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In this study, flotation of fine galena, chalcopyrite and pyrite was performed after grinding with different extent of oxidation-reduction condition adjusted by grinding media. Sodium dithionite and iron ions were added in mill to simulate pulp potentials and iron oxidation species produced by grinding media, respectively. The types and quantities of the metal oxidation species on mineral surfaces were determined by EDTA extractions, while the surface electrical properties of minerals and interaction of different types of metal oxidation species were studied by zeta potential measurements. It was found that the nature and concentration of the absorbed metal oxidation species were dependent on oxidation atmosphere controlled by the iron amount of grinding media. These species interacted with each other and had an important role in determining flotation of fine galena and chalcopyrite as well as activation of fine pyrite by lead and copper.

Jan 1, 2006

By C. O. Staples, J. G. Morrow

The application of cationic flotation to the upgrading of magnetic concentrates was investigated in the laboratory by both batch and continuous test procedures. It was found that the collection of coarse gangue particles with amine, heretofore considered a serious obstacle to this particular application of cationic flotation, is greatly enhanced by a drastic reduction in what might otherwise be considered normal impeller speed. Gangue flotation is in-dependent of variations in the rate of aeration. The collector and Crother additions and the impeller speed which favour the formation of a matte froth yield optimum results.

Jan 1, 1966

By K. Kawagishi, K. Matsumoto, Y Koizumi, H. Harada

A new burner rig for cyclic and hot corrosion testing of Ni-base superalloys and high-temperature coatings has been developed at the National Institute for Materials Science (NIMS) in Japan. The concepts of the rig design include: use of kerosene as fuel, easy operation for materials research and multi-specimen testing capability per test run. The burner rig consists of six blocks including combustion block, corrosion-solution injection block, furnace block, specimen block, controller block and outdoor facility block. During verification testing, it was confirmed that the rig had accurate specimen temperature control within ±1? from 600 to 1100? and automated easy operation. Cyclic testing of several Ni-base superalloys was conducted. The results from 50 cycle testing indicated that a new NIMS alloy developed for 1700? class gas turbine had higher oxidation resistance than CMSX-4. This new burner rig testing capability at NIMS can be very useful for future oxidation, hot corrosion and coating durability studies.

Jan 1, 2010

By A. Khodadadi, M. Abdolahi, P. Taimory

Cyanide is used by the mining and chemical industries in tremendous quantities without attention being given to its hazardous properties. The use of cyanide compounds in mining is one of the most important environmental issues for the mining industry due to the acutely toxic properties of many cyanide compounds to humans and aquatic life. Cyanide tends to react readily with most other chemical elements, producing a wide variety of toxic, cyanide-related compounds and because cyanide is carbon based an organic compound it reacts readily with other carbon-based matter, including living organisms. This research is aimed at investigating a feasible and economical technique for the removal of cyanide from tailing wastewater of Muteh gold mine. In this research, removal from Muteh factory's waste water, was achieved at Tarbiat Modares University's mineral processing laboratory through the oxidation of cyanide by calcium hypochlorite. Cyanide oxidizes and changes to cyanide (CNO-) which is 1000 times less environmentally hazards than cyanide. Cyanide titration was accomplished using Rhodanine solution and silver Nitrate. Cyanide concentration in the wastewater, was 270 mg/L. Cyanide removal was achieved at an optimum pH of 12.3. However, at higher temperatures, cyanide removal was complete at this pH level. Optimum Dosage for complete removal of cyanide using calcium hypochlorite was 1.43g/L.

Jan 1, 2005

By Jamel Sgaoula

During 1998 COGEMA Resources Inc. announced that operations at the Cluff Lake mine will be suspended indefinitely by the end of year 2000 as a result of deteriorating uranium market conditions. To remain profitable, Cluff Lake mine started an aggressive cost reduction program. A cost reduction team was formed to look for ways to lower production costs. The focus of this team was to screen all areas and to come up with ideas to improve the economy of the mine and ensure the viability of the operations over the remaining three years of operations. Among the areas where significant savings were achieved are: (1) replacement of portion of cement with fly ash in backfill; (2) backfill optimization; and (3) new shotcrete plant installation on site for bulk in-house shotcrete production. This paper details the research work carried out by Cluff Lake mine on these projects and results of its application.

