Search Documents

By T. Sugawara, S. Hara, Y. Mitsui

Surfaces of rock slopes in cold regions often become frozen in winter. Therefore, understanding time-dependent behavior of frozen rock, as well as that of unfrozen rock, is important for long-term stability assessment of rock slopes. In this study, a series of uniaxial compression tests and creep tests were carried out on Shikotsu welded tuff under dry and water-saturated conditions at -20 °C to clarify timedependent strength and deformation of the frozen rock. The influence of water content on them also was investigated. It was found that the amount of deformation of the water-saturated specimen was much greater than that of the dry specimen. It also was found that the creep behavior of the water-saturated specimen was similar to that of polycrystalline ice. These show that deformation of the water-saturated specimen is strongly affected by pore ice. The UCS of the water-saturated specimen was approximately equal to that of the dry specimen at a strain rate below 4.2×10-6/s, and its value was about 17 MPa. However, the former increased up to 26 MPa at 4.2×10-4/s with loading rate, whereas there was little increase in the latter. This means that the UCS of the water-saturated specimen was always greater than that of the dry specimen at higher strain rates. The creep life of water-saturated specimens was longer than that of the dry specimens at stress level greater than 15 MPa. These results of UCS and creep life show that inclusion effect due to presence of pore ice plays an important role on strength of the water-saturated specimen. Creep life of the non-failure specimen that was loaded for more than three days was estimated by the relationship between creep life and axial strain rate at 10 s on failure specimens. It was found that creep life of the water-saturated specimens was shorter than that of the dry specimen at stress levels less than 14 MPa. This suggests that estimation of creep life of frozen rock under water-saturated condition is important for the stability assessment of frozen rock slopes. It was clear that the loading-rate dependency of UCS was related to the stress-level dependency of creep life in both dry and wet conditions. This indicates that there are common fracture mechanism in creep and uniaxial compression tests. It also indicates that the creep life can be estimated by the relationship between the UCS and the loading rate. The time dependencies of the water-saturated specimen were in good agreement with those of polycrystalline ice. This confirms that pore ice strongly affects the strength of the water-saturated specimens as, well as the deformation behavior.

Jan 1, 2015

By W. H. Gauvin, N. J. Themelis

I N ADDITION to its practical importance in the beneficiation of iron ores and in direct-iron processes, the study of the reduction of iron oxides involves many aspects of challenging theoretical interest. The complexity of the reduction process combined with the fact that under different experimental conditions the controlling stage for the reaction may not necessarily be the same, has led experimenters in this field to a wide diversity of opinion regarding the reaction mecl1anism. As a rule, each investigation has been restricted to the study of one or two variables over a comparative]~• narrow range of experimental conditions, and consequently, it be-comes necessary to examine the significance of each published work in the light of the results of other experimenters in the field.

Jan 1, 1962

By A. Haldar

The major problem encountered in the casting of hypereutectic Al-Si alloys is the stoppage of flow below the rigidity level of solid fraction. In this study, the flow stoppage mechanism was studied using three Al-Si alloys with 14%, 18% and 22% silicon. The horizontal foam patterns used were 12.50 mm (0.50 inch) wide with two section thicknesses 12.50 mm (0.50 inch) and 6.25 mm (0.25 inch) with a common sprue. The primary silicon distribution along the length of the casting was studied to determine the mechanism of flow stoppage. It was found that the surface of the flow tip of Al-14%Si alloy was smooth with a few undulations. As the silicon level increased, undulations at the flow tip increased. The number and size of undulations were maximum for the Al-22%Si alloy. Microstructural analysis using optical image analyzer revealed that the flow tip consisted mainly of eutectic silicon in the aluminum matrix and a few primary silicon crystals (PSC). The PSC were in the interlocked condition few centimeters behind the flow tip. It was also found that the gap between the flow tip and the PSC concentrated area increased with an increase in silicon level. Phase characterization was done with SEM-EDX to identify the precipitating phases.

