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By G. Russo

During the construction of the S.Martin La Porte access adit, 9m in diameter, extreme squeezing conditions occurred while crossing Carboniferous schistose formations, with diametric convergence up to 2m. Back-analysis of monitoring results shows that an acceptable simulation of the observed excavation behaviour can be derived using a combined analytical and numerical approach, with simple elasto-plastic laws but a progressive reduction of residual parameters and a relevant increase of dilatancy.

May 1, 2009

By Behzad Vaziri Hassas, Firat Karakas, Esra Tanisali, Mehmet S. Çelik, Ahmad Hassanzadeh

Coagulation is basically an aggregation process where particles settle under the influence of interfacial forces with electrostatic forces playing a governing role. Although particle morphology consisting of shape and roughness dictates the physical encounter of two particles, their eventual coagulation is not only influenced by columbic forces but also other interfacial forces such as hydrophobic interaction, which affects the extent of aggregation of particles through increasing the distance of interaction. Roughness is well known to increase the effective contact angle on hydrophobic surfaces and also enhance interfacial forces. In this study, the effect of morphology of particles and particularly roughness on the settling velocity and in turn coagulation tendency was investigated. Batch settling tests (BSTs) of different particle morphologies were investigated as a function of pH. Two different morphologies of silica particles were utilized with the same particle size distribution (PSD) including smooth-spherical and rough-spherical (Etched). Rough particles were prepared by acid etching technique using hydrofluoric (HF) at different time intervals (15-300 sec). Etched samples were identified and quantified by optic profilometry. Settling test results showed that the settling velocity of particles in a suspension of 2% solids in the massive settling region is significantly affected by particle morphology of the suspension. Coagulation results further revealed that aggregation of rough particles is faster than smooth-spherical particles. Coagulation results are elucidated on the basis of particle morphology and its effect on distance of separation through hydrophobic forces.

Jan 1, 2016

By Mitchell Gordon

"In almost all thickener applications the highest possible solid/liquid separation efficiency is what is desired by the user. There is a trend in the industry due to monetary restraints and environmental pressures to look at ways to extract this maximum performance by either retrofitting existing thickeners or installing the most cost effective new thickener. This paper looks at some of the common problem areas and presents a range of solutions developed by Outokumpu Mintec in North America and outokumpu's subsidiary Supaflo Technologies Pty. Ltd.The Emerging PictureAfter many hours of discussions with a large number of plant personnel over the last two years a picture began to emerge regarding current thickening operations in the industry. Initially, it seemed that everybody had their own unique process problems and therefore needed a correspondingly unique solution. Looking more closely at all the cases and the ideas that we had either implemented or suggested, it gradually became apparent that the majority of operators all had one and the same process need ....""Better Separation Efficiency""The range of operational problems that were uncovered in the survey were much more varied than expected and often were not even considered initially to be thickener problems. Often, it was only after the rejection of many solutions to the problem, generally due to capital cost, that the actual cause of the problem was looked at and found to be a thick-ener.A summary of the problems that have so far been identified is presented in Table 1. They are subdivided under three major categories of environmental, process and paste fill to highlight the wide range of mining activities that can be affected by poor thickener performance. These seem to be the major areas where the need for better separation efficiency is rooted."

Jan 1, 1995

By J. F. Henderson

"IntroductionTHE National Advisory Committee on Research in the Geological Sciences was set up by the Privy Council of Canada in 1949. It was set up because you, the Geology Division of the Canadian Institute of Mining and Metallurgy, asked that it be set up. The Committee is, therefore, to a consider-able degree, your offspring. In the role of good parents you, of the Geological Division of the C.I.M., should be interested in the progress of your progeny. How is the Committee organized? What has it recommended? What has it accomplished? On behalf of the National Advisory Committee, that is what I want to tell you about this afternoon.HistoryYou will remember that, in 1946, the Geology Division of the C.I.M. set up a Committee on Geological Research. This Committee, under the Chairmanship of Dr. J. E. HAWLEY, found ""that there is no national organization interested in surveying, co-ordinating, and implementing with financial help, fundamental and much needed geological research. Accordingly, the first and most necessary step to put the geological sciences in Canada on a proper footing .is the recommendation that a National Advisory Committee on Research in the Geological Sciences be formed"" (l).This recommendation was endorsed •by the President and Council of the C.I.M. in 1947 and submitted to the Minister of Mines and Resources."

