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By YONGQIONG YANG, Ning Wang, CHONGGUANG LUO, LI ZHU, Hanjie Wen, SHENGJIANG DU, Hannian Gu

Niobium in kaolin clay from the Late Permian sequences was reported in the range of several hundreds of micrograms per gram and was considered as a potential resource for its high concentrations and large areal distribution. Ti-bearing minerals associated with kaolin clay were identified as the main host phase for niobium in some case studies. However, the correlation between the concentration of niobium and titanium is poor, and the types of Ti-bearing minerals and modes of occurrence of niobium are not clear. Typical kaolin clay samples from the Late Permian sequences from southwest China were characterized, and the final products derived from kaolin clay sample were investigated using XRF, ICP-MS, XRD, SEM, and TEM (EDS). The results reveal that there were three types of TiO2 mineral phases in the clay samples: (a) massive TiO2 minerals and (b) aggregates of nano TiO2 minerals did not contain niobium while (c) granular TiO2 minerals were the source of niobium from the EDS analysis. The granular TiO2 minerals included anatase and rutile, both of which were the sources of niobium in kaolin clay in the current study. The findings are of great theoretical implication for source and origin study of Ti-bearing minerals and guidance for separation and recovery of niobium from kaolin clay.

Nov 30, 2020

By T. Gupta, T. Ghosh

Rare earth elements (REEs) and their compounds are essential in a multitude of mundane and sophisticated applications such as renewable energy technologies, catalysts, medicine, and defense applications. The global supply deficit could be attributed to the destabilization of REE market that has, as a result, incentivized indigenous production of REEs. Cost-effective and environmentally benign opportunities are being explored for the production of REEs from non-conventional mineral sources including coal and coal by-products to stabilize the supply chain. Coal from Healy coal mine and Wishbone Hill deposits in Alaska have been quantified for REEs and were found to possess elevated total REE concentrations as compared to world average levels (60– 70 ppm). The objective of the study was to concentrate the REEs in the froth phase by froth-flotation of the fine size fraction (< 75 μm). A Box-Behnken design of experiment was employed to ascertain the main and interaction effects of operational parameters on response variable by analyzing 3D response surfaces. Experiments were carried out to maximize REE recovery and concentration by modeling and optimization of three operating variables (frother dosage, pulp density (% solids), and collector dosage). Based on the results, the optimum flotation conditions for maximum recovery at an elevated concentration of REEs in the froth fraction was obtained at 4.2% solids and 32.7 ppm of frother dosage for Healy sample and 10% solids and 37.9 ppm of frother dosage for Wishbone Hill coal sample. The quadratic relationship between the input and response variable was found to be independent of collector dosage suggesting good surface hydrophobicity and floatability of the two coal samples.

By George W. Heunisch

The properties of Neutra-Fix® and Neutra-Ment® , two new lime substitutes for the treatment of acid mine drainage (Arm), have been compared with lime and Alkament®, two products presently in use for AMD treatment. The two new products are basically dolomitic byproducts and produce sludges that are more compact than those from lime. Sludge settling rates are faster than lime with iron concentrations after 24 hours that comply with EPA regulations. Material utilization and optimum pit are reported.

Jan 1, 1984

By R. K. Mensah-Biney, M. T. Hepworth, K. J. Reid

The loading characteristics of gold-bromide species onto activated carbon were evaluated using a batch system. The overall loading of gold onto activated carbon was rapid for the first few hours, but it continued without cessation as a result of the reduction of gold. Therefore, conventional equilibrium considerations were not applicable. Although loading continued slowly after several days, an abnormally high, loading capacity value of 10-12 meq/g carbon (650-800 kg Au/t) could be attained in 72 hours. The loading of gold-bromo species by activated carbon was by the mass transfer of (AuBr4)- species to the external surface to be reduced to metallic gold by carbon. Elution of gold from loaded carbon was feasible provided the carbon had not been loaded to high capacity values. If loading is carried to high levels, complete elution becomes impractical, and the gold may be recovered by ashing the carbon. For the high loading capacities observed, this option would appear to be cost effective. The effect of several variables on the loading capacity of the activated carbon for gold-bromo species is discussed.

Jan 1, 1994

By B. L. Gibbs

The mining industry is constantly in a state of flux -boom or bust; mine openings and closings. Part of the reason is the nature of ore deposits -they are there or they are not. Once they are mined, they are reclaimed and the move is on to the next deposit. Risks are usually high, and payoffs can be great or not so great. Many factors go into making a property payoff, and mining companies are continually searching for ways to remain profitable as long as possible. Computers and the people who can make them work are one of the ways available to improve productivity and ensure this happens. Computers have been used in the mining industry for the last 30 years (and more in a few cases). During the past 10 years, the explosion of micro-computing has changed how many mining companies do their work.

