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By E. Gervais

"In today's marketplace, heavy competition between materials is the norm. This is particularly true f or the base metals, which are being increasingly challenged by new or improved materials in all traditional applications. Current usage of base metals results from a combination of a metal's intrinsic properties, and technology. The future of the base metal industry rests with innovative, high-quality product development, its ability to take advantage of the results of worldwide, massive material R&D investments, and with the dynamism and effectiveness of its market development programs.The ZA casting alloys program is an illustration of the zinc industry’s efforts to protect and expand its market position in the casting field through state-of -the-art technological developments. The market potential f or these advanced engineering alloys is substantial, and their impact on traditional zinc die casting alloy consumption is particuarly important. The ZA alloys, in offering increased performance through zinc castings produced at low cost and by a wide range of moulding processes, have unlocked a multitude of new end-use applications.Following a review of the development of ZA alloys, of their key properties and of their performance characteristics, the numerous challenges that the alloys present to the zinc industry and to the R&D community are discussed.IntroductionZinc is anodic to steel and has a low, uniform rat e of corrosion; it has a low melting point, can be cast with precision , and is readily finished. In addition to its use in protecting steel and in the production of a wide range of castings, zinc is employed : (1) to produce brass, high-strength aluminum alloys and magnesium die casting alloys, (2) in the wrought state for coinage and in building products, particularly as roofing materials , and (3) as an oxide, in the rubber industry, in ceramics, glass, cosmetics, pharmaceutical products and as the starting materials for many chemicals.Zinc die castings are produced with accuracy at high speed, at low cost, are easily finished and have excel1ent mechnical properties . Car fuel economy, changes in automobile styling, competition from other materials, increased sophistication of design and miniaturization have all led to a dramatic change in the volume of zinc consumed for die-casting applications. This has been particularly notable in the United States. Throughout the 19505 and the I960s, casting was the fastest growing major use of zinc; it was firmly established, accounting for 35% of the total zinc consumption(1), By 1983, the volume of zinc being purchased for casting applications had dropped to less than 20% of all zinc consumed in the United States. In the western world(2), consumption for zinc casting application s is currently at about 15%; being nearly equal to the zinc consumed by the brass industry. Coating applications dominate with a consumption of more than 40% of the total market."

Jan 1, 1987

By S. Dallaire

"RÉSUMÉLes revêtements céramiques ont une moins grande visibilité que les revêtements métallurgiques. Ils ont cependant jour un role significatif dans noire développement technologique. Les procédés de revêtement ont permis de s'affranchir de barrières technologiques importantes dans le domaine de l'optique, de l'électronique, de l'usure, des hautes temperatures. L'introduction de nouvelles technologies ou la mise en service de nouveaux matériaux peut nécessiter l'adaptation de certain procédés actuels ou le recours a des procédés qui ont peu percé jusqu’ à maintenant.ABSTRACTApplications concerned with ceramic coatings are not as well known as those with metallic coatings. However, ceramic coatings have played a tremendous role in the development of technology. Ceramic coating processes made it possible to overcome technological barriers in the areas of optics, electronics, wear resistance and high temperature applications. Ceramic coatings can provide new properties to materials never considered for demanding applications. They can also open new frontiers and revitalize materials which are maturing or in decline."

Jan 1, 1990

By Jochen Petersen, Caroline Muzawazi

The technical feasibility of ammonia leaching of PGM bearing Platreef flotation concentrates was investigated as an alternative method for the recovery of base metals prior to precious metal recovery. The composition of the concentrates includes 2.02% Cu and 3.17% Ni, and the major base metal minerals are chalcopyrite and pentlandite. Optimal leaching conditions were initially established in shake flask experiments to be a solution containing 4 M NH4OH, 4 M (NH4)2CO3 and a pH range between 9 and 10. These were used as base case conditions in column and batch stirred tank reactor tests, where the effects of total ammonia concentration and operating temperature were explored further. At optimal conditions nearly 100% Cu and Ni extraction were obtained in the batch stirred tank reactor, and 95% Cu and 60% Ni extraction was obtained in columns. The activation energy for chalcopyrite and pentlandite was 36 kJ/mol and 16 kJ/mol, respectively, in both reactors, indicating different reaction pathways for the two minerals. Gas-liquid mass transfer appears to be the limiting reaction step in columns much more than in tanks, and the degree of ammonia loss to air is significant. This initial test work indicates the feasibility of using ammonia leaching for this and similar materials as an alternative route to conventional smelting and refining prior to PGM recovery, but a number of technical challenges still need to be overcome.

