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Surface characterization techniques, i.e. contact angle measurement, atomic force microscopy (AFM) surface force and surface imaging measurement, were applied to investigate the molybdenite surface in aqueous solution. It was shown that the cleaved basal surface of molybdenite was very hydrophobic with a 92 degree water contact angle. The non-polar component of the solid surface free energy is 50.52 mJ/m2 while the polar components are almost zero. The solid surface was not reactive and was only weakly charged at the pH 6. When the aqueous media changes from water to 1×10-4 M KEX solution, the measured contact angle, adhesion force and surface roughness all increase slightly. However, ethanol rinsing made the surface change back to the bare substrate. It was suggested that the hydrophobic chemical, i.e. dixanthogen, which was shown in the morphology of patches by the AFM image, physically adsorbed on the hydrophobic molybdenite surface through the hydrophobic interaction.

Jan 1, 2009

By J. Brent Hiskey

INTRODUCTION Metal electrodeposition processes are of fundamental technological importance to a number of fields. Electrorefining, electrowinning, electroplating, and electrogalvanizing have all been the subject of intense study for over a century. More recently, electrochem- ical deposition has played a critical role in advances in microelectronics and lately has been an enabling technology for the production of certain nanostructured materials. Electrometallurgists have most frequently been concerned with the structure and morphology of massive deposits. For example, in metal recovery steps such as electrorefining and electrowinning, deposits demonstrating adherent coarse-grained characteristics are most desirable. In the case of electroplating, a bright fine-grained, tenacious and strongly adherent deposit is required. The fabrication of microelectronic devices and the production of nanoscale structures such as nanoparticles, nanowires, and nanorods requires a keen understanding of early stage deposition effects. The initial stages of metal deposition, usually referred to as electroclystallization, are fundamentally linked to nucleation and growth phenomena. Early stage deposits are typically very ordered. Whereas, bulk metal deposition structures are much more ran- dom. In both cases, the discharge of a metal ion at an electrified interface is represented by simple cathodic reduction as follows: [ ] Me(H2O)xn[ ] is a hydrated metal ion residing in the bulk solution and Me is the metal atom occupying a crystallographic lattice position. A similar reduction reaction can be

Jan 1, 2005

By R. W. Brann, R. C. Freas

Franklin Industrial Minerals operates several mines/quarries, including two room and pillar underground mines. Both of these mines are operated as multiple level room and pillar including heading and bench operations on one or both of the levels. This paper focuses on Franklin’s Crab Orchard, Tennessee mine, which produces both high purity chemical grade limestone and crushed stone for construction applications. The high purity chemical specifications for the chemical grade limestone and filler/extender applications are inconsistent with the non-chemical rock being produced to supply the crushed stone market. As a consequence Franklin has developed a unique mine plan and operation to maintain both product balance and a safe and stable working environment.

Jan 1, 2003

By Michael Fehler, Hidenshi Kaieda, Leigh House

Hydraulic fracturing has gained in popularity in recent years as a way to determine the orientations and magnitudes of tectonic stresses. By augmenting conventional hydraulic fracturing measurements with detection and mapping of the microearthquakes induced by fracturing, we can supplement and independent1 y confirm information obtained from conventional analysis. Important information obtained from seismic monitoring includes: the state of stress of the rock, orientation and spacing of the major joint sets, and measurements of rock elastic parameters at locations distant from the wellbore. While conventional we1l 1ogging operations can provide information about several of these parameters, the zone of interrogation is usually limited to the immediate proximity of the borehole. The seismic waveforms of the microearthquakes contain a wealth of information about the rock in regions that are otherwise inaccessible for study. By reliably locating the hypocenters of many microearthquakes, we have inferred the joint patterns in the rock. We observed that microearthquake locations do not define a simple, thin, planar distribution, that the fault plane solutions are consistent with shear slippage, and that spectral analysis indicates that the source dimensions and slip along the faults are small. Hence we be1 ieve that the microearthquakes result from slip along preexisting joints, and not from tensile extension at the tip of the fracture. Orientations of the principal stresses can be estimated by using fault plane solutions of the larger microearthquakes. By using a joint earthquake location scheme, and/or calibrations with downhole detonators, rock velocities and heterogeneities thereof can be investigated in rock volumes that are far enough from the borehole to be representative of intrinsic rock properties.