Jan 1, 2007

By X. -G. Chen, K. Liu

Nowadays, great interests are rising on aluminum alloys for the applications at elevated temperature, driven by the automotive and aerospace industries requiring high strength, light weight and low cost engineering materials. As one of the most promising candidates, Al-Mn-Mg 3004 alloys is found to possess considerably high mechanical properties and creep resistance at elevated temperature resulted from the precipitation of a large number of thermally stable dispersoids during heat treatment. In present work, the effect of Fe contents on the evolution of microstructure as well as high temperature properties of Al-Mn-Mg 3004 alloys has been investigated. Results show that the dominant intermetallic changes from a-Al(MnFe)Si at 0.1 wt.% Fe to Al6(MnFe) at both 0.3 wt. % and 0.6 wt. % Fe. In the Fe range of 0.1 to 0.6 wt.% studied, a significant improvement on mechanical properties at elevated temperature has been observed due to the precipitation of dispersoids, and the best combination of compression strength and creep resistance at 300°C is obtained in the alloy with an intermediate Fe content (0.3 wt.%) with finest size and highest volume fraction of a-Al(MnFe)Si dispersoids. The superior properties obtained at 300°C makes 3004 alloys more promising for high temperature applications. The relationship between the Fe content and the precipitation of stable dispersoids as well as the materials properties has been discussed.

Jan 1, 2015

By L. C. Stevens

The particular purpose of this paper is to direct attention to the development of underground conveying as applied to methods of working coal in the mines of Alberta. Historical A retrospective view of coal mining discloses a continuous effort, on the part of those interested, to substitute mechanical contrivances for hand labour. A patent for a coal-cutting machine was granted to Michael Menzies in 1761, at which time much of the transportation of coal underground was accomplished by means of sledges. Early forms of cutting machines attempted to duplicate the action of a miner's pick, and one hundred years lacer than Menzies? patent we still find this class of machine, driven by water power or compressed air, in use to a limited extent. A coal-cutter using the principle of a circular saw and worked by hand was exhibited in London in 1851, and from these crude beginnings the machines of today have been evolved. Transportation of coal underground has similarly been subject to considerable improvement. The above mentioned Michael Menzies took out a patent in 1750 covering the use of a self-acting incline plane, which is probably the earliest record of any system devised to lighten the load of the crammer or car-pusher of those days. In the year 1868 the Gillot & Copley machine was patented, this being a compressed-air-driven disc coal-cutter which proved highly successful. The chain cutters were a natural development from this type, and for a number of reasons they have been even more successful in the majority of cases.

Jan 1, 1930

By M. Xiao Bo

In recent years, there has been a heightened interest in the hydrometallurgical processing of sulfide ores and concentrates (especially copper sulfide ores and concentrates) mostly in the USA and Chile. Currently, hydrometallurgical operations account for about 30% of the primary copper production. In the present research, the leaching phenomena of IOCG (iron-oxide hosted copper-gold) ores and concentrates were studied. The IOCG ore, which is characterized as having a predominant amount of magnetite with fine chalcopyrite, is currently the center of attention for new copper resources. Heap leaching of IOCG ore is desirable because of its low cost. However, the leaching characteristics of the ores and concentrates and the mechanisms of copper leaching require investigation. This study defines the factors, which affect the leaching operation, such as the ORP, pH and oxidizing agents. Based on these results, the optimal leaching conditions are provided for pilot column leaching test and ultimately, commercial operations.

Jan 1, 2007

By K. S. Coley, G. A. Irons, T. Kaneyasu

"It is very important to reveal the lime dissolution mechanism in steelmaking slag, to promote its dissolution without calcium fluoride, which is now almost forbidden for use in most industrialized countries. In this research, the purpose was focused on the development of an experimental method to measure the mutual diffusivity of Ca2+ under the condition of lime dissolution into slag. By forming diffusion couples using a ""vacuum slag aspirating technique"", the method was established. The following mutual diffusivities of Ca2+, in CaO-SiO2-FeO slag systems, imitating oxygen steelmaking slag, were determined using this method:4.1*10-10 m2/s at 1400°C for 27wt.%CaO-53wt.%SiO2-20wt.%FeO slag,4.3* 10-10 m2/s and at 1400°C for 20wt.%CaO-40wt.%SiO2-40wt.%FeO slag, and 1.3*10-10 m2/s at 1250°C for 20wt.%CaO-40wt.%SiO2-40wt.%FeO slag.It was also verified that, if the basicity and ferrite content of the bulk slag are low, then a calcium silicate film forms on the lime surface, and drastically deters the lime dissolution."