May 1, 2001

By T. Abu Leil

A new class of ternary Mg-Sn-Ca alloys is being developed to address the dual demands of corrosion and creep resistance at service temperatures. While tin has proven to enhance the corrosion resistance, calcium is expected to significantly increase their creep resistance of binary magnesium alloys. Their effects in ternary magnesium alloys are not yet known. The series of alloys studied has Sn and Ca in the ranges 3-6% and 1¬2%, respectively. The results indicate that these alloys have two-phase structures with CaMgSn phase dispersed in a matrix that is predominantly a solid solution of magnesium. The corrosion behavior of these alloys has been investigated by means of salt spray tests and potentio-dynamic measurements. Creep behavior of these alloys was measured at a temperature of 135 C under an applied compressive stress of 85 MPa. Scanning Electron Microscopy with Energy Dispersive X-ray facility and X-ray Diffraction techniques were used to characterize the microstructures. The results indicate the prospect of designing alloys that can provide optimum combinations of corrosion and creep resistance by adjusting the relative compositions of Sn and Ca in the system.

Jan 1, 2006

By C. Mattich, Å. Holmström, L. Hedström

"The fluidized bed at Division Ministro Hales (DMH) division of Codelco in Calama, Chile is currently the largest operating roaster for partial roasting of arsenic rich copper concentrates. The roaster converts the Mina Ministro Hales (MMH) enargite rich (Cu3AsS4) copper concentrates into calcine with a low arsenic content that is suitable for mixing with other copper concentrates feeding a flash furnace. The plant sets a new standard for the processing of arsenic rich concentrates, both from the quality of the calcine as well as the environmental performances. The process technology and expertise are based on the solid practical experience of treating arsenic rich concentrates from both the Boliden smelter and Outotec.The partial roasting process is located next to the mine and concentrator and includes a sulphuric acid plant with auxiliary equipment. The produced calcine has an arsenic content significantly below target and the residual sulphur meets the requirement of the flash furnace. The plant operates with high efficiency cyclones resulting in a low amount of calcine passing to the hot electrostatic precipitator (HESP). The small flow of HESP calcine dust can be combined with the low arsenic calcine and still meet the flash furnace feed arsenic requirements.SO2 formed during roasting is converted into sulphuric acid, while volatized arsenic is recovered in the wet gas cleaning section of the acid plant along with a large proportion of antimony present in the MMH concentrate. Arsenic is stabilized as calcium arsenate and sent to disposal at a specially prepared site.The present production rate (September/October 2015) is close to or higher than the original maximum design capacity of the plant.INTRODUCTIONMineralogyThe mineralogy of an ore and concentrate is important, since there is a direct link between roasting performance and concentrate mineralogy. The MMH concentrate has a good combination of minerals that makes the roasting process efficient and flexible. The main minerals are pyrite, enargite and chalcocite (Figure 1). The inert content is about 15% and consists mainly of silicate and alumina based minerals. The lead content is very low and this is desirable, since the presence of even a small amount of lead will cause a substantial increase of sintering during roasting."

Jan 1, 2016

By C. Lara-Valenzuela, R. Perez-Garibay, F. López-Saucedo, A. Uribe-Salas, L. Magallanes-Hernandez

A relationship between gas dispersion parameters, namely gas rate (Jg), gas holdup (Eg), average bubble size (db) and bubble surface area flux (Sb), with the metallurgical performance (e.g., grade and recovery) has been established.. Results of eleven columns operating at five concentrators of Grupo Pefioles (Mexico), ranging between 1.52 to 3.35 min diameter and performing in the cleaning stages of lead and zinc circuits, are presented and discussed. The results showed that the effect of gas dispersion parameters was consistent and that both, Sb and Eg, correlate well with recovery particularly when the influence of feed pulp density is also considered.

Jan 1, 2009

By R. L. Eadie, J. L. Luo

The effect of plastic deformation on near-neutral pH stress corrosion cracking (SCC) also known as environmentally assisted cracking was studied by cracking rate measurements. All the tests were conducted in a synthetic near-neutral pH solution. The traditional potential drop tests using compact toughness (C-T) specimens with 2-3 mm long pre-cracks showed varying plastic deformation by rolling would increase the material's susceptibility to SCC. This was confirmed by cyclic loading tests using double notched flat tensile specimens with 200-300 µm long pre-cracks which gave the same results that the specimen with large scale plastic deformation by tensile loading had a relatively faster crack growth rate than that with only small scale plastic deformation.