Jan 1, 1986

By Yanchuan Li, Haifei Yao, Haiyan Wang

"Dust pollution is very serious in coal mining process, which is a great threat to the underground staff health and equipment and facilities safety. Coal seam water injection in mining process is an effective way to reduce coal mine dust concentration at the source. However, the effectiveness of water injection is limited in high-pressure and low-porosity coal seam. To improve the moisture content of coal seam, expand the wetting range and enhance the effect of dust reduction by water injection, the injectability and influencing factors of coal water injection are analyzed by numerical simulation method, and the sealing technology under high-pressure condition is studied. Then, according to the practical conditions of Tangkou coal mine, the parameters and process system of process system are designed, the effect of high-pressure water injection in coal seam was determined by testing water injection quantity, water increment and dust concentration. It is showed that the dust-removal rate of the high dust concentration operation such as falling coal and moving frame is 63.49% and 59.72%, the maximum dust-removal rate of multi-processes is 53%, which achieve a high level of application. The research results in this paper is of important theoretical and practical value to improve the water injection effect of high-pressure and low-porosity coal seam and improve the efficiency of dust removal in coal mining process.Introduction With the increasing of the depth and mechanization of coal mining, coal dust, the impact of ground pressure, ground temperature and other natural disasters continue to upgrade the harm degree (Wang 2011, Wu et al 2012), disaster incidents occur frequently, which seriouslythreaten the safe and efficient mining and the physical and mental health of underground staff. Coal seam water injection can effectively reduce the coal dust when coal crushing, prevent the impact of mine pressure, coal and gas outburst disasters, by increasing the thermal conductivity of coal, reduce coal temperature, and prevent spontaneous combustion of coal. In addition, coal seam water can soften the hard coal, so that speed up the recovery rate, improve coal production and efficiency (Wu et al 2008, Nie et al 2007). However, the coal seam in many mining area is with high-pressure and low-porosity feature, Coal joint cracks are not developed and relatively hard, water injection is difficult in these coal seams, then the desired disaster prevention effect cannot be achieved (Jin et al 2001, Zhao et al 2000). In this paper, the numerical simulation and field test methods are used to design the high-pressure and low-porosity coal seam water injection technology, so as to solve the difficult problem of coal dust control in high-pressure and low-porosity in deep well mining process."

Jan 1, 2017

By James M. Johnson, David Landriault, Frank Palkovits

The term “Paste Technology” was first used in the late 1980’s. It was used to describe a high fines (15 wt% or greater minus 20 microns), low water content backfill material that could be transported underground through a borehole/pipeline distribution system (4” to 8” dia.) at a yield stress similar to fresh concrete (100 to 400 centipoise). This “Paste Backfill”, unlike slurry transported backfills does not segregate into separate solid and liquid phases at low pipeline transport velocities or upon disposal into the underground stope. Paste backfills can consist solely of fine material, or can include fines plus sand and aggregate similar to a concrete mix. Pipeline transport of paste requires that sufficient fine material (minus 20 micron content) is contained within the mix to lubricate the pipeline walls to create a plug flow condition. For concrete, the fine material is supplied through the cement addition to achieve high compressive strength. For paste, the fine material is generally available in large quantities in the form of mill tailings. The paste tailings can be transported underground for use as backfill or discharged on the surface in a tailings management facility (TMF). This natural abundance of fine grained material is not exclusive to mine tailings but is common to many waste streams in many different industries. This makes the disposal of many waste materials very amenable to paste pipeline transport and placement as a non-segregating slurry. The potential use of paste technology for a wider group of waste materials was realized by these authors and others over two decades ago. Through the effort of this small group the use of paste technology has expanded over the years to become recognized as a low cost, environmentally superior, and technologically controllable method of transporting and placing specific material waste streams with a low water content and high placement density. The high yield stress nature of a paste also lends itself well to the blending of one or more coarse waste materials into the fine waste material paste stream. This allows all the waste materials to be transported by pipeline, increases their placement density; decreases the supernatant release/treatment, reduces contaminant mobilization, hydraulic conductivity and oxygen/water reactivity through encapsulation in the paste matrix. The following paper describes the present state-of-the-art use of paste technology in the world today. It also describes future uses of the technology that are under development and speculates on the overall use of the technology for waste management in the future.

Jan 1, 2005

By E. M. Wilde

Through the USGS's National Coal Availability program, coal resource appraisals have been completed for three 7.5-minute quadrangles (Willow Crossing, Colstrip East, Colstrip SW) in the Powder River Basin area of southeastern Montana. Available coal reserves (original reserves minus tonnages affected by current restrictions) vary from 44 to 70 percent of the original reserves. Major restrictions impacting each area also vary. In each area, one or two beds contain most of the reserves, but up to eleven beds contain available coal. The main beds in completed studies are the Knobloch, Rosebud, Sawyer and Flowers-Goodale. Three additional areas (six 7.5-minute quadrangles) are in preparation.