Jan 1, 2014

By Fulchand Shende

Around the world many potash mines experience brine inflow problems. The presence of brine in underground excavations may induce structural and stability problems. A study has been carried out to simulate the effect of brine on the performance of pillar support. The testing program consisted of loading potash specimens in a creep frame, and simulating inflows by continuously pumping brine into an experimental cell. Brine temperatures and load conditions were varied to simulate several mining and inflow conditions. Specimens were fitted with acoustic emission transducers to monitor energy emissions during an eight-hour test duration. Samples of brine were also collected to provide K+ and Na+ concentration data necessary for an accurate assessment of the dissolution process. Test results indicated that dissolution rates are highly dependent on brine temperature and load conditions. Loads approaching 50% UCS tend to generate very high rates of energy emissions, often leading to the failure of the simulated pillars. This study demonstrated that acoustic emission could be effectively used for predicting the performance of pillars when exposed to inflow brine.

May 1, 2001

By D. Doyle, T. Cienski

"This paper presents and discusses the results of a detailed study conducted on the subject of energy consumption in the comminution of industrial minerals. The study was based on pilot circuit testing, plant operating data collection, detailed equipment data and literature research. The areas covered by investigations include: high efficiency classification; air classifiers for cement grinding circuits; grinding aids in dry grinding; and dry grinding circuit control based on particle size measurement. Results obtained indicate a large potential for the reduction of energy consumption, in particular in the cement clinker grinding circuits. Better classification techniques and correct application of grinding additives can significantly reduce power used per tonne of product and also substantially increase grinding circuit output."

Jan 1, 1992

By Paul Johnston

or is it? Mining Automated Loader Technology Application ? Intelligent software mounted in hardware on a remotely controlled scoop. ? Led by INCO, Sudbury, with ? C-CORE, St. John?s ? Automated Mining Systems, Aurora ? Bell Canada, Sudbury ? Laurentian University, Sudbury ? University of Western Ontario, London Completed: March 2000

May 1, 2008

By C. Juers

Laboratory chromate coating was applied on AM50 and AZ91D alloys and compared to phosphate-permanganate one. Evaluation of the corrosion behaviour was performed using electrochemical DC and AC methods in ASTM water D1384-87. This electrolyte was chosen because it was moderately aggressive and found to give generally good correlations with long period exposure results in atmospheric conditions. Electrochemical impedance spectroscopy was used to determine more accurately the corrosion rates from the analyses of the high frequency capacitive loop. Anodic polarization was applied in order to evaluate the pitting resistance of the different coatings. These results were correlated with weight loss data evaluated from experiments performed by immersion tests in ASTM water D1384-87 and climatic cyclic chamber tests.