Jan 1, 1993

By Leena Suopajärvi, Karin Käär, Marcin Szumny, Jari Joutsenvaara, Md Ariful Islam, Helmut Mischo, Georg Meissner, Ossi Kotavaara, Catalina Vrabie

This study outlines implemented tactics and results for community empowerment through participation in questionnaire surveys, educational programs, and discussion on sustainable sourcing from new critical raw materials (CRMs) projects. Utilising questionnaire surveys, including the Public Participation Geographic Information System (PPGIS), the research gathered public opinions from Estonia, Germany, Poland, and Zambia, receiving 1,068 responses. These responses addressed various social, economic, and environmental issues related to CRM projects. Feedback from educational courses with participants from over 25 nations and public events provided additional insights. The collected data and feedback offer crucial input for advancing sustainable and responsible CRM sourcing strategies in these regions.

Feb 1, 2025

By Enrico Pavese, Tim Kearney, Stefan Lemke

Watertightness is of central importance in hydraulic and underground structures but has always been associated with a risk, as demonstrated by the very high impact that water inflows have on the damage of linings and infrastructure (Howard, 1991; Sandrone and Labiouse, 2011). Concrete is vulnerable to groundwater and chemical contaminants in the soil. These can leach into the pores and cracks of the concrete and degrade its integrity, causing spalling and corroding the reinforcing steel. Moisture migrating into the building can also degrade structural elements over time and lead to mold and other hazards to occupants’ health. In this connection, the demands placed on the setup and detailed design of the seal depending on the negative influence by water on the one hand and on the other hand on the function of a construction in view to its watertightness classification. Thus, the reliable functioning of a seal is of particular significance in the case of traffic tunnels, which are not easily accessible for all subsequent repairs after the construction in seepage water and especially when located in a pressure water zone (risk–cost assessment). Requirements for the long-term efficiency and quality of underground structures have increased in recent decades. Today, the standard lifetime requirement for an underground infrastructure project is 100 to 120 years and, in some cases, even higher. This calls for high increased attention to the durability of the whole structure and of each individual element. Standards, which started as application guidelines given by the manufacturers, are available in the market since the 1980s and are constantly adapted to the current developments in various technical committees. Differentiations are made between: Manufactures application guidelines, case studies or published articles Test standards for the laboratory to guideline the testing procedures (air temperature, type of test equipment, dimensions, test speed, test duration, concentration, type of liquids, monitoring, tolerances, interpretation of results, documentation, etc.), developed by committees based on material and laboratory experts Application standards, which include test standards but also the related minimum performance requirements (values) for material, processing, and quality assurance (practical tolerances), developed by committees based on a wide range of experts (e.g., designers, construction companies, applicators, manufactures, owners, test institutes, quality engineers) and therefore also based on a wide field of experience, different views and up-dated case studies. In the following there are some examples of guidelines and published information’s, ranked according to the year of issue, which are relevant for the development of waterproofing specifications in the tunnel industry:

Jun 13, 2023

By G. Pan

A geostatistical approach is proposed for the design of infill drilling programs. The method is consisted of three major steps: developing geological favorability models, delineating mineralization and ore envelopes, and classifying reserves or resources. Geological modeling aims at developing favorable geological zones in which drilling is designed. Modeling mineralization and ore envelopes establishes criteria on potential blocks to be drilled. Top target blocks should be those included within ore envelopes. The framework of resource categories includes five types: probable reserves, indicated reserves, indicated resources, possible resources, and barren. Indicated reserves or resources are the top priority to be drilled for the definition of minable reserves. Possible resources may be considered as targets for further exploration. The algorithms involved in the analysis include indicator favorablity analysis, ordinary kriging, and indicator kriging. A case study presented here involves a gold deposit of Carlin type. The deposit was delineated by a sparse drilling program with 230 feet of average spacing. The infill drilling program designed by the new method suggests a significant reduction on the number of holes from a regular-grid infill drilling pattern.

