Search Documents

By P. L. Crouse

"SynopsisFluorine – in the form of hydrofluoric acid, anhydrous hydrogen fluoride, elemental gaseous fluorine, fluoropolymers, volatile inorganic fluorides, and more – has played, and still plays, a major role in the nuclear industry. In order to enrich uranium, the metal has to be in the gaseous state. While more exotic methods are known, the standard and most cost-competitive way of achieving this is by means of uranium hexafluoride (UF6). This compound sublimates at low temperatures, and the vapour is enriched using centrifugal processes. The industrial preparation of uranium hexafluoride requires both elemental fluorine gas and anhydrous hydrogen fluoride (HF). HF is prepared by the reaction of sulphuric acid with fluorspar (CaF2). Fluorine gas in turn is prepared by the electrolysis of HF. Yellowcake is first converted to uranium tetrafluoride (UF4), using HF, after which the compound is treated with fluorine to yield UF6. After enrichment, the UF6 is reduced to UO2 for use in fuel elements in pellet form.South Africa has the largest reserves of fluorspar internationally, and is the third largest producer after Mexico and China. Fluorine technology has many associated difficulties, because of the reactivity of fluorine and the toxicity of HF. The main barriers to entry into the fluorochemical industry are thus the abilities to produce both HF and F2. Both these substances are produced locally, at the industrial scale, at Pelchem SOC Ltd. Should South Africa contemplate developing its own nuclear fuel cycle as part of the awaited new-build nuclear project, it will be imperative to leverage the existing skills with respect to fluorine technology, resident at both Pelchem and Necsa, for this purpose. This paper summarizes the fluorochemical skills developed locally over the past several decades, and suggests strategies for maintaining the technology base and developing it for the next generation of scientists and engineers.IntroductionFluorine chemistry has always had a very close relationship with the nuclear industry. Although the first mention of fluorspar was recorded in the sixteenth century, and the fundamentals had been well-developed by the Second World War, it was only during the Manhattan Project (Banks et al., 1994), when almost unlimited funds were made available for the large-scale industrialization of fluorine and related compounds, that the technology took off. Expertise in both the chemistry and the engineering aspects of fluorine is essential for the design and running of several of the unit processes in the nuclear fuel cycle."

Jan 1, 2015

By G. Akdogan, C. Bergmann, C. J. Coetzee, Q. G. Reynolds, S. J. Baumgartner

Submerged arc furnaces (SAF) are used extensively in the production of ferrochrome, where charge material – consisting of mixtures of carbonaceous reductants, fluxes such as silica, and ore in the form of pellets – is fed through chutes into the vessel. The feed typically forms a thick bed or ‘burden’ of solid particulates above a bath of molten material below. This burden layer surrounds three electrodes, which are typically arranged in a triangular configuration in circular SAFs. A major challenge in the industry is the availability of sought-after reductants, volatile market conditions, and increasing electricity tariffs in South Africa. A good understanding of the physical properties of the raw materials in the charge is therefore of great value in order to best deal with the reductants available at any given time, and thereby maximising furnace throughput. This paper presents a study of the effects of different particle properties on particle flow behaviour relevant to SAF operations. Discrete element model (DEM) simulations were used to estimate the sensitivity of the particulate flow of beds of charge material to properties such as the coefficients of friction, particle shape and size, and others. The present study lays the groundwork for the development of full DEM models of the SAF that will greatly improve understanding of the flow of complex mixtures of solid particles in the submerged arc furnace, and how the relative physical properties of each component in the charge can influence electrical behaviour of the burden.

Sep 1, 2021

By А. Klemyatov, T. Vologdina, U. Gordeeva, S. Zbinets, А. Kalugin, N. Rozhdestvenskiy

The plants integrated in the PhosAgro group of companies perform processes from scientific research to the project, from ore mining to shipment of fertilisers and feed additives to consumers. An extensive process chain maintains smooth interaction at all stages from research to production. As an example, the paper shows the revamp of two beneficiation plants (ANOF-2 and ANOF-3), requiring a comprehensive approach to task solving. The intention of the revamp was to increase the total yield of apatite and nepheline concentrate, taking into account the gradual decline in the quality of ore being processed and ensuring the yield stability of final products during re-equipment of the plants. At ANOF-3, the crushing and grinding cycle was modernised, the production of nepheline concentrate was implemented, and the capacity of apatite flotation, dehydration, and drying was increased. At ANOF-2 a new process chain was implemented for the production of apatite concentrate in workshops previously used for the production of nepheline concentrate. The main building was withdrawn from operation, where ore grinding, apatite flotation and apatite concentrate thickening had been carried out. The total increase in apatite concentrate yield at two beneficiation plants was 1.3 times. A further increase in concentrate production is planned. Keywords: Apatite, nepheline, fertilisers, beneficiation, flotation, column flotation machines, revamp, fine screening

