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By SONGHE WANG, YI XUE, PENG HOU, CAIHUI ZHU, XUANYE JIAO, Feng Gao

The abstract discusses the challenges of coalbed methane development in China due to low coal seam permeability. It highlights protective layer mining as a method to reduce in-situ stress and enhance permeability for improved gas drainage and disaster prevention. The study involves experimental and numerical simulations to analyze gas migration and permeability changes during stress release. It includes a stress-strain-seepage coupled test on coal, development of a mathematical model for coal seepage under mining unloading, and a numerical model based on the Wulan coal mine to explore in-situ stress release, permeability evolution, and gas drainage in an unloaded coal seam. The aim is to demonstrate the effectiveness of combining protective layer mining and gas drainage technology for gas outburst risk elimination.

Mar 14, 2022

By Robert Hochscheid

When the original water-only cyclone patents were established in the 1950?s, the supplies of low cost oil and natural gas were abundant and low selling prices for metallurgical and steam coal provided little incentive for developing more sophisticated coal cleaning systems. Bituminous coal sold for less than $5.00 per ton, and in this period many domestic coal producers discarded to the slurry pond the coal finer than 0.5-mm. For many producers, the selling price would not permit the recovery of the capital and operating costs required for dewatering and drying the fine coal. Water-only Cyclones Clean Fine Metallurgical Coal The first broad interest in the water-only cyclone became evident in the mid- 19601s, and though some work was done on coarser coals, investigators were particularly interested in cleaning coal finer than 0.5-mm. Flotation was the only fine coal cleaning method that was broadly accepted, but short-comings were recognized and investigators were looking for an effective fine coal cleaning device or system. Because of the greater market value and the need for reducing pyritic sulfur in metallurgical coals, much of the development work of the 1960's was done on coking coals.

Jan 1, 1981

By Jim Huerta

Diesel fuel usage in the mining industry continues to escalate. This is because approximately 60 percent of all mined materials are surface extracted by large equipment using diesel fuel, which continues to increase in cost per gallon. For example, coal mining uses large equipment such as wheel loaders, wheel dozers, draglines and [ ] dredgers. In one year, three of the largest U.S. coal mining operations consumed approximately 567 million to 852 million L (150 million to 225 million gal) of diesel. At an approximate cost average of $3.25/gal the expenditure on diesel is $487 million to $731 million per year. So, are there any solutions that could reduce this cost burden? Yes, there are. Coal mining companies can extract less ore; use more efficient extracting equipment that consumes less fuel; wait for a significant reduction in the cost of fuel; or find and use technology that would create efficiencies that would lower the cost. Nanotechnology is one such technology that might provide the means to create the efficiencies that will significantly lower diesel fuel costs.

Jan 1, 2011

By R. M. Parlman

Interest is increasing in obtaining incremental improvements in mineral recoveries in flotation processes because of changing world economic conditions. Research on collector reagents, long indispensable components in flotation systems may provide the cheapest and simplest route to higher metal recoveries. Sulfhydryl group - containing compounds (-SH) and their salts, e.g., dithiophosphates, xanthates and a few other derivatives are commonly used to promote the flotation of sulfide minerals. Alkyl mercaptans, another class of sulfhydryl compounds, have long been known to have collecting properties but have been relegated to dormancy for one reason or another. This paper reports results from new investigations of alkyl mercaptans, trithiocarbonates, and a petroleum oil with a variety of western domestic and Canadian ores for copper and molybdenum sulfides recovery. Specific opportunities are pointed out to the industry for mineral recovery enhancement through the use of the proper reagent combination.

