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By Naeimeh Shabani, Hamid Mirzaie, Javid Sadeghi, Hoda Jafarizadeh-Malmiri, Afshin Javadi

Iron oxide nanoparticles (Fe3O4 NPs), despite their small size, are stable and have a large surface area that allows for absorption and removal of ions as well as turbidity in a short period of time. Thus, the present study addressed the synthesis and characterization of Fe3O4 NPs synthesized using the co-precipitation method and evaluated their effect on the coagulation process in water treatment. The Fe3O4 NPs characteristics were evaluated as follows: magnetic properties were measured using a vibrating sample magnetometer (VSM), surface area using Brunauer–Emmett–Teller (BET), crystal phase using X-ray diffraction (XRD), and morphology using field emission scanning electron microscopy (FESEM). In addition, the effects of the synthetic Fe3O4 NPs on the turbidity reduction of water in various pH levels were evaluated. The synthesized Fe3O4 NPs were without any impurity in the sizes of 22–32 nm, surface area of 99.6 m2/g, pores’ mean diameter size of approximately 10.6 nm, and maximum magnetic saturation of 66.21 emu/gram (emu/g). Using 0.2 g of synthetic Fe3O4 NPs with an initial turbidity of 17 NTU and pH of 6 could reduce all water turbidity (100%). Considering the cheap and facile production and separation, as well as the possibility to reuse them and reduce the sludge water content, iron oxide Fe3O4 NPs can be effectively used for turbidity reduction in the water treatment process.

Oct 26, 2020

By J. M. Wood

Green algae have been found to be much more resistant to heavy metals than blue-green algae. Several mechanisms for resistance to toxicity have been recognized in laboratory strains of Cyanidium, Chlorella and Chlamycomonas. Cyanidium and Chlorella both grow at low pH in acid mine water. Cyanidium removes metal ions from solution by precipitation as metal sulfides whereas Chlorella complexes metal ions to the cell surface i.e. cell wall) and therefore functions as an efficient ion exchange vehicle. We have shown that Ca2+, Mg2+, K+ and Na+ are of critical importance in both the resistance and bioaccumulation of toxic heavy metals.

Jan 1, 1986

By Jaeheon Lee, Junmo Ahn, Jiajia Wu

To reduce the environmental footprint of hydrometallurgical processing of black mass from spent lithium-ion batteries (LIBs), a green leaching system based on glycine and sodium metabisulfite (Gly-SMS) was proposed. The leaching study demonstrated that the highest cobalt and lithium recoveries of 100 percent and 99.8 percent were achieved under optimal conditions. The leaching mechanism revealed that the dissolution of LiCoO2 in the Gly-SMS solution followed the shrinking core model. The apparent activation energies for cobalt and lithium were determined as 48.05 and 41.51 kJ/mol, respectively, indicating a surface chemical reaction controlling mechanism. The leachate was then processed by an acidification- precipitation technique with oxalic acid as the precipitant to remove cobalt. Glycine complexes with metal ions by zwitterionic ligand and recycles in the leaching-precipitation circuit, reducing the reagent cost. Compared to other studies, this leaching system has near-neutral operating conditions and is cost-effective, making it an economically viable alternative for treating cathode materials from spent LIBs.

Dec 1, 2024

By M. Stefanakis

Respect for the people is one of the main values of S&B. Such respect needs to be manifested by actions ensuring the bodily and spiritual integrity of personnel in pursuing their work. The ultimate target is to achieve zero accidents by developing the culture and infrastructure required to support it. Within this framework, the following proactive safety practices were introduced in 2004 and are implemented at S&B Greek sites: (a.) Management Safety Visits (MSVs) of shop floor operations to address safety attributes of work guidelines, (b.) Monitoring compliance with critical work guidelines, using a ?safety barometer? tool. The proactive nature of both above systems, facilitates communication with employees on safety behaviors and their adoption in our facilities at Milos and Fokis, has been successful. Above all, these practices corroborate the management?s concern for the people and its commitment to continuously improve the working environment.

Jan 1, 2007

By Betty L. Gibbs

The ultimate objective of mine design is to determine the development and untilization of mining resources. Computer Aided Design (CAD) and automated mapping are becoming very popular in engineering and in mining. Any computer program which produces a design or model with the interaction of an engineer can be considered computer-aided design (CAD), but' the term CAD is often associated with interactive graphic design and mapping capabilities. Graphics can be effectively used to describe and model two-or-three dimensional mine workings, orebodies, and geologic structures. Interactive computer graphics is applied to mine design with a combination of deposit modeling techniques and the use of AutoCAD for interactive graphics and mapping. The combined system can perform a large part of the calculations and drafting work for geologic and mining design. Using computer calculation and graphics techniques, comparisons of alternatives, can be made quickly.