Jan 1, 2020

By K. Basaure, S. Palma, R. L. Castro

"Mud rushes are sudden inflows of fine wet ore within underground mines; they can harm people and equipment as well as cause production delays. Block and panel caving mines are prone to mud rushes in their production levels, with mud flowing from the drawpoints. Different mines have developed methods to control drawpoint conditions and thus perform safe ore extraction. The aim of this study is to develop a decision matrix and apply it to samples from drawpoints for the Diablo Regimiento mine, Codelco, El Teniente Division (Chile). The Abrams’s Cone was used to perform slump tests on mud samples and characterize their consistency by setting the saturation degree and packing. The unconfined strength for different saturation degrees and packing was then evaluated. The results show that conditions for fluid response in slump tests correspond to conditions for low strength in unconfined compression tests. We also found the water content value at which the flowing consistency changes from plastic to soft behaviour according to the slump test classification for each sample. This value varied between 12.2% and 16.9%, depending on the sample tested. Finally, a fluid security factor was defined in order to design an extraction pattern for the samples tested, based on the water content. We conclude that a very densely packed ore is not prone to flowing. The flow properties depend strongly on the specific properties of the ore tested, and consequently a specific criterion should be developed for different types of ore at a particular mine. The criterion developed for Diablo Regimiento ore provides critical water content values from 11% to 15%, depending on the ore type. IntroductionBlock/panel caving has the lowest cost and the highest production rates of all underground methods (Heslop, 2000; Hubert et al., 2000). Good management of the risks is important to ensure the security of personnel and infrastructure. Operational risks for the method include rockbursts, air blasts, and mud rushes (Hubert et al. 2000). A mud rush is defined as a sudden inflow of mud from a drawpoint or other underground opening into the mine (Butcher, Joughin, and Stacey, 2000; Butcher, Stacey, and Joughin, 2005). Mud rushes can cause dilution, production delays, and damage to equipment as well as injuries and fatalities. The elements necessary for mud rushes are mud-forming material, disturbances, a discharge point, and water (Butcher, Joughin, and Stacey, 2000). All these elements are present in block/panel caving mines. Mud-forming material comes from ore milled by the caving process; water comes from underground and surface sources. Drawpoints in the production level are discharge points for the mud. Finally, several types of disturbance could trigger the mud rush phenomena: blasting, earthquakes, operation of equipment (Call & Nicholas, Freeport McMoRan, and Hydrologic Consultants, 1998; Jakubec, Clayton, and Guest, 2012), arch collapse above drawbells (Butcher, Joughin, and Stacey, 2000; Butcher, Stacey, and Joughin, 2005; Jakubec, Clayton, and Guest, 2012) and ore drawing (Butcher, Joughin, and Stacey, 2000; Butcher, Stacey, and Joughin, 2005; Call & Nicholas, Freeport McMoRan, and Hydrologic Consultants, 1998; Jakubec, Clayton, and Guest, 2012)."

