jan 1, 1976

By Madaah Hosseini H. R., P. Abachi, S. Miraghaei

In this study, the effects of milling time, chemical composition and heat treatment on microstructure and magnetic properties of nanocrystalline Fe-Si (6.5-25 at.% Si) alloys prepared by mechanical alloying have been investigated. The results show that increasing the milling time or the Si content, decreases the lattice parameter and increases the internal microstrain. The prepared powders mainly consist of micron-sized particles with an average grain size of less than 20 nm. The specific saturation magnetization values are slightly less than those of single crystal or conventional Fe-Si alloys and decrease as Si content increases. The coercive force values of the nanocrystalline as-milled powders are much higher than those of corresponding Fe-Si bulk alloys with a minimum at 13.5 at.% Si. The values of coercive force decreased after annealing but it seams that the residual strain developed during milling is not the major contributing factor to the higher values of coercive force in the mechanically alloyed powders and nanocrystals behave as single-domain particles without exchange interaction between them.

Jan 1, 2006