Jan 1, 1980

By John M. Arnold

Several years ago it became apparent to some of our people that; there was developing a very definite need for largee coal reserves in the West to satisfy- the need for fuel for the furnaces of electric generating plants with the rapid development of, the West, of both population and industry, it was impossible for hydro-electrics plants to keep up with the ever increasing demand for electricity. In 1960, Mr. E. R. Phelps, then associated with the engineering department of Peabody Coal Company, began a search for and development of coal deposits in the very remote northeast section of Arizona near the village of Kayenta. Travel to this section of the country was not easy even at this late date, and it was an eight hour drive from Farmington, New Mexico to Kayenta, Arizona, a distance of some 130 miles. The trip was over roads that even' a-horse and wagon had trouble negotiating and a four wheel drive vehicle was about the only type of transportation that could satisfactorily traverse these roads, as testify many badly beaten sedans and coupes that tried it. Since that time a very excellent road has been constructed from Shiprock; New Mexico to Cameron, Arizona where it junctions with another excellent road that runs north to Page, Arizona and the Lake. Powell area and south to Flagstaff, Arizona on highway 66. Kayenta is a small village nestled at the foot of the Black Mesa near its northeast extremities. The coal deposits of interest were on the surface of the mesa. This location presented another problem, as the only trail to the top of the mesa was intended for walking, horseback, or a brave soul In a horse and wagon. Once again the four wheel drive vehicle was about the only answer. To reach the coal deposits you must climb the mesa, which is vertical ascent of some 1,500 feet, and then proceed southward into the bowl of the mesa with an ensuing descent of some 1,000 feet, finally coming to an elevation of 6,500 feet, at which elevation the coal outcrops become apparent.

Jan 1, 1969

By Naeimeh Shabani, Hamid Mirzaie, Javid Sadeghi, Hoda Jafarizadeh-Malmiri, Afshin Javadi

Iron oxide nanoparticles (Fe3O4 NPs), despite their small size, are stable and have a large surface area that allows for absorption and removal of ions as well as turbidity in a short period of time. Thus, the present study addressed the synthesis and characterization of Fe3O4 NPs synthesized using the co-precipitation method and evaluated their effect on the coagulation process in water treatment. The Fe3O4 NPs characteristics were evaluated as follows: magnetic properties were measured using a vibrating sample magnetometer (VSM), surface area using Brunauer–Emmett–Teller (BET), crystal phase using X-ray diffraction (XRD), and morphology using field emission scanning electron microscopy (FESEM). In addition, the effects of the synthetic Fe3O4 NPs on the turbidity reduction of water in various pH levels were evaluated. The synthesized Fe3O4 NPs were without any impurity in the sizes of 22–32 nm, surface area of 99.6 m2/g, pores’ mean diameter size of approximately 10.6 nm, and maximum magnetic saturation of 66.21 emu/gram (emu/g). Using 0.2 g of synthetic Fe3O4 NPs with an initial turbidity of 17 NTU and pH of 6 could reduce all water turbidity (100%). Considering the cheap and facile production and separation, as well as the possibility to reuse them and reduce the sludge water content, iron oxide Fe3O4 NPs can be effectively used for turbidity reduction in the water treatment process.

Oct 26, 2020

By Jackson M. Langton

INTRODUCTION The Morenci-Metcalf district is located on the southern slope of the white Mountains in Greenlee County, Arizona. Both porphyry copper deposits are four to six miles northwest of Clifton, the county seat, and the new Metcalf mine is situated approximately one mile northeast of the Morenci open pit (Figure 1). Chase Creek, a south-flowing tributary of the San Francisco River, dissects the district and separates the two ore bodies. More than 1,200 exploration and development drill holes have been completed in the district and the Morenci-Metcalf ore bodies have been delineated on a 400-foot grid. Recently initiated drilling programs have revealed new data about deeper protore and associated hypogene alteration. This information, correlated with surface mapping and petrographic studies, was utilized to propose a plausible geochronologic sequence for this region. The reasoning behind this study has been helpful in locating new ore beneath leached capping indicative of only protore mineralization. The scope of this paper is to establish a practical solution to a highly theoretical problem of ore genesis and to familiarize the reader with stratigraphic, structural, and mineralogic events responsible for localizing ore in this district. Continued research will possibly alter the proposed time span and relative displacements, but it is doubtful that the order of events will vary significantly. Geochronologic conclusions are therefore presented as general hypotheses and additional geologic mapping,

Jan 1, 1972

By J. M. Wood

Green algae have been found to be much more resistant to heavy metals than blue-green algae. Several mechanisms for resistance to toxicity have been recognized in laboratory strains of Cyanidium, Chlorella and Chlamycomonas. Cyanidium and Chlorella both grow at low pH in acid mine water. Cyanidium removes metal ions from solution by precipitation as metal sulfides whereas Chlorella complexes metal ions to the cell surface i.e. cell wall) and therefore functions as an efficient ion exchange vehicle. We have shown that Ca2+, Mg2+, K+ and Na+ are of critical importance in both the resistance and bioaccumulation of toxic heavy metals.

