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By J. L. Reuss

The Bureau of Mines derived information on the softening characteristics of both unfired and indurated iron ore pellets as measured by hot compression strength in a laboratory study. A surprisingly high hot strength (240 1b per ½ -inch spheroid) was developed by unfired magnetite pellets near 900° C; lesser maxima were developed by pellets made from hematite and specularite concentrates near 1,000° C. Those from goethite remained weak throughout the pre induration heating. Fully indurated commercial pellets retain a high resistance to softening when heated in air. On the contrary, in a hot reduing atmosphere their high cold crushing strength dissipates rapidly. At 1,000° C, for example, the average compression strength of seven different commercial pellets was 110 lb; at 1,100° C, the hot strength was only 60 lb. After a rather sharp initial drop, the loss of strength with increase of temperature was gradual. There was no sudden collapse, nor any significant difference, in behavior of commercial pellets whether made from magnetite or hematite concentrates.

Jan 1, 1968

By Craig C. Hustwit

A pilot-scale treatment study was conducted on a copper-zinc bearing metal mine drainage using a pipeline treatment system called the In-Line System (ILS). The objective of this U.S. Bureau of Mines study was to determine whether the ILS could be extended from the treatment of coal mine drainages to the treatment of metal mine drainages. Hydrated lime (Ca(OH)2), quick lime (CaO), and caustic soda (NaOH) were used to neutralize the drainage. A novel reagent slurry of Ca(OH)2 and type C fly ash was also evaluated. Except for Ca(OH)2-fly ash slurry, treatment performance was evaluated for all reagents at pH values of 7,8,9, and 10. The Ca(OH)2-fly ash slurry was evaluated at a pH of 10. All reagents tested neutralized the metal mine drainage and substantially reduced the dissolved metal concentrations. It was concluded that the ILS could be useful in the treatment of metal mine drainages.

Jan 1, 2010

By A. Sainato, S. J. Kravits, G. L. Finfinger

This report describes a project conducted by the Bureau of Mines in which the accurate directional drilling of a borehole was demonstrated with the objective of intercepting a designated target. The project was conducted at Navajo Dam in northern New Mexico at the request of the Bureau of Reclamation. Borehole survey and drill logs are provided in an appendix. The trajectory of the demonstration borehole was designed to intercept a 5-ft-radius target at the final or "punchout" distance of 885 ft. The elevation of the borehole at this distance was within the target; the borehole punchout coordinates were 8.81 ft southwest of the target. As a result of the demonstrated accuracy, the Bureau of Reclamation has contracted the accurate drilling of boreholes as long as 600 ft from the inside of a short tunnel, to control water seepage in the right abut- ment. This resulted in a substantial cost savings compared to the orig- inal plan of constructing a longer tunnel and drilling 150-ft boreholes.

Jan 1, 1987

By JOSEPH F. CULLEN, Dorsey A. Lyon

In connection with its investigation looking to the prevention of waste and the increase of safety and efficiency in the mineral indus- tries the Bureau of Mines has undertaken a study of the possible uses of the electric furnace in metallurgy. This bulletin presents a com- pilation of such data as seem to be useful for the information of persons who may be interested in the matter. In the application of electricity to metallurgy three kinds of processes are involved, namely, mechanical, thermal, and electrolytic. Under the mechanical application of electricity come those proc- esses of dressing and concentrating ores that are known as either electrostatic or electromagnetic processes. In electrothermic processes the current is used as a source of heat. The fundamental differences between the various types of electric furnace that are at present in commercial use relate to the manner in which the electric current is applied, as may be noted by reference to that part of this report in which the subject is discussed. In electrolytic processes the electric current is used for depositing metals from solutions. The process may be conducted in one of the following ways: (1) The material to be treated may be put into solu- tion and then electrolyzed, the material thus treated forming the electrolyte; (2) the material to be treated may form the anode or be placed in contact with the anode; or (3) the material to be treated may form the cathode or be placed in contact with the cathode. This report treats of electrothermic processes, with the possible exception of those for the reduction of aluminum from its ores. Moreover, of the processes used in the so-called electrochemical in- dustries only those for the reduction of an ore to metal, or to a com- pound of the metal that is of value in itself, or is an aid in metallurgical work, are here discussed.