Jan 1, 2005

By Vlad Ruzicka

"Uranium deposits in the Rabbit Lake-Collins Bay area are associated with the sub-Athabasca unconformity which separates crystalline Archean or Aphebian basement rocks from Helikian clastic sedimentary rocks of the Athabasca Group. The basement rocks are a part of Wollaston lithostructural domain.Most of the high grade deposits, such as Collins Bay ‘A’ and 'B' Zones and Eagle Point are associated with altered rocks of the basal unit of the Wollaston Group. Some deposits, such as Raven and Horseshoe are confined to the uppermost unit of this Group. The Rabbit Lake deposit occurs in the middle, meta-arkose unit of the sequence. Locations of some deposits (Rabbit Lake, Collins Bay ‘A’ and 'B' Zones) are also controlled by thrust faults, such as Rabbit Lake Fault and Collins Bay Fault.The deposits contain either monometallic (uranium) mineralization (Rabbit Lake, Raven, Horseshoe) or polymetallic (mainly uranium-nickel) assemblages (Collins Bay “A’ and 'B' Zones).IntroductionThe Athabasca Basin region, a part of the Churchill Geological Province of the Canadian Shield, is composed of Archean and Aphebian crystalline basement and younger, Helikian, unmetamorphosed supracrustal rocks. The Rabbit Lake-Collins Bay area is situated at the eastern margin of the Athabasca Basin region, which hosts a substantial proportion of Canadian uranium resources.The crystalline basement complex was subdivided by Lewry and Sibbald (1979) into lithostructural domains and these domains were grouped into major crustal units designated, from northwest to southeast, as Western Craton, Cree Lake Mobile Zone, consisting of Wollaston, Mudjatic and Virgin River domains, and Rottenstone Complex (Fig. 1)."

Jan 1, 1986

By Francis Breton, Lei Pan, Kun Liu

"Effects of Fe, Cu and Mg minor alloying elements on creep properties of 8xxx aluminum conductor alloys were investigated by conducting compressive creep tests at 100 ºC under a constant load of 69 MPa. The microstructural evolution was studied using an optical microscope and electron backscatter diffraction technique. The creep properties were characterized by the primary creep strain in the first stage and the minimum creep rate in the second stage of creep deformation. Results showed that additions of all three minor alloying elements (Fe, Cu and Mg) demonstrated a beneficial effect on the creep resistance but individual alloying elements exhibited different impacts on creep properties. The additions of Fe and Mg showed a strong impact on both the primary creep strain and minimum creep rate, while the Cu addition displayed a favorable effect on the primary creep strain but no impact on the minimum creep rate. Microstructure observation revealed that with increasing Fe contents, the volume fraction of fine intermetallic dispersoids gradually increased while the subgrain size and misorientation angle became smaller, providing strong barriers to the dislocation and grain boundary movements. The addition of Cu moderately reduced the subgrain size and misorientation angle and in combination of solid solution strengthening it promoted the retardation of the creep deformation during the primary stage.INTRODUCTIONThe 8xxx aluminum conductor alloys offer significant advantages such as low density, high conductivity to weight ratio and low price over copper conductors and become an attractive candidate in electrical engineering and building wiring (McQueen, Chia, & Starke, 1986; Birol, 2009; Engler, Laptyeva, & Wang, 2013). The mass resistivity of aluminum conductors is one-half of copper conductors. Thus, only one-half the weight of aluminum is required for equivalent capacities. Therefore, this unique property coupled with a relatively low price of aluminum offers significant economic advantage to develop aluminum conductor alloys for electrical applications in the electrical wire industry."

Jan 1, 2016

By Richard Lavallée

La Mine Louvicourt est une mine hautement mécanisée exploitant un gisement polymétallique avec des chantiers transversaux minés et remblayés selon une séquence primaire-secondaire. Dans certaines parties du gisement, il n'y avait qu'un accès à la coupe inférieure, car il n'était pas rentable d'avoir aussi un accès par coupe supérieure. Le minerai situé au-dessus des chantiers avec trous ascendants était considéré comme ressource non rentable par minage mécanisé. L'option de miner ces ressources avec des sous-niveaux avec accès par monterie alimak et forage long-trous de petit diamètre fût donc étudiée et démontra une rentabilité intéressante, particulièrement en considérant les tonnes ainsi minées comme tonnage supplémentaire au tonnage planifié. Dans ces chantiers, les détonateurs électroniques ont été très utiles et de plus, les coûts d'explosifs ont étés réduits considérablement par l'utilisation d'émulsion pompée en vrac.