Jan 1, 1995

By G. V. Henderson

Large reserves of high calcium limestone have been outlined in the Redwall formation at Nelson, Arizona. Geologic mapping, core drilling and shallow seismic refraction studies have outlined more than 100 million tons of high quality, chemical and metallurgical grade limestone in the Mooney Falls member of the Mississippian Redwall Limestone. Well developed Karst zones in the Redwall were delineated by field mapping, seismic profiling and core drilling. Development of large reserves of high quality, thick beds of limestone near the present mine and rail facilities was the basis for the current mine and plant expansion. When completed in 1978 the planned 1800 Tpd production will represent the largest lime operation in the Western United States.

Jan 1, 1978

By H. Kellerwessel

This paper refers to the new crushing and grinding process, which was invented by Professor Schönert (Ref.1), Clausthal, Germy (author of one of the papers presented at this meeting). The process is known as high pressure particle bed comminution or interparticle crushing. Several papers by Professor Schonert and his coworkers and by specialists of the companies producing the necessary equipment under license agreements already described fundamentals of the process, the equipment used, results of lab size and large scale tests and finally the first results of truly commercial operations (Ref .2 to 11). Therefore it should be sufficient to summarize the main facts here: - To a bed of bulk material a pressure of more than 50 MPa is applied. Comminution is achieved mainly by the pressure which one particle transfers to the other and not by squeezing single particles between the working surfaces of some crusher or grinding media.

Jan 1, 1987

By P. J. Bethell

In the froth flotation process the detrimental effect of slimes on the froth flotability of valuable minerals has long been known.1 Work by Aplan2 on the froth flotation of coal has shown that the presence of clay slimes causes loss in flotation selectivity, and recovery of combustibles. Obviously then the presence of clay slimes to any great extent in the froth cell feed in a coal preparation plant is undesirable. This problem is exacerbated in plants treating raw 600 um (28#) by zero material due to the variation in flotation with size. The net effect of this phenomenon in a bank of cells treating raw minus 600 µm (28#) material s that by the time adequate flotation of the coarsest size fractions has occurred the finer sizes are already producing undesirable high ash material, which often leads to unacceptable overall quality. Reduction in aeration rate and/or chemical addition to combat this, further decreases the flotation rate of the coarsest fraction leading to heavy losses of coarse low ash coal to the tailings. The above mentioned characteristics formed a key aspect of the fine coal circuitry design at Elk Run Coal Company in Sylvester, WV. The plant was designed to produce compliance steam coal (less than 1.20 lbs. S02/million b.t.u.) Desliming ahead of the froth flotation was included, as the slimes in the plant feed were clay rich, had very high ash levels, and low potential recovery. Lab testwork had also shown that poor selectivity would be expected if raw minus 600 um (28#) material was froth floated.

Jan 1, 1986

By A. D. Rovig

Metallurgical evaluation of autogenous grinding of Anaconda&apos;s Berkeley Pit ores indicated that tonnage throughput increases, at a finer flotation feed size, were possible by converting autogenaus mills to steel ball mills. In addition, initial test work showed that the improved grind resulted in slight recovery gains in subsequent flotation processing.

Jan 1, 1974

By Yang Zhao, Wanping Wang, Siqing Liu, Shuming Wen

"In China, most reserves of rich iron ores have now been depleted and sustainable development of low-grade iron ores has become a critical discussion topic in the mining industry today. The aim of this study was to evaluate the applicability of beneficiating a low-grade, hematite-magnetite ore (assaying 18.64% Fe) for subsequent utilization. In this study, process mineralogy and beneficiation of the ore were carried out in the laboratory. First, mineralogical investigation shows that the main metal minerals are hematite, magnetite and a little octahedrite that cannot be used at present, and the main gangue minerals include albite, quartz and ankerite. Based on the above, a combined process of magnetic separation and gravity concentration has been developed by using laboratory low- and high- intensity magnetic separators and a slimes shaking table, respectively. Factors affecting these separation methods are discussed, including process mineralogy on the tailings of the high-intensity separator, where the iron minerals were found to be finely disseminated in the gangue as inclusions. By applying a two-stage grinding step and a magnetic separation stage together with gravity concentration, a marketable iron concentrate assaying 60.79% Fe at a recovery of 60.23% can be obtained, when the feed assays 18.75%Fe, which provides some useful information for the sustainable use of low-grade iron ore.IntroductionIron is the world’s most commonly used metal. Steel, of which iron ore is the key ingredient, represents almost 95% of all metal used per year, primarily in structural engineering applications and for maritime purposes, automobiles and general industrial applications. By the end of 2009, the iron and steel production in China ranked the first in the world, and reached 0.567 and 0.537 billion tons, respectively. The domestic supply of iron ore was 0.88 billion tons and about 0.628 billion tons of iron ore were imported in 2009."