Jan 1, 2004

By W. E. MacDonald

This paper relates the story of 100 years of mining in the Harbour Seam at the Princess Colliery, Sydney Mines, Nova Scotia. Several interesting anecdotes are included along with the discussion of the evolution of coal mining methods in the area. Finally, some of the recently introduced equipment at Princess Colliery is described, and prospects for the future of the industry are outlined.

Jan 1, 1968

By Wignall. T. K., J. De Geoffroy

Statistical models are fitted to the observed distributions of eighteen characteristics of the population of commercial porphyry deposits of North and South America. The statistical base required for the formulation of the statistical models includes 58 commercial porphyry-copper-molybdenum deposits of the Cordilleran Belt from which geological, geometric and economic data were collected. Predictive and composite models are derived from the statistical study to assist explorat10n. planning, engineering studies and fmanc1al analyses as required for the development of new porphyry deposits in the Cordilleran Belt.

Jan 1, 1973

By Gregory C. More O'Ferrall

Generally pillars in the Southern African hard rock tabular underground mining environment are designed using either empirical pillar design formulae or numerical modelling (analytical) methods utilizing the Hoek-Brown failure criterion. However, none of the pillar design methodologies employed takes cognizance of weak layers either within the pillar material or in the immediate foundation of the pillar. Over the past few years, the presence of a weak layer either within the pillar material or within the immediate foundation of the pillar has resulted in the closure of one platinum mine (Everest Mine), closure of one chrome mine (Wonderkop Chrome) and large-scale instability in a couple of chrome and platinum mines in South Africa and Zimbabwe. A study has been initiated to better understand the failure mode and strengths of the pillars where pillar failure associated with weak layers occurred. Owing to the infancy of the study into the failed pillar strength and failure mechanism, the purpose of this paper is to highlight the circumstances that led to the collapse of mining sections and a shaft, and the difficulty associated with designing pillars in the Southern African chrome and platinum mining operations.

Jun 1, 2012

By R. O. Burt

The original flowsheet of the TANCO mill consisted of a simple two-stage gravity circuit for the recovery of the tantalum concentrates. With decreasing grade and grain size of the tantalum minerals, considerable modifications to the circuit have been required. This paper discusses the various recent improvements carried out 011 all stages of the flowsheet, which have resulted in a 10% increase in recovery. Future improvements, including on stream analysis, and the possibility of tantalum flotation , are also discussed.

Jan 1, 1979

By Patrick R. Taylor, T. A. R. Putra

A review of various methods to treat high arsenic copper concentrates through pyrometallurgical processing is presented. Examples are drawn from various past and current operations and research. Various aspects of the engineering alternatives for treatment methods are discussed. Some of the methods discussed include: controlled oxidation roasting, adaptation of some smelter technology to accept higher amounts of arsenic, complete oxidation with arsenic fixation; sulfation roasting; acid baking, soda ash roasting, and others methods. Other topics include: a short discussion of other problematic impurities; the effects of arsenic on copper electro-refining and product purity; and methods for the ultimate disposal, or marketing, of the arsenic. The latest work being done at the Colorado School of Mines on soda ash roasting is also presented.

Jan 1, 2014

By J. P. Dick

THIS paper is a description of the milling practice and metallurgy at the Moneta Porcupine mine, Timmins, Ontario. The results obtained with an all-cyanide circuit and later with flotation followed by cyanidation are described. The ?investigation which prompted the various changes in milling practice have also been dealt with. Moneta ore is possibly the most refractory now being milled in the Porcupine district. This is due to the ultra fine state in which the gold occurs and to its intimate association with pyrite. No doubt there is ore of similar characteristics on the neighbouring properties but it probably forms only a small portion of the tonnage being mined, whereas at Moneta the bulk of the ore requires an extremely fine grind to liberate the gold. The fineness to which an ore can be ground economically has gone far beyond what was thought to be the limit only a few years ago. Formerly, a set of standard screens was all that was required to measure the fineness to which an ore was ground. At present, the Haultain infrasizer is practically indispensable, and the nominal micron has become a familiar unit of measurement to all those dealing with the problems of fine grinding.

