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By A. Khan, C. Ciriello

The purpose of this paper is to demonstrate the value of constraint modelling in optimization of mineral processing systems. This will be achieved by first understanding the overall concept of variation and constraints present in any system. Next, the value of using a Constraint Model in optimization is demonstrated through comparison of business cases. The benefit of understanding the severity of constraints and movement of the bottleneck within a mineral processing system will be understood through the use of a case study. Paper will conclude with a summary of all optimization benefits that utilization of a constraint model can bring.

Jan 1, 2015

By K. Duckworth

The treatment of Turam data by conventional procedures does not permit the interpreter to make any estimate of induced current magnitudes. This problem may be overcome by using an alternative data treatment procedure. It is shown that the conventional and alternative procedures are equally satisfactory in terms of their ability to provide the location of line currents and estimates of conductor quality. A full description and evaluation of both procedures is presented in conjunction with field examples to show how the alternative procedure may assist interpretation when used to complement the conventional approach.

Jan 1, 1973

By D. H. Wilson

"This paper examines the increasing need for mechanical-electrical people within the industry and some of the reasons why such a shortfall exists. It is suggested that, in part, it is image related. The present industry-education relationship in addressing the situation is examined and some thoughts are expressed on how these may be built on, in order to help solve the problem of attracting people to this critical area.IntroductionAs a long-time proponent of plant engineering and maintenance as a management function, I would like to review the progress made by the industry/ educational approaches in satisfying the needs in that area. In doing so, I would like to make the following points:1) that there has been an accelerating shortfall of mechanical-electrical people relative to the needs of the industry;2) that the condition will probably get worse before it gets better; ,3) that the past industry I educational approaches to alleviate the problem have met with limited success; and finally4) I would like to review some of the things being done and consider how these efforts might be extended."

Jan 1, 1981

Applications of proven real time, through-conveyor elemental analysis technology and benefits achieved will be discussed using case studies in base metals, iron ore and phosphate operations. PGNAA (Prompt Gamma Neutron Activation Analysis) technology and its background in minerals applications and applications which are expected to further improve its utilization will be reviewed. Short payback through operational benefits such as removal of waste from feed, increased feed grade and overall improved productivity will be demonstrated based on results achieved at several processing operations. PGNAA technology is most applicable to conveyed flows as it is unaffected by belt speed, particle size, segregation/layering, mineralogy or dust. As a transmission method able to penetrate in excess of 500mm of rock it provides extremely representative results continuously measuring through the full conveyed cross section and reporting results typically on one to five minute accumulated increments to the control room. Multi-elemental results and moisture content are used for active process control: diverting conveyed flow increments(bulk sorting), blending ore types in plant feed, and providing advance warning of significant quality changes to the downstream plant operators (e.g. flotation). Elements of interest may include deleterious components as well as target metals. Ore feed quality measurements are also useful in metal accounting, ore reconciliation and real time feedback to mining operations. Further benefits can result when combined with other technologies such as particle sorters, to upgrade diverted increments of subeconomic material to achieve higher feed grades and lower deleterious content to the main process. Measurement of elements (e.g. silica) which correlate with ore hardness or grinding characteristics can be used to moderate feed rate to grinding mills to prevent overload, hence optimizing grinding performance and reducing energy and grinding media consumption. Pebble flows can be analysed and uneconomic increments diverted to prevent recirculating flows consuming mill capacity unnecessarily. This also increases average feed grade.

