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By S. Vivek

An atomic force microscope (AFM) was used to measure the surface forces between silica plate and glass sphere in sodium oleate solutions. Hydrophobic forces were observed when the two surfaces were activated by CaOH+ or MgOH+ ions. The force measurements conducted in the absence of the surfactant showed that the activated silica surfaces do not exhibit the primary hydration forces that have been observed between unactivated surfaces. The activation mechanism was studied by calculating the contributions from electrostatic and chemical interactions to the total free energy change. The results suggest that the adsorption of the hydroxo-complexes is controlled mainly by the lateral interactions between the adsorbed species on the silica surface.

Jan 1, 1999

By A. L. Coello Velázquez

The subject of this paper is particle population balance models (PBM) that describe mineral impact crushing behavior; it is mainly concerned with the selection and fragmentation distribution function due to their importance in this context. The data obtained by Datta (1999) by applying impact pendulum testing to single limestone particles, used by Austin (2002, 2004a and 2004b) to obtain the principal parity of fragmentation functions, were processed in order to compare them with the results of other authors, such as Nikolov (2002 and 2004) and Vogel and Peukert (2003 and 2005) so as to increase knowledge of impact crushing. From this data it has been possible to obtain the performance models of the principal parameters of fragmentation function, thereby reducing the number of experiments necessary to model the impact crushing process. The authors also propose a simplification of the selection function model posited by Austin (2002).

Jan 1, 2011

By D. Lelinski

Air-sparged hydrocyclone (ASH) flotation is one of the new promising technologies. Numerous applications have been successfully tested since its conception; nevertheless, research and development efforts have continued to provide for further improvements with respect to operating conditions and design considerations. Results from experimental studies on bubbles generation in the ASH system are presented in this paper. Bubble size distributions generated during ASH operation have been determined using a high-speed photographic technique. The influence of many factors including surfactant concentration, water flowrate, and porous tube pore size has been studied. Test results indicate that these process variables have a profound effect on the bubble size distribution. With an increase in surfactant concentration or water flowrate (shear field) the bubble size distributions become narrower and shift toward smaller average bubble diameters. However, the influence of pore size is more complicated. Depending on the experimental conditions the average bubble size was found to range from about 100 to 300 microns in diameter.

Jan 1, 1995

By D. Wenstrup, K. Perry, J. Hatfield, P. Sainato, B. Lusk

Concrete-infused cloth is used in several civil and mining surface applications whose circumstances are similar to some of those in underground mining. A feature of this material is that it cannot be overhydrated. In underground conditions, however, the excess supply of water to the cloth for hydration could lead to muddy and potentially unsafe working conditions, as well as resource wastage by supplying more water to the construction site than is needed. The objective of this study is to verify the water-to-cloth ratio and study the effect of hydration level on the strength of the Concrete Cloth product. We found that the strength increases with increased hydration up to a 1:2 water-to-cloth ratio by weight, after which the strength holds steady regardless of additional hydration. This confirms the 1:2 water-tocloth ratio by weight for hydration and confirms that strength is retained even if the cloth is excessively hydrated.