Jan 1, 1941

By L. Kilburn

"A survey of 281 mineral exploration agreements examines the ratios among three ways that may be used to purchase an interest in a mineral property, viz: pay cash, pay shares and make future expenditures on the property.The dollar value of the future expenditures exceeds that of cash or shares by about nine times in most of the 110 agreements that contain cash-expenditure or share-expenditure components. Results suggest that cash and shares are treated about the same in terms of value.Buyers and sellers have opposing priorities for the way that they prefer to purchase a mineral property. These opposing priorities should give rise to a perceived 50:50 balance between cash/share payment and future expenditures to satisfy the idealized situation described by most definitions of fair market value (FMV). This balance between cash/share payments and future expenditures appears to be rationalized in negotiations to a FMV when expenditures are nine times greater than cash and/or payments.On this basis, it is proposed that the FMV of a property may be determined by aggregating the dollar amount of the cash/share payments plus one-ninth the dollar value of future expenditures, as set forth in the respective purchase agreement, and proportionately applying such aggregate to full property value."

Jan 1, 2005

By J. E. Dutrizac

The dissolution of low-iron sphalerite, (Zn,Fe)S containing 0.08% Fe, in ferric sulphate-sulphuric acid media was investigated using closely sized fractions of crushed sphalerite crystals and sintered disks made from the crushed crystals. Linear kinetics are observed, and the predominant reaction products are ZnSO4, FeSO4 and elemental sulphur. The leaching rate increases systematically with increasing temperature, and the calculated apparent activation energy is 56 kJ/mol for the sized sphalerite and 54 kJ/mol for the sintered disks. The relatively high apparent activation energy suggests that the rate is chemically controlled, a conclusion supported by the insensitivity of the rate to the disk rotation speed. The rate increases as the 0.22 power of the Fe(SO4)1.5 concentration, and as the 0.22 power of the H2SO4 concentration. However, in the absence of ferric ions, the rate increases more significantly with increasing H2SO4 concentrations, and relatively rapid rates are observed in solutions containing >0.5 M H2SO4. In 0.1 M Fe(SO4)1.5-0.3 M H2SO4 media, the measured rate decreases with increasing sulphate concentrations, added as Li2SO4. The rate of dissolution of low-iron sphalerite is promoted by dissolved copper concentrations as high as 800 mg/L. In contrast, dissolved silver, even in the 0-2 mg/L concentration range, significantly retards the dissolution of the low-iron sphalerite.

Jan 1, 2008

By B. J. Walsh

ABSTRACT Segregation of sphalerite minerals in zinc concentrates into christophite, marmatite and ordinary sphalerite by means of magnetic fractionation is investigated. A Frantz ferromagnetic filter, 1.2 amp., and a Dings magnet, 0.3 amp., is used to fractionate seven zinc concentrates produced in the Province of Quebec. The Dings magnetic product contains the pyrrhotite, and the sphalerite as christophite. The Frantz magnetic product contains sphalerite as marmatite, while the Frantz nonmagnetic product contains ordinary sphalerite. The results indicate that the magnetic susceptibility of sphalerite increases with increasing isomorphous iron content and that a satisfactory separation into christophite, marmaite, and ordinary sphalerite may be accomplished by magnetic fractionation. INTRODUCTION SPHALERITE, the chief ore of zinc, is almost never pure zinc sulphide. Iron is almost always present isomorphously replacing an ?equivalent amount of zinc. What may be referred to as 'ordinary' sphalerite contains up to 10 per cent iron. More highly ferriferous varieties, with 10 to 26 per cent or more iron, have been named marmatite .and christophite.