Jan 1, 1989

By William J. Miles

The markets and applications of Wyoming bentonite deposits are primarily determined by the functional properties of a bentonite ore which results from the unique mineralogy and chemistry of each deposit. Commercial bentonite products contain sodium montmorillonite as the major mineral component, with minor concentrations of accessory minerals such as quartz, opal (silica hydrate), mica, feldspar, gypsum and zeolites. The chemical composition of the sodium montmorillonite influences the functional properties of the bentonite in significant ways. The type and concentration of various accessory minerals also influence the acceptability of the bentonite in each market.

Jan 1, 1995

By R. L. Wiegel

Some of the mineral deposits that are being processed today, and especially those expected to be processed in the future, have relatively low compositions of the valuable mineral. With these low-grade ores, it is necessary to be able to design processes that are sufficiently low-cost to permit exploitation. One approach to minimizing the capital and operating costs for these processes is to use the capabilities of computer process simulation in the design phase of development, to make important technical and economic decisions regarding the evaluation of alternative process flow schemes, the selection of equipment and the choice of operating conditions. There are mathematical simulation models for most mineral processing operations, including several each for size reduction, size classification and mineral separations. To be able to tie these individual operating models together in an integrated mineral process simulation, however, it is important, in fact in some cases essential, that there be a model which describes how the mineral system responds to size reduction in making the liberated valuable and waste mineral particles available for concentration or rejection operations and the locked particles available for possible recirculation. This, then, is the role played by the mineral liberation model, showing the relationship between particle size, quantity and composition throughout the process.

Jan 1, 2011

By Lloyd H. Yeager

Good morning gentlemen. I'm very pleased to be a part of this fine program for the Society of Mining Engineers. Gypsum, as many of you know, is one of the most unique minerals on earth. The very excellent presentations which you have just witnessed, revealed the geological aspects of gypsum operations. It is not our purpose this morning to pursue this subject further. Instead, we felt you would be interested in some of the uses of gypsum . . . and what the future holds for gypsum products. To help accomplish this, we're going to first show the Gypsum Association's new film, "Shape Of The Future. ' This short movie traces gypsum f ram mines and quarries to its ultimate destination in homes, schools, offices -- in virtually every type of construction. We think you'll be particularly interested in the description of gypsum's fire resistive nature.