Jan 1, 2015

By Derek J. McCracken, William G. Holroyd

Emery is a rock that at one time held a large share of the abrasives market. The introduction of synthetic abrasives, however has forced it to settle for only certain niches in the marketplace. This loss of market share is due mainly to the higher amounts of impurities and weaker internal structure that naturally occurring minerals have compared to manmade materials. The use of rocks and minerals as abrasives dates back to early man, who used flint, quartz, and other natural materials to fabricate various tools. During the 19th century, with the Industrial Revolution imminent, the character of the abrasives industry was changed forever as synthetics were introduced. Frank B. Norton is credited with producing the first manmade abrasive when, in 1855, he manufactured a vitrified grinding wheel using emery grit and clay. Before Norton&apos;s accomplishment emery had been the only commercially available abrasive. The latter part of the 20th century has seen synthetics capture an increasing share of the abrasives market from natural materials. The term emery is believed to have been derived from the words emeri (French), smeriglio (Italian), and smiris (Greek). The term corundum, for the principal mineral of emery, seems to have originated from kauruntaka, the Indian name for the mineral. GEOLOGY Emery is a gray to black, granular rock comprised of various minerals including corundum (A1,0,), an iron-bearing mineral (usually magnetite-Fe,O,, hematite-Fe,O,, or hercynite- FeAI,O,), and several trace impurities such as mullite, titania, silica, and magnesia. The hardness of emery normally ranges between 7 and 9 on the Mohs scale, depending on its mineral com- position and level of impurities. Corundum, the hardest mineral in emery, typically has a hardness of 9. The specific gravity of emery ranges from 3.2 to 4.5, also depending on mineral composition and purity. The crystallography of each mineral contained in emery differs somewhat. Corundum exhibits an hexagonal crystal structure, whereas magnetite forms within the isometric system, frequently as octahedral crystals. Hercynite, an iron spinel, is also isometric. Hematite has an hexagonal structure but often is found as botryoidal and reniform masses. Principal deposits of commerical emery are found in the United States, Turkey, and Greece. In the United States two emery producers in the Westchester County-Peekskill area and one in the Cortlandt County area of New York closed their mines in the late 1980s. Commercial production in the United States now comes only from the western Cascade Range in Oregon. The emery in New York has a typical A1,0, content of 41.5%. Most of the rock is not true emery because it contains a mixture of spinel and magnetite but very little corundum. The deposits are of Late Ordovician-Early Silurian age and consist of veins in which emery is mixed with olivine, pyroxene, and hornblende. The veins evidently were formed by contact metamorphism and are surrounded by Precambrian schists that contain mica, sillimanite, cordierite, garnet, and quartz. The deposits in Oregon were formed during Miocene time by the contact metamorphism of ferrunginous bauxite by intrusive lamprophyric dikes and plugs. Emery is found in thin layers bordering these tabular dikes, which are usually oriented perpendicular to bedding, and in "surficial placer deposits. The emery deposits in Turkey occur as small, massive, lens- shaped bodies and as surficial placers. They are believed to have formed during Permian and Triassic times. In Greece the principal site of emery production is at Cape Emeri on the Island of Naxos. These deposits consist of lenticular masses of emery surrounded by marble. They originated during Mesozoic time, evidently by metasomatic replacement. Smaller deposits on several other Aegean islands were formed by the metamorphism of bauxite or other alumina-rich materials.

Jan 1, 1994

By Richard Emberley, Timothy Shaw, José L. Torero, Jurij Karlovsek, Timothy Gibson

"Tunnel closures are highly undesirable and the lengthiest are generally attributed to structural failures (e.g. Mont Blanc). Although historical data shows structural failures are closely linked to fire, design parameters for tunnel safety are not well defined. Current research has focused on defining the fire heat release rate and temperature, but these parameters cannot be easily used to determined structural performance. The energy transferred to the structure, the heat flux, is required but current literature lacks these values. Full scale experiments were undertaken on passenger vehicles resulting in heat fluxes between 20-70kW/m2. Analysis shows a vehicle fire’s duration is closely linked to its mass. Further analysis shows small vehicle fires can be scaled as a function of the tunnel diameter and the characteristic height of the desired vehicle. The present work provides engineers an appropriate design methodology to undertake informed thermal-structural analysis to minimize the risk of tunnel structural failure.INTRODUCTION Quantifying the effects of a tunnel fire depends on many factors such as the type of occupants, their vehicles and spacing, ventilation conditions and the geometric shape of the tunnel (Ingason and Lonnermark 2011). For design engineers investigating the thermal-structural performance of a tunnel, these factors are typically converted into spatial and temporal temperature distributions (Usmani et al. 2001) using various design curves such as those of ISO834-1, Hydrocarbon, Rijkswaterstaat (RWS) or RABT-ZTV (Promat 2013). However, to define a temperature profile through a structural element these curves require a heat transfer model that incorporates an appropriate boundary condition. The appropriate boundary condition is the net heat flux which is the result of a complex energy balance. For use in heat transfer calculations the net heat flux must account for the tunnel geometry as well as thermal properties of a given structural element and all other surfaces and mediums affecting the transfer of heat (Torero 2014)."