Jan 1, 2016

By James Tuer, John R. Goode, Jim Cambon

"Hudson Resources Inc. (Hudson) has defined a major resource of high purity anorthosite (calcium feldspar) assaying about 30% Al2O3 at the White Mountain (Naajat) deposit in Western Greenland. Extensive beneficiation and evaluation testwork has shown that the material can be simply beneficiated to produce a feed material ideal for the production of low-alkali E-glass used for making glass fibre. An offtake agreement is in place with a major US fibreglass manufacturer and, subject to the mine construction schedule, shipments are scheduled for late 2016 or early 2017. In parallel with the E-glass program, Hudson has completed an initial program of metallurgical testwork which shows that the White Mountain anorthosite can be processed by hydro- and pyro-metallurgical processes to yield either smelter-grade alumina (SGA), suitable for conversion to aluminium metal, or a high purity, chemical/specialty-grade alpha-alumina (CGA) commanding a premium price. The process includes dissolution of the anorthosite in hydrochloric acid, HCl sparging to precipitate aluminium chloride hexahydrate (ACH), recycle of the ACH filtrate to leaching with a bleed stream processed for HCl regeneration from CaCl2, and two-stage calcination of the ACH to regenerate HCl and produce SGA and/or CGA. Calcium silicate and amorphous silica are marketable by-products. This paper discusses the White Mountain anorthosite deposit; the process testwork completed to develop production processes for SGA and CGA; production plans, and indicative economics.INTRODUCTIONHudson Resources Inc. (Hudson) holds a 100% interest in the Naajat Exploitation Licence in Western Greenland that cover the White Mountain high-calcic anorthosite deposit. Anorthosite is a calcium aluminosilicate of slightly variable composition but generally containing about 30% Al2O3. The alumina content is similar to that in bauxite and anorthosite has long been studied as a feedstock for the production of alumina. Other potential uses include feedstock for the high-end fiberglass (E-glass) industry and as a filler for use in paint and plastics."

Jan 1, 2016

By Nickvinder Bhath, Johnson Matthey Plc, Jamie Baker, Daniel Kim, Jeff Lucht, Shijie Wang

"Precious metals (PM) in copper anode slimes are traditionally recovered by pyrometallurgical processes. Due to the compliance with increasingly stringent environmental regulations, it has made hydrometallurgical processing an attractive method for recovery of precious metals, including relatively inert metals such as gold and platinum group metals (PGMs). In this paper, a new method to recover PGM from complex and difficult feed streams is described. Using a proprietary Advanced Ion Exchange (AIX) adsorbent which has a high selectivity for PGMs over other metals and can achieve high PGM mass loadings with a series of incredible pilot test data plus the business case generated from the study results are also presented in the paper.INTRODUCTIONPrecious metals in copper anode slimes are traditional recovered by pyrometallurgical processes. Due to the compliance with increasingly stringent environmental regulations, it has made hydrometallurgical processing an attractive method for recovery of many metals, including relatively inert metals such as gold and platinum group metals (PGMs). Fully hydrometallurgical processes for extraction and recovery of gold and silver from copper anode slimes were employed in major copper refineries since 1995, which was first developed at Rio Tinto Kennecott Utah Copper.In Rio Tinto KUC process, the wet chlorination and gold solvent extraction were utilized to enable recovery of gold and silver as well as other metal compounds. The availability of water and the interaction and amenability of gold processing in water-based solution makes it possible that gold and silver are produced in only five days, compared with a traditional pyrometallurgical process that took 45 days. Most copper refineries are still following the tradition, but the use of hydrometallurgical technologies is increasing as the world demand for metals increases, energy utilization, and environmental viability."

Jan 1, 2016

By G. W. Zhang, Changsha Research Institute of Mining and Metallurgy, X. Xiao, Y. Long, L. L. Huang