Jan 1, 2017

By M. H. M. von Wielligh

"Brick manufacturers supply a variety of uniquely coloured facebricks to the building industry, which requires a high level of colour consistency in the products. Colour variation in bricks is influenced by the composition and consistency of the white clay raw material. By blending varieties of naturally occurring white clay the manufacturers produce a unique range of facebrick products. Homogeneity of the white clay raw materials mined at Lenasia is crucial for producing bricks of consistent colour. Geostatistical investigations of the major element distributions (SiO2, Al2O3, Fe2O3, and K2O) and loss on ignition (LoI) were conducted. An analysis of the spatial continuity of these variables followed by ordinary kriging indicated that the upper white clay layer at Lenasia is richer in K2O and Fe2O3 than the lower layer. Consistency in the colour of facebricks depends critically on careful management of the variability in the K2O and Fe2O3 content of the clays. The geostatistical approach to understanding the distribution of elements in the clay allows miners to construct clay stockpiles of consistent quality for feeding the brick-making process. Geostatistical investigation of the chemical contents in other clay domains within the deposit is recommended, and could be extended to all facebrick manufacturers to assist in improving the colour consistency of their products. IntroductionMost clay in South Africa is used in the manufacturing of tiles, pipes, bricks, whiteware, refractories, and pottery. Bricks are manufactured from a wide variety of clay types, the behaviour of which during firing depends critically on the the clay mineralogy and chemical composition, but this relationship not well understood (Stein, 1982). The variety among clay deposits is related to the different processes of formation (Deer, Howie, and Zussman, 1992). The geochemical composition of the clay can vary between layers and within the same layer in an individual deposit (Lurie, 1984). The properties of clay minerals are determined by their structures and the different combinations of silicate layers, cations, and hydroxyl ions (Kingery, Bowen, and Uhlmann, 1976). South African clays can be classified as either kaolinite or montmorillonite and are seldom found in a pure form (Lurie, 1984). Different clay minerals affect the drying, forming, firing behaviour, colour, and quality of the brick product in different ways. Laboratory tests (full physical analysis) can indicate the suitability of a clay for the manufacture of ceramic products. The minerals most essential for the manufacturing of clay brick products are kaolinite, illite, and quartz (Stein, 1982)."

Jan 1, 2017

By S. Krishnannair

Singular Spectrum Analysis (SSA) is an effective data-adaptive multimodal tool for monitoring chemical processes. However, monitoring multiscale signals using principal component analysis obtained from the multilevel decomposition of process signals using basic SSA assume the upper control limits of monitoring charts (" ) to have a Gaussian distribution. This assumption deteriorates the performance of basic SSA when applied to the monitoring of nonlinear processes. To address the issue in this paper, the kernel density estimation (KDE) was used to estimate upper control limits of monitoring charts for basic SSA based nonlinear process monitoring techniques. The monitoring performance of the resulting basic SSA-KDE approach was then compared with a basic SSA approach of which upper control limits of the monitoring charts were determined based on a Gaussian distribution. Application on nonlinear dynamic simulated process and base metal flotation plant chemical processes showed that the SSA-KDE approach provided better overall performance than the SSA approach with Gaussian assumption-based upper control limits for its monitoring charts. Keywords: Fault detection, singular value decomposition, singular spectrum analysis, kernel density estimation

Jan 1, 2020

By C. G. Verkerk

The paper discusses the transport and rheological characteristics of high concentration slurries or pastes for backfill purposes. The influence of pipe size, particle size distribution, additives, coarse material and mass concentration on these characteristics is addressed.

Jan 1, 1988

By R. Haldenwang, R. Erasmus, P. T. Slatter, R. P. Chhabra

Notches are used routinely for measuring the flow rate of water with free surface flows. As far as can be ascertained, no work has been done to investigate the performance of these flow rate measurement devices for non-Newtonian suspensions. The Flow Process Research Centre at the Cape Peninsula University of Technology has investigated the flow rate of kaolin and bentonite suspensions from a tank for two notch shapes, namely rectangular and triangular, and for 3 different concentrations of each suspension. The notches were calibrated using water and then the kaolin and bentonite suspensions were tested in them. The rheological characterisation of the fluids was done with a Paar Physica MC-1 rotary viscometer fitted with a cup and roughened bob. Analysis of the results shows a significant increase in discharge coefficient with increase in concentration, and the discharge coefficient has been correlated to the yield stress. This is the first such study, and further investigation is needed to confirm and extend these findings.

Jan 1, 2007

By M. Solomon

During the course of 2011 the nationalization of mines emerged as one of the most contentious and emotive political issues under review. Some four years after the African National Congress electoral conference held in Polokwane, which had led to a change of leadership within the country's ruling party, elements within the ruling party's youth league, which had been virulently supportive of the change in leadership, turned on the incumbent President, using the mining question as its rallying call. At issue was the expressed perception that mining has, since the country's democratization, not delivered the anticipated benefits to the population as a whole, continues to be the preserve of the capitalist element of the South African community, and is therefore in need of radical reform. Aspersions were made that transformation within the industry had failed dismally and that mining companies had not delivered against their commitments to the Mining Charter and social and labour plans. The debate became extremely vocal and heated, evoked dramatic and emotive opinions, and vigorous skirmishes on the matter were fought in the media over much of 2011 and into 2012.