Jan 1, 1952

By B. McFadzean, I. Achaye, T. Chidzanira, J. Wiese

"Froth stability has an overriding effect on metallurgical recovery and grade for many ore types. Froth recoveries of less than 10% are common for low stability froths such as those in sparsely mineralized ores or in cells at the back end of flotation circuits. It is well known that, aside from chemical factors such as frothers and electrolytes, the mineral particles themselves have the dominant influence on froth stability. The particle properties of size and hydrophobicity are expected to have the greatest effects on froth stability. The aim of this study was to understand the effects of particle size on froth stability and to quantify these relationships.The study compared a synthetic ore of pyrite and quartz, with carefully controlled size ranges and hydrophobicity, with conventionally milled platinum-bearing UG2 ore and the bulk reverse flotation of hematite ore. A novel bench-scale continuous column flotation cell and continuous mechanical hybrid cell with large relative froth volumes, as well as a three-phase froth stability column were used to characterize the froths.It was found that froth stability could be related to the concentrate particle surface area by a Langmuir-type relationship. This is indicative that the mechanism by which particles stabilize the thin films in froths is similar to the mechanism by which surfactants lower surface tension. Different froth stabilities were found for different ores and this was thought to be the result of different particle sizes and distributions, which resulted in different packing densities in the thin films and Plateau borders. Interestingly, there was a clear relationship between the feed particle size and the froth stability even though froth stability was dependent on the concentrate particle surface area. It seems that the feed particle size is a good predictor of the surface area of particles in the concentrate. Concentrate particle size did not show a clear relationship with froth stability since it was already shown that it is both the size and the amount of the particles in the froth that contribute to the stability.INTRODUCTIONThe stability of the froth in froth flotation is important to the recovery and grade of the valuable mineral. Too stable a froth and the grade is reduced; not stable enough and the recovery may be compromised. Platinum-bearing ores with fragile, poorly mineralised froths are known to have froth recoveries that are routinely less than 10% (Crosbie et al, 2009). There are a number of chemical, physical and operating parameters that can affect froth stability, including reagent dosages, air flow rate, pulp density and particle properties. Arguably, the largest contribution to froth stability is from the particles that stabilise (or destabilise) the thin films in froths. Particle size, hydrophobicity and shape all affect froth stability to some extent."

Jan 1, 2016

By Walter Curlook

"With Inco recording record profits over the past year, most people have forgotten the painful years of the last recession/depression when Inco was losing up to a million dollars a day for a short period . While high nickel prices have contributed to the exceptional recent profits, the real achievements stem from the tremendous advances in productivity and cost improvements that make Inco one of the lowest cost nickel producers.Some of the major advances in productivity have occurred in the mines. The establishment of Mining Research Departments in both Thompson and Copper Cliff in 1979/80 provided the stimulus and the opportunity to dedicate personnel to specific research projects, on a full-time basis; and more particularly to concentrate on the efficiency of the total mine system. The Copper Cliff North Mine was brought back into production as a research mine dedicated to the development and testing of new mining methods and equipment. A shop facility known as the ""Murray Shop"" was set up as the centre of innovation for the development and construction of prototype equipment required for new bulk mining methods. While other expenditures were being curtailed , investment in mining research was being increased. An early success was an ""in the hole"" drill that could be broken down into small components to access even the remotest sectors of a mine to convert labour intensive undercut-and-fill mining to "" vertical crater retreat "" , VCR, bulk mining. A new mine manufacturing company-Continuous Mining Systems-was incorporated with the objective of building innovative mining equipment, with strong focus on automated continuous sytems. Continuous Mining Systems has now grown to a $25 million per year business. With these synergistic thrusts, the VCR bulk mining method was implemented in all of the Ontario Division mines, raising the percentage of ore mined by bulk mining techniques from 320/0 in 1981 to over 90% today. Coupled with re-designed job responsibilities, sup- ported by appropriate training, mine productivity more than doubled. It was discovered that VCR mining could be adapted to the narrower Thompson mine ores with identical improvements in productivity. Development of the Thompson Open Pit North had an additional favourable impact on production cost s in Thompson. The timing of the open pit development could not have been better. It permitted Inco to rapidly increase production at high productivity and low cost, in years of record demand and prices."