Jan 1, 2014

By D. K. DeForest

The olfactory system (sense of smell) is crucial to the ability of fish to avoid predators, recognize kin, and synchronize reproduction (Baldwin et al. 2003). Copper (Cu) has been shown to impair olfaction in juvenile freshwater life stages of salmonids (including Pacific salmon and trout) in some laboratory experiments; and in the United States, public concerns have been expressed that current regulatory criteria for Cu in fresh water are not adequately protective of olfactory function in salmonids (e.g., OSU 2007; Pearson 2007). These concerns have largely been raised because some Cu concentrations that have caused olfactory impairment in salmonids in the laboratory are less than Cu concentrations that have been shown to reduce salmonid survival, growth, or reproduction (the effects endpoints that are typically considered in deriving ambient water quality criteria). However, two important and interrelated points that must be considered: (1) freshwater Cu criteria are "driven" by the sensitivities of several invertebrate species that are more sensitive than the olfactory impairment threshold in salmonids when (2) the influence of water chemistry on Cu bioavailability is properly considered in deriving Cu criteria. Bioavailability refers to the ability of various chemical forms of Cu to interact with receptors on the surface(s) of organisms and thus directly cause toxicity or uptake by the organisms. The toxicity of Cu and other metals to aquatic organisms is a function of water chemistry. For example, acute Cu toxicity in fresh water generally decreases as pH, water hardness (Ca2+ and Mg2+), alkalinity, and dissolved organic carbon (DOC) concentrations increase (Meyer et al. 2007). The U.S. Environmental Protection Agency (USEPA) has recommended hardness-based freshwater aquatic life criteria for Cu and other metals since the 1980s (e.g., USEPA 1985); and hardness-based metals criteria decrease (i.e., become more restrictive) as water hardness decreases. More recently, the USEPA has recommended freshwater aquatic life criteria for Cu based on the biotic ligand model (BLM; USEPA 2007), which accounts for the influence of multiple water chemistry parameters, including DOC, pH, alkalinity, Ca2+, Mg2+, and several other cations and anions. The BLM-based Cu criteria generally decrease as DOC concentration, pH, alkalinity, and water hardness decrease. Because DOC has a stronger influence on Cu bioavailability than water hardness, hardness-based and BLM-based Cu criteria can differ considerably. For example, in water that has low DOC and high hardness, the hardness-based Cu criterion would be relatively high (because it is driven by the high hardness) but the BLM-based Cu criterion would be relatively low (because it is driven by the low DOC). Thus, any evaluation of the protectiveness of Cu criteria against a given effect, such as olfactory impairment, must properly account for the chemistry of the exposure water. Meyer et al. (2013) compiled data on Cu-induced olfactory impairment and olfactory-induced behavioral effects from tests in which BLM parameters were measured. They demonstrated that the USEPA's BLM-based freshwater life criteria for Cu are protective against olfactory impairment, because it adequately accounts for water chemistry (whereas the USEPA's hardness-based Cu criteria are not consistently protective). Olfactory impairment by Cu is now receiving increased attention in Canada and Europe (e.g., Wall 2013; Stang 2013). Accordingly, in this paper we have expanded the analysis of Meyer et al. (2013) to consider copper guidelines from various other countries and whether these guidelines are protective against olfactory impairment.

Feb 23, 2014

By W. C. Hirt

Selective flocculation was used to produce superclean zinc concentrate with minimized silica contamination. Research was carried out on a flotation concentrate from the Jersey Miniere Zinc Company (JMZ) in Gordonsville, Tennessee. The material was first dispersed with sodium silicate and then causticized tapioca starch was used to selectively flocculate the sphalerite, leaving the silica in suspension. This technique has been applied commercially to iron ore beneficiation but has never been used for processing zinc. The feed material assayed 0.45% Si02. Use of 0.56 kg/tonne (1.13 lb/st) of sodium silicate and 0.070 kg/tonne (0.141 lb/st) of causticized tapioca starch resulted in 98.2% zinc recovery in a purified zinc concentrate assaying 66.0% Zn and 0.24% silica. The present target level for silica contamination in JMZ zinc concentrates is 0.3% Si02. This work has shown that selective flocculation offers a potential method for cleaning flotation concentrates, particularly where low silica products are required.

Jan 1, 1993

By S. S. Peng

The generation and transportation of the airborne dust are mainly governed by the velocity and the movement pattern of the ventilation air in the longwall face. Generally speaking, the higher the air velocity, the more the airborne dust will be generated and the longer the period of the dust of certain size will be carried away from the source. In order to effectively prevent the production and the spread of the airborne dust, The airborne dust concentration distribution in the longwall face must be known in advance. Before the dust concentration distribution can he predicted theoretically with confidence, the air velocity distribution pattern of the ventilation air in the longwall face area must be determined first. However, the complicated, time-dependent and unpredictable mining conditions along and around the face area make the theoretical studies of the problem rather difficult. For instance, one of the factors commonly affecting the air velocity distribution at the longwall face is the air leakage, either into or from the gob area. The leakage quantity and the location of occurrence differ from mine to mine, face to face, and time to time. They depend not only on the compactness of the caved roof fragments in the gob, but also on the degree of obstructions in the working space and in the return entry. Another obstacle to the theoretical studies about the velocity distrbution is the complicated boundary conditions of the ventilated spnce which is very difficult to represent accurately in mathematical forms. In this paper, the air velocity distributions measured in four longwall faces are presented. A statistical model for each longwall face is also derived for prediction of air velocity distribution in the longwall face.