Jan 1, 2001

By K. Saberyan

A technique is described for the solvent extraction of zirconium. In this method, zirconium has been extracted quantitatively from 0.005 M sodium salicylate solution at pH 2.5 - 3 using 0.01 M triphenylphosphine oxide dissolved in toluene as an extractant. Zirconium has also been recovered quantitatively from 0.2 M potassium thiocyanate solution, but extractions in nitric and hydrochloric acids (as media) were negligible. The resulting extracted metal ion has been stripped with sulfuric acid (0.5 M) and determined with inductively coupled plasma atomic emission spectrometry. This method has been applied successfully to achieve 95% recovery of zirconium from zircon concentrate.

Jan 1, 2010

By A. J. Stewart, M. Guay, J. W. Critchfield, A. P. Hoddeson

The MetroWest Water Supply Tunnel project includes three main work shafts, excavated primarily in rock. Shaft L is 9.8 m (32 ft) diameter and 124.1 m (407 ft)deep. Shaft E is 7.0 by 12.8 m (23 by 42 ft) and 91.4 m (300 ft) deep. Shaft 5A is 7.9m (26 ft) diameter and 72.5 m (238 ft) deep. Construction methods are compared and contrasted. Lessons learned involve a differing site condition in soil overburden, contractor-proposed modifications, and remedial slurry wall work. Other aspects discussed include noise and vibration control, groundwater inflow, water treatment, muck handling and contract administration issues.

Jan 1, 1999

By Jacob L. Mathis, Todd Tharpe, Jonathan Steflik, R. M. True

In June 2022, Louisville MSD completed a 6.5 km (4-mile), 6.1 m (20-foot) finisheddiameter CSO conveyance and storage tunnel system located along the Ohio River in downtown Louisville, Kentucky. During construction, the Ohio River Tunnel alignment was expanded 2.4 km (1.5 miles) into areas where natural gas was detected. Without delaying construction, the project team developed and implemented a natural gas risk mitigation strategy to safely excavate the tunnel via TBM and install concrete lining. The risk mitigation strategy included the installation of gas-vent borings, increased tunnel ventilation, retrofitting tunneling equipment for “gassy” operations, and modifying the project specific HASP.

Jun 13, 2023

By Duah Philip, Awuah-Offei Kwame

Regulatory pressure to mitigate the cement industry’s environmental impact has intensified recently, spurring innovation in low-carbon cement technologies. In the United States, cement production, consumption, and carbon emissions are accelerating. Despite this trend, the adoption of environmentally friendly dry clinker production technology with combined preheater-precalciner systems has surged from 53.3% in 2002 to 88.5% in 2019. Concurrently, reliance on wet technologies, known for their higher environmental impact, has dropped from 16.5% to 0.6% within the same period. This paper presents the results of our comprehensive study, utilizing over 100 years of industry data, to analyze these technological shifts and their environmental implications.

Feb 1, 2025

By J. L. Huiatt, D. G. Foot, J. D. McKay

The US Bureau of Mines compared column flotation using either fine or coarse bubbles with conventional flotation on a Montana chromite ore. On deslimed ore, fine-bubble column flotation produced a &.7% Cr2O3-grade rougher concentrate with 87% recovery, compared with 43.8% and 43.5% Cr2O3-grade rougher concentrates with 85% and 77% recovery for coarse-bubble column flotation and conventional flotation, respectively. On undeslimed ore, coarse- and fine-bubble column flotation produced rougher concentrates containing approximately 41.5% Cr2O3 with 95% recovery, exceeding conventional flotation, which produced 35.6% Cr2O3 -grade concentrates with 87% recovery.

Jan 1, 1987

By Eric Ohl

Due to the world's ever increasing minerals and energy demands, process plants have to cope economically with ever growing throughput rates. This trend has accelerated the development of high capacity vibrating screens. Screens with screening areas of 30 to 50 square meter (322 to 540 square feet) and width of 5.5 meter (18') are technically possible and are being used presently with great success. This paper will concern itself with the general aspects of large screen design, by using modern technology and the latest findings with regards to fatigue strengths relative to the laws of vibration. It also will investigate the technical and economical limits of such designs.

Jan 1, 1983

By Paul Gribbon, Greg Colzani, Jim McDonald

The $300 million West Side Combined Sewer Over?ow Project consists of over5.5 kilometers of soft ground tunnel, an 833-million liter per day (220-MGD) deep shaft pump station, 3 kilometers of micro tunneling, and other miscellaneous shafts and pipelines. The construction contract, underway since September 2002, is a reimbursable cost plus fixed fee contract that included a quali?cations-based contractor procurement process and has undergone some modi?cation since execution. This paper will describe the contractual issues addressed to date, dispute resolution, where improvements can be made, and how an Owner can evaluate whether this type of contract is the best approach for an underground project.