"The paper presents a scale-up and design method of vertical screw stirred mill, in which the closed circuit of mill and hydrocyclone was assumed as one factor, theoretically regardless the affects inside system of the mill and hydrocylone. The specific energy is chosen as a scale-up criterion, based on the premise that when fed the same feed material, mills of different sizes delivering the same specific energy will yield products.Batch grinding tests are conducted to determine the specific energy, and combined with industrial production data, scale-up and design of vertical screw stirred mill for industrial production are accomplished. Having developed this method for the vertical screw stirred mill used in regrinding duty of iron ore in Ma Steel, it has now been successfully applied in other installations.INTRODUCTIONThe Towermill was developed in Japan in the 1950s, by the Tower Mill Kubota Corporation, it was fine and ultra-fine grinding mill of the metallic ores and concentrates. Due to the rapid development of metal mining and useful minerals disseminated fine, fine grinding and ultrafine grinding equipment has also been more wide used in minerals processing industry. Typical fine and ultra-fine grinding mil are the Vertimill and Stirred Media Detritor (SMD) Mill of Metso, Eirich Towemill, Outotec HIGmill, FLSmidth VXPmill, Xstrata Isamill and the vertical screw stirred mill (JM) of CRIMM, etc.JM series of vertical screw stirred mill were invented by Changsha Research Institute of Mining and Metallurgy in the 1980s. Energy saving and consumption reducing have been achieved through the optimization and engineering practice. More than 500 units JM series of vertical screw stirred mill are used in the iron ore, copper ore, copper-molybdenum ore, molybdenum ore, Pb-Zn ore and Au ore."

Jan 1, 2016

By R. B. Kaunda

One fundamental requirement for surface and underground rock engineering is the ability to characterise the rock mass. An accurate characterisation of the rock mass allows rock engineers to optimize designs safely and economically. A number of classification systems have been developed in the past 50 years to help characterise rock masses such as RMR, Q system, Rmi, and several others. The challenge in developing rock characterisation schemes is often practicality, i.e. creating systems with relatively simple inputs for the everyday practitioner. A second challenge is the degree of subjectivity often inherent in commonly used classification systems. These challenges are especially exacerbated in weak rock or densely jointed rock masses. This paper introduces a new approach to characterise densely jointed rock mass using artificial neural networks and principal component analysis, based on principles commonly used in the geotechnical engineering of rock fills and waste rock dumps. Thirteen input parameters are dimensionally compressed using principal component analysis. Using a global database with more than 100 case histories, an artificial neural network is developed to conduct the rock mass characterisation. The advantage of this approach is less subjectivity as commonly used engineering (quantitative) terms are put to use. A further advantage is that given that the method is site-data dependent, it allows for ‘fine tuning’ of the model for a specific site.

Jan 1, 2015

By Randolph A. Pax

"The internal operation of a tumbling mill is a very hostile environment and precludes the sustainable operation of internal sensors to measure the mechanisms of charge motion and breakage events. Instead indirect methodologies are required to expand the current understanding developed within a framework of perfect mixing of the mill contents. A number of measurement approaches have been successfully used to explore the operation of SAG mills including strain instrumented lifter bolts, mill shell strain measurement and thermal (energy balance) of operating mills.Early acoustics measurement was developed by Hardinge using a 'microphone' located close to the expected toe location. This signal was an indicator of the mill fill. Improvements were implemented with the use of two microphones straddling the toe location to try to increase the sensitivity of the measurement and reduce ambiguities. Further improvements included a filtered signal indicative of steel interactions. Unfortunately, the mechanisms of signal generation and the complexity of the processes do not provide a consistent signal.In recent years, advanced acoustic measurement using arrays of microphones utilising signal processing techniques have been implemented as SmartNoise and validated on over 30 mills. This paper will discuss the results obtained with signals such as water holdup, mill shell steel hits and two each of the toe and shoulder angles. An estimate of the internal mill component wear rates is also accessible.Advanced acoustic measurements with wide bandwidths when combined with physics models and process understanding has achieved a step change in the understanding of the dynamic internal operation of a tumbling mills on time scales of 80 ms. These techniques have been used extensively on SAG mills, but have also been applied to FAG and ball mills. Acoustic measurement is used for the rapid diagnosis of mill conditions and holistic control for optimisation and stability."