Jan 1, 1985

By N. Chow

The recovery of manganese from lower-grade resources has been studied for a number of years. Of key importance in prior work was the discovery that higher-valent manganese can be readily leached with sulfurous acid. This eliminates the need for high-temperature reduction roasting that is conventionally used in processing high-grade material. High-temperature roasting is energy intensive, emits a large amount of carbon dioxide and would not be economical for processing lower grade material. While the prior work provides important information for extracting manganese from lower-grade resources, the production of unwanted byproducts and high water and energy usage has limited its commercial use. This paper describes the results from laboratory work that demonstrate solutions to problems that to this point have precluded commercial development. Preliminary mass and energy balances show that a significant opportunity exists in producing manganese with this hydrometallurgical scheme in a low-cost, environmentally friendly manner. The emphasis of the work is on low water use, low overall energy use and economic destruction of unwanted byproducts.

Feb 1, 2012

By Ming-yi Zhang, Zhong-nian Yang, Xiao-ming Guan, Quan-wei Liu

"In slurry balanced shield tunneling, how to ensure the safety of construction and to reduce the influence on the environment has arisen wide attention of scholars both at home and abroad. But now it is still in the stage of experience as to the instability mechanism of the slurry shield tunneling excavation and its stability analysis. Based on the large-diameter model tests and FLAC 3D, the effect of the different waterhead (non-water, 0.9m and 1.1m) on stability of excavation face of slurry balanced shield is investigated, and the stability mechanics is proposed. The results show that: waterhead heights play an important role on excavation face instability features of slurry balanced shield in sandy stratum, Regarding the different waterhead heights, the development mode of the excavation face instability features can be divided into non-water mode, lower-waterhead mode and higher-waterhead mode; soil arching is existed in the process of excavation face instability, the settlement of ground lags behind excavation face failure, the soil arching will block or eliminate the effects of ground settlement; excess pore water pressure need to be considered besides earth pressure and hydrostatic pressure when the supporting force is calculated. INTRODUCTION With the development of the society, for the cities all over the world, the exploitation of underground space has become an important measure to solve the problems about population, resources and environment and an important way to heal the city syndrome and implement the sustainable development strategy of city. Constructing shield tunnel with large diameter is the major trend for development of tunnel construction (Yin, 1999). Instability of excavation face caused by relief of shield soil stress is still one problem that needs to be solved (Xiang, 2001). How to reduce the effects of construction on surrounding environment? How to accurately determine the instability of shield excavation face and to effectively and reasonably select the supporting force? These are the crucial problems which need to be solved during shield construction."

Jan 1, 2016

Sphalerite is commonly floated in an alkaline environment and under such conditions the overall activation mechanism is obscured by the hydrolysis of Cu2+ and precipitation of Cu(OH)2. Electrokinetic and kinetic flotation tests show that the activation of sphalerite is a two-stage process; the activation products formed on the surface of sphalerite in near neutral and in alkaline solutions in the first rapid activation stage are "flotation-inactive". These layers, when formed in an alkaline solution, are unstable and are transformed into the "flotation-active" form in the second stage. However, the surface layers formed during activation in alkaline environment by copper in the presence of lead ions are very stable and even after a long conditioning time the flotation rate is not improved. Consequently, while both Cu2+ and Pb2+ activate sphalerite flotation, quite unpredictable effects may result when both are present in the solution.

Jan 1, 1997

By B. Valentim

Policies for reducing NOx emissions have led power plants to restrict O2, resulting in high-carbon fly ash production. Therefore, some potentially useful fly ash, such as the economizer fly ash, is discarded without a thorough knowledge of its composition. In order to characterize this type of fly ash, samples were collected from the economizer of a Portuguese power plant burning two low-sulfur bituminous coals. Characterization was also performed on economizer fly ash subsamples after wet sieving, density and magnetic separation. Analysis included atomic absorption spectroscopy, loss-on-ignition, scanning electron microscopy/energy-dispersive X-ray spectroscopy, optical microscopy, and micro-Raman spectroscopy. Key words: Fly ash; Petrology; Petrography; Economizer fly ash

Jan 1, 2009

By Stanisław Prusek, CHONG WEI, Huawei Xu, Jun Wang, Andrzej Walentek, Artur Dyczko, Derek B. Apel