Jan 1, 1986

By Jaeheon Lee, Junmo Ahn, Jiajia Wu

To reduce the environmental footprint of hydrometallurgical processing of black mass from spent lithium-ion batteries (LIBs), a green leaching system based on glycine and sodium metabisulfite (Gly-SMS) was proposed. The leaching study demonstrated that the highest cobalt and lithium recoveries of 100 percent and 99.8 percent were achieved under optimal conditions. The leaching mechanism revealed that the dissolution of LiCoO2 in the Gly-SMS solution followed the shrinking core model. The apparent activation energies for cobalt and lithium were determined as 48.05 and 41.51 kJ/mol, respectively, indicating a surface chemical reaction controlling mechanism. The leachate was then processed by an acidification- precipitation technique with oxalic acid as the precipitant to remove cobalt. Glycine complexes with metal ions by zwitterionic ligand and recycles in the leaching-precipitation circuit, reducing the reagent cost. Compared to other studies, this leaching system has near-neutral operating conditions and is cost-effective, making it an economically viable alternative for treating cathode materials from spent LIBs.

Dec 1, 2024

By R. L. Wiegel

Some of the mineral deposits that are being processed today, and especially those expected to be processed in the future, have relatively low compositions of the valuable mineral. With these low-grade ores, it is necessary to be able to design processes that are sufficiently low-cost to permit exploitation. One approach to minimizing the capital and operating costs for these processes is to use the capabilities of computer process simulation in the design phase of development, to make important technical and economic decisions regarding the evaluation of alternative process flow schemes, the selection of equipment and the choice of operating conditions. There are mathematical simulation models for most mineral processing operations, including several each for size reduction, size classification and mineral separations. To be able to tie these individual operating models together in an integrated mineral process simulation, however, it is important, in fact in some cases essential, that there be a model which describes how the mineral system responds to size reduction in making the liberated valuable and waste mineral particles available for concentration or rejection operations and the locked particles available for possible recirculation. This, then, is the role played by the mineral liberation model, showing the relationship between particle size, quantity and composition throughout the process.

Jan 1, 2011

By Richard E. Beane

For several decades, the minerals industry has used leaching techniques to extract metals from rocks whose grade was too low to be treated profitably using conventional metallurgical techniques, and, as of 1972, about 15% of domestic copper production was derived using leaching methods (Beall 1). Increasing interest is currently being directed toward solution mining, particularly with respect to copper, for basically two reasons. In the first place, geological exploration has outlined several copper deposits of large tonnage and 1m', grade which are buried at sufficient depth to preclude open-pit mining which would make such mineral deposits ore deposits. Nevertheless, these occurrences provide significant potential if they could be treated by chemical leaching in situ. Secondly, the porphyry deposits of the western united States, which provide by far the largest percentage of domestic copper, do not terminate geometrically with sharp borders. These large disseminated bodies commonly decrease in grade laterally away from volumes of rock containing ore grade metallization, and the distinction between ore and waste is strictly economic. In order to extract ore grade material from the ground, a significant amount of rock containing sub-ore-grade copper must also be removed which, when placed on dumps, is amenable to solution mining. These two considerations clearly indicate the reasons for the growing interest in solution , leaching techniques--namely the ability to exploit deeply buried low grade deposits and the expansion of reserves in deposits currently under production.

Jan 1, 1977

By R. S. Jurani

Sunshine Mining Company's Kellogg operation is the primary silver producer in the United States, and maintaining a comfortable working environment in this deep underground mine historically has been a complex and costly problem. To improve the ventilation and cooling systems at a time of declining and uncertain silver market, it was proposed to optimize the performance of existing facilities at minimum cost. This paper discusses a 2-year, $400 000 optimization program that resulted in increased total mine airflow, cooler ambient temperatures, reduced compressed air usage, and lower energy consumption by primary fans, air compressors, and refrigeration plants, thereby saving the company approximately $650 000 per year.