Jan 1, 1914

By Robert M. Doerr

Isothermal oxidation kinetics were determined for three grades of Ni and for 99.99 percent Co in Ca and in air from 800° to 1,200° C. The oxidation reactions followed approximately the parabolic rate law. For 99.99 percent Ni in 02 at 1,200° C, the parabolic rate constant was 2 mg cm-2 hr-2. For 99.99 percent Co in dry air, the constant ranged from 1 mg cm-2 hr-2 at 800° C to 18 mg cm-2 hr-2 at 1,200° C; for 99.99 percent Co in 02 the constant was 2 mg cm -2 hr-2 at 800° C and 10 mg cm-2 hr-2 at 1,000° C. For 99 percent Ni in dry air, the constant ranged from 0.2 mg cm 2 hr-2 at 800° C to 3 mg cm 2 hr-2 at 1,200° C. By X-ray diffraction measurements, only divalent oxides were found in the scales. Volumetric and quartz-helix gravimetric methods were used. The volumetric apparatus was designed to permit less stringent restrictions on the corrosion specimens; it was also more convenient to use. The agreement between the weight gain determined gravimetrically and the 02 consumption determined volumetrically was not good enough for direct comparison of gravimetric and volumetric results.

Jan 1, 1963

By N. S. Dalal, Xianglin Shi

"Electron spin resonance (ESR) spin trapping experiments have been carried out to investigate the mechanism of sulfite oxidation em¬ploying 5,5-dimethyl-l-pyrroline-1-oxide (DMPO) as a spin trap. The results show that sulfite autoxidation, catalyzed by Mn(II), involves not only the SO-3 radicals but also the •OH radicals. An addition of H2 02 to the sulfite aqueous medium significantly increases the •OH radical formation. This result provides new clues to the chemical mechanism of the sulfite oxidation and the sulfite toxicity.INTRODUCTIONStudies of the oxidation of the sulfite (SO 2-/3) ions under various conditions are of high current interest because excessive exposure to sulfite is toxic and the origin of this toxicity seems to involve sulfite oxidative pathways [1]. An important fact is that human exposure to sulfite is on the increase [1,2]. Some of the increase in the sulfite exposure is linked to the fact that SO2 is a major air pollutant [2] and in aqueous media SO2 exists in equilibrium with SO2-/3. In addition, beverages and foods are common sources of sulfite intake. For example, sulfite is used extensively in the wine industry as an inhibitor of yeasts and bacteria and is present in finished wines in concentrations up to 6 mM [1]. Sulfite is also often added to dehydrated fruits, vegetables and soups, as well as fruit juices and beer [1,3,4]. Because of these, the mean daily intake of sulfite from diet (in the United States) has been estimated to be between 0.0014 and 0.14 mM/kg body weight [1]. At such high levels, sulfite exposure can have toxic effects, such as the induction of an acute asthmatic state [5,6]. Sulfite also appears to have adverse genetic effects [7] and can act as a mutagen or comutagen [8] and a cocarcinogen [5,7-9]."

Jan 1, 1990

By Henry Kreisinger, J. F. Barkley

This book is one of a series of publications being issued by the Bureau of Mines for the purpose of disseminating information in regard to the methods by which the fuels in this' country may be used most efficiently. A knowledge of the temperature of the gases in boiler settings and in other commercial apparatus using heat tends to develop improved designs of apparatus and better methods of operation, thus reducing waste of fuel. The following pages present, for the benefit of those designing, operating, and testing such apparatus, information as to the accuracy of temperature measurements made under certain conditions and the corrections that can be safely applied.

Jan 1, 1918

By Michael V. Markel

This report summarizes work performed under USBM Contract No. J0100047 revealing the performance characteristics of a composite-type resilient screen deck. The ability of the composite to perform or compete with steel in noise attenuation and longevity was of interest. Tests were conducted at the River King Preparation Plant of Peabody Coal Company. This facility was chosen because it provided parallel process flow and met standard coal cleaning requirements. Comparisons could be made between the adjacent resilient and steel screen decks under similar operating conditions. Noise reductions of 1-6 dBA were realized in the near field. Although the test period did not determine resilient screen life, indications are favorable for their longevity.