Jan 1, 1990

By W. B. Evans, D. P. Taylor

"ANFO has two major disadvantages as an explosive low density and no water resistance. ANFO can be blended with more dense, water-resistant explosives to form ""Heavy ANFO"". The use of emulsion or slurry explosives as a matrix is an attempt to correct deficiencies on the basic ANFO while maintaining cost effectiveness.This paper will deal with four main topics.1. Product description, general properties, strengths and weaknesses.2. Technology of ""Heavy ANFO"" , the emulsion matrix concept and the range of products.3. Relative performance and economics in various rock types.4: Current status in Canada and worldwide, and the expectations for future use.IntroductionANFO has been in use for roughly three decades and remains the explosive of choice where conditions are suitable. ANFO has not become the universal explosive - despite its undoubted superiority in cost effectiveness - because it has serious flaws as an explosive. The most serious of these flaws are the low density and absence of water resistance in ANFO. Low density implies a low concentration of explosive energy in a borehole. The amount of energy available can be increased by. adding an energetic material, generally aluminum, or by drilling more holes. Both solutions add considerably to the over-all costs. The absence of water resistance in ANFO is inherent and can only be overcome by changing the fundamental nature of the product. The history of research in the explosives industry since the advent of ANFO is mainly the story of the various attempts to overcome one or both of ANFO's shortcomings.Many technologies and products have been developed to compete against ANFO, among them slurries, emulsion s and the so-called Dense ANFOs (ANFO with an extra nitroalkane liquid sensitizer). None of them was cost-competitive with ANFO so their market penetration has been limited to wet holes or specialized applications. The exception to this result is Heavy ANFO. The aim here was to have the best of both worlds, the high density and water resistance of emulsions or slurries plus the low cost of ANFO. The concept is very simple. ANFO is about 50 % air, roughly 30% in the prills and 700,10 between the prills . The air in the prills provides the necessary sensitivity but the air between them is waste volume. If one fills this volume with a high density, waterproof product, the resultant mix will be denser and more water resistant than ANFO and with very little added cost. This basic concept was invented by B. Clay in the 1970s and is covered by Canadian Patent No. 1 115 959. The water resistance and/or density of the mix can be tailored by changing the emulsion level. Because Heavy ANFO is relatively inexpensive while providing good in-hole densities and water resistance, it can compete successfully against all other bulk products. It competes against ANFO and Al / ANFO by allowing pattern expansion and reducing over-all costs while it competes against emulsions and slurries on price."

Jan 1, 1987

By A. Montini, M. H. Moys

"A conductivity probe mounted in the shell of the mill has been used to measure the behaviour of the load in the mill as a function of operating variables. It was found that certain properties of the conductivity signal correlate strongly with the per cent solids of the slurry passing through the mill; in particular the angular location ?D of the shoulder of the load is an increasing function of the per cent solids. A method for measuring the viscosity of the pulp discharging from the mill has also been developed. The use of the measurements in mill control is illustrated by simulating various control strategies for open circuit milling. It is shown that the use of ?D allows very tight but imprecise control of the slurry rheology in the mill, while the use of viscosity is subject to severe limitations in speed of response. A cascade control system involving both measurements provides adequate control of slurry rheology within the mill. Applications to closed circuit milling are discussed.IntroductionMultivariable control of milling circuits continues to receive a lot of attention in the literature. Hulbert and co-workers and Niemi, et al. have described the use of Inverse Nyquist Array (INA) techniques while Herbst has recently described the use of Optimal Control. It is significant that in neither of these three projects was any variable associated with the grinding mill itself (e.g. power or properties of the mill discharge) used in the control strategy. Pauw, et al.do, however, use mill power in their multivariable peak-seeking controller for pebble-mill control. Little work has been published on the use of measurements of the properties of the slurry being discharged from grinding mills, in spite of the fact that milling efficiency is known to be strongly affected by slurry rheology».Moys has recently developed a technique for measuring the dynamic behaviour of the load in the grinding mill. This method involves the monitoring of the response of a conductivity probe mounted in the shell of the mill which gives a measurement of the orientation of the load inside the mill. It was found that the load behaviour was strongly influenced by slurry rheology. In this project a technique was also developed for the measurement of the viscosity of the slurry in the mill discharge. It was, thus, decided that it would be worth investigating the use of these measurements in mill control schemes since direct control of the slurry rheology in the mill must inevitably increase the efficiency and productivity of the grinding circuit as a whole.This will be done by using the dynamic responses measured by Moys and Montini to simulate the behaviour of an open circuit ball mill. While the control of open circuit mills is of little interest, this simulation provides a simple but powerful demonstration of the advantage provided by these measurements, advantages which should apply to closed circuit operation of any mill type (including autogenous milling). Investigations into multivariable control of a closed circuit ball mill are currently nearing completion and will be published soon."