Jan 1, 2013

By G. van der Westhuizen, F. E. du Plessis

Ticor South Africa operates a dry mill at the town of Empangeni in the province of KwaZulu-Natal on the east coast of South Africa. The dry mill processes a non-magnetic mineral stream constituting rutile, leucoxene and zircon as major minerals, and minor quantities of ilmenite and other non-valuable minerals. For plant control and optimization, continuous ‘real time’ information about the mineral and chemical compositions in various plant streams is required. The current practice is to take samples at regular intervals and submit them for mineralogical(grain counting) and chemical analyses. However, these methods are time consuming, and in the case of manual grain counting, tedious and operator dependent. Until now an on-line or real-time instant mineral quantification system, which will be of great value in a plant operations environment, has not been available. Blue Cube Systems has developed a mineral quantification system using spectral mineral analysis. It measures and quantifies the composition of mineral samples instantly, providing consistent data in real time. A series of process stream samples from the dry mill mentioned above were used to evaluate the Blue Cube Systems instant mineral quantifier. This article will •describe the procedure of setting up and evaluating the Blue Cube Instant MineralQuantifier equipment •present its results, and •discuss the intended applications.

Jan 1, 2003

By L. P. Fatti

An important feature affecting the classification of a remotely sensed scene is that the data are, in general, spatially correlated. Various approaches are discussed towards incorporating the correlation between neighbouring pixels when they are classified on the basis of their spectral reflectance data.

Jan 1, 1987

By M. K. Matthews

The use of backfill has important environmental control implications which, although frequently overlooked, can be both beneficial and problematical. Where backfill is widely used, the reduction in stope heat load and improved air utilization influence the overall mine ventilation and refrigeration requirements significantly. A programme of work examining in detail all the environmental consequences of backfilling is currently underway at the Environmental Engineering Laboratory of the Research Organization of the Chamber of Mines. This paper gives an overview of the work and presents some findings. In so doing, the environmental implications to be considered when backfilling are highlighted.

Jan 1, 1988

By A. Montini

The problems encountered in the design of control systems for milling cir- cuits when the model of the system and the model parameters are uncertain are discussed. Considering these uncertainty factors has led to the development of a technique that gives a quantitative assessment of real system stability, reveals the trade-offs between performance and stability and helps the designer in deciding what level of model complexity to use in the controller design. Furthermore, it allows for on- or off-line optimization of the milling circuit performance as it provides the base for the design of a controller which is stable over the plant operating range.

Jan 1, 1987

By S. K. Gilman, P. S. Marcos

There are basic areas of importance within a concentrator or mineral separation plant, which require focus to ensure acceptable recoveries, throughputs remain at an acceptable level and product grades meet specification. Professional and para-professionals within the mineral sands industry are in demand due to the booming resource sector. Added to this, new mineral sands operations are being commissioned straining the industry further. These factors have increased staff turnover and introduced many new people to the industry. It is essential these new entrants are armed with basic plant troubleshooting skills relevant to the minerals sands industry to minimize production lost through poor recoveries. Mineral sands processing does not involve highly technical or sophisticated unit processes. However, success is often slow to arise due to a lack of detailed understanding, as well as managing multiple interrelated unit processes within a plant. Fundamental background physical conditions (such as equipment loading and water quality) must be met for unit processes to be efficient. Technical management of these process plants should always include observation of these background conditions for they often provide the answer to underperformance. Examples are presented with an indication of the possible effects on recovery and product grade.

Jan 1, 2007

By J. A. Venter, M. K. G. Vermaak, J. G. Bruwer

Electrostatic separation is employed in the concentration of zircon and rutile. The zircon concentrate undergoes an acid treatment to remove impurities from the surface of both the zircon and rutile. The purpose of the acid treatment is to increase the difference in the resistivities of the two minerals, thus ensuring the best possible electrostatic separation efficiencies. Previous test work suggested that these impurities are not removed, but only modified; the surface modification seemed more prevalent in the case of the rutile. The resistivity of the rutile changes with pH and thus the electrostatic separation of the rutile is influenced. X-ray photoelectron spectroscopy (XPS) indicates that there is an increase in the OH and adsorbed H2O concentrations on the rutile surface. XPS also showed significant differential charging on the rutile surface, which indicates that the species on the rutile surface have different resistivities. The zircon particles from the conducting and non-conducting streams have similar resistivities and no major differences in their surface species. Zircon losses during the final electrostatic separation appear not to be due to surface effects, but due to shielding of particles during the separation.