The excavation-induced stresses transferred from the panels or pillars in upper coal seams play a key role in the occurrence of rockbursts in driving roadways during close-distance coal seam mining, which has become a common problem and threat to many underground mines. The authors established a 3D finite-difference numerical model via FLAC3D software using the closedistance coal seam mining conditions in the Zofiówka Mine as a case example to reveal the rockburst mechanism in such conditions. The excavation-induced vertical stresses are analyzed, which provides a basis to build a conceptual model to explain the possible source mechanism of the rockburst under such conditions. Nine typical rockburst indicators considering different contributing factors are then selected as the evaluation criteria to assess rockburst potential in the study site. The results suggest that the superposition of multiple excavation-induced stresses of the main drift and tailgate provides an environment for stress concentration and energy accumulation. The side abutment stress induced by mining in the upper coal seam has a “strengthening” effect to the rockburst occurrence. The great deviatoric stress induced by complex excavating situations is another important exterior cause. A strict calibration procedure should be implemented before using indicators to predict rockburst potential. A methodology was proposed to estimate the location and magnitude of rockbursts combined with numerical modeling, laboratory tests, and feedbacks from the field. The study could provide some references and guidelines for preventing and mitigating rockbursts in underground mines under similar engineering conditions.

Aug 26, 2021

By C. S. Wageman

Staying competitive in the highly aggressive Powder River Basin is a challenge facing all operators. Any advantage that a mine utilizes to improve productivity and reduce costs could mean the difference in the tight spot coal market. Technological advances in mining equipment and data acquisition at the Eagle Butte Mine in Gillette, Wyoming result in productivity gains and increased maintenance awareness. A new overburden haulage truck fleet with an onboard payload and fault monitoring system interacts via telemetry with the loading shovel and PC's located in production and maintenance offices, enabling staff to monitor production and maintenance on a real-time basis. This paper will describe the system and highlight the benefits realized as a result of its implementation.

Jan 1, 1996

By R. M. Parlman

Interest is increasing in obtaining incremental improvements in mineral recoveries in flotation processes because of changing world economic conditions. Research on collector reagents, long indispensable components in flotation systems may provide the cheapest and simplest route to higher metal recoveries. Sulfhydryl group - containing compounds (-SH) and their salts, e.g., dithiophosphates, xanthates and a few other derivatives are commonly used to promote the flotation of sulfide minerals. Alkyl mercaptans, another class of sulfhydryl compounds, have long been known to have collecting properties but have been relegated to dormancy for one reason or another. This paper reports results from new investigations of alkyl mercaptans, trithiocarbonates, and a petroleum oil with a variety of western domestic and Canadian ores for copper and molybdenum sulfides recovery. Specific opportunities are pointed out to the industry for mineral recovery enhancement through the use of the proper reagent combination.

Jan 1, 1980

The role of ZnSO4 in activation of sphalerite (ZnS) and deactivation of lead-activated sphalerite has been investigated. Adsorption of metallic ions at the solid-solution interface, electrokinetic results for sphalerite under different chemical conditions, and thermodynamic calculations were used to elucidate the mechanisms involved. It is shown that flotation response of sphalerite in absence of activators is rather weak and that adsorption of ethyl xanthate on the mineral mainly electrostatic in nature. Zinc sulfate is found to activate the mineral but only in a narrow acidic pH range. This is attributed to the increase of zeta potential as well as the possible increase in amount of negatively charged bulk precipitated zinc xanthate. Lead ions activate sphalerite in a wide pH range and the lead activated mineral assumes a flotation behavior similar to that of galena (PbS). However, addition of ZnSO4 depresses the lead-activated sphalerite by replacing lead ions at the mineral/solution interface.

Jan 1, 1999

By Rees D. Groves

Cement copper is ordinarily converted to marketable metal by processing in a conventional smelter and refinery. Because of rapidly increasing cement copper production and limited excess smelting capacity, other techniques were investigated for preparing marketable copper products. One route was to make copper powder for industrial use. The process scheme employed flotation for rejecting the bulk of the impurities, acid leaching to remove residual iron and aluminum, reduction sintering to eliminate oxygen, and grinding to obtain powder. Another route was to sinter the floated and leached copper into the form of anodes and electrolyze these to yield refined copper cathodes. At a current density of 30 amperes per square foot, power consumption for electrorefining was 185 kwhr per ton of copper. The feasibility of preparing commercial-size anodes by sintering is still to be assessed.