Jan 1, 2016

By N. Damiano, C. Zhou, R. Jacksha, J. Srednicki

Modern electronic devices and systems used to enhance miner safety and health are becoming commonplace in underground coal mines. The ability for these devices and systems to function properly in the presence of electromagnetic emissions from other electronic and electrical devices and systems is not entirely understood. To investigate potential electromagnetic compatibility issues of critical mine electronic devices and systems, researchers from the National Institute for Occupational Safety and Health (NIOSH) are conducting surveys of electromagnetic emissions in underground coal mines. This paper presents the measurement system, methods, and results of electric field electromagnetic emission surveys conducted in three underground coal mine environments in the frequency range of 10 kHz to 1000 MHz. The survey data show that in some environments electric field electromagnetic emissions in underground coal mines approached or slightly exceeded limits as defined by other industrial sectors.

Mar 2, 2022

By Michael G. Zabetakis

Effective accident prevention programs utilize a broad spectrum of activities, including meaningful training programs. In practice, such programs must be directed towards specific, defined needs. These needs are considered here for three categories of employees: new, re-assigned, and experienced.

Jan 1, 1983

By William P. Lorenz

Overlying the sulfide mineralization at Anamax Mining Company&apos;s Twin Buttes Mine is an oxidized zone up to one hundred meters in thickness. The principal copper minerals in this zone are chryso-colla, tenorite, cuprite, native copper and copper-manganese-iron wad. This ox¬idized zone also contains minor amounts of uranium ranging in concentration from 0.002 to 0.010 percent. Since pit development through 1980, some 38 million tonnes of oxide ore with copper contents greater than 0.6 percent have been brought to the surface. Copper in the oxide ore is extracted at Twin Buttes in, an agitated sulfuric acid leach plant followed by solvent extraction and electrowinning producing 90 tonnes per day of copper cathode. During leaching of the oxide ores small amounts of uranium are solubilized along with the copper values. This is not limited to Twin Buttes as most acidic copper bearing leach solutions throughout the southwestern United States contain small amounts of uranium.1

Jan 1, 1982

By Robert W. Bruhn

State and federal regulations require that surface mine overburden be investigated in advance of mining for naturally occurring earth materials that are detrimental to animal and plant life or to uses of water. Proper identification of these toxic materials is necessary to permit development of environmentally sound reclamation programs. Intensified use of present laboratory methods to meet anticipated testing demands would be both costly and time consuming. This paper discusses the desirability of and general requirements for a geophysical system capable of locating toxic zones in the overburden of surface mineable lands of the Northern Great Plains Coal Province. The paper (1) identifies the types and character of naturally occurring overburden substances that must be investigated in advance of mining, (2) discusses the economic justification for development of a geophysical system to replace or to complement conventional laboratory test methods, and (3) discusses the potential applicability of downhole geophysical methods to overburden analysis.

Jan 1, 1981

By Cleland N. Conwell

The term "tender tundra" is a myth---a well-developed myth, but contrary to the fact. Any area that supports herbivores must have a plant base to supply food, In Alaska, herds of caribou migrate and live north of the Arctic Circle. And, if there is enough growth in the moss and lichens and arctic grass to support a caribou herd, the "tender tundra" can heal after it has been disturbed by mining. Another myth is that Alaska is an ice box. Actually, many areas In the state---particularly the Interior---have a high agricultural potential. Nevertheless, the fact remains: whether it is reclaimed by advancing the productivity from forest to agriculture or is allowed to remain a wild-life habitat, Alaskan land will revegetate. Reseeding speeds reclamation, but left to nature, native species will reclaim the land whether it was disturbed by forest fires, roads, villages, or mining. In fact, it is impossible to find many of the old gold mining camps.

Jan 1, 1975