Jan 1, 1987

By Qingming Feng, Jinhong Zhang

A study has been carried out to apply fly ash as a high strength, water-resistant precast construction material through geopolymerization. Experiment results show that the working conditions such as water content, the concentration of NaOH, curing temperature, and curing time significantly affect the mechanical property of geopolymermatrix. Through optimization, an above-100MPa compressive strength has been achieved with the geopolymerization products. The optimum working conditions involves 10MNaOH concentration, 14–15% water content, and curing at 90 °C in an oven for 1 day or at ambient condition for 3 weeks. Adding Ca(OH)2 does not help to increase the compressive strength of the specimen.Water soaking tests show that the geopolymerization product has a very high water resistance without losing noticeable compressive strength, even after a 1-month soaking time. To elucidate the geopolymerization mechanism, microscopic techniques such as SEM/EDS (scanning electron microscopy and energy-dispersive X-ray spectroscopy), XRD (X-ray diffraction) and ATR-FTIR (attenuated total reflectance Fourier transform infrared) are also applied to investigate the microstructure, the elemental and phase composition of geopolymerization products. The findings of the present work provide a novel method for applying fly ash as a high-strength water-resistant precast construction material.

Aug 17, 2020

By Lana Alagha, Fardis Nakhaei, Jose L. Corchado-Albelo, Noelia Munoz-Garcia, Michèle Heitz

Sulfide tailings from past and present mining activities are important hosts of critical elements and precious metals. This review paper presented a literature survey on the recovery practices of some critical minerals containing Te from sulfide tailings with a special focus on the physical beneficiation and hydrometallurgical separation methods. Finally, a conceptual framework and possible processing flowsheets were proposed. The findings of this review will be useful for the researchers in the field of geochemistry, mineral processing, and metallurgy to evaluate the separation processes for reprocessing of mine tailings for the recovery of critical minerals.

Feb 1, 2024

By Frank Agyemang, Zainab Nasrullah, Richard LaDouceur, Mehran Saddat

To sustain the circular economy, defence applications, and other renewable technologies, recycling rare earth elements (REEs) and other critical elements from their secondary resources is important. This cause has resulted in rigorous research and development for viable extraction and separation of REEs. Previously, Sm-Co recycling has been done with technologies, which fall under the categories of pyrometallurgy, physical separation, and hydrometallurgy. All these methods have limitations associated with energy, cost, and environment. Reportedly, the chemical leaching technology has successfully recovered and separated Sm-Co. Still, it has limitations associated with slow mass transfer and leaching kinetics, and there is a need to intensify the process to make it time efficient. This approach has also adversely impacted the environment by an extensive use of toxic, corrosive, non-selective, and expensive reagents. In this research study, chemical leaching of Sm-Co was performed using this new class of solvents, Deep Eutectic Solvents (DESs), which fall under the category of ion metallurgy. Four different DESs were used, proven to be green, non-toxic, biodegradable, cheap, and selective for cobalt over samarium by 82% leaching conversion. To improve the slow mass transfer and leaching time, this new technology of resonant vibratory mixing (RVM) was also tested. RVM intensifies mixing by establishing near instantaneous, low energy mixing conditions through resonance. It has been shown to improve the adsorption kinetics and was tested for the leaching kinetics. Four combinations of DESs were prepared, which are made up of two quaternary salts: Choline Chloride and Tetra Butyl Ammonium Chloride, and three organic compounds: Oxalic Acid, Urea, and Ethylene Glycol. These combinations were used for chemical leaching of Sm-Co with leaching factors of time, temperature, and type of DESs. After leaching, the samples were tested with and without resonant vibratory mixing with conditions of time, intensity (%), and type of DESs. Samples were analysed with Induced Coupled Plasma - Optical Spectroscopy (ICP - OES). Future work will involve a life-cycle assessment to assess the RVM technology with other conventional mixers, and an extensive study of DES properties to improve selective leaching.

