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By M. D. Carver

The purpose of this investigation was to determine the effects of variations in content (near the residual level) of the impurities aluminum, nitrogen, manganese, and copper on the corrosion rate in pressurized hot water and in pressurized steam of zircaloy-3, a zirconium-base alloy of 0.25 percent tin and 0.25 percent iron. Thirty-five 10-pound ingots were cast with the appropriate additions of impurity elements, and these were converted to wrought sheets. These specimens were then tested both in water and in steam. The analysis of the resulting data showed that in environments of either pressurized hot water or superheated steam, corrosion rates increased with increasing content of aluminum, nitrogen, or manganese, but were not affected by variations of copper. The effects of aluminum and nitrogen were found to be greater than the effect of manganese. INTRODUCTION At the request of the Atomic Energy Commission (AEC) in August 1956, the Federal Bureau of Mines, in cooperation with Bettis Plant of Westinghouse Electric Corp., began investigating the effects of certain impurity elements on the corrosion rates of zircaloy-3 in pressurized hot water and in pressurized steam. It was necessary to know these effects in order to set control limits on residual impurity levels in zirnaloy-3, intended for heat transfer service in the nuclear reactor of the pressurized water type. A factorial expert it was designed by Westinghouse statisticians. The Atomic Energy Commission provided raw zirconium sponge purchased from Wah Chang Corp. The Bureau's laboratory at Albany, Oreg., made material of different combinations of impurity levels and subjected the material to corrosion tests. This report will describe the work done at the Bureau laboratory and will show, quantitatively the effects of different residual levels of aluminum or nitrogen, or manganese or copper on corrosion rates.

Jan 1, 1961

By Rolland L. Blake

The Bureau of Mines is concerned with extracting minerals from residual geothermal brines after their heat content and some demineralized water have been recovered. This literature study is based on a survey of the literature and discussions with individuals knowledgeable on various aspects of the subject. This report examines the potential of the domestic geothermal mineral resources, considers the technical problems involved, and outlines possible effects on the environment from reservoir fluid withdrawal and reinjection. Geothermal resources in the Western United States were extensively explored during the 1960's. Limited development operations included exploratory drilling and operating wells producing hot brine, separating steam for experimental electric power generation, and recovering minerals in solar evaporation ponds or in extraction plants. Interest in the recovery of minerals and salts from geothermal fluids waned because of corrosion and scaling problems and low or no market value of the mineral products. Most of these problems can be controlled with existing technology and careful planning of processes and equipment. Extracting geothermal minerals is technically feasible, but the problems of low or no market value for major mineral products, and insufficient amounts of more valuably major products, make mineral recovery uneconomical at present.

Jan 1, 1974

By Zsuzsanna Zborovszky

Experimental study directed toward gaining improved understanding of the exact mechanisms causing ignition in the PTB breakflash. Investigation and comparison of tungsten and copper wires as to their ability to cause hot wire ignition. Evaluation of the importance of discharge duration in the ignition process. Study of the parameters influencing the duration of a discharge (minimum discharge voltage, purity of electrode materials, purity and properties of the gaseous atmosphere contaminations, deposits on the electrode surface).

Jan 1, 1976

By Charles W. Huggins

Knoop hardness indentations were studied and measured with the electron microscope on TiB2, HfC, and A1B12 crystals. A detailed description of replicating the indentations using collodion and Faxfilm is made. A John Hopkins grating having 28,800 lines per inch was used to accurately determine the magnification used on the electron microscope. The primary objectives were to prepare carbon replicas of hardness indentations, to measure the indenations accurately, and to compare the results with those obtained with the light microscope. The resulting data showed excellent agreement between the measurements made on the replicas with the electron microscope and those made with the optical microscope. The replicas made from collodion showed slightly better agreement with the light optical values than did the replicas made from Faxfilm.

Jan 1, 1963

By T. O. Glover

The Bureau of Mines surveyed unit trainloading and storage installations in the midwestern, eastern, and southeastern coalfields. Nine individual operations were studied in detail as a representative cross section of unit train operations in these areas. Of the nine operations studied, three were in Illinois, two in Kentucky, and one each in West Virginia, Tennessee, Ohio, and Pennsylvania. Information was obtained from coal producers, coal sale agencies, railroads, construction and equipment companies, and power companies.