Jan 1, 1987

By W. B. Morrey

"In recent years, the major effort in detonator development has been concentrated on ""non-electric"" systems. Existing types all involve some form of explosive reaction to transfer ignition energy from outside the borehole to the pyrotechnic delay element contained within the detonator. These may be based on low-energy detonating cords having grained or plasticized explosive cores, shock tube energy transmission principals and explosive gas ignition systems. Each has properties of internal and external effects not present in electric conductors.The MAGNADET System introduces transformer coupling into electric blasting circuits. Safety features with respect to current leakage, stray currents of AC or DC source, electrostatic energy and radio-frequency radiation are comparable to ""non-electric"" systems, with advantages in simplicity, speed of hook-up and range of application.The transformer device used is a small ferrite ring or toroid which is an integral part of each specialized detonator. The detonator legwires form the secondary side of the transformer winding. The primary side is a single wire loop common to all units within the circuit. Power is supplied from a frequency-tuned portable exploder with unique circuit-sensing features.The MAGNADET System is expected to have particular application to shaft sinking, raising and tunnelling where the protective features as well as speed and efficiency are critical factors. Applications of the 'MAGNA' booster in quarries, open pits and longhole deck charges offer control over vibration problems and elimination of surface noise.IntroductionFor many years, electric detonators and electric blasting systems dominated surface and underground applications where controlled delay times were required. Control over the instant of detonation by blasting machines or power-line switches is the major safety feature.Electrical energy exists in many forms. It may originate from many sources. Electrical energy can be difficult to contain. It may enter or escape through a variety of conductive paths. It may fluctuate, concentrate or dissipate to pose a most elusive potential hazard."

Jan 1, 1982

By E. G. Parker

"Sherritt's zinc pressure leaching process converts zinc sulphide concentrates directly to zinc sulphate solutions and elemental sulphur. Thus, one pressure process step replaces both the roasting and leaching operations of the conventional roast-leach route. In addition, high single-pass extractions eliminate the need for residue treatments to recover unleached zinc. Because pressure leaching produces elemental sulphur, rather than sulphur dioxide, acid plants and smoke stacks are not required, and air pollution control and work-place hygiene are greatly improved. .In 1977, Cominco Ltd. and Sherritt Gordon Mines Limited jointly operated a three-tonne-per-day pilot plant to demonstrate pressure oxidative leaching of Sullivan zinc concentrate and the subsequent separation of elemental sulphur. The process consisted of regrinding the concentrate, continuous leaching at 150°C at elevated oxygen pressures in a four compartment autoclave and the subsequent recovery of elemental sulphur, either in the molten liquid form from a decantation autoclave or as a flotation concentrate. Of the zinc contained in the concentrate, 97% was extracted in 90 minutes, and 96% of the sulphur was converted to the elemental form.Following the successful pilot campaign, Cominco began building the world's first commercial zinc pressure leaching plant. This plant, which was in operation by late 1980, will eventually treat about 25% of Cominco's planned zinc capacity of270,000 tonnes per year.This paper describes the general process principles, the results obtained from the pilot plant and the integration of the process into Cominco's operations at Trail. The application of pressure leaching to a ""grass-roots"" plant is also discussed, and compared with conventional roast-leaching."