Jan 1, 2005

By Robert J. Guardia, James Rustvold, Robert A. Robinson, Christopher A. Robertson

In 1999, the Bonneville Power Administration (BPA) replaced approximately 730 m(2,400 ft) of damaged 42- and 36-inch concrete pipe by microtunneling Permalock pipe through sand and partly below groundwater. Microtunneling saved $3.5 to $5 million from the estimated cost of a shored excavation and avoided a railroad and contaminated valley fill. A slurry microtunnel boring machine (MTBM) was used for two segments where groundwater was present and a wheel excavator MTBM was used for one segment where groundwater was not present. This paper describes design and construction of this project that was completed within 2% of the bid and engineer’s estimate.

Jan 1, 2001

By Marian W. Otrebski, Julian A. Korneck

Long distance, overland conveyors require significant capital outlay of which up to 70% may be contributed to the cost of belting. Significant savings may be achieved by identifying possible risk areas and applying modern technology methods to reduce or eliminate risk. Recently, Sasol Coal commissioned an overland belt conveyor system comprising three belt conveyors of 7 km, 5 km and 4.5 km in length. These were designed and constructed taking the above into consideration. Contained in the paper are the belt conveyor system requirements, designing assumptions and methods applied in the designing process as well as ways and means to eliminate or at least reduce risks.

Jan 1, 1998

By T. Gouri Charan, G. V. Rao

A spherical agglomeration process for the separation of scheelite fines of less than 30 µm in very low concentration of 0.04% WO3 in a binary mixture with quartz fines of less than 30 pm has been described. A concentrate containing 14% WO, with more than 90% recoveries could be achieved by means of anionic sodium sulfo succinate collector at pH 3.5 and also with commonly used anionic sodium oleate at pH 10.5 as per the conceptual flowsheet suggested. Such a process is envisaged as commercial potential for the recovery of fine-grained scheelite present in the tailings of gold plants as found in India.

Jan 1, 1991

By S. P. Girrens

A coupled finite element geomechanical- hydrology code is currently under development for application to the problem of predicting groundwater disturbances associated with mine subsidence. The structural-fluid coupling is addressed by calculating the subsided mine geometry, with emphasis placed on determining the strata disturbance and locating damaged regions, for input into a hydrology code, which determines localized volume flow rates and aquifer fluctuations. Benefits from coupling will be best realized when field measurements, an additional aspect of the study concurrent with analytical investigations, indicating the relationship between increasing rock strain and increasing permeability are incorporated into hydraulic material descriptions. Hydrologic and struc- tural calculations are presented to demonstrate computational capabilities applicable to mine subsidence

Jan 1, 1982

By Francis B. Gularte, James E. Monsees, John-Paul Whyte, Gary E. Taylor

In a short section of the Los Angeles Metro Rail system approximately 222.5 m (730 ft) of 6.4 m (21 ft) diameter twin-tube tunnels separated by a 1.8 m (6 ft) narrow pillar were designed to pass under a major eight lane freeway and a metropolitan intersection with only 3.7 m (12 ft) to 5.8 m (19 ft) of loose fill and alluvium cover. The design considerations and the chemical grouting program used to stabilize the alluvial materials is discussed. Also included is a discussion of the novel shield used for tunnel excavation and the effects of the subsequent fire.

Jan 1, 1991

By S. A. Kupferman

Cement raw materials used in southern California and Arizona cement plants occur in a wide variety of geologic environments. Limestone, the primary material making up 75-80% of the raw materials mix used in cement manufacture, is mined solely from Paleozoic Era deposits. During this time, 570-245 million years ago, vastly more limestone was formed in California and Arizona than at any other time (continent was in southern latitudes). The general geology of each limestone deposit associated with the eight southern California and two Arizona cement plants will be reviewed. Many of these deposits are geologically complex, having been subjected to Mesozoic deformation, metamorphism and instrusive events, along with Cenozoic uplift and deformation. All of the cement plants in this region require the use of secondary additives in order to meet the chemical requirements for cement. The kinds of additives vary greatly, depending upon the chemistry of the limestone deposit, cement specifications, and the cement manufacturing process. In some cases, clay deposits with suitable chemistry on or near the limestone sources are utilized. Where alkali limitations or need for alumina-rich materials exist, then specialty clay deposits are used. Iron-rich sources in the region include iron ore deposits and slag or mill scale from local steel mills. The geologic setting and location of these additives, along with gypsum and silica-rich deposits presently in use, will be mentioned.

Jan 1, 1987