Jan 1, 1970

By Carl Fisher

A microseismic roof fall warning system was field tested in Western and Eastern coal mines in the United States to better define the capabilities and limitations of the microseismic method in predicting roof fall Microseismic event and energy type data were obtained and documented for twenty-three coal mine roof falls. Field test results indicate that both the microseismic event and energy methods, as applied in this development effort, have a high probability for successful application in a commercially practical roof fall warning system. Based on the results and experience obtained during field testing, a commercial prototype microseismic roof fall warning system was designed and constructed. Although it was the intent of the program to field test the commercial prototype system, delays in equipment fabrication and contract time limitations did not permit field testing.

Jan 1, 1980

By H. H. Schrenk

[There is a need for method of determining: benzene vapor in air which is simple and accurate and suitable for making industrial hygiene surveys. The most widely used method in this country is the modification of the Elliott and Dalton6/ procedure. This depends on the nitration of the benzene to reduction to phenylenediamine with all excesses of standard titanous chloride; solution, and titration with e standard ferric ammonium sulphite solution. This method has the disadvantages of being what time consulting: and cumbersome it requires considerable apparatus, and a special modification is necessary in the presence of toluene.]

Jan 1, 1935

By H. H. Schrenk

There is a need for a method of determining benzene vapor in air which is simple and accurate and suitable for making industrial hygiene surveys. The most widely used method in this country is the Smyth modification of the Elliott and Dalton procedure. This depends on the nitration of the benzene to m-dinitrobenzene, reduction to phenylenediamine with an excess of standard titanous chloride solution, and back titration with a standard ferric ammonium sulphate solution. This method has the disadvantages of being somewhat time-consuming and cumbersome; it requires considerable apparatus, and a special modification is necessary in the presence of toluene. Recently Cook and Ficklen have published a method based on the oxidation of benzene with hydrogen peroxide in the presence of iron salts. This method requires the use of solid carbon dioxide to freeze out the benzene. The reaction Which produces the color is complex; and only approximate quantitative estimations can be made, except in a very narrow range.

Jan 1, 1935

By Rustu S. Kalyoncu

Nonoxide ceramics with improved high-temperature properties could substitute for high-temperature alloys and reduce toe Nation's dependence on imports of Cr, Co, Ni, and Mn. To meet this objective, the Bureau of Mines conducted research to synthesize u1trafine reactive boron nitride (BN) powders BN powders were prepared at temperatures ranging from -75? to 750? C. Low-temperature reactions (-75? to 200? C) between boron halides and N compounds led to formation of e1emento-organic compounds that were thermally decomposed to u1trafine (approximately 100-to 150-A particle size) reactive BN powders. BN powders were also prepared through the reaction of a 10w-me1tinginorganic B compound (boric acid, borax) with an organic N compound (carbimide and thiocarbimide) in N2 and/or ammonia (NH3) atmospheres at temperatures between 500? and 750? C.

Jan 1, 1986

By W. P. Yant

A previous report of the Bureau of Mines dealt with the toxicity of dichlorodifluoromethane, a new refrigerant that has a remarkably low toxicity. Continued research by the Frigidaire Corporation and toxicological experiments performed in the Laboratory of Applied Physiology of the University of Cincinnati revealed another organic fluoride, dichlorotetrafluoroethane, whose toxicity also appeared to be of a very low order and whose physical and chemical properties make it suitable for refrigeration purposes. In addition to low toxicity, safety in its use is further enhanced by its physical properties, which permit the design of equipment that operates at comparatively low pressures and hence mitigates the dangers and problems of leakage. The investigation described in this report was performed by the Bureau of Mines at the request and with the cooperation of the Frigidaire Corporation.

Jan 1, 1932

By K. E. Tame

The Bureau of Mines is studying possible modifications in conventional ore-processing methods that will confine and permit controlled disposal of radioactive liquid wastes. Stream and ground water pollution from radio-active nuclides, principally radium 226 and thorium 230, in liquid wastes from uranium mills can be minimized by reusing the waste solution within the mill. Such reuse of waste solution in an acid leach-resin-in-pulp flowsheet was investigated in the laboratory. The process consists of acid leaching for dissolution of the uranium, sand-slime separation and countercurrent decantation washing for recovery of a pregnant slime slurry, and the use of ion-exchange resin for recovery of uranium from the slurry. Reuse of clarified barren effluent for washing in the simulated mill circuit was carried through 55 cycles. Dissolution of uranium from the ore averaged 97.5 percent. Washing efficiency of 99.9 percent was attained when using 4.35 volume tons4 of combined barren effluent and makeup water per ton of ore. Absorption of uranium from the pregnant slime slurry by an ion-exchange resin averaged over 99.9 percent.