Jan 1, 1981

By Harold J. Bennett

The purpose of this study was to develop methods for the financial evaluation of mineral deposits. This includes the selection of the best alternative mining and processing methods and production rates. This was done by performing a financial evaluation through computer simulation using sensitivity and probabilistic risk analysis. The criterion used to measure the relative advantages of these investment and operating alternatives is the discounted-cash-flow rate of return. Included is a description of the theory and methods used in the probabilistic analysis approach, which is based on the premise that the expression of a range of values in establishing an estimate for a parameter is more realistic than the choice of a single value. Numerous simulations are made using randomly selected values of the input parameters resulting in a frequency distribution of the rates of return and their relative probability of occurrence. The sensitivity analysis method is described and combined with the probabilistic analysis to interrelate mineral reserves, capital investments, operating costs, and production rates. The ability to vary these input parameters on successive runs has permitted the selection of the best alternative mining and processing methods and production rates for a given mineral deposit. For illustrative purposes the evaluation of a mineral deposit was performed using three alternative mining and processing methods at three different quantities of resources and various production rates and prices. The computer program used in this analysis was written in FORTRAN II for maximum compatability and should run without modification on most computers having BK (8,000-word) core memory, a card reader, and printer (120 characters per line).

Jan 1, 1970

By Edward D. Thimons

The Bureau of Mines developed a stopping design that allows the stopping to be blown down by strong blast forces without incurring any permanent damage. Trials with the new stopping, dubbed the quick-fix blowout stopping, have been conducted in the Bureau's Safety Research Coal Mine at Bruceton, Pa., and in two New Mexico uranium mines. Results have been favorable in all cases. Compared with conventional brattice stoppings or wood bulkheads, the quick-fix blowout stopping is easier and less time consuming to install, is easier to maintain, and in most cases is just as efficient an air barrier. There is same indication that the shape of the stopping makes it more resistant to blast fore s than the fabric stoppings now in use.

Jan 1, 1976

By Yael Miron

The presence of pyrite (FeS2) in coal can cause or contribute to several problems for the coal mining industry. These problems, which include spontaneous combustion, roof falls, floor heave, and accidental explosions in coal surface mining when ammonium nitrate fuel oil (ANFO) explosives are used, result from pyrite oxidation. Pyrite oxidizes exothermically in the presence of air and moisture to form a large variety of products, including hydrated ferrous and ferric sulfates, and sulfuric acid. Some of the products are reactive chemicals and strong oxidants. The volume of many of these oxidation products exceeds the original volume of the pyrite; as a result, the adjacent coal disintegrates and its surface increases, rendering it more susceptible to oxidation. The heat from pyrite oxidation raises the temperature of the adjacent coal, accelerating the oxidation and self-heating rates of the coal. These combined chemical, physical, and thermal effects are the cause of the aforementioned problems. When ANFO is used in surface coal mines and contacts ferrous sulfate, a highly exothermic reaction ensiles. Additional hazards are fires or explosions caused by the frictional ignition of methane when the pyrite in the coal is struck by a cutting bit during mining.

Jan 1, 1994

By Ronald T. Mayerle

There are no producing or developing mines in the Rattlesnake RARE II area. Specific areas with mineral occurences are prospects for: 1) stratabound copper and silver in Belt sedimentary rocks on the northwest border of the study area; 2) base metal sulfides, in thin veins and shear zones in Belt sedimentary rock, and diabase dikes and adjacent metasedimentary rocks in the southern part of the study area; 3) barite in sedimentary rocks near Rattlesnake Creek and Sheep Mountain; 4) limestone near Rattlesnake Creek and Blue Point; and 5) silica in quartz veins near the headwaters of Rattlesnake Creek and Sanders Lake. Stone, sand and gravel suitable for construction material are in the study area; however, equal or better quality deposits are common throughout the region. The RARE II area has no known oil and gas, coal, or geothermal energy deposits.