Jan 1, 1981

By L. A. Melis, A. R. Marchbank, S. A. Webster

"Certain northern Saskatchewan uranium ores have a high content of nickel and cobalt which offer the potential for recovery as a by-product to uranium. A nickel/cobalt recovery process has been developed as a viable method of recovering a marketable concentrate from typical uranium raffinate solution.Impurities are first removed from the raffinate and the pure solution is then treated with sodium carbonate to recover a bulk nickel/cobalt carbonate precipitate for sale to a primary nickel producer. All contaminants of concern are removed to very low levels and the product is free of radioactive contamination with gamma emissions significantly below natural background. Cost estimates have shown that installation of a nickel/cobalt recovery circuit within a uranium process plant is economically feasible.The testwork that led up to the selected process is described along with recommendations for further investigations such as additional testing of hydroxide precipitation as a possible viable alternative to carbonate. The selected process is described and project economics are briefly reviewed.PROCESS TEST PROGRAMBackgroundExtensive metallurgical research has been performed over the years to develop a process for recovering uranium from the Midwest deposit in northern Saskatchewan. During the course of this research, a certain amount of information became available which suggested that recovery of nickel and cobalt from uranium raffinate could be economically feasible. It was decided to undertake a test program which would investigate methods of separating nickel and cobalt from radioactive and other metal contamination to permit production of a saleable product.Available technology suggested that three general approaches could be taken to recover nickel and cobalt. The first and simplest approach would be to selectively precipitate the impurities of concern, primarily arsenic, iron and radium, and then recover a bulk concentrate from the purified raffinate. The second approach would be to purify the raffinate and then remove cobalt from solution by solvent extraction producing pure nickel and cobalt solutions for further treatment. The third approach would be to precipitate all metals from solution and then selectively re-dissolve nickel and cobalt in ammoniac solution which would be further treated by solvent extraction for nickel recovery, leaving cobalt for further treatment."

Jan 1, 1993

By A. MacKinnon, P. W. Kingston, W. F. Caley

"Wollastonite (CaSiO3]) is experiencing increased usage in a variety of applications, such as fillers in paints, plastics and resins, as an extender to replace both non-fibrous and fibrous materials (e.g. asbestos), and in the glass and ceramics industries. Significant new deposits of wollastonite have been discovered in Marmora Township, about 175 km northeast of Toronto. The geological setting of these large-tonnage. High grade deposits has recently been investigated to assess the possibility of their development. A preliminary study of the chemistry, as well as the mineralogy of six occurrences is presented. Based upon this information, it is suggested that several of the deposits have an excellent development potential.INTRODUCTIONWollastonite is an anhydrous calcium metasilicate (CaSiO3), with a theoretical composition of 48.3% CaO and 51.7% SiO2; the calcium may be partially replaced by iron, manganese, magnesium, and strontium. Commonly associated minerals include diopside, tremolite, idocrase, grossularite andradite, quartz, and calcite. Wollastonite forms as a contact metamorphic mineral within impure limestone near intrusive bodies of granite, or other acidic rocks, as the result of metasomatism of calcareous sedimentary rocks, or by the crystallization of certain magmas (e.g. carbonautes). Generally, the reaction of calcite with silica to produce wollastonite occurs when siliceous hydrothermal fluids from a granitic intrusion or primary silica in the limestone/marble react with calcite in limestone at temperatures between 450°C and 600°C."