Jan 1, 1962

By Homer J. Ballinger

The Alma, Degraff and other mines controlled by the Mon-Ark Mining Co. comprise one of the more important groups of zinc-lead mines in Christian County, Mo. The mines were first operated in .1857 and produced more than 5 million pounds of lead from rich, shallow ore deposits. Recent exploration and development led to the discovery of zinc sulfide ore at a depth of 165 to 214 feet in the northern part of the Alma mine. After examination of these mines in September 1942 by Bureau of Mines engineers, investigation of the extension -of the Alma mine and of the depth of mineralization at the other mines appeared justified in order to encourage the production of additional zinc and lead for war purposes. Twenty-nine churn-drill holes totaling 6.463 feet of bore were completed by the. Bureau from September 1943 to January 1944.

Jan 1, 1948

By Jr. Herty

Ferromanganese continues to be an indispensable requirement in steel manufacture. Approximately 470,000 of the 80 per cent ferro-alloy was consumed in 1929 and increasing amounts will be required annually by the steel industry unless some satisfactory substitute is found. An average of 14 pounds of metallic manganese is used for each ton of steel produced, The principal use of manganese is for de-oxidation of the metal in the steel refining processes, although a considerable amount is also used for the production of special manganese steels. Unfortunately, domestic production of manganese ore is inadequate to meet normal peace-time requirements, not to mention increased abnormal war-time demands. The rather large quantities of low-grade manganiferous iron ores which occur in the Coruna Range in Minnesota have for a number of years greatly appealed to those interested in the development of a domestic source of the supply. The North Central Experiment station of the Bureau of Mines has made an elaborate study of the possibilities of the pyrometallurgical treatment of ores from these deposits and much of the valuable information secured by them has already been published.

Jan 1, 1930

By C. H. Herty

[Ferromanganese continues to be in indispensable requirement in steel manufacture. Approximately 470,000 tons of the 80 per cent ferro-alloy was consumed in 1929 and increasing amounts will be required annually by the steel industry unless some satisfactory substitute is found. An average of 14 pounds of metallic manganese is for each ton or steel produced, The principal use of manganese is for deoxidation of the metal in the steel refining processes, although a considerable amount r s also used for the production of special manganese steels. Unfortunately, domestic production of manganese ore is inadequate to meet normal peace-time requirements, not to mention increased abnormal war-time demands.]

Jan 1, 1930

By E. C. Tarpley, H. M. Cooper, R. F. Abernethy

"INTRODUCTION The determination of moisture in coal is an empirical test, because the time, temperature, and equipment are specified. The essential features of the equipment, and details of the procedure are given in A.S.T.M. Designation: D271-44 5/. According to the specifications, the following features should be incorporated in the equipment used:1. Oven must have uniform temperature in all parts.2. Oven must be constructed with minimum of air space.3. Oven must have means of changing the air two to four times per minute.4. Air must be dried over sulfuric acid (sp. gr. 1.84).The analytical procedures governing most of the nation's coal purchases are those given in A.S.T.M. Standards referred to above. These standards are general and of such scope as to cover all ranks and types of coal. In cases where only the moisture is required, a faster method than the standard procedure is desired.The semi-automatic moisture tester manufactured by the Brabender Corp. has proved itself in many industrial processes where the rapid estimation of moisture is of vital importance. With the approval of A. C. Fieldner, chairman, A.S.T.M. Committee D-5, and through the courtesy of Lowell Malan, chief chemist, United Electric Coal Companies, who loaned the tester, tests were made to determine the feasibility of using this instrument to determine the moisture in coal."

Jun 1, 1948

By Herbert H. Einstein

Rock mass deformability is commonly predicted using correlations with RQD or other indices of rock mass quality, or by extrapolation from large in-situ tests. Based on the probabilistic description of rock masses empirically developed in Part I a new approach was attempted in modeling for predictions of deformability. This approach decomposes the rock mass into spatially variable joints described by probability distributions, and intact rock blocks. Stiffnesses and elastic parameters are associated with the joints and intact blocks respectively, and deformations built up by adding the contributions of each. This model allows relaxation of many of the simplistic geometric assumptions which constrain parallel attempts to model deformation in rock masses. The model has been applied to four standard cases in order to test its results against previously existing models, and to check whether it replicates empirical correlations. When joints are taken as parallel, common empirical correlations are closely approximated by the model output. However, the closeness to empirical correlation breaks down when variability of the jointing geometry is increased.