Jan 1, 1965

By E. R. Pantos

US coal production increased 3% to a record 832 Mt (917 million st) in 1987, according to preliminary Energy Information Administration (EIA) data. Most of the increase was due to the unusually warm summer and the increased coal-fired electricity demand for air conditioning. Drought conditions in the Northwest lowered hydroelectric generation, contributing to the higher use of coal by electric utilities. However, excess production capacity and increased competition from natural gas added further downward pressure on delivered coal prices, continuing the declining price trend of the last several years. Coal production by region Appalachian coal production reached 402 Mt (443 million st) in 1987. This is about 3% more than in 1986 and just short of its 1984 peak. Virginia produced 7% more than its 1986 level, due to increased coal-based electricity demand. Smaller percentage increases were attained in eastern Kentucky, Pennsylvania, and West Virginia. Ohio and Alabama were the only major coal-producing states in Appalachia that produced less coal in 1987 than in the previous year. In the Interior region, 1987 coal production reached a record 182 Mt (201 million st), about 2% above 1986. Illinois is the largest coal-producing state in that region. Production there fell about 3.7%, primarily because of lowered demand at electric utility plants in Alabama and Tennessee. However, this was more than offset by production increases in western Kentucky, Texas, and Indiana. After falling slightly in 1986, coal production in the West resumed its upward trend to a record 248 Mt (273 million st). Wyoming is that region's dominant coal producer. It mined 7% more coal than in 1986. Wyoming's increase offset the 11% decline in New Mexico production and smaller declines in other Western states. Coal consumption and prices Domestic coal consumption reached a record 759 Mt (837 million st) in 1987. Most of the increase resulted from the unusually warm summer that led to higher than normal peak demands for electricity in the third quarter. Electric utility coal consumption was also boosted by the below-normal hydroelectric generation that resulted from low water levels in the Northwest. These factors more than offset the effects of increased nuclear power generation and competition from natural gas. As a result, coal provided 56.9% of electric utility generation in 1987, compared with 55.7% in 1986. Electric utilities consumed a record 651 Mt (718 million st) of coal. While electric utility coal consumption increased, the average cost of coal to utilities was down, from $1.58 per million Btu in 1986 to $1.52 in 1987. The average price of coal delivered to utilities in 1987 was $35.09/t ($31.84 per st), the lowest since 1981. Coal prices were held down by a glut of coal supplies and by a decline in the average price of natural gas to electric utilities. Coal consumption at coke plants in 1987 was 2.6% above the 1986's 32.5 Mt (36 million st). This increase reflects steel's recent resurgence. Coking coal demand, though, was reduced by the increased use of continuous casting and electric furnace technologies. The average price of coal delivered to coke plants fell from $56.02 to $51.35/t ($50.83 to $46.59 per st). Coal consumption in the industries other than coke plants amounted to 68.2 Mt (75.2 million st) in 1987, slightly less than in 1986. Coal lost part of its market share to natural gas, which was priced favorably relative to coal. The average price of coal delivered to manufacturing plants was at its lowest level of the current decade. It fell from $39.50/t in 1986 to $37.27/t ($35.84 to $33.81 per st). Residential and commercial coal consumption fell to 6.2 Mt (6.9 million st) that is 9.8% below 1986 and the lowest since 1980. This decline is also attributed to the relatively low price of natural gas in 1987. Coal stocks Coal consumers held 169 Mt (186 million st) of coal stocks at the end of 1987, 5.9% above the 1986 year-end level. Most of this increase was due to stockpiling by electric utilities in anticipation of a possible strike by the United Mine Workers of America early in 1988. Stocks at electric utilities increased to an estimated 154 Mt (171 million st) at the end of 1987, 5.6% higher than the previous year. This was much lower than 1984's stock buildup. Coke plants increased their coal stocks by 30% in 1987 to 3.5 Mt (3.9 million st), rebounding from the unusually low inventories of 1985 and 1986. Other industries increased their stocks slightly in 1987. Coal producers and distributors ended 1987 with 25 Mt (28 million

Jan 5, 1988

By George K. McCord

It is a pleasure to participate in this Fall meeting of the Society of Mining Engineers to discuss energy conservation trends in the cement industry. Energy is the "life blood" of American industry, and the ability to use available energy resources efficiently may well determine the future of our nation and of its industries. The Federal Energy Administration has classified cement manufacture as one of several energy-intensive industries in the U.S. and has selected the Portland Cement Association to make a detailed study of possible energy conservation measures. Member companies of the Portland Cement Association represent about 85% of the cement producing capacity of the United States and 100% of Canadian capacity. Stated briefly, the purpose of the Association is to extend the uses of portland cement and concrete through research and development, market promotion, education, and public affairs work. PCA's general offices and research laboratories are located in Skokie, Illinois. Our staff of engineers, scientists, and research personnel make the PCA uniquely qualified to perform an energy conservation study of the kind requested by FEA.

Jan 1, 1975

By Richard E. Beane

For several decades, the minerals industry has used leaching techniques to extract metals from rocks whose grade was too low to be treated profitably using conventional metallurgical techniques, and, as of 1972, about 15% of domestic copper production was derived using leaching methods (Beall 1). Increasing interest is currently being directed toward solution mining, particularly with respect to copper, for basically two reasons. In the first place, geological exploration has outlined several copper deposits of large tonnage and 1m', grade which are buried at sufficient depth to preclude open-pit mining which would make such mineral deposits ore deposits. Nevertheless, these occurrences provide significant potential if they could be treated by chemical leaching in situ. Secondly, the porphyry deposits of the western united States, which provide by far the largest percentage of domestic copper, do not terminate geometrically with sharp borders. These large disseminated bodies commonly decrease in grade laterally away from volumes of rock containing ore grade metallization, and the distinction between ore and waste is strictly economic. In order to extract ore grade material from the ground, a significant amount of rock containing sub-ore-grade copper must also be removed which, when placed on dumps, is amenable to solution mining. These two considerations clearly indicate the reasons for the growing interest in solution , leaching techniques--namely the ability to exploit deeply buried low grade deposits and the expansion of reserves in deposits currently under production.