Jan 1, 1989

By Brian McIntrye, Bo Trygg

"The need for grinding mills of ever increasing capacity and greater feed openings has tended toward mill trunnion diameters being beyond the size limits for roller bearings.Hydrodynamic plain bearings need to be wide enough to achieve the necessary bearing pressure in order to obtain an oil film with sufficient carrying capacity at low rotational speeds. This greater width increases edge loading resulting from the deflection of the mill under load.Because of the high surf ace pressure involved, the life of support rollers and girth rings is often inadequate-fatigue leads to flaking on the contact surfaces. Heat treatment of the girth rings also has its problems.The hydrostatic shoe bearing permits unlimited trunnion diameter and a high carrying capacity. The self-aligning shoes compensate automatically for radial deviations and large deformations can be tolerated at the girth ring.The sliding surfaces are completely separated by oil under pressure, enabling negligible starting torque and good damping capacity to be achieved together with low rotational speeds.IntroductionHydrostatic bearings have been known within machine technology since 1865, when the Frenchman Girard received a patent for such a bearing. During the following 75 years, these types of bearings were used sporadically for thrust bearings, primarily in water turbines. The first usable radial bearing was not designed until 1938. Since the 1950s, when hydrostatic bearings started to come into use within the field of machine tools, extensive research and development work has been carried out at various institutions and research centres throughout the world. Many support problems are now solved by means of hydrostatic plain bearings and the primary factor in deciding to use them is their unique characteristics:• ability to carry high loadings• no starting torque• large damping capacity• no wear• large running accuracyThe hydrostatic shoe bearing has been developed specially for use in the heavy machine industry, with the requirements for high loadings and large support diameters which this market demands."

Jan 1, 1982

By T. Yalcin

"This paper describes the development of a process flowsheet designed to provide high dewatering rates and to bring about savings in tailing disposal costs. The flowsheet comprises a hydrocyclone, a settling cone and a thickener arranged in closed circuit. The mill tailing, after pulp density adjustment, is fed to the hydrocyclone which yields two products. The underflow product is sent to the settling cone for further dewatering. The overflow product, together with the settling cone overflow, goes to the thickener which, with the aid of flocculants, gives a clear effluent and a relatively dilute underflow. The latter combines with the original mill tailing to form the hydrocyclone feed. Solids finally leave the system in the settling cone underflow which can reach pulp densities of up to 78%, making it suitable for direct disposal or for use as mine backfill.Some discussion is included for the selection and sizing of equipment required for this process. INTRODUCTIONDewatering is an essential process for the disposal of mill tailings which forms an added burden in milling practice, often with little or no return. It is, therefore, desirable to conduct this process as economically as possible. One way of reducing costs would be to increase the rate of dewatering so that savings can be made in the size of dewatering unit s which would lead to lower capital and operating expenditures.A common method of dewatering mill tailings is gravity sedimentation which is frequently carried out with the aid of flocculation. In most cases, flocculation greatly enhances the sedimentation process, but only until a pulp density of 50% to 55% is reached in the settled material.Centrifugal sedimentation in hydrocyclones can provide high pulp densities rapidly, but does not result in a clear effluent.This paper outlines a suitable combination of gravity and centrifugal sedimentations that results in an over-all high rate of dewatering. The system developed produces a material of high pulp density while at the same time giving clear effluent."

Jan 1, 1989

By V. V. Pankov, W. R. Chen, L. R. Zhao

Diffusion nickel aluminide and overlay NiCrAlY coatings were deposited on single crystal Ni-base superalloy CMSX-4 substrate using the chemical vapour deposition and cathodic arc evaporation techniques, respectively. The NiCrAlY coating underwent a post-deposition heat treatment in an argon atmosphere at 1100°C for 2 hours. All the coated specimens were subjected to furnace cyclic oxidation testing at 1000°C up to 1500 one-hour cycles. The morphology, elemental composition and phase constituents of the oxide scales formed on the coating surface were analyzed using scanning electron microscopy, energy-dispersive spectroscopy and X-ray diffraction. It was observed that the diffusion aluminide coating experienced accelerated weight gain at an early stage of the test (150-400 cycles), whereas the overlay NiCrAlY coating fabricated by cathodic arc evaporation maintained steady-state weight gain throughout the entire 1500 cycle test duration. This difference in oxidation behaviour between the two types of coatings is attributed to the early development of nickel-aluminum spinel on the surface of the diffusion aluminide coating, in contrast to the stable aluminum oxide scale formed on the overlay NiCrAlY coating during cyclic oxidation testing.