Jan 1, 2007

By J. Abdollahisharif

Optimal cut-off grade is one of the most critical parameters in open-pit mine design because it defines the ore and waste and thus determines the maximum net present value possible from the mining operation. Although the algorithm presented by Lane (Choosing the optimum cut-off grade. Colorado school of Mines Quarterly, vol. 59, no. 4, 1964. pp. 811-829) is the most common one in the literature, it does assume constant capacities of the mine, processing, and refinery. In this paper, Lane's original algorithm has been modified to consider variable processing capacities in order to determine the optimal cut-off grade in open-pit mines. The new algorithm proposed here is compared to both Lane's original algorithm and to a previous modification that incorporated rehabilitation costs into the cut-off grade estimation. The algorithm proposed here that permits variable processing capacities is shown to be superior for the determination of optimal cut-off grade to both these previous versions. In addition, a computer-based program was developed in Microsoft Office Excel© to calculate the optimal cut-off grade as proposed here.

Jan 1, 2012

By P. Goosen

The paper presents a basic summary of the approach to hydraulic scale-model tests as may typically be applicable to slurry flow situations. A case study is presented illustrating how hydraulic scale-model tests can be of significant benefit in evaluating the performance of novel or unproven slurry handling equipment. In this case the equipment tested was a fan-shaped expansion piece used to spread the discharge from a launder over the full width of a dewatering screen. The tests showed that the device did indeed distribute the slurry flow both in terms of volume and solids mass, but not perfectly uniformly. Unfortunately the equipment was not taken beyond the model test phase. The scale-model test approach did, however, prove to be very useful as it is considered to have provided a good indication of the expected performance of the full-size unit. Significantly, this was achieved at very low cost compared to the cost of installing the device into the proposed plant and having to later change it out for an alternative or live with the less than optimal performance. The paper illustrates the value that can derive from applying hydraulic scale-model testing techniques to evaluating the performance of new or unusual slurry handling equipment. There is particular value in situations that do not lend themselves to numerical modelling.

Jan 1, 2007

By C. E. Dohm

The paper serves to show the importance of both a geological model and geostatistical model that support one another in mineral resource evaluation. It highlights the advantage of reference models for the geometry, the geological, statistical and geostatistical models of various orebody types and introduces a method for quantifying the combined uncertainty in these models. The example presented reveals how the above levels of information can be applied to add value to a resource evaluation process. It is a generic example in that it is the technique of combining uncertainty in the geological model (boundaries) as well as the grade model to assess the overall risk in the estimation of the resource. Data from the coal industry is used to illustrate the techniques. The geological uncertainty is considered via categorical simulations and these are combined with simulations of the variables (grades, thickness,) being estimated in the resource. The simulation techniques used are based on the application of GSLIB software1and a general discussion of the two simulation processes is included. In conclusion the paper demonstrates how the results of two types of conditional sequential simulation can be combined to produce confidence limits that take both uncertainties into consideration. This technique does not replace the resource estimation; it serves as an additional tool to quantify confidence in the resource evaluation model. The topics considered in this contribution are in terms of continuous improvement of mineral resource evaluation.

Jan 1, 2003

By L. Dison

There are many potential uses in gold mining for an initially stiff element of backfill that will yield at a predetermined load and maintain that load to beyond a compression of 30%. Such elements could be used as yielding rib pillars, as replacements for more conventional supporting packs, as con- fining bulkheads for mass backfill, as supports to provide lateral constraint, and load-carrying augmentation to overloaded rock pillars. The paper describes a system of reinforced cemented backfill that can be used to provide the above requirements. The necessary characteristics of the reinforcing and the cemented tailings are described together with the method of design to obtain a predetermined stiffness and yield load. The load-compression characteristics of the reinforced tailings elements are described and the effect of changing various of the design parameters is demonstrated.

Jan 1, 1988

By E. Dermietzel

The fundamental ideas of Computer Aided Lignite Mining (CALM) with respect to hardware and software used at Rheinbraun are explained and outlined in detail. The computers used in the main data processing department and in the different departments in the mines are described. Special emphasis is laid upon the network connecting the computers at different places for data-exchange. Concerning technical applications, the main facilities of CALM are deposit and pit modelling, complex geomechanic computations and mass calculations, data recording from the production process in the pits and refining plants, and detailed information and planning systems for water management and mining equipment. Concerning administrative applications, the main facilities of the software are the accounting system with cost controlling and planning, the materials management system with stock control, forward planning and computer supported order procesing, a system for the administration of property within and surrounding the mines, and systems for personnel administration and payroll. The various software systems developed for these application and the influence of data processing technique, such as data base management and the interconnection of data processing systems, are demonstrated.

Jan 1, 1987