Jan 1, 2006

By Z. Zhao, B. Li

"Fractures are the key channels for fluid flow and mass transport in fractured rocks of low/negligible matrix permeability. In single rock fractures, surface roughness causes fluid flow in tortuous paths, and reduces the overall fracture conductance. A number of empirical models have been proposed to relate the reduced hydraulic aperture to the mechanical aperture due to surface roughness, which were revisited and compared. Using two of those relationships between hydraulic apertures and mechanical apertures, we studied the influences of local surface roughness of fractures on fluid flow and solute transport processes at the macroscopic scales of fracture networks. The results show that fracture roughness can affect the flow rates and residence time to varying extent, mainly depending on the empirical models between hydraulic apertures and mechanical apertures. However, fracture roughness has negligible influences on the general patterns of fluid flow (channeling) and solute migration (e.g., travel paths and shape of breakthrough curves). This is because the connectivity of a fracture network is mainly determined by other geometrical parameters (fracture positions, orientations, and lengths), rather than roughness or apertures. INTRODUCTIONIn fractured crystalline rocks of low or negligible matrix permeability, fluid flow and contaminant migration mainly occur within the connected fractures. An understanding of fluid flow and contaminant migration in fractured rocks is a crucial issue in many deep underground projects, e.g. underground repositories for radioactive waste, CO2 sequestration, enhanced geothermal systems, oil and gas production, etc. Rock fractures are typically rough-walled, and surface roughness appears to have first order control on the mechanical and hydraulic behavior of single rock fractures (Boutt et al., 2006).It is well known that the mechanical aperture of a rock fracture is usually larger than its hydraulic aperture, due to fracture surface roughness (Tsang and Witherspoon, 1983). However, for naturally fractured rocks including numerous discontinuities, the effects of this reduced hydraulic aperture in local fractures on macroscopic fluid flow and solute transport in complex fracture systems still remain unclear. Many previous studies assumed identical hydraulic and mechanical apertures in discrete fracture network models for simplicity (Min et al., 2004; Zhao et al., 2011). Therefore, the main objective of this study is to evaluate the influences of local surface roughness of fractures on fluid flow and solute transport processes at the macroscopic scales of fracture networks, by employing the empirical models that relate the hydraulic aperture to the mechanical aperture."

Jan 1, 2015

By N. Kacira

"Canada's largest known chromite deposit occurs in a layered intrusion in the Bird River area of Manitoba. However, numerically most of the chromite occurrences are in the Appalachians. Few, apparently minor, occurrences are also known in the Cordillera.In the Appalachians, chromite occurs as lenses and pods in dunite; they are of ""podiform"" type. The individual concentrations vary in size from a few pounds to tens of thousands of tons. Locally, chromite concentrations form discontinuous zones extending several hundred feet along strike and presumably down dip, therefore resembling boudinaged layers. Chromite layering and lineation are commonly concordant to those of the host rocks.The Appalachian chromite occurrences are thought to have been formed by fractional crystallization and perhaps also by liquid immiscibility. Their present shape and distribution are largely the result of deformation mostly prior to complete solidification of their host rocks. Therefore, the attitude of layering, foliation, lineation and other features related to deformation provide valuable guides in predicting the probable distribution of chromite, and hence are helpful in exploration.Chromites fulfilling the requirements for metallurgical, refractory and chemical grades occur in the Appalachians. Although the Appalachian deposits are similar in size and grade to some of the chromite deposits being mined elsewhere, they are unlikely to be economic, at present, in the higher wage Canadian environment. However, in case of shortages in chromite ore supply which may result, among other reasons, from increasing tendency to further processing in the producing countries, the Appalachian occurrences may become sources of ore. Such eventual shortages combined with relative abundance of electricity in Canada and recent innovations in oxide ore reduction technology may hasten the time when ferrochrome manufacture based on local chromite sources becomes economically viable."

Jan 1, 1982

By A. Sutherland Brown

"The ProblemMany science activities receive substantial funding from governments without much direct economic benefit accruing to state or individuals. In contrast, the search for knowledge has never been an acceptable so le justification of geoscience activity, perhaps because of its utility right from its inception. William Smith's geological activities were embraced because of their usefulness in building canals. Utility has been expected ever since.For decades it has been accepted at senior level s of government, without much understanding of the process, that geological surveys are necessary as a basis of resource evaluation and utilization. Recently, government treasury board s, staffed with economist s, have questioned these near axioms and in many cases the budget s of geological surveys have reflected their stone y-eyed appraisal s. Are government surveys necessary? Can their functions be reduced? Can some or all of their functions be privatized?Government geologists have been muted in trumpeting their successes outside their own ranks. Companies have been reluctant to give specific public feedback on the work of government surveys that have truly aided or guided them toward discovery. Lack of acknowledged linkages between survey work and discovery has dogged survey managers in budget reviews. Impoverished surveys cannot perform adequately so the circle is completed and the doubters' prophecy fulfilled. This is the genera l problem; British Columbia is the archetypical province."