Jan 1, 1951

By T. E. Warren, K. W. Bowles

"IntroductionTHE PROBLEM of producing synthetic liquid fuels from coal and other raw materials is of increasing importance in Canada as well as in the United States. This is due, to a large extent, to the continually increasing demand for gasoline and other liquid products which are now obtained solely from petroleum. The United States has reached a position where domestic supplies of crude petroleum must be augmented by imports and Canada is still a long way from self-sufficiency. In the event of war, there might well be an immediate need to find supplementary sources of liquid fuels. It is, therefore, expedient to consider alternative sources of production now -well in advance of the time when supplies of petroleum may prove inadequate to meet requirements.The purpose of the present paper is to give a short review of the history of liquid fuel production from coal, to describe briefly the research sponsored by the Federal Government on the coal hydrogenation process, and finally to evaluate the present status and future trend of the synthetic fuel industry, with special reference to necessary research work.History of the Oil-From-Coal IndustryThe history -of coal liquefaction began in 1913, in Germany, with the work of Frederick Bergius. His first approach to the subject was not deliberately planned."

Jan 1, 1952

By John H. Nicholls

In this paper, Imperial Oil Limited reports briefly on the drilling by contract rigs of twenty-nine slim holes in the Virden, Smiley, and Souris Valley areas. The investigations showed that slim-hole penetration rates, as a result of careful control of drilling variables, can approach those achieved with 7 7/8-inch bits. It is concluded that slim-hole drilling is acceptable for development or exploratory work. Imperial also reports on the completion techniques and equipment that have been developed on twenty-seven tubingless 2 1/2-inch casing completions. Indications are that the method is economically desirable where excessive gas or water production is not anticipated.

Jan 1, 1958

By D. G. Eskin

"It is well known that it takes some time for the solid phase to completely dissolve upon melting, especially inside the defects of insoluble particles, e.g. oxides. Until then the oxides remain active solidification substrates in the case of subsequent solidification. It is also known that ultrasonic melt treatment causes grain refinement through activation and dispersion of solidification substrates (one of the mechanisms) and also accelerates the dissolution of solid metal in the melt. In this study we combine these effects and demonstrate that the introduction of an alloy rod into the matrix melt of the same composition results in significant grain refinement, this effect being increased by the ultrasonic vibration of the rod. The achieved grain size is comparable to that obtained by a standard Al–Ti–B grain refiner. All samples were cast using a standard TP-1 mould to enable correct comparison. The effect of the temperature range of the rod introduction, as well as the effect of ultrasonic vibrations are discussed.INTRODUCTION The fact that by introducing solid metal into the melt one can achieve structure refinement is rather well known. As early as in the 1930s–1950s a series of papers and patents have been published, showing the benefits for grain refinement when dissolving solid metal in the melt before solidification (Danilov and Neimark, 1938; Scheil, 1956). Later on this way of structure refinement was developed further and dubbed “suspension casting” or introduction of “internal chills” (Madyanov, 1969; Zatulovsky, 1981). The solid metal was added in a form of cut wire, cut sheet, or powder, with the resulting grain refining, elimination of columnar grain structure in ingots and castings of steel, copper and aluminium alloys. The underlying mechanisms have been suggested as (1) rapid cooling of the melt due to the latent heat consumption upon melting of the solid metal with the resultant melt undercooling and (2) introduction of many solidification substrates in the form of crystal fragments and active non-metallic inclusions (Danilov & Neimark, 1938; Balandin, 1973). A number of patents have been filed where either the same solid alloy or a master alloy with additions (e.g. Ti for Al alloy) is introduced in the amounts up to 50% (typically less than 10%) into the melt close to the liquidus temperature (Schmidt, 1966; Talbot & Soller, 1973, Krupp, 1974; Bondarev, 1979). The main reason that this technique is not widely used in industry is the possible incomplete dissolution of the solid parts introduced into the melt with ensuing inhomogeneous as-cast structure and potential defects. Also the selection of the temperature range where the technology works the best is not clear."

Jan 1, 2018

By W. van der Merwe

ABSTRACT With the gold industry processing more complex ores, the online measurement and control of cyanide addition to the gold leaching circuit has become more critical. This paper compares the two commonly employed ‘free’ cyanide online analysis methods (amperometric and potentiometric endpoint silver nitrate titration) with the rhodanine endpoint silver nitrate titration and ion selective electrode methods common at site laboratories. Measurement differences between these methods are presented and discussed for cyanide solutions containing copper and zinc with varying cyanide to metal ion ratios. The resulting cyanide available to leach gold is also compared using these measurement techniques.

Jan 1, 2013