Jan 1, 2016

By Gordon Sparks, Lyle Kajner

"An often over-looked component in the assessed value of a mining property is the value derived from the ability of the operator to limit financial losses during adverse economic times (i.e. low market price, high energy prices, etc.) by suspending operations. Overlooking the value of this type of operating flexibility when conducting mine investment analysis may negatively bias the risk profile for the investment by over estimating the investment's downside potential, thereby effectively undervaluing the investment. This paper illustrates the nature of the value of operating flexibility and discusses how it may be explicitly quantified within the context of conducting stochastic mine investment analysis. IntroductionMining properties are evaluated using an array of techniques ranging from simplistic non-discounted payback calculation s to sophisticated, discounted-stochastic simulation. Stochastic simulation analysis is perhaps the most robust mine investment analysis technique as it not only provides an estimate of the expected value of the property, but also quantifies the associated risks (for examples of stochastic mine investment analysis, see: Billingsley and Yaychuk, 1986; Gentry and O'Neil, 1984; Munro, 1977; or Harris, 1970).The quantification of risk is important as it provides the necessary yardstick required to allocate the corporation's resources efficiently. Resources are said to be allocated efficiently when the corporation's expected long-term financial reward is maximized while at the same time minimizing its risk (see Hertz, 1968; or Markowitz, 1952 for in depth discussions on efficiency as it relates to investment policy). The efficient allocation of resources should be the objective of any rational corporation. Therefore, rational corporations should employ stochastic evaluation techniques when screening their investments."

Jan 1, 1992

By H. K. Taylor

"As a mining engineer with over 50 years' experience in underground operations and mine planning, I appreciate the enormous amount of work that went into the paper; and despite an imbalance between geology-geostatistics and the profit-earning actions of mining and treating (possibly because of sponsorship only by the Geological Society), I agree with probably 85% of the detail. But the paper fails to build on its own sound foundations and, like many predecessors, drifts instead into idealism. Even the starting quotation from the US SEC Form S-18 is little more than a platitude. An American consultant (l) has observed: ""an evaluation that accepts ore reserves as guaranteed because their definition meets SEC criteria is an invitation to disaster"".Idealism enshrines at least two myths that have bedevilled definition over the last several decades. The first is that the only purpose of 'ore reserves' is to promise successful new mines, and that 'ore reserves' must necessarily follow feasibility studies.In practice, the identification of what is likely to be mined if a mine is started must often be done on broad economics long before the feasibility study, and there may be only little later flexibility. The second myth is that there can be a perfect deposit with a simple exploration-appraisal-development sequence (the paper's Figure 2) against which all inferiors can be matched. If the field of definition be regarded as a pyramid, the quest for perfection and the imposition of rigid promises upon the terms 'ore' and 'reserves' drive definitions so near the apex (or the bottom right corner of Figure I, if preferred) that little is left to define. The process is reminiscent of the legendary super-medicine, the one so powerful that the patient had to be in perfect health to take it!"

Jan 1, 1992

By K. R. Barnard, K. D. Marte, T. V. Gamarano

"The first commercial scale application of CSIRO’s direct solvent extraction (DSX) technology has been in operation at the Boleo project in Mexico since December, 2015. In this application, DSX is a synergistic solvent extraction system consisting of the extractants LIX 63 and Versatic 10 for recovery of cobalt and zinc from a solution background of manganese, magnesium, and calcium. Key operating parameters such as metal extraction, phase disengagement and extractant stability are summarized and discussed in this paper.INTRODUCTION Commissioning of the Boleo processing plant, located on Mexico’s Baja peninsula, began with the copper circuit starting in late 2014, with first copper cathode production achieved in January, 2015. The cobalt and zinc circuits began commissioning in December, 2015 with first zinc sulphate monohydrate (ZSM) and cobalt cathode production achieved in February and April, 2016 respectively. The Boleo project flow sheet and development has been described in detail in previous publications (Dreisinger, et al. 2005; Dreisinger, Baxter, & Molnar, 2006; Dreisinger, et al. 2008; Dreisinger, et al. 2009) and is summarized schematically in Figure 1. Boleo is a mixed oxide/sulphide Cu-Co-Zn-Mn high clay deposit that is processed in a whole ore, atmospheric, oxidative and reductive, sulphuric acid/seawater leach. Copper is recovered as cathode by conventional solvent extraction and electrowinning. Cobalt and zinc are recovered, from a solution background of manganese, magnesium, and calcium, by CSIRO’s synergistic solvent extraction technology Direct Solvent Extraction (DSX). Cobalt and zinc are bulk stripped from the DSX circuit and then further purified by phosphinic acid solvent extraction to produce zinc sulphate monohydrate granules via spray dried granulation and cobalt cathode rounds via divided cell electrowinning."