Jan 1, 1986

By G. Gu, B. Fang, R. W. Revie, M. Elboujdaini

Electrochemical behavior of an X-80 pipeline steel, including frequency-sweep electrochemical-impedance spectroscopy (EIS), time-sweep EIS at a constant frequency and open-circuit potential (OCP) monitor, was investigated using four-point bending specimens subjected to a stress-corrosion cracking (SCC) test in a near-neutral pH environment. The capacitive loop became smaller with test duration, revealing an increase in the corrosion rate. The resistance obtained in the constant-frequency EIS test showed two regions, of which the region with a remarkable decrease in resistance transformed into a region of slow decrease, whereas the capacitance increased with test time indicating that iron dissolution was fast at first, and then a corrosion product or film formed and covered the surface, leading to the pitting formation.

Jan 1, 2005

By J. Satur

In copper mineral processing, pyrite coexisting with copper sulfide minerals like chalcopyrite is separated by flotation as tailings and its oxidation in tailing dams causes the formation of acid mine drainage. This paper proposes carriermicroencapsulation (CME) as a new method for suppressing pyrite flotability, as well as its oxidation. In this method, an organic carrier combined with Ti is used to form a thin Ti02 layer on pyrite, which gives a hydrophilic property and acts as a protective coating against oxidation. To form the coating, a ground pyrite sample was treated with Ti-catechol complex solution under various conditions. Bubble pick-up experiments and flotation experiments showed that the treatment of pyrite with Ticatechol complex changed the hydrophobic nature of pyrite into hydrophilic even in the presence of xanthate as a flotation collector. Oxidation testing of the CME-treated pyrite by 0.02 kmol m-3 HN03 showed that Fe release was suppressed by the CME treatment with respect to the control. This is assumed to be due to the formation of Ti02 coating on the pyrite surface. The effect of CME treatment on chalcopyrite wettability is also discussed.

Jan 1, 2007

By J. Arzúa, L. R. Alejano, P. Rodríguez

"After six years of successful excavation with a support pattern, some roof failures have happened in a room-and-pillar underground mine excavated in a stratified rock mass. In this paper the authors give explanation to the failure mechanisms and redesign the support in order to solve the recent problems of roof collapse.The mine magnesite bed is approximately 14 m thick, and runs in the E-W direction with an average dip of 18º. Due to mine constraints and the inexpensiveness of the ore, the excavation is performed in the mineral itself, avoiding the need for mining dumps and waste excavation. Rooms and drifts are oriented in the mineral bed to form an angle of 19º to the direction of the strata, reducing the roadway gradients to less than 10%. Rooms are 11 m wide and pillars are 7 m wide. They are designed to leave a 1 meter thick magnesite bed in the roof of the rooms to act as a supporting beam. More often than not there is a layer of very poor quality marly shale up to 1 m thick resting on this magnesite beam. Overlying the poor quality marly shale there is a better quality, self-supporting sandy shale.First, a characterization of the involved rock masses (magnesite, marly shale and sandy shale) is performed, collecting the geotechnical data from previous studies and performing new in situ geotechnical surveys to check the soundness of the previous data. A distinction is made between different quality zones inside the mine by means of the RMR classification, associated to the occurrence of faults.Back-analysis of some of the failed rooms and data from exploration boreholes were used to determine the failure mechanisms (associated to Voussoir type failure or occurrence of sub-horizontal joints crossing the magnesite beam). Based on an understanding of these mechanisms, the method used to design the support and to analyse the stability of the different possible thicknesses of the magnesite beams of the rooms and drifts of the mine were improved.Numerical models of the most relevant conditions found in the mine were performed in order to better understand the behaviour of the roofs and to simulate the supporting solution obtained in the previous analyses.The most relevant conclusions with regard to the main elements causing the instability of the roof include the appearance of sub-horizontal discontinuities crossing the magnesite bed, which causes total instability of the roof and usually leads to collapse; excessive thinness of the magnesite beam in the problematic rooms; and the relaxation of the deepest (around 270 m in depth) zone of the mine because of existing faults."