Jan 1, 1970

By Pramod C. Thakur

Coal is a major source of energy in the world today and will, undoubtedly, continue to be so for the next few centuries. Naturally, a great number of studies has been made of its physical and chemical properties. Unfortunately, the work on technical properties which influence the mining of coal and the consequent yield of inflammable gases and respirable dust particles has not progressed at a comparable pace. Coal is a brittle material. Irrespective of the mechanism of breaking coal, some dust is always produced. In mining parlance dust is defined as solid particle, smaller than 100 microns (micron = 10-6 meter), in size Coal dust, when raised into a cloud, creates two well known hazards in mines, namely, the coal dust explosion and Coal Workers' Pneumoconiosis (CMP). The latter is, perhaps, the greatest environmental hazard in U.S. coal mines today. In this context it is not only natural but also necessary to investigate the proneness of a coal seam to respirable dust production. It has been established that the amount of dust produced is a function of two groups of variables (1), (2), viz. (1) Material dependent variables, e.g., moisture content, compressive strength, hardness, etc. (ii) Breaking mechanism dependent variables, e.g., type of machine, depth of cut, etc.

Jan 1, 1973

By F. N. Siddiquie, Mohd Shaif, Rajiullah Khan, Juned Alam

Manganese ore bodies of Banswara Mn belt were classified into stratiform and stratabound types, based on their mode of occurrence, distribution, and their chemical characters. These ore bodies generally composed of braunite, pyrolusite, cryptomelane/ psilomelane, wad, etc. The stratiform-type Mn ore bodies are conformable with the associated host rocks (Mn phyllite, etc.) and occurred in the form of layers, bands, etc., which are variable in their shape and size. These ore bodies are also strongly folded with the enclosing host rocks. The others, which are stratabound-type Mn ore bodies, also showed an intimate association with the associated host rocks. These types of ore bodies occurred in thin layers, pockets, lenses, stringers, etc. The classified ore bodies are confined with Kalinjara formation of Aravalli Supergroup of Paleoproterozoic age. The ore bodies are structurally controlled and well associated with phyllite, schist, limestone, quartzite, etc. The stratiform-type ore bodies constitute a marginal to low Mn grade and are also characterized by lower Mn content (26.19–39.24%) along with the Mn/Fe ratio of 7.16–12.23, while the stratabound-type Mn ore bodies are rich in Mn (35.92–49.64%) along with the higher Mn/Fe ratio of 14.15–23.97. However, the poor Mn grade along with high siliceous impurities of Banswara Mn deposits is subjected to them for intermittent mining activities in the past and, consequently, did not attract the scientific and industrial community for the evaluation of these resources. Therefore, the authors attempted this study in a scientific and systematic manner (mode of occurrence/distribution and possible methods for evaluation/exploration) to evaluate the potential of existed and newer Mn deposit resources in the Banswara Mn belt. The whole findings would be very much helpful for exploration/ mining geologist along with other concerned, to completely evaluate these Mn deposits in the future.

Aug 16, 2021

By R. Hogg

A standard procedure for determining size-specific gravity distributions of fine coal (including the -400 mesh fractions) by sieving and centrifugal sink-float separation is described. The significance of using a centrifugal sink-float technique and the effect of the magnitude of the centrifugal force on the separation of fine coal are confirmed in the present study. The relative merits of cumulative versus incremental sink-float are discussed. The procedure is evaluated quantitatively using data obtained for the products of froth flotation of -100 mesh coal.

Jan 1, 1994

By LUKAS FAHLE, Andrew J. Petruska, JURGEN F. BRUNE, Gabriel Walton, Elizabeth A. Holley

Adverse ground behavior events, such as convergence and ground falls, pose critical risks to underground mine safety and productivity. Today, monitoring of such failures is primarily conducted using legacy techniques with low spatial and temporal resolution while exposing workers to hazardous environments. This study assesses the potential of novel simultaneous localization and mapping (SLAM)-based light detection and ranging (Lidar) data quality for rapid, digital, and eventually autonomous mine-wide underground geotechnical monitoring. We derive a comprehensive suite of quality metrics based on tests in two underground mines for two state-of-the-art mobile laser scanning (MLS) systems. Our results provide evidence that SLAM-based MLS provides data of the quality required to detect geotechnically relevant changes while being significantly more efficient for large mine layouts when compared to traditional static systems. Additionally, we show that SLAM-specific processing can achieve an order of magnitude better relative accuracy relevant for change detection than quality metrics derived from traditionally deployed tests would suggest while reducing SLAM drift error by up to 90%. In collaboration with an operating block cave mine, we confirm these capabilities in field tests on a mine-wide scale and, for the first time, demonstrate methods of rockfall detection using MLS data. While more work is required to investigate optimal collection, processing, and utilization of MLS data, we demonstrate its potential to become an effective and widely applicable data source for rapid, accurate, and comprehensive geotechnical inspections.

Aug 16, 2022