Jan 1, 2017

By N. Torres, G. Melcher

"An alternative to building new copper smelters, because of either stringent environmental regulations or in order to expand current plant capacity, could be achieved through the retrofitting of old reverberatory furnaces by making use of tonnage oxygen. The CONTOP® technology offers unique advantages over other techniques for this purpose, especially regarding substantial reduction in bath, capital and operating costs. This is possible to achieve since the reverb throughput could be largely increased with no major structural modifications to the furnace.The following options are offered to the smelter operators: dirty concentrates can be treated in an adjacent Contop system, or the cyclones can be mounted on the reverb roof for either dual operation or full Contop operation. ln the tatter case the furnace will be used as a settling chamber and f or slag c1eaning by top blowing with reducing gases.By incorporating Contop technology, the furnace throughput can be increased, higher malle grade, fixation of sulphur from furnace off-gas and substantial savings in energy consumption are possible to attain.IntroductionCopper smelting has been revolutionized during the last quarter century to such an extent that the standard type of plants consisting o f roasters and reverb furnaces seem a thing of the past, or almost. Though the building of new, more energy efficient smelters is a very likely opportunity for a grassroots plant, it would be hardly justifiable to replace an old existing plant unless there are heavy environmental or economic constraints(1,2,3)."

Jan 1, 1984

By Vicken Aprahamian

"The Royal Canadian Mint (RCM) operates a gold and silver refining toll operation in Ottawa, Ontario, Canada. The silver refining line is a recent addition and was commissioned in 2005. One source of silver in the refinery is from gold doré which undergoes Miller chlorination before electrorefining to 99.99% cathode gold. Treatment of the Miller salt or silver-copper chloride produced consisted of a 2-stage high temperature reduction process step using soda ash prior to 2005. Copper-rich silver bars were produced and shipped offsite for further refining.The copper-rich bars could not be blended into sufficient high grade silver doré to dilute the copper and allow electrorefining in a silver nitrate medium. A new wet process was developed and commissioned to replace the high temperature reduction and allow removal of bulk copper. Thus upgraded impure silver produced was cast into anode for electrorefining to 99.9% purity silver flake. The 2005 RCM Hydromet Slag process is presented as well as its more current version. In addition, mention is made of a novel processing scenario for the introduction of Miller chlorination silver into the electrorefining circuit."

Jan 1, 2015

By E. J. Schwarz, A. A. Winir

"Absolute magnetite contents were determined for asbestos specimens in various stages of milling by using a Faraday-type thermomagnetic balance. Comparison of these results with magnetic ratings (MR) supplied by the mining companies cooperating in this study reveals strong scatter. The main cause of this scatter is thought to be that the MR values were obtained in magnetic fields well below the saturating field of magnetite (5,000 oe). However, only the saturation moment is an intrinsic property and consequently must be used for the purpose of obtaining reliable estimates of the magnetite content. Curie points indicate that virtually pure magnetite and possibly Ni3Fe is present in all samples, and another phase, probably (Cr, Al) magnetite, is present in a few samples. The susceptibility in fields stronger than 5,000 oe is positive and falls in the normal paramagnetic range, whereas sy nthetic chrysotile exhibits weak diamagnetism. This suggests that, as a general rule, the least adulterated natural chrysotile concurs with the samples showing the smallest positive susceptibility above 5,000 oe. The magnetite appears to increase in quantity with a decrease in fibre length and to be somewhat more uniform in distribution for samples showing substantial fiberization (opening of the fibres)."