Jan 1, 2015

By M. Brochu

In this paper, we present a computer-vision approach developed for wall-thickness measurements of corroded pipes inspected by double-wall radiography. The main objective of the work is to optimize data collection and film interpretation using computerized image analysis. To date, the system is able to identify the inner and outer contours of a pipe and perform wall thickness measurements at each pixel of a radiograph. This will be presented by analysing pipes having different dimensions. Another important feature of the system concerns the algorithms' adaptability to pipe wall texture. In other words, image analysis is automatically refined around rough or corroded areas. This allows more precise thickness measurements and shape identification in critical sections as will be demonstrated with examples. Finally a brief overview of results exploitation will be given and compared with human interpretation. It will show the reliability of automated image analysis and the many possibilities offered by complete output analysis.

Jan 1, 2005

By M. A. Upham

"Prairie Evaporites of the Province of Saskatchewan in a deep oil-well hole. Exploitation started in 1950 under a shroud of doubt that this huge reserve could be mined. It was fraught with almost insurmountable physical problems in penetrating the Prairie Evaporites. After 12 years of experimentation and development of new shaft-sinking methods, mining equipment and processes to treat the high-grade potash ore (sylvanite), a new era of high-risk resource development dawned in Saskatchewan.The development of 10 new mines opened up the largest known mineable potash reserves in the world and Canada became the second largest. producer of potash to supply domestic (U.S.A. and Canada) and overseas markets. A monumental program in marketing-devising new transportation systems and strategically locating warehouses-was developed in order to expeditiously service domestic and overseas customers. The year 1969/70 started a period of overcapacity and the problem of prorationing. As the market strengthened in 1974, the Saskatchewan Government applied the reserve tax to the industry. Then, they announced the setting up of a Crown corporation to acquire ownership by purchase of up to fifty per cent of the industry. During this time, potash was discovered in New Brunswick within 50 to 60 miles of a seaport, where two deposits have been explored by the same pioneers who started the potash development in Saskatchewan.With this background, the paper will examine various elements of the economics and marketing of Canadian potash."

Jan 1, 1980

By L. A. Melis, J. W. Rowson

"Cluff Mining has successfully operated a gold recovery plant at its Cluff Lake operation in northern Saskatchewan to recover gold f rom Phase 1 uranium leach tailings. The operating circuit consists of tailings repulping, grinding, cyanidation, carbon-inpulp, gold recov ery, and cyanide destruction by acidification, volatilization and re-neutralization. The process is described and operating data and metallurgical results from the operation are provided.INTRODUCTIONCluff Mining, a Saskatchewan partnership, is owned 20 per cent by Cameco and 80 per cent by Amok Ltd. /Ltée. (Amok), manager and operator of the partnership.The current operation includes the Phase II uranium mining and milling facilities, located at Cluff Lake, 700 km north of Saskatoon, capable of processing 300 000 tonnes o f ore to produce about 4 000 000 lb UPs (1500 tonnes of uranium) per year.The Phase I operation was initially established to process the very high grade ""0"" uranium orebody from 1980 to 1983. The leach tailings from the Phase I mill operation were found to contain elevated level s of gold . These high gold values were partially due to the gravity pre-concentration step included in the uranium recovery circuit, and to the naturally high levels of gold associated with the uranium mineralization in the""0"" orebody .During the Phase I operation some 6475 tonnes of leach tails were produced and stored in a total o f 2916 large concrete containers (vaults). This method of storage was, at the time, deemed to be the preferred method of temporary storage for the tailings.This temporary storage of high-grade gold tailings facilitated the reclamation and reprocessing of the leach tail s for gold recovery. The primary reason for reprocessing the Phase 1 leach tails was to provide for long-term permanent disposal of the material as an admixture with Phase II tailings in the Cluff Lake tailings disposal area. Although there was limited tonnage, the high gold content in the material made the in stallation of a gold recovery circuit economically justifiable."

Jan 1, 1989

While this paper is directed towards the ?Bellambie? type of rope attachment, the principles can be applied to any brand of rope fitting however, it is a only a broad outline and the specific installation and maintenance procedures can be obtained from the attachment supplier. The types of attachment to be discussed are:- ?Thimble Type rope cappel ?Wedge Type cappel ?WRC Rope Clamp ? (Rope Glands) ??Hoist and Balance Rope Sockets In each case, the assembly and stripping (disassembly) plus the basic maintenance procedures is briefly described. A guide for Risk Assessment is also included but because of his familiarity with the installation, the end-user is in the best position to draft the final version.