Oct 1, 2004

By T. ?kre, O. M. Dotterud, S. Haarberg, J. Thonstad, G. M. Haarberg

An electrowinning pilot plant has been constructed at Falconbridge Nikkelverk A/S, Kristiansand, Norway. The equipment consists of a mixing tank where the electrolyte composition and temperature are controlled, an electrowinning tank equipped with five cathodes and six anodes of commercial size and design and a dechlorination facility. Electrowinning experiments were carried out in this pilot plant using acid cobalt chloride solution from the cobalt tankhouse. Key parameters were varied to obtain an improved understanding of the cobalt electrowinning process, focusing on the detrimental deposition of cobalt oxide on dimensionally stable anodes. The extent of anode scaling was found to be dependent on the electrowinning conditions. Low pH, temperature and cobalt concentration resulted in less scale being formed, however at the expense of cobalt current efficiency and cell voltage, adversely affecting electrowinning production capacity and energy consumption. When operating at high acidity, pH in the anolyte was higher than in the catholyte, which is believed to be due to H+ ions taking part in the current transport across the diaphragm, migrating out of the bags surrounding each anode.

Jan 1, 2005

By Masatsugu Morimitsu

This paper introduces new technology of oxygen evolution anodes which can be applied to produce copper, zinc, cobalt, and other metals by electrowinning. The anode consists of nano iridium oxide particles dispersed in amorphous tantalum oxide matrix as a catalytic layer formed on a titanium substrate. The anode can reduce oxygen evolution potential by 0.25 to 0.55 V compared to commercially available lead alloy anodes and can suppress unwanted side reactions such as manganese oxyhydroxide, lead oxide, cobalt oxyhydroxide which occur during oxygen evolution in the electrowinning solutions. This technology is effective for environmentally friendly electrowinning processes with low energy consumption and less anodic deposition.

Jan 1, 2011

By J. A. Finch, A. M. Elmahdy

Blending frothers is becoming common in flotation practice apparently enhancing performance. However, there have been no studies to understand the blend mechanism. In this paper, the effect of two frother blends ofF150 (polyglycol) with MIBC or pentanol (both alcohols) on bubble size, gas holdup and froth height is reported. The blends focused on a small addition of the polyglycol to the alcohols as base frother. The tests showed that the bubble size at blend concentration below the critical coalescence concentration (CCC) of the base frother was decreased but was significantly larger above the base CCC. Froth build-up showed a strong synergistic effect.

Jan 1, 2009

By Randy McMeekin, Chris Twigge-Molecey, J. Peter Blake

The business objectives of a metallurgical project determine targets and constraints, such as the range of products, production capacities, in-service dates, and capital and operating cost parameters. Permitting is usually left to the project team, as are decisions regarding site location, technology, and construction approach. Success requires an orderly methodology, represented in this book by front end loading (FEL) phases: FEL1 examines several alternative approaches; FEL2 ranks and eliminates less economically or technically attractive options; and FEL3 develops the preferred option to the point of major permit completion, with defined scope, schedule, and cost to submit for approval to proceed with implementation in FEL4. Working through FEL1, FEL2, and FEL3, the project definition improves, estimates become more accurate, and project risks are reduced. The project design basis at the end of FEL3 is the control document for project implementation in FEL4.

Jan 1, 2015

By N. Saracoglu, R. H. Wallis, J. E. Betz, F. L. Jagodits, B. R. Krause

"Geophysical test surveys were conducted with various methods (EM, lP, gravity and magnetic) over the McClean uranium deposits of the Canadian Oxy- lnco Joint Venture. The result s were assessed to judge the contribution each method might make toward further discoveries of graphite-associated uranium occurrences.The best drill targets have proven to be discontinuities in graphitic conductors and locations where the tatter are intersected by fracture zones in the Athabasca. The tests demonstrated that the preferred combination of geophysical survey s is horizontal loop EM to locate graphitic conductors in the basement and VLF-EM to locate the fractures.IntroductionThe discoveries of the McClean North and South uranium deposit s (Fig. 1) are essentially geophysical successes resulting from drilling MaxMin delineations of INPUT airborne electromagnetic responses (Saracoglu et al., 1983). After the initial discovery in 1979, various geophysical methods, techniques and instruments were employed to test their effectiveness in this environment and to guide exploration for other deposit s of a similar nature in the remainder of the 260 km2 property.The McClean uranium deposits lie below 150 m to 180 m of overburden and Athabasca Group. Radioactive signatures might be expected; however, the Athabasca Group acts as a barrier to radioactive emanations. Fortunately, the uranium mineralization is associated with graphite in the crystalline basement. Prior drilling of ground electromagnetic anomalies confirmed that EM surveys could locate and out line basement graphitic conductors. However, as there were many anomalies, most of which could not reasonably be expected to be associated with uranium , there was need to identify additional parameters, related to mineralization, which could be detected geophysically and used to narrow the search."