Jan 1, 1979

By C. A. Herbert

Timber decay is due largely if not wholly to a fungus growth on the timber from which it derives' food; a warm, moist atmosphere is necessary for rapid growth. The decay is spread from infected timber to sound timber by countless microscopic spores or seeds given off by the fungus growth and carried by air currents or by long, cottonlike threads, which spread from timber to timber. Haulage roads in most mines in the central coal fields are also return aircourses; hence moisture and temperature conditions are ideal for the rapid decay of mine ties and mine timber. Possibly the return air, which contains a higher percentage of carbon dioxide than normal outside air, also stimulates the growth of fungi. Those familiar with coal mining have observed the more pronounced growth of fungi and decay of timber in poorly ventilated worked-out sections of mines where the air is moist and where usually the percentage of carbon dioxide in the air is considerably above normal.

Jan 1, 1934

By T. F. Mitchell, Walter J. Long

"SUMMARYThis report is one of a series giving results of laboratory and pilot-plant investigations of the concentration of western manganese ores begun in December 1940. Data given summarize results of laboratory investigation of three samples of complex oxide manganese ores from the Madeline property, Lake View, and Victory claims, Clallam County (Olympic Peninsula), Wash. The samples represented an extremely intimate and complex association of manga¬nese oxide minerals with silica and iron.Owing to the complex nature of the ores, no effective concentration by ore-dressing methods was possible. No high-grade manganese concentrates were produced and the highest recovery at minimum accountable grade was only 55 percent on one of the ores tested.Since the Clallem County ores did not respond to ore-dressing methods, leaching processes were investigated, results of which are to be published in a separate report.INTRODUCTIONOre-beneficiation tests were conducted on three samples of manganese oxide ere from the Madeline, Lakeview, and Victory claims, Clallam County, Wash. The ores are extremely complex because of the unusually small size of manganese mineral particles, their mode of occurrence, and relationship to the gangue. None of the three ores was amenable to the production of high-grade manganese products by ore-dressing methods."

Dec 1, 1945

By Theodore Kessler

The purpose of this Bureau of Mines investigation was to determine what new organic compounds or high concentrations of a particular organic species can be formed by exposure of coal derivatives to ultrasonic energy. Tetralin, l-methylnaphthalene, and pyridine were used as model compounds. Gaseous and solid reaction products resulting from the ultrasonic irradiation of these coal derivatives were determined using mass spectrometry. Products from the irradiation of tetralin were studied as a function of time, atmosphere, and sample size. The sonolysis (chemical reactions produced by ultrasonic energy) of tetralin and l-methylnaphthalene produced C2H2, HCN, CH4, H2, CO, and CO2, depending upon the experimental conditions. The ultrasonic irradiation of tetralin also produced diacetylene under certain experimental conditions. The cleavage of organic chemical bonds by ultrasonic cavitation in the absence of water was also observed in this study.

Jan 1, 1967

By Vladimir Adamek

This paper describes the Bureau of Mines development of a novel subsidence prediction methodology suitable to the mining and geologic conditions in the Northern Appalachian Coal Region. It describes the computation of vertical and horizontal movements, inclination, curvature, and horizontal strains. The substance of this method is the separation of the effects of lithology by introducing a correlation between hypothetically homogeneous overburden and existing lithologic conditions, while providing for different mining conditions, i.e., underground geometry and overburden thickness. The effects of lithology have been expressed in the form of a variable subsidence coefficient within the subsidence trough. The subsidence co-efficient is considered a constant for other predictive methods. Field data from 16 test sites at 11 Bureau longwall panel studies were used in the analysis. For each panel, the characteristics of the variability of the subsidence coefficient were defined. Regression analysis of the subsidence coefficients from all test sites on their locations relative to the edges of their respective panels yielded a third-degree polynomial equation. The results from additional longwall panel studies, not included in the regression analysis, were used to prove the validity of this method. To facilitate the use of this precalculatlon methodology, a computer program was written in BASIC for use on a personal computer.

Jan 1, 1987