Jan 1, 2015

By X. -G. Chen, E. M. Elgallad

Direct chill (DC) cast ingot plates of 2xxx alloys have been increasingly used for large mold applications in the plastics and automotive industries. A novel heat treatment practice for Al-3%Cu-1%Mg DC cast ingot plates has been developed, involving solution treatment, furnace cooling to the desired aging temperature and holding for appropriate time at the aging temperature. The mechanical properties of the plates were studied for different combinations of aging temperature and time, using hardness measurements and tensile testing. The evolution of the strengthening precipitates was investigated under different cooling rates corresponding to cold water quenching, still-air cooling and furnace cooling, using electrical conductivity measurements. The results showed that by applying the novel heat treatment, the cast ingot plates could provide a wide range of combinations of strength and ductility satisfying the design specifications of large molds. This, in turn, offers a practical solution for the fabrication of extremely large DC cast plates combining between good mechanical properties and low levels of residual stress using the shortest possible heat treating cycle.

Jan 1, 2015

By M. Lahtinen, B. Saxén, M. Latva-Kokko

The conventional jarosite precipitation process with neutralization by zinc calcine is widely utilized in the zinc industry. However, it has a significant drawback of causing losses of valuable metals like zinc, lead and silver to the jarosite. This comes mainly from the content of these metals in the calcine used for neutralization. As the zinc plants today want to maximize metal recoveries and minimize the amount of residues, this matter has become more and more relevant for zinc producers. Outotec developed and patented in early 2000 an improved version of the jarosite precipitation process in which the need for neutralization can be minimized, thus the metal losses to the jarosite also can be minimized. At the same time, the iron content of the jarosite increases and the amount of produced jarosite is smaller. The main feature of this process is to start the precipitation from ferrous iron after having reduced all the iron by zinc concentrate in a separate step before jarosite precipitation. Iron is then oxidised back to the ferric form simultaneously with jarosite precipitation. By this method, the formation of sulphuric acid is only half that compared to the conventional method and the need for calcine for neutralization can be avoided. High mixing and oxygen dispersion capability are needed in this jarosite precipitation process. Such capabilities are found in the Outotec OKTOP® reactor series. High performance reactors are not only needed to generate high quality precipitates, but also to maximize oxygen utilization; i.e., to minimize operation costs. Outotec’s latest development in this area is the OKTOP® plant product in which not only the reactors, but also all the accessories are designed, manufactured and delivered by Outotec. One responsible supplier ensures efficient and fast delivery and can provide mechanical and performance guarantees for the entire plant unit.

Jan 1, 2016

By Leopoldo Gutierrez, Sergio Castro, Lina M. Uribe, Janusz S. Laskowski

"The effect of sulfite and metabisulfite ions on the amyl xanthate flotation of copper-activated pyrite, in distilled water and seawater, has been studied by micro-flotation tests and redox potential measurements. The activation of pyrite was carried out varying copper ions concentration. It was found that in the presence of copper ions in solution, sulfite and metabisulfite are able to depress copper-activated pyrite at neutral or slightly acid pH. After the addition of sulfite or metabisulfite ions the resulting pH is more acidic with metabisulfite ions. A significant increase of the redox potential of the solution was observed as copper ions concentration increased. Then, the initial reducing conditions brought about by sulfite and metabisulfite ions, change abruptly to oxidizing conditions in the presence of copper ions. Under these oxidizing conditions, the metabisulfite showed to be an effective depressant for pyrite mainly in seawater. However, sulfite was a pyrite depressant in both distilled water and seawater. Based on these results, the pyrite depression by sulfoxy-depressants during the flotation of Cu/Mo ores in distilled water and seawater is discussed.INTRODUCTIONDepression of pyrite by sulfoxy-depressants (sulfite and metabisulfite) in the presence of copper ions is an important issue. This is particularly true when pyrite depression in the flotation of Cu/Mo sulfide ores is carried out in seawater. The use of lime in seawater must be avoided because the formation of magnesium hydroxy-complexes and precipitating magnesium hydroxide strongly depresses molybdenite flotation (Castro et al., 2014). In order to solve this problem, one large plant in Chile uses sodium metabisulfite (MBS) instead of lime to depress pyrite in seawater. In plant practice, this also improves molybdenite flotation since with the use of MBS the pyrite depression is carried out at pH 6-7, instead the pH 11-12 usually employed with lime.From a general point of view, pyrite exhibits some natural floatability over acidic pH ranges and may be partially floated without thiol collectors (a coating of sulfur/polysulfides has been claimed). Therefore, pyrite flotation with xanthates is usually high in the acidic pH region, but decreases greatly at alkaline pH (Leppinen, 1990; Fornasiero and Ralston, 1992; Zhang et al., 1997)."