Jan 1, 1986

By C. Robinson

The Diavik Diamond Mine is located in one of the most remote and forbidding places in the world, 220 kilometres south of the Arctic Circle and on the bed of a vast northern lake, Lac de Gras. A single road, built out of ice and crossing frozen lakes, connects the mine with other operations and Yellowknife, the capital of the Canada's Northwest Territories. Diamonds were first discovered in the Lac de Gras region in the early 1990s, and construction of the Diavik Diamond Mine was completed in 2003. Diavik currently mines three kimberlite pipes. Open pit mining has now concluded and all three pipes are mined using underground mining methods. In early 2010, Diavik began mining and processing initial ore from its new underground mine; underground mining operations are expected to continue beyond 2020. The initial mine ventilation system was an exhausting (pull) system with fresh air supplied by a fresh air raise and a main ramp. Return air was exhausted via two raises and a secondary ramp. The system had a total flow capacity approximating 401-411 m3/s. With planned increased production and with changes in mining method, it has been proposed to change the mine ventilation system to a positive (forcing) ventilation system in order to meet projected increases in flow requirements of 566-708 m3/s. Extensive engineering work was developed in order to successfully achieve the changes in system configuration. In the proposed configuration, the main ramp is in an exhaust configuration and exhaust raises are converted to fresh air raise. A number of system implementation options were investigated and phased plans for system execution have been developed. The proposed changes to the ventilation system are substantial and involve extensive construction work. Work was commenced in 2011, each planned phase has been successfully completed to date, and system changes continue today in order to achieve complete system flow reversal and increased flow distribution. This paper details the design of the modified ventilation system and commissioning work which will allow the mine to meet its future production targets.

Aug 1, 2013

By M. J. Nicol, C. van Wensveen

The kinetics of the oxidation of thiosulfate by copper(I I) in ammoniacal solutions have been studied in the presence and absence of dissolved oxygen. The formation of an intermediate mixed ammine/thiosulfate copper(II) complex ion has been confirmed and the rate of the reaction monitored by simultaneous on-line spectrophotometric, dissolved oxygen and potentiometric measurements. The rate of the anaerobic oxidation of thiosulfate by copper(II) was found to be orders of magnitude slower than that in the presence of dissolved oxygen and is inhibited in the presence of ammonia and anions such as sulfate and chloride as a result of competition with thiosulfate for the axial coordination sites on the copper(II) tetrammine complex. In the presence of dissolved oxygen, it was found that the copper(I) thiosulfate complexes are only very slowly oxidized while the copper(I) diammine complex is rapidly reoxidised to the copper(II) state. Thus, the initial rapid reaction with copper(II) leads to a pseudo steady-state condition in which the concentration of copper(I) is relatively constant and the rate of oxidation of thiosulfate can be predicted from the measured rate of oxidation of copper(I) by oxygen in ammoniacal solutions. The effects of the concentrations of ammonia and thiosulfate on the oxidation rate can be rationalized on the basis of the above coupled to the species distribution of copper(I) in the ammonia/thiosulfate system. It is shown that, with relatively simple measurements of dissolved oxygen and copper concentrations, the rate of oxidation of thiosulfate can be predicted under typical leaching conditions.

Jan 1, 2005

By Guoxiang Chi

The Cornwallis Fold Belt in the Canadian Arctic Archipelago contains numerous Mississippi Valley-type (MVT) Zn- Pb occurrences and the world-class Polaris deposit. The occurrences are mainly hosted by the dolostone in the Thumb Mountain Formation which spreads over 25000 km2. Success in exploration requires further understanding of the genesis of these occurrences and an assessment of their parentage with the giant Polaris deposit. Syn-sulfide dolomites in regional occurrences share C-O-Sr isotopic characteristics similar with Polaris dolomites, indicating warm basinal brines enriched in 87Sr. The dolomites and sphalerites contain fluid inclusions with ice-melting temperature between ?45° and ?25°C, which is significantly lower than for most MVT districts in the world (?30° and ?10°C). These characteristics indicate that all the Cornwallis occurrences were produced by fluids of the same sources and/or aquifers. The deposit size was largely controlled by the rate and duration of the metal-carrying fluid flow, and by the availability of reduced sulfur at the site of mineralization.

May 1, 2001