Jan 1, 1977

By R. S. Jurani

Sunshine Mining Company's Kellogg operation is the primary silver producer in the United States, and maintaining a comfortable working environment in this deep underground mine historically has been a complex and costly problem. To improve the ventilation and cooling systems at a time of declining and uncertain silver market, it was proposed to optimize the performance of existing facilities at minimum cost. This paper discusses a 2-year, $400 000 optimization program that resulted in increased total mine airflow, cooler ambient temperatures, reduced compressed air usage, and lower energy consumption by primary fans, air compressors, and refrigeration plants, thereby saving the company approximately $650 000 per year.

Jan 1, 1987

By Qingming Feng, Jinhong Zhang

A study has been carried out to apply fly ash as a high strength, water-resistant precast construction material through geopolymerization. Experiment results show that the working conditions such as water content, the concentration of NaOH, curing temperature, and curing time significantly affect the mechanical property of geopolymermatrix. Through optimization, an above-100MPa compressive strength has been achieved with the geopolymerization products. The optimum working conditions involves 10MNaOH concentration, 14–15% water content, and curing at 90 °C in an oven for 1 day or at ambient condition for 3 weeks. Adding Ca(OH)2 does not help to increase the compressive strength of the specimen.Water soaking tests show that the geopolymerization product has a very high water resistance without losing noticeable compressive strength, even after a 1-month soaking time. To elucidate the geopolymerization mechanism, microscopic techniques such as SEM/EDS (scanning electron microscopy and energy-dispersive X-ray spectroscopy), XRD (X-ray diffraction) and ATR-FTIR (attenuated total reflectance Fourier transform infrared) are also applied to investigate the microstructure, the elemental and phase composition of geopolymerization products. The findings of the present work provide a novel method for applying fly ash as a high-strength water-resistant precast construction material.

Aug 17, 2020

By A. D. Kalogeropoulos, T. N. Michalakopoulos

This paper deals with the numerical simulation of rock cutting laboratory tests using the discrete element method. The main objective is to provide a method for calibrating numerical DEM models of rock cutting in a systematic way so that realistic results are yielded. The numerical models are developed with the discrete element code Yade, which models rocks as a collection of bonded spheres. The models are calibrated in a four-step process based on the design of experiments method and optimization. The calibrated models are evaluated both quantitatively and qualitatively against actual laboratory cutting tests, in terms of the ratio of the simulated mean cutting force to the actual one and the cutting force time series, respectively. The fully calibrated models showed that the simulated cutting process matched qualitatively the actual cutting force recordings and underestimated the mean cutting force by approximately 3%. It is concluded that well-calibrated numerical simulations of the rock cutting process can provide not only a better understanding of the process itself but also quantitative data regarding the cutting force and energy requirements.

Dec 28, 2022

By Reese E. Mallette

This paper makes five major points which may be contributions to the art of limestone sinkhole engineering. First, solution cavity development in limestones is dependent in great measure on pyrite contained within the limestone. Second, rock failure is rarely involved in sinkhole problems, while soil failures are almost always the mode of occurrence. Third, draw down, depression of the water table, is a primary causative factor in sinkhole development. Fourth, lateral movement of vadose water along the soil-rock interface, sub-soil erosion, is the mechanism by which soil is stoped, raveled, piped, or removed from the soil cavern. Fifth, the ultimate or triggering factor in localizing a sinkhole collapse is any superposed mechanism which disrupts the continuity of an impermeable clay soil overburden. The above theses are presented as extensions of our observation and of published literature, with the suggestion that additional study of these mechanisms is warranted.

Jan 1, 1975

By Lana Alagha, Fardis Nakhaei, Jose L. Corchado-Albelo, Noelia Munoz-Garcia, Michèle Heitz

Sulfide tailings from past and present mining activities are important hosts of critical elements and precious metals. This review paper presented a literature survey on the recovery practices of some critical minerals containing Te from sulfide tailings with a special focus on the physical beneficiation and hydrometallurgical separation methods. Finally, a conceptual framework and possible processing flowsheets were proposed. The findings of this review will be useful for the researchers in the field of geochemistry, mineral processing, and metallurgy to evaluate the separation processes for reprocessing of mine tailings for the recovery of critical minerals.