Jan 1, 1971

Who is ArcelorMittal Mines Canada ?One of Canada's leading suppliers of iron ore to steel markets around the world ?Past company name = ??Quebec Cartier Mining?? ?Operator of one of North America's largest open-pit mines ?Mont Wright Mines ?Fire Lake Mine ?Largest ArcelorMittal iron ore mining subsidiary ?Annual production of 15 million tonnes of concentrate ?Major expansion program to 24 MT/Y ?Internationally competitive pellet plant ?9.0 million tonnes annually

May 1, 2011

By K. MacMaster

"This paper deals with the history, development, present and future of the Employee Assistance Programs in place at the Inco Ltd. operations in Thompson, Manitoba. It should be noted that, although many similar programs exist in various industries and jurisdictions, these programs had to be fine-tuned to meet the needs of Inco employees, having in mind the helping professional resources available in Thompson and its geographic location. IntroductionIn the late 70s, many Canadian industries and the Canadian Labour Congress and their affiliates commenced discussions on the value of the Employee Assistance Program (E .A.P.) philosophy to both management and labour.In the contract signed between Inco Ltd., Manitoba Division and Local 6166, U.S.W .A. in 1981, a commitment was made to establish a joint E.A.P. for the hourly workforce in Thompson, Manitoba. With this background and sequence of events in mind, it is appropriate to explain the methodology and the steps that were taken for the implementation of the hourly program. Development of Hourly ProgramIt was agreed by the company and the union that the committee to develop the program should consist of equal numbers from both sides: three active union members plus an advisor representing the Union and three supervisory personnel plus an advisor representing the Company; in addition, a person familiar with E.A.P.s from the Alcoholism Foundation of Manitoba was to act as a facilitator. The Union appointed a social worker who was working as a counsellor for union members as their advisor , and the company appointed a staff employee who had worked voluntarily in the field of alcohol and drug abuse for many years. The makeup of the committee was extremely important in order to give credibility to the entire process. The makeup of the committee is shown in Table 1.The facilitator selected from the Alcoholism Foundation of Manitoba was well known in the community and highly respected in his profession."

Jan 1, 1989

By C. P. Verschuren, P. W. Kingston, W. F. Caley

"In recent years, there has been rapid growth in the use of natural stone building and construct ion products. The largest growing markets are for pre-fabricated natural stone panels for interior and exterior wall facing and flooring. This increased demand is attributed to advanced quarrying and processing technologies, renewed appreciation for the aesthetic appeal of natural stone, and to the superior durability of natural stone when compared to glass, steel, and concrete. Geologically, plutonic rocks, and to a lesser extent marble and limestone/dolostone, are used extensively for these applications. This paper details the economic structure of the dimension stone industry, describes the necessary characteristics of a stone quarry, and outlines the geological criteria which favour an economic quarry.INTRODUCTIONThe world building stone industry has remained relatively stable over the last 5 to 6 years. In contrast, the North American stone industry has experienced substantial growth during that period. The increased use of commercial granite is primarily responsible for this growth, where use as exterior wall veneer for commercial, industrial, and institutional buildings represents the largest and fastest growing market.This increased usage in the construction industry has been sparked by the application of new technologies in quarrying, processing and installation , ma king natural stone more competitive with man-made materials which are energy intensive to produce, and have risen dramatically in price. The development of safer, time-saving stone installation techniques has also appealed to the liability-conscience construction industry. Finally, there is a trend by designers and architects toward utilizing long-la sting weather-resistant building materials, and a renewed appreciation of the aesthetic appeal of natural stone. The other large user of granite is the monument industry of North America which, although it has decreased slightly in recent years, still consumes approximately 40% of all commercial granite produced. The local use of commercial marble has remained relatively stable, and North America still relies heavily on European sources and suppliers. There has been some concern over the use of marble for exterior applications in areas subject to acid rain, and in colder climates where the marble ma y be vulnerable to freeze thaw cycles. Despite these concerns, the greatest problem is not with the structural breakdown of marble but the inability of some marbles to retain their polished finishes in the se environments. As a result, there has been an increase in the use of granite at the expense of marble for exterior applications. Finally, commercial marble is used extensively for interior flooring, wall s, counter tops, furniture, sculptures, and stairway components"