Jan 1, 2016

By Xiaoxing Hu, Guibing Zheng, Yangge Zhu, Xingrong Zhang

"In China, more than 90 percent of titanium resources are reserved in vanadic titano-magnetite deposits. In this type of ore, the same elements such as Ti, Fe, Ca, Mg exist on surface of both ilmenite and titanaugite (the gangue mineral) because of isomorphism, which makes selective flotation difficult. Therefore, how to enlarge the floatability difference between these two minerals has always been a research emphasis and still needs to be studied further. In this paper, the pre-treatment methods using ultrasonic wave were proposed. The results indicate that ultrasonic treatment shows beneficial effect to enlarge the floatability difference, and the effect will be strengthened by extending the ultrasonic treatment time or increasing the ultrasonic power. The mechanism was investigated through infrared spectroscopic (FT-IR) analysis. Collector interacts with Ca and Mg which results in titanaugite flotation, after ultrasonic treatment, the dissolution of Ca and Mg is intensified, which leads to the lack of active points on mineral surface, so the floatability of titanaugite is depressed. Meanwhile, collector mainly interacts with Fe which results in ilmenite flotation, and the present of ultrasonic might promote its oxidation (Fe2+ to Fe3+), so the floatability of ilmenite after sonication is increased.INTRODUCTIONUltrasonic is the sound wave with frequency of 2 × 10-4 Hz~2 × 10-9Hz. Since the first International Symposium of Sonochemistry in 1986, the application of ultrasonic wave is more and more extensive. In researches about mining and metallurgy, various investigators have shown that intensive acoustic fields can modify the state of a mineral, leading to chemical or dispersive effects. Generally, the effect of ultrasonic vibration depends upon the nature of the mineral and also the way ultrasonic wave is applied (Celik, 1989; Ozkan, 2002). In addition, ultrasonic treatment usually plays roles of removal of reagents adsorbed layer from minerals and emulsification of flotation reagents when it is used in flotation (Nicol, Engel, & Teh, 1986; Slaczka, 1987; Djendova & Mehandj, 1992; Farmer, Collings, & Jameson, 2000; Gurpinar, Sonmez, & Bozkurt, 2004)."

Jan 1, 2016

By Tatyana Alexandrova

The problem of processing refractory (rebellious) gold ores is important for all the countries involved in recovering precious metals from ores. Technological aspects of processing precious metal ores are examined in two respects: enhancing gold recovery from double refractory ores; and using carbonaceous ores on a production scale. The dispersed carbonaceous matter (DCM) present in concentrates causes the adsorption of [Au(CN)2]- complex on their surface during cyanidation process. Depending on the degree of graphitization and the organic carbon content in DCM (including kerogens and bitumen), the technology used to recover precious metals varies considerably. The problem of processing refractory (rebellious) gold ores is important for all the countries involved in recovering precious metals from ores. Depending on the degree of graphitization and the organic carbon content in DCM (including kerogens and bitumen), the technology used to recover precious metals varies considerably. The possibility of rare metals recovery, including rhenium, from black-shale rocks, has been examined. Comparative assessment of analytical methods of rare metals detecting has been carried out. It has been proved that neutron activation analysis is a promising technique. It has been shown that colloid-salt fraction (nanofraction) with particle size less than 1000 nm makes up to 3 wt% of black shale samples and is extracted by water under special conditions. The use of water instead of chemically active reagents provides insolubility of the mineral matrix and fully reflects the colloid-salt element of the samples. To sum up, the justification of the choice of technology for processing of carbon-bearing ores is based on examining the type of carbonaceous matter and its adsorption behavior. When the content of carbon of high degree of metamorphism is considerable, it is possible to recover platinum group elements and rare elements from this type of ores. The obtained results predetermine the general guidelines for creating new methods and techniques of processing carbonaceous material for integral development of solid minerals in the mining and oilfield areas of Russia.

Jan 1, 2016