Jan 1, 1983

By Juel H. Stears

The bureau of Mines analyzed data from 47 coal mine roof-fall resupport accidents that occurred from 1966 through 1974 to identify critical hazards .and problems. These accidents resulted in 62 injuries or fatalities. It was concluded that the majority of the accidents might have been prevented by observance of recommended practices and use of available technology such as setting temporary supports, adequate roof testing, etc. Additional work is needed in the following problem areas where present technology is inadequate: (1) warning of impending roof falls shortly before they occur, (2) better methods of detecting unsafe roof and ribs, (3) providing access to and temporary support of high roofs for testing and bolting, (4) reducing the noise level of stopers, (7) developing temporary roof support; that have greater stability and can be remotely installed, and (6) reducing the number of roof falls through better permanent support.

Jan 1, 1976

By R. V. Ramani, K. V. K. Prasad, M. Swaminathan

"INTRODUCTIONMine ventilation planning is an engineering design process requiring a substantial amount of qualitative knowledge obtained through experience. A concept for a knowledge-based ventilation expert system was developed by Ramani and Prasad (1987).1 11 An expert system based on the above scheme was conceived with the motivation of providing a tool to facilitate decision making for ventilation engineers in the context of computer assisted ventilation planning. Options for the implementation of the system were then examined and several commercial, personal computer (PC) based shells assessed toward this end. The options considered, the evaluation criteria and procedure arc discussed in Prasad ·and Ramani, (1989).Cll Following the above study, a scheme was developed to represent the components of the expert system.<3> Evaluation of several commercial shells indicated that there was none available which permitted interfacing with a large external algorithmic program. It was therefore decided to develop the KBS in LISP and custom build the necessary interfacing routines to ""hook out• to the network analysis program (NAP). Due to this choice of development strategy, the computer implementation aspects of the KBS arc important as all the interfacing components had to be developed with the basic tools offered by LISP.In this paper, the implementation of the knowledge based system (KBS), in terms of its component, the interfaces among the various components of the KBS and between the KBS and the user arc described. The ventilation KBS consists of an AES (analysis expert system), an IES (interpretation expert system)' and an algorithmic NAP (network analy5is program). The AES analyzes the input to the NAP considering the legal 5tipulations governing the various mine ventilation network parameters and principles of good ventilation, helping the ventilation engineer develop and represent represent the problem for solution by the NAP. The IES diagnoses the output from the NAP in terms of the critical parameters in the context of the given problem. Thi5 loop is continued till a satisfactory salution is obtained. The implementational details of the AES, the IES and the approaches to the validation of the expert system arc also discussed."

Jan 1, 1990

By A. Y. Lee

Prior work at the Bureau of Mines resulted in the successful development of a bench-scale, combination electrorefining-electrowinning method for recycling the lead from scrap batteries using waste fluosilicic acid (H2SiF6) as electrolyte. This paper describes larger scale experiments. Anodes cast from scrap battery lead were electrorefined in a 20-L multielectrode cell for 3 to 7 days. The anodes, containing 2 to 2.5 pct antimony, were ideal for obtaining firm and adherent slime blankets. Cathode deposits, assaying 99.99 pct Pb, were obtained, with current efficiencies near 99 pct. Sludge leaching was done in 100-L tanks followed by filtering in 61 cm square vacuum pan filtersu Lead of greater than 99.99-pct purity was recovered from the filtrate by electrowinning in a 20-L multielectrode cell using insoluble Pb02-Ti (lead dioxide-coated titanium) anodes and pure lead cathodes. The fluo-silicic acid electrolyte depleted in lead was repeatedly recycled to leach more sludge, and there was no problem with impurity buildup. The amount of Pb02 formed on the anodes during electrowinning was less than 1 pct of the total lead deposited on the cathodes, as long as the phosphorus concentration in the electrolyte was greater than 1.3 giL. Emissions of lead in air were less than 10 ~g/m3, well below the proposed OSHA limit of 50 ~g/m3.

Jan 1, 1984

By Wesley A. Grosh

The Valzinco mine, Spotsylvania County, Va., is a lead-zinc deposit with minor quantities of copper. The property was reopened n 1942 by Panaminas, Inc. The Bureau of. Mines, in an effort to increase the reserves of the deposit to justify greater production, diamond-drilled nine holes totaling 4,213 feet during 1943. Drilling by the Bureau delimited the original ore body and discovered another ore body on the hanging-wall side, which was being developed by the company at the close of the project.

Jan 1, 1949

By S. H. Katz

Artisans and laborers in mineral industries where the air is dusty with particles of reel: are subject to a peculiar pulmonary disease known as miners' phthisis or stone cutters' consumption. In granite cutters the disease is specifically designated as granite pneumoconiosis. Very fine particles of the harder rocks are especially injurious when inhaled into the lungs. It is estimated particles about one micron (1/23000 part of an inch in diameter) are most injurious, because larger particles are more readily removed by the cilia and,wet surfaces of the respiratory passages before reaching the lungs, while smaller particles either do not readily lodge or are more easily eliminated. Silica, of which quartz and flint are composed, and which forms a large part of granite, is one of the hardest of the common rock-forming materials. It is also very insoluble when silica lodges in the lungs elimination is difficult. Rock constituents of granite other than silica are probably injurious but in a lesser degree, and this is also probably true of limestone and the softer rocks. Ultimately a worker who daily inhales much granite dust has considerable deposited in his lungs. If he continues at his trade the lung tissue becomes harder and less elastic, he finds himself short winded, and in extreme cases death may come either directly or indirectly as a result of lung failure.

Feb 1, 1921

By IRVINGC. ALLEN, W. A. Jacobs

Realizing the great importance and wide application of petroleum and its products for fuel,lighting and lubrication, and the absence of authentic and comprehensive information in the literature on the commercial value of American petroleums, the United States Geological Survey has for a number of years' been making analyses and other examinations of these oils and their products. In 1907 the technologic branch of the Survey began a study of certain economic problems having to do with the natural mineral oils. The prime object of the investigations was to determine the economic value of the petroleums and natural gases in the United States with special reference to the supplies in the public lands, and to ascertain how these resources could be utilized in the industries withleast waste and greatest efficiency. This work, which is now being conducted by the petroleum section of the Bureau of Mines under authority of the act of May 16, 1910, will include the collection at the wells and refineries of information as to the following details: Facilities for handling and storage at the wells. Facilities for transportation, whether by pipe line, rail, or water. Distance to the nearest port or center of industry and time necessary for delivery. Facilities for storage at such point of delivery. Suitability of the crude oil for fuel, or the treatment necessary to convert itmost economically into the best fuel. Best processes of refining or of converting the crude oil into its many products. The examination of these products. The utilization of the by-products and residues of the refineries. The collection of adequate and reliable samples, and the complete chemical and physical examination ofthese samples in the laboratory.

Jan 1, 1911

By Edward D. Thimons

This Bureau of Mines report presents expected levels of air pollutants in the face areas of oil shale mines, based upon data collected by the authors and previous investigators. Ventilation requirements to maintain these pollutant levels below their threshold limit values and Federal and local mine air quality standards are discussed. Two practical face ventilation systems are discussed in terms of actual in-mine test experience.

Jan 1, 1986

By J. S. Tosh

The Federal Bureau of Mines has investigated the equilibrium of the system potassium carbonate (K2C03) potassium bicarbonate (KHCO3) potassium bisulfide (KHS) carbon dioxide (C02) hydrogen sulfide (H2S) water (H20). Partial pressures of hydrogen sulfide, carbon dioxide, and water vapor were measured at 70° to 130° C. over solutions of 20-, 30-, and 40-percent-equivalent potassium carbonate containing from 20 to 3,000 grains of equivalent hydrogen sulfide per gallon of solution. This study was made to obtain equilibrium data for evaluating the feasibility of using solutions of hot potassium carbonate for removing, hydrogen sulfide from gas mixtures. The equilibrium partial pressure of hydrogen sulfide may be correlated with the ratio of the molal concentrations of the solutes (KHC03) (KHS)/ (K2CO3). The relationship is shown graphically for the 30- and 40-percent solutions. Once this ratio is determined, the partial pressure of hydrogen sulfide can be obtained from the curves. The equilibrium data show that effective removal of both carbon dioxide and hydrogen sulfide can be achieved simultaneously with hot solutions of potassium carbonate.

Jan 1, 1960