Jan 1, 1989

By H. Oterdoom, S. Pilger, T. P. Bui, J. Rotarius

"Most FeNi furnaces used to rely on post-combustion and off-gas cooling inside the furnace to eliminate the produced CO gas, and control the off gas temperature. As furnace load, capacity, and thus gas volumes increased over the years, this led to increased instabilities that can cause problems in controlling the operation. Some of the large capacity furnaces nowadays work with partial or full combustion outside the furnace, more similar to the steel industry. Forced combustion with or without enriched air and other additions can support in controlling post-combustion, stabilizing and even reducing off gas amounts, and affecting composition. This paper presents some of the possibilities and advantages of having a specially designed post-combustion system for the FeNi laterite industry, but that could also be applied to other processes as well.Large Scale Furnaces In the FeNi industry, the Rotary Kiln Electric Furnace (RKEF) process is still going strong in spite of continuous hope that hydrometallurgical processes will one day make the RKEF plant obsolete. Within the pyrometallurgical plants there is a continuous trend for larger scale furnaces. The development for a number of furnaces that were started before 1985 and increased capacity by “natural growth” is given in Figure 1. Natural growth refers to the development of the plants that after having mastered a certain level of operation, were ready for a higher load that could be installed either with a new furnace on the same site, or during a revamp. The advantages of natural growth are numerous, for example: •,Deep knowledge of the ore and its’ behavior, no need for testing, and little risk of surprises. •,Mining, laboratory, equipment, etc. is all proven technology for the conditions on site. •,Starting a furnace with increased capacity is a re-start, not a green-field commissioning. •,Typically, when increasing the production capacity of an existing plant, not the entire plant is commissioned for the first time, but only a part. In the FeNi laterite industry for example, the kilns may already have had the capacity to provide enough material."

Jan 1, 2017

By O. Laitinen, M. Rudolph, J. A. Sirviö, H. Liimatainen, R. Hartmann, University of Oulu

The increasing complexity of the ores composition worldwide calls for suitable collectors with specific properties, such as selectivity, wettability, and in regard to current regulations, environmental sustainability. Therefore, collectors have to satisfy many features to improve the efficiency of flotation processes. Cellulose nanocrystals gain more and more interest due to the versatile synthesis routes which enable the integration of specific functional groups and components with different degrees of hydrophobicity within the molecular structure. Consequently, cellulose nanocrystals can be employed in flotation processes as depressant or collector molecules, respectively. Nonetheless, the usage of cellulose nanocrystals is still limited due to a lack of the characterization of nanocrystal-mineral interactions and the change of the surface wetting properties of minerals after adsorption phenomena between nanocrystals and minerals. In these studies, butyl-amine cellulose nanocrystal (BAC) and quartz are used as model system to investigate physicochemical properties of both, BAC and quartz, and examine the applicability of BAC in flotation processes. Therefore, the surface charge distribution and electrophoretic mobility of BAC and quartz are investigated and compared to understand the effect of electrostatic interactions between BACs, and BAC and quartz. Based on this, the adsorption of BAC on quartz is examined. Finally, microflotation experiments test the efficiency of BAC to be used in flotation processes. The flotation response is correlated to the specific surface charge of BAC revealing the dominant effect of surface charges on effective particle-bubble adhesions.

Jan 1, 2016