Feb 1, 2025

The mineral sands industry is oriented primarily toward the supply of titanium (Ti) raw materials (titanium feedstocks) for the production of titanium dioxide (TiO2) pigment and titanium metal. Titanium minerals ilmenite, rutile and leucoxene, and titanium slag and synthetic rutile are all used principally as feedstocks for the production of white TiO2 pigment. It accounts for almost 90 percent of the world?s consumption of titanium minerals. The remainder is used for the production of titanium metal, fluxes for welding rods and as a metallurgical flux in iron and steel making. Titanium dioxide pigment is produced by two alternative process routes, the sulfate process or chloride process. The bulk of the world?s titanium dioxide is derived from the mineral ilmenite, which also contains iron oxide and other minor impurities. At some mining operations, the iron present in ilmenite is removed (ilmenite beneficiation) to produce a high TiO2 feedstock (slag or synthetic rutile) typically containing between 80 percent and 95 percent TiO2. Pigment producers then further process it to produce pigment.

Jan 1, 2011

By B. M. Davis

Characterizing exploration prospect potential has aspects that differ from those encountered during ore reserve estimation. One problem is determination of the ore reserve potential prior to acquisition of significant volumes of hard data. The evaluation is subjective and data are usually sparse and of uncertain quality. However, estimations of the ore reserve potential are commonly demanded by management before project funding will be approved. The estimations from several prospects, along with the uncertainties inherent to the estimation, are then used to compare and contrast the potential of several prospects, often with widely varying geologic models.

Jan 1, 1990

By Caroline L. Herzenberg

Recently, neutron-induced gamma spectrometry has been introduced and gained provisional acceptance as a method for continuous automated analysis of coal. Instrumentation based on this technique has been under development for and in testing at coal preparation plants and a coal gasifier. To provide a deeper understanding of, and extended capability in applying this method, theoretical calculations have been performed of the absorption of thermal neutrons by various coal compositions, and the thermal neutron capture prompt gamma emission spectra produced by these compositions have been calculated. Selected results of these computer calculations and the computer generated spectra are presented.

Jan 1, 1984

By Roe-Hoan Yoon, Kaiwu Huang

Derjaguin and Dukhin (1961) were the first to develop a model for bubble-particle interaction in flotation from first principles by considering the surface forces in wetting (or flotation) films. The model predicted that the energy barriers to bubble-particle attachment arise from the ζ-potentials of fine particles, which corroborates well with an earlier work of Fuerstenau (1957) reported for the flotation of quartz using dodecyl ammonium acetate (DAA) as collector. In the present work, a series of surface force measurements have been conducted by accurately monitoring the changes in bubble curvature during bubble-silica surface interactions. The curvature changes are then used to determine the capillary force, which is the sum of the hydrodynamic and surface forces. By subtracting the former that can also be determined from the curvature changes, one obtains the surface forces (or disjoining pressure). The results obtained as functions of pH and collector concentrations show that control of the ζ-potentials of bubbles relative to those of the silica surfaces is critical for maximizing the negative disjoining pressure, which is conducive to promoting bubble-particle attachment in flotation.

By J. L. Kearns

The importance of optimizing equipment replacement decisions becomes more critical each year due to the rising costs of buying new equipment versus maintaining old equipment. Replacing equipment when it is physically worn out, or replacing it too soon or too late relative to its Economic Life (when it is economically worn out), is very costly. After extensive literature review and research, Kennecott has developed its Equipment Replacement Guide (ERG) system which identifies, evaluates, and justifies the replacement of uneconomical equipment. The system considers such critical factors as inflation, decreasing work capability, increasing maintenance/repair and operating costs, taxes, time value of money, return on investment, salvage value, and investment tax credit. These factors are used in a system of equations which balance the costs of new equipment against the total operating costs of old equipment. The solution of the equations determines the Economic Life of equipment. Replacement of equipment at the determined Economic Life will earn the specified, required return on investment that is used in the calculation of the Economic Life.

Jan 1, 1979