May 1, 2003

By D. A. Trotter

"Low-pressure sodium light sources have been available for several years, but have not received wide acceptance in underground mining. This is because they are difficult to operate using DC power, they are not an intrinsically safe light where explosive gases may be encountered and they give poor colour rendition.With the need for energy conservation, several Canadian hard-rock metal mines are now changing their lighting to low pressure sodium, as it has the highest efficacy of any light source in terms of lumens per watt. Studies have pointed out several other advantages as well. Glare can be controlled, they penetrate fog well, they are easily maintained, they have a long life and they give the highest visual acuity when compared to other types of lighting. As well, in an underground mine, contrast is much more important than colour for task identification. For close work, the colour problem is alleviated with the use of cap lamps.Case studies are presented from Canadian practice. These show how the lights are modified for underground use, calculations preceding light installation, and how and where the lights are installed in the underground environment. Mention is made of worker reaction to the lights and possible physiological effects.IntroductionThe importance of good underground lighting to the total environment of mining cannot be overemphasized. In addition to the obvious benefits of improved worker morale, available studies show that good lighting practices reduce accident severity and frequency as well as increase production."

Jan 1, 1982

By Andreas Zielonka

To meet the increasing demands of the quality and long term stability of technical systems also the applied materials have to full fill higher standards. This is of special importance where the function of a whole system depends on the reliability of the used materials for example for connector systems in automotive, computer and other electronic equipment?s. In most cases for connector systems electro deposited top layers are applied. To improve the quality of the applied layers new electro deposited systems are developed. One important field of research are the development of composite materials as dispersion coatings and multilayer systems. Multilayers are systems with a high number of single inter-layers of different metals or alloys with the wide chance of the alloy composition. As gold is one of the most important contact material for high quality connector systems it is used as basis for the development of multilayer systems. For the electrodeposition of multilayers two different methods can be applied, the single and the dual plating process. As in the dual plating process two different electrolytes are used, the single plating process allows the formation of multilayers from one electrolyte. In the presented research results cobalt and nickel are used besides gold for the formation of the multilayers. The properties of the layers can be influenced in a wide range by the change of electrolyte composition and the process parameters as current density, current waveform, temperature, hydro-dynamic conditions at the electrode surface and by the number and thickness of the inter layers of the deposited materials. The paper describes the fundamentals of the electro deposition of multilayer systems. For the investigation of the properties of the multilayers different techniques are applied. One of the most important parameter are the thickness of the total layer and of the applied sublayers. The thickness of the sublayers can be varied between a few nanometers up to micrometers. The wear resistance, the contact resistance and the plug-in forces are measured as these parameters are important for the technical application of such layers. For the description of the structure composition and surface properties the sample where also investigated by scanning electron microscopy (SEM), energy dispersive x-ray-analyses (EDX) and glow discharge optical spectroscopy (GDOS). The paper shows that the deposition of gold based multilayers is possible and that the properties of such systems can be varied in a wide range what opens new fields of applications of such materials.

Oct 1, 2003

By M. Fafard, D. Picard, J. -F. Bilodeau, G. Soucy

To simulate adequately the behaviour of a Hall-Heroult electrolysis cell, a finite element model must take into account the properties of each material. However, it has some lacking knowledge on the mechanical behaviour of materials, like the long-term visco-elastic (creep/relaxation) behaviour of cathode. A three-dimensional model is then proposed in this paper and will be ready to be implemented in the finite element code FESh++. The model was developed using the three-dimensional model based on thermodynamic of irreversible processes where the choice of the internal variables is based on a phenomenological approach. All parameters of the model are represented by constant constitutive tensors and the temperature and chemical dependencies are taking into account through scalar functions multiplying the constant constitutive tensor. The goal of the first part of this project was to determine the parameters of the threedimensional visco-elastic model at the reference state (virgin material at ambient temperature) of three different cathode materials. This paper presents the theoretical model and the results of creep tests at ambient temperature for the semi-graphitic carbon cathode.

Jan 1, 2006