Feb 1, 2024

By Frank Agyemang, Zainab Nasrullah, Richard LaDouceur, Mehran Saddat

To sustain the circular economy, defence applications, and other renewable technologies, recycling rare earth elements (REEs) and other critical elements from their secondary resources is important. This cause has resulted in rigorous research and development for viable extraction and separation of REEs. Previously, Sm-Co recycling has been done with technologies, which fall under the categories of pyrometallurgy, physical separation, and hydrometallurgy. All these methods have limitations associated with energy, cost, and environment. Reportedly, the chemical leaching technology has successfully recovered and separated Sm-Co. Still, it has limitations associated with slow mass transfer and leaching kinetics, and there is a need to intensify the process to make it time efficient. This approach has also adversely impacted the environment by an extensive use of toxic, corrosive, non-selective, and expensive reagents. In this research study, chemical leaching of Sm-Co was performed using this new class of solvents, Deep Eutectic Solvents (DESs), which fall under the category of ion metallurgy. Four different DESs were used, proven to be green, non-toxic, biodegradable, cheap, and selective for cobalt over samarium by 82% leaching conversion. To improve the slow mass transfer and leaching time, this new technology of resonant vibratory mixing (RVM) was also tested. RVM intensifies mixing by establishing near instantaneous, low energy mixing conditions through resonance. It has been shown to improve the adsorption kinetics and was tested for the leaching kinetics. Four combinations of DESs were prepared, which are made up of two quaternary salts: Choline Chloride and Tetra Butyl Ammonium Chloride, and three organic compounds: Oxalic Acid, Urea, and Ethylene Glycol. These combinations were used for chemical leaching of Sm-Co with leaching factors of time, temperature, and type of DESs. After leaching, the samples were tested with and without resonant vibratory mixing with conditions of time, intensity (%), and type of DESs. Samples were analysed with Induced Coupled Plasma - Optical Spectroscopy (ICP - OES). Future work will involve a life-cycle assessment to assess the RVM technology with other conventional mixers, and an extensive study of DES properties to improve selective leaching.

Feb 1, 2025

The mineral sands industry is oriented primarily toward the supply of titanium (Ti) raw materials (titanium feedstocks) for the production of titanium dioxide (TiO2) pigment and titanium metal. Titanium minerals ilmenite, rutile and leucoxene, and titanium slag and synthetic rutile are all used principally as feedstocks for the production of white TiO2 pigment. It accounts for almost 90 percent of the world?s consumption of titanium minerals. The remainder is used for the production of titanium metal, fluxes for welding rods and as a metallurgical flux in iron and steel making. Titanium dioxide pigment is produced by two alternative process routes, the sulfate process or chloride process. The bulk of the world?s titanium dioxide is derived from the mineral ilmenite, which also contains iron oxide and other minor impurities. At some mining operations, the iron present in ilmenite is removed (ilmenite beneficiation) to produce a high TiO2 feedstock (slag or synthetic rutile) typically containing between 80 percent and 95 percent TiO2. Pigment producers then further process it to produce pigment.

Jan 1, 2011

By B. A. Wills

With the increasing need to mine lower grade ores, high energy-related costs in comminution are of major concern. Very fine grinding is needed to liberate the very fine mineral particles in these ores. Not only is this expensive but it leads to greater losses in 'slimes'. In the early 1970's, 50% of the tin mined in Bolivia, 30% of the phosphate mined in Florida and 20% of the world's tungsten were lost in this way (Somasundaran, 1979). Gravity concentration techniques become unacceptably inefficient for particle treatment below 25-50µm, and even flotation fails in the ultra-fine range. Two approaches can be adopted to try to overcome this problem. The first involves increasing the efficiency of existing equipment or developing new slimes treatment processes. Gravity devices such as the Bartles-Mozley concentrator have been developed for this purpose and good recovery has been reported from 100µm down to 5µm. Such machines, however, have relatively low throughputs, so that large areas of plant space are generally required. Flotation is rapidly growing in importance for the treatment of ultra-fine minerals traditionally treated by gravity concentration.

Jan 1, 1986

By Roy A. Grancher

Construction materials indeed face a dilemma...as does the building industry as a whole. A stop & go economy; a severe drop; in housing starts; lingering indecision over just what corrective steps are to be taken or to their degree of commitment; no less basic disagreement in regard to which of the, Nation's problems is really the most pressing -- inflation or recession? Optimism has become a rare quality these days. At moat the cautious view is that this new year will see a long, hard struggle back, with hopes that 1976 at least can truly mark a dual anniversary celebration for the United States and its economic health. Yet the paradox is that once recovery does return, those very construction minerals and materials --which in recent years have experienced the ups and downs of overcapacity, shortage, and now declining demand again-- will once more face the spectre of mass inability to service revived and growing needs for its product. Mounting costs, present marginal expansion investment, and substantial lead times required for new facilities to come into production, could well form a bottleneck to economic upswing. The result again can be another cycle of shortage-induced inflation, and with it continued gyrations within the demand supply relationships of the country's building